Prediction of the reactive intermediates in alkane activation by tris(pyrazolyl borate)rhodium carbonyl
Само за регистроване кориснике
1998
Чланак у часопису (Објављена верзија)
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Приказ свих података о документуАпстракт
Two intermediates are observed in the time-resolved IR spectra of the photoinitiated alkane (RH) activation reaction of Tp*Rh(CO)(2) (Tp* = HB-(3,5-dimethylpyrazolyl). Density functional calculations suggest that the first observed intermediate is (eta(3)-Tp*)Rh(CO)...(RH) (RH weakly bound), which subsequently rearranges to (eta(2)-Tp*)Rh(CO)(RH) (RH strongly bound) before undergoing oxidative addition to the product (eta(3)-Tp*)-Rh(CO)(R)(H).
Извор:
Journal of Physical Chemistry. Part A: Molecules, Spectroscopy, Kinetics, Environment and General Th, 1998, 102, 11, 1963-1964Издавач:
- Amer Chemical Soc, Washington
DOI: 10.1021/jp971713f
ISSN: 1089-5639
WoS: 000072622400011
Scopus: 2-s2.0-0001269224
Колекције
Институција/група
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Zarić, Snežana D. AU - Hall, Michael B. PY - 1998 UR - https://cherry.chem.bg.ac.rs/handle/123456789/368 AB - Two intermediates are observed in the time-resolved IR spectra of the photoinitiated alkane (RH) activation reaction of Tp*Rh(CO)(2) (Tp* = HB-(3,5-dimethylpyrazolyl). Density functional calculations suggest that the first observed intermediate is (eta(3)-Tp*)Rh(CO)...(RH) (RH weakly bound), which subsequently rearranges to (eta(2)-Tp*)Rh(CO)(RH) (RH strongly bound) before undergoing oxidative addition to the product (eta(3)-Tp*)-Rh(CO)(R)(H). PB - Amer Chemical Soc, Washington T2 - Journal of Physical Chemistry. Part A: Molecules, Spectroscopy, Kinetics, Environment and General Th T1 - Prediction of the reactive intermediates in alkane activation by tris(pyrazolyl borate)rhodium carbonyl VL - 102 IS - 11 SP - 1963 EP - 1964 DO - 10.1021/jp971713f ER -
@article{ author = "Zarić, Snežana D. and Hall, Michael B.", year = "1998", abstract = "Two intermediates are observed in the time-resolved IR spectra of the photoinitiated alkane (RH) activation reaction of Tp*Rh(CO)(2) (Tp* = HB-(3,5-dimethylpyrazolyl). Density functional calculations suggest that the first observed intermediate is (eta(3)-Tp*)Rh(CO)...(RH) (RH weakly bound), which subsequently rearranges to (eta(2)-Tp*)Rh(CO)(RH) (RH strongly bound) before undergoing oxidative addition to the product (eta(3)-Tp*)-Rh(CO)(R)(H).", publisher = "Amer Chemical Soc, Washington", journal = "Journal of Physical Chemistry. Part A: Molecules, Spectroscopy, Kinetics, Environment and General Th", title = "Prediction of the reactive intermediates in alkane activation by tris(pyrazolyl borate)rhodium carbonyl", volume = "102", number = "11", pages = "1963-1964", doi = "10.1021/jp971713f" }
Zarić, S. D.,& Hall, M. B.. (1998). Prediction of the reactive intermediates in alkane activation by tris(pyrazolyl borate)rhodium carbonyl. in Journal of Physical Chemistry. Part A: Molecules, Spectroscopy, Kinetics, Environment and General Th Amer Chemical Soc, Washington., 102(11), 1963-1964. https://doi.org/10.1021/jp971713f
Zarić SD, Hall MB. Prediction of the reactive intermediates in alkane activation by tris(pyrazolyl borate)rhodium carbonyl. in Journal of Physical Chemistry. Part A: Molecules, Spectroscopy, Kinetics, Environment and General Th. 1998;102(11):1963-1964. doi:10.1021/jp971713f .
Zarić, Snežana D., Hall, Michael B., "Prediction of the reactive intermediates in alkane activation by tris(pyrazolyl borate)rhodium carbonyl" in Journal of Physical Chemistry. Part A: Molecules, Spectroscopy, Kinetics, Environment and General Th, 102, no. 11 (1998):1963-1964, https://doi.org/10.1021/jp971713f . .