Kinetic and thermodynamic studies of facial and meridional uns-cis-[Co(eddp)gly] complexes
Apstrakt
Thermal properties of facial and meridional uns-cis-[Co(eddp)gly]. 0.5H(2)O complexes were investigated by means of DSC and TG techniques. It was shown that the processes of thermal decomposition of these complexes are multi-step degradation processes, which can also be well separated into individual steps, depending on the molecular symmetry. Thus, the process of thermal degradation of the meridional isomer of the above complex consists of 4 well-separated steps in the temperature interval from 100 to 500 degrees C. The corresponding kinetic and thermodynamic parameters of this process were determined, and a possible mechanism is discussed.
Ključne reči:
facial and meridional Co(III) complexes / kinetics / thermodynamicsIzvor:
Journal of Thermal Analysis and Calorimetry, 2000, 59, 3, 807-814Izdavač:
- Springer, Dordrecht
DOI: 10.1023/A:1010157821694
ISSN: 1388-6150
WoS: 000086006400022
Scopus: 2-s2.0-0033748798
Kolekcije
Institucija/grupa
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Petranovic, N AU - Minić, Dragica M. AU - Sabo, Tibor AU - Dokovic, D PY - 2000 UR - https://cherry.chem.bg.ac.rs/handle/123456789/430 AB - Thermal properties of facial and meridional uns-cis-[Co(eddp)gly]. 0.5H(2)O complexes were investigated by means of DSC and TG techniques. It was shown that the processes of thermal decomposition of these complexes are multi-step degradation processes, which can also be well separated into individual steps, depending on the molecular symmetry. Thus, the process of thermal degradation of the meridional isomer of the above complex consists of 4 well-separated steps in the temperature interval from 100 to 500 degrees C. The corresponding kinetic and thermodynamic parameters of this process were determined, and a possible mechanism is discussed. PB - Springer, Dordrecht T2 - Journal of Thermal Analysis and Calorimetry T1 - Kinetic and thermodynamic studies of facial and meridional uns-cis-[Co(eddp)gly] complexes VL - 59 IS - 3 SP - 807 EP - 814 DO - 10.1023/A:1010157821694 ER -
@article{ author = "Petranovic, N and Minić, Dragica M. and Sabo, Tibor and Dokovic, D", year = "2000", abstract = "Thermal properties of facial and meridional uns-cis-[Co(eddp)gly]. 0.5H(2)O complexes were investigated by means of DSC and TG techniques. It was shown that the processes of thermal decomposition of these complexes are multi-step degradation processes, which can also be well separated into individual steps, depending on the molecular symmetry. Thus, the process of thermal degradation of the meridional isomer of the above complex consists of 4 well-separated steps in the temperature interval from 100 to 500 degrees C. The corresponding kinetic and thermodynamic parameters of this process were determined, and a possible mechanism is discussed.", publisher = "Springer, Dordrecht", journal = "Journal of Thermal Analysis and Calorimetry", title = "Kinetic and thermodynamic studies of facial and meridional uns-cis-[Co(eddp)gly] complexes", volume = "59", number = "3", pages = "807-814", doi = "10.1023/A:1010157821694" }
Petranovic, N., Minić, D. M., Sabo, T.,& Dokovic, D.. (2000). Kinetic and thermodynamic studies of facial and meridional uns-cis-[Co(eddp)gly] complexes. in Journal of Thermal Analysis and Calorimetry Springer, Dordrecht., 59(3), 807-814. https://doi.org/10.1023/A:1010157821694
Petranovic N, Minić DM, Sabo T, Dokovic D. Kinetic and thermodynamic studies of facial and meridional uns-cis-[Co(eddp)gly] complexes. in Journal of Thermal Analysis and Calorimetry. 2000;59(3):807-814. doi:10.1023/A:1010157821694 .
Petranovic, N, Minić, Dragica M., Sabo, Tibor, Dokovic, D, "Kinetic and thermodynamic studies of facial and meridional uns-cis-[Co(eddp)gly] complexes" in Journal of Thermal Analysis and Calorimetry, 59, no. 3 (2000):807-814, https://doi.org/10.1023/A:1010157821694 . .