Synthesis, characterization, DFT calculations and antimicrobial activity of Cd(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent
Authors
Romanović, MimaČobeljić, Božidar
Pevec, Andrej
Turel, Iztok
Grubišić, Sonja
Radanović, Dušanka D.
Anđelković, Katarina K.
Milenković, Marina
Milenković, Milica R.
Article (Accepted Version)
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The chloro (1) and isocyanato (2) Cd(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and trimethylammonium acetohydrazide chloride (Girard's T reagent) (HLCl) have been synthesized and characterized by elemental analysis, IR, and NMR spectroscopy. The crystal structure of chloro Cd(II) complex (1) was determined. In 1 and 2, coordination surrounding of Cd(II) consists of deprotonated hydrazone ligand coordinated through NNO-donor atoms and two monodentates at the rest of the coordination places. Quantum chemical calculations of the molecular structures and the relative stabilities of linkage isomers of the Cd(II) complex showed that the isomer with N-Cd-N coordination of OCN- is the most stable. The investigated Cd(II) complexes showed lower activity than standard antimicrobial drugs. [GRAPHICS] .
Source:
Journal of Coordination Chemistry, 2017, 70, 21, 3702-3714Publisher:
- Taylor & Francis Ltd, Abingdon
Funding / projects:
- Interactions of natural products, their derivatives and coordination compounds with proteins and nucleic acids (RS-MESTD-Basic Research (BR or ON)-172055)
- [COST-STSM-CM1305-37566]
- COST Action [CM1305]
- Slovenian Research Agency [P1-0175]
Note:
- This is the peer-reviewed version of the following article: Romanović, M. C.; Čobeljić, B.; Pevec, A.; Turel, I.; Grubišić, S.; Radanović, D. D.; Anđelković, K. K.; Milenković, M.; Milenković, M. R. Synthesis, Characterization, DFT Calculations and Antimicrobial Activity of Cd(II) Complexes with the Condensation Product of 2-Quinolinecarboxaldehyde and Girard’s T Reagent. Journal of Coordination Chemistry 2017, 70 (21), 3702–3714. https://doi.org/10.1080/00958972.2017.1405262
DOI: 10.1080/00958972.2017.1405262
ISSN: 0095-8972
WoS: 000418940000010
Scopus: 2-s2.0-85034657439
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Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Romanović, Mima AU - Čobeljić, Božidar AU - Pevec, Andrej AU - Turel, Iztok AU - Grubišić, Sonja AU - Radanović, Dušanka D. AU - Anđelković, Katarina K. AU - Milenković, Marina AU - Milenković, Milica R. PY - 2017 UR - https://cherry.chem.bg.ac.rs/handle/123456789/3000 AB - The chloro (1) and isocyanato (2) Cd(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and trimethylammonium acetohydrazide chloride (Girard's T reagent) (HLCl) have been synthesized and characterized by elemental analysis, IR, and NMR spectroscopy. The crystal structure of chloro Cd(II) complex (1) was determined. In 1 and 2, coordination surrounding of Cd(II) consists of deprotonated hydrazone ligand coordinated through NNO-donor atoms and two monodentates at the rest of the coordination places. Quantum chemical calculations of the molecular structures and the relative stabilities of linkage isomers of the Cd(II) complex showed that the isomer with N-Cd-N coordination of OCN- is the most stable. The investigated Cd(II) complexes showed lower activity than standard antimicrobial drugs. [GRAPHICS] . PB - Taylor & Francis Ltd, Abingdon T2 - Journal of Coordination Chemistry T1 - Synthesis, characterization, DFT calculations and antimicrobial activity of Cd(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent VL - 70 IS - 21 SP - 3702 EP - 3714 DO - 10.1080/00958972.2017.1405262 ER -
@article{ author = "Romanović, Mima and Čobeljić, Božidar and Pevec, Andrej and Turel, Iztok and Grubišić, Sonja and Radanović, Dušanka D. and Anđelković, Katarina K. and Milenković, Marina and Milenković, Milica R.", year = "2017", abstract = "The chloro (1) and isocyanato (2) Cd(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and trimethylammonium acetohydrazide chloride (Girard's T reagent) (HLCl) have been synthesized and characterized by elemental analysis, IR, and NMR spectroscopy. The crystal structure of chloro Cd(II) complex (1) was determined. In 1 and 2, coordination surrounding of Cd(II) consists of deprotonated hydrazone ligand coordinated through NNO-donor atoms and two monodentates at the rest of the coordination places. Quantum chemical calculations of the molecular structures and the relative stabilities of linkage isomers of the Cd(II) complex showed that the isomer with N-Cd-N coordination of OCN- is the most stable. The investigated Cd(II) complexes showed lower activity than standard antimicrobial drugs. [GRAPHICS] .", publisher = "Taylor & Francis Ltd, Abingdon", journal = "Journal of Coordination Chemistry", title = "Synthesis, characterization, DFT calculations and antimicrobial activity of Cd(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent", volume = "70", number = "21", pages = "3702-3714", doi = "10.1080/00958972.2017.1405262" }
Romanović, M., Čobeljić, B., Pevec, A., Turel, I., Grubišić, S., Radanović, D. D., Anđelković, K. K., Milenković, M.,& Milenković, M. R.. (2017). Synthesis, characterization, DFT calculations and antimicrobial activity of Cd(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent. in Journal of Coordination Chemistry Taylor & Francis Ltd, Abingdon., 70(21), 3702-3714. https://doi.org/10.1080/00958972.2017.1405262
Romanović M, Čobeljić B, Pevec A, Turel I, Grubišić S, Radanović DD, Anđelković KK, Milenković M, Milenković MR. Synthesis, characterization, DFT calculations and antimicrobial activity of Cd(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent. in Journal of Coordination Chemistry. 2017;70(21):3702-3714. doi:10.1080/00958972.2017.1405262 .
Romanović, Mima, Čobeljić, Božidar, Pevec, Andrej, Turel, Iztok, Grubišić, Sonja, Radanović, Dušanka D., Anđelković, Katarina K., Milenković, Marina, Milenković, Milica R., "Synthesis, characterization, DFT calculations and antimicrobial activity of Cd(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent" in Journal of Coordination Chemistry, 70, no. 21 (2017):3702-3714, https://doi.org/10.1080/00958972.2017.1405262 . .