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Synthesis and structure of aqua-2',2'''-(2,6-pyridindiyldiethylidene) dioxamohydrazide-copper(II) hydrate
dc.creator | Anđelković, Katarina K. | |
dc.creator | Ivanović, I. | |
dc.creator | Niketic, SR | |
dc.creator | Prelesnik, B | |
dc.creator | Leovac, Vukadin M. | |
dc.date.accessioned | 2018-11-22T00:01:56Z | |
dc.date.available | 2018-11-22T00:01:56Z | |
dc.date.issued | 1997 | |
dc.identifier.issn | 0277-5387 | |
dc.identifier.uri | https://cherry.chem.bg.ac.rs/handle/123456789/2601 | |
dc.description.abstract | In a template synthesis from copper(II) acetate, 2,6-diacetylpyridine, and semioxamazide (NH2CO CONHNH2), two new copper(II) complexes, [Cu(dapsox)(H2O)]. H2O and [Cu(Hdapsox)(H2O)]ClO4, (where H(2)dapsox = 2',2'''-(2,6-pyridindiyldiethylidene)dioxamohydrazide) were obtained and characterized. The structure of the former complex was determined by a single-crystal X-ray analysis. Cu-II is located in a square pyramidal environment. The polydentate ligand, dapsox(2-), is coordinated in dianionic form, as an unsymmetrical quadridentate planar system forming one six-membered and two five-membered metal-chelate rings. The fifth coordination site is occupied by a water molecule. (C) 1997 Elsevier Science Ltd. | en |
dc.publisher | Pergamon-Elsevier Science Ltd, Oxford | |
dc.rights | restrictedAccess | |
dc.source | Polyhedron | |
dc.subject | copper(II) complexes | en |
dc.subject | 2,6-diacetylpyridine derivative | en |
dc.subject | crystal structure | en |
dc.subject | square-pyramidal geometry | en |
dc.subject | IR spectra | en |
dc.title | Synthesis and structure of aqua-2',2'''-(2,6-pyridindiyldiethylidene) dioxamohydrazide-copper(II) hydrate | en |
dc.type | article | |
dc.rights.license | ARR | |
dcterms.abstract | Ивановиц, И; Прелесник, Б; Aнђелковић, Катарина; Леовац, ВМ; Никетиц, СР; | |
dc.citation.volume | 16 | |
dc.citation.issue | 24 | |
dc.citation.spage | 4221 | |
dc.citation.epage | 4228 | |
dc.identifier.wos | A1997YH12700006 | |
dc.identifier.doi | 10.1016/S0277-5387(97)00265-9 | |
dc.citation.other | 16(24): 4221-4228 | |
dc.type.version | publishedVersion | en |
dc.identifier.scopus | 2-s2.0-0001380606 |
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