Stacking interactions of the methylated cyclopentadienyl ligands in the crystal structures of transition metal complexes
Само за регистроване кориснике
2020
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
In the crystal structures of methylated cyclopentadienyl (Cp) complexes (MeCp, Me4Cp and Me5Cp) deposited in the Cambridge Structural Database, certain orientation types of stacked contacts can be noted as the most frequent. These orientation preferences can be well explained by the matching of oppositely charged regions of electrostatic potential. Parallel displaced stacking, large offset stacking and C - H⋯π interactions are the dominant interaction types that are responsible for the arrangement in the crystal structures of stacked methylated Cp complexes.
Кључне речи:
C - H⋯π interactions / cyclopentadienyl (Cp) complexes / stacking interactionsИзвор:
Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials, 2020, 76, 2, 252-258Издавач:
- International Union of Crystallography
Финансирање / пројекти:
- Нековалентне интеракције pi-система и њихова улога у молекулском препознавању (RS-MESTD-Basic Research (BR or ON)-172065)
DOI: 10.1107/S2052520620002206
ISSN: 2052-5206
WoS: 000525346200010
Scopus: 2-s2.0-85083085574
Институција/група
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Malenov, Dušan P. AU - Blagojević Filipović, Jelena P. AU - Zarić, Snežana D. PY - 2020 UR - https://cherry.chem.bg.ac.rs/handle/123456789/4029 AB - In the crystal structures of methylated cyclopentadienyl (Cp) complexes (MeCp, Me4Cp and Me5Cp) deposited in the Cambridge Structural Database, certain orientation types of stacked contacts can be noted as the most frequent. These orientation preferences can be well explained by the matching of oppositely charged regions of electrostatic potential. Parallel displaced stacking, large offset stacking and C - H⋯π interactions are the dominant interaction types that are responsible for the arrangement in the crystal structures of stacked methylated Cp complexes. PB - International Union of Crystallography T2 - Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials T1 - Stacking interactions of the methylated cyclopentadienyl ligands in the crystal structures of transition metal complexes VL - 76 IS - 2 SP - 252 EP - 258 DO - 10.1107/S2052520620002206 ER -
@article{ author = "Malenov, Dušan P. and Blagojević Filipović, Jelena P. and Zarić, Snežana D.", year = "2020", abstract = "In the crystal structures of methylated cyclopentadienyl (Cp) complexes (MeCp, Me4Cp and Me5Cp) deposited in the Cambridge Structural Database, certain orientation types of stacked contacts can be noted as the most frequent. These orientation preferences can be well explained by the matching of oppositely charged regions of electrostatic potential. Parallel displaced stacking, large offset stacking and C - H⋯π interactions are the dominant interaction types that are responsible for the arrangement in the crystal structures of stacked methylated Cp complexes.", publisher = "International Union of Crystallography", journal = "Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials", title = "Stacking interactions of the methylated cyclopentadienyl ligands in the crystal structures of transition metal complexes", volume = "76", number = "2", pages = "252-258", doi = "10.1107/S2052520620002206" }
Malenov, D. P., Blagojević Filipović, J. P.,& Zarić, S. D.. (2020). Stacking interactions of the methylated cyclopentadienyl ligands in the crystal structures of transition metal complexes. in Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials International Union of Crystallography., 76(2), 252-258. https://doi.org/10.1107/S2052520620002206
Malenov DP, Blagojević Filipović JP, Zarić SD. Stacking interactions of the methylated cyclopentadienyl ligands in the crystal structures of transition metal complexes. in Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials. 2020;76(2):252-258. doi:10.1107/S2052520620002206 .
Malenov, Dušan P., Blagojević Filipović, Jelena P., Zarić, Snežana D., "Stacking interactions of the methylated cyclopentadienyl ligands in the crystal structures of transition metal complexes" in Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials, 76, no. 2 (2020):252-258, https://doi.org/10.1107/S2052520620002206 . .