Synthesis and characterization of uns-cis-(1,3-propane-diamine-N,N '-diacetato)cobalt(III) complexes with symmetrical beta-diketonato ligands
Abstract
The mixed uns-cis(beta-diketonato)(1,3-propanediamine-N,N'-diacetato)cobalt(III) complexes (beta-diketonato ligands = 2,4-pentanedione, 1,3-diphenyl-1,3-propanedione and 2,2,6,6-tetramethyl-3,5-heptanedione) were prepared by the reaction of sodium uns-cis-(1,3-propanediamine-N,N'-diacetato)(carbonato)cobaltate(III) and the corresponding symmetrical beta-diketone at 75 degrees C. The complexes were isolated chromatographically and characterized by elemental analysis, infrared and electron absorption spectroscopy.
Keywords:
synthesis / cobalt(III) complexes / 1,3-propanediamine-N,N '-diacetic acid / beta-diketonatesSource:
Journal of the Serbian Chemical Society, 1999, 64, 1, 31-37Publisher:
- Serbian Chemical Soc, Belgrade
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Institution/Community
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Trifunović, Srećko R. AU - Vuckovic, N AU - Grujic, SA AU - Tešić, Živoslav Lj. AU - Sabo, Tibor PY - 1999 UR - https://cherry.chem.bg.ac.rs/handle/123456789/406 AB - The mixed uns-cis(beta-diketonato)(1,3-propanediamine-N,N'-diacetato)cobalt(III) complexes (beta-diketonato ligands = 2,4-pentanedione, 1,3-diphenyl-1,3-propanedione and 2,2,6,6-tetramethyl-3,5-heptanedione) were prepared by the reaction of sodium uns-cis-(1,3-propanediamine-N,N'-diacetato)(carbonato)cobaltate(III) and the corresponding symmetrical beta-diketone at 75 degrees C. The complexes were isolated chromatographically and characterized by elemental analysis, infrared and electron absorption spectroscopy. PB - Serbian Chemical Soc, Belgrade T2 - Journal of the Serbian Chemical Society T1 - Synthesis and characterization of uns-cis-(1,3-propane-diamine-N,N '-diacetato)cobalt(III) complexes with symmetrical beta-diketonato ligands VL - 64 IS - 1 SP - 31 EP - 37 UR - https://hdl.handle.net/21.15107/rcub_cherry_406 ER -
@article{ author = "Trifunović, Srećko R. and Vuckovic, N and Grujic, SA and Tešić, Živoslav Lj. and Sabo, Tibor", year = "1999", abstract = "The mixed uns-cis(beta-diketonato)(1,3-propanediamine-N,N'-diacetato)cobalt(III) complexes (beta-diketonato ligands = 2,4-pentanedione, 1,3-diphenyl-1,3-propanedione and 2,2,6,6-tetramethyl-3,5-heptanedione) were prepared by the reaction of sodium uns-cis-(1,3-propanediamine-N,N'-diacetato)(carbonato)cobaltate(III) and the corresponding symmetrical beta-diketone at 75 degrees C. The complexes were isolated chromatographically and characterized by elemental analysis, infrared and electron absorption spectroscopy.", publisher = "Serbian Chemical Soc, Belgrade", journal = "Journal of the Serbian Chemical Society", title = "Synthesis and characterization of uns-cis-(1,3-propane-diamine-N,N '-diacetato)cobalt(III) complexes with symmetrical beta-diketonato ligands", volume = "64", number = "1", pages = "31-37", url = "https://hdl.handle.net/21.15107/rcub_cherry_406" }
Trifunović, S. R., Vuckovic, N., Grujic, S., Tešić, Ž. Lj.,& Sabo, T.. (1999). Synthesis and characterization of uns-cis-(1,3-propane-diamine-N,N '-diacetato)cobalt(III) complexes with symmetrical beta-diketonato ligands. in Journal of the Serbian Chemical Society Serbian Chemical Soc, Belgrade., 64(1), 31-37. https://hdl.handle.net/21.15107/rcub_cherry_406
Trifunović SR, Vuckovic N, Grujic S, Tešić ŽL, Sabo T. Synthesis and characterization of uns-cis-(1,3-propane-diamine-N,N '-diacetato)cobalt(III) complexes with symmetrical beta-diketonato ligands. in Journal of the Serbian Chemical Society. 1999;64(1):31-37. https://hdl.handle.net/21.15107/rcub_cherry_406 .
Trifunović, Srećko R., Vuckovic, N, Grujic, SA, Tešić, Živoslav Lj., Sabo, Tibor, "Synthesis and characterization of uns-cis-(1,3-propane-diamine-N,N '-diacetato)cobalt(III) complexes with symmetrical beta-diketonato ligands" in Journal of the Serbian Chemical Society, 64, no. 1 (1999):31-37, https://hdl.handle.net/21.15107/rcub_cherry_406 .