2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior
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2021
Authors
Ristić, PredragFilipović, Nenad R.
Blagojević, Vladimir A.
Ćirković, Jovana
Barta Holló, Berta
Đokić, Veljko R.
Donnard, Morgan
Gulea, Mihaela
Marjanović, Ivana
Klisurić, Olivera R.
Todorović, Tamara
Article (Published version)
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Show full item recordAbstract
Four silver-based coordination polymers, {[Ag(L1)2]NO3}∞(1), {[Ag(L1)2]ClO4}∞(2), {[Ag(L2)2]NO3·H2O}∞(3) and {[Ag(L2)2]ClO4}∞(4), were synthesized using the thiomorpholine-4-carbonitrile (L1) and piperazine-1,4-dicarbonitrile (L2) ligands. Compounds1and2are two-dimensional, while3and4are three-dimensional. L1 and L2 are 1,4-bis-monodentate ligands in all compounds, while Ag(i) ions are four-coordinated in a slightly distorted tetrahedral geometry. Topological analysis in standard representations suggests that underlying nets in1and2have ansqltopology, while3and4exhibit adiatopology. Thermal analysis shows that3loses crystalline water at room temperature, while other compounds show good thermal stability. All compounds show good photocatalytic activity for photocatalytic degradation of the mordant blue 9 dye, with reaction rates in the range 0.029 to 0.061 min−1. The best result was obtained for compound4, which can be correlated to its largest lattice volume.
Keywords:
metal-organic frameworks / crystal-structure / sonochemical synthesis / catalytic degradationSource:
CrystEngComm, 2021, 23, 27, 4799-4815Publisher:
- Royal Society of Chemistry
Funding / projects:
- Ministry of Science, Technological Development and Innovation of the Republic of Serbia, institutional funding - 200135 (University of Belgrade, Faculty of Technology and Metallurgy) (RS-MESTD-inst-2020-200135)
- Ministry of Science, Technological Development and Innovation of the Republic of Serbia, institutional funding - 200125 (University of Novi Sad, Faculty of Science) (RS-MESTD-inst-2020-200125)
- Ministry of Science, Technological Development and Innovation of the Republic of Serbia, institutional funding - 200175 (Institute of Technical Sciences of SASA, Belgrade) (RS-MESTD-inst-2020-200175)
- Ministry of Science, Technological Development and Innovation of the Republic of Serbia, institutional funding - 200116 (University of Belgrade, Faculty of Agriculture) (RS-MESTD-inst-2020-200116)
- Ministry of Science, Technological Development and Innovation of the Republic of Serbia, institutional funding - 200168 (University of Belgrade, Faculty of Chemistry) (RS-MESTD-inst-2020-200168)
Note:
- Supplementary material: https://cherry.chem.bg.ac.rs/handle/123456789/4832
Related info:
- Referenced by
https://cherry.chem.bg.ac.rs/handle/123456789/4832
DOI: 10.1039/d1ce00394a
ISSN: 1466-8033
WoS: 000664682100001
Scopus: 2-s2.0-85110010702
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Institution/Community
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Ristić, Predrag AU - Filipović, Nenad R. AU - Blagojević, Vladimir A. AU - Ćirković, Jovana AU - Barta Holló, Berta AU - Đokić, Veljko R. AU - Donnard, Morgan AU - Gulea, Mihaela AU - Marjanović, Ivana AU - Klisurić, Olivera R. AU - Todorović, Tamara PY - 2021 UR - http://cherry.chem.bg.ac.rs/handle/123456789/4831 AB - Four silver-based coordination polymers, {[Ag(L1)2]NO3}∞(1), {[Ag(L1)2]ClO4}∞(2), {[Ag(L2)2]NO3·H2O}∞(3) and {[Ag(L2)2]ClO4}∞(4), were synthesized using the thiomorpholine-4-carbonitrile (L1) and piperazine-1,4-dicarbonitrile (L2) ligands. Compounds1and2are two-dimensional, while3and4are three-dimensional. L1 and L2 are 1,4-bis-monodentate ligands in all compounds, while Ag(i) ions are four-coordinated in a slightly distorted tetrahedral geometry. Topological analysis in standard representations suggests that underlying nets in1and2have ansqltopology, while3and4exhibit adiatopology. Thermal analysis shows that3loses crystalline water at room temperature, while other compounds show good thermal stability. All compounds show good photocatalytic activity for photocatalytic degradation of the mordant blue 9 dye, with reaction rates in the range 0.029 to 0.061 min−1. The best result was obtained for compound4, which can be correlated to its largest lattice volume. PB - Royal Society of Chemistry T2 - CrystEngComm T1 - 2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior VL - 23 IS - 27 SP - 4799 EP - 4815 DO - 10.1039/d1ce00394a ER -
@article{ author = "Ristić, Predrag and Filipović, Nenad R. and Blagojević, Vladimir A. and Ćirković, Jovana and Barta Holló, Berta and Đokić, Veljko R. and Donnard, Morgan and Gulea, Mihaela and Marjanović, Ivana and Klisurić, Olivera R. and Todorović, Tamara", year = "2021", abstract = "Four silver-based coordination polymers, {[Ag(L1)2]NO3}∞(1), {[Ag(L1)2]ClO4}∞(2), {[Ag(L2)2]NO3·H2O}∞(3) and {[Ag(L2)2]ClO4}∞(4), were synthesized using the thiomorpholine-4-carbonitrile (L1) and piperazine-1,4-dicarbonitrile (L2) ligands. Compounds1and2are two-dimensional, while3and4are three-dimensional. L1 and L2 are 1,4-bis-monodentate ligands in all compounds, while Ag(i) ions are four-coordinated in a slightly distorted tetrahedral geometry. Topological analysis in standard representations suggests that underlying nets in1and2have ansqltopology, while3and4exhibit adiatopology. Thermal analysis shows that3loses crystalline water at room temperature, while other compounds show good thermal stability. All compounds show good photocatalytic activity for photocatalytic degradation of the mordant blue 9 dye, with reaction rates in the range 0.029 to 0.061 min−1. The best result was obtained for compound4, which can be correlated to its largest lattice volume.", publisher = "Royal Society of Chemistry", journal = "CrystEngComm", title = "2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior", volume = "23", number = "27", pages = "4799-4815", doi = "10.1039/d1ce00394a" }
Ristić, P., Filipović, N. R., Blagojević, V. A., Ćirković, J., Barta Holló, B., Đokić, V. R., Donnard, M., Gulea, M., Marjanović, I., Klisurić, O. R.,& Todorović, T.. (2021). 2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior. in CrystEngComm Royal Society of Chemistry., 23(27), 4799-4815. https://doi.org/10.1039/d1ce00394a
Ristić P, Filipović NR, Blagojević VA, Ćirković J, Barta Holló B, Đokić VR, Donnard M, Gulea M, Marjanović I, Klisurić OR, Todorović T. 2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior. in CrystEngComm. 2021;23(27):4799-4815. doi:10.1039/d1ce00394a .
Ristić, Predrag, Filipović, Nenad R., Blagojević, Vladimir A., Ćirković, Jovana, Barta Holló, Berta, Đokić, Veljko R., Donnard, Morgan, Gulea, Mihaela, Marjanović, Ivana, Klisurić, Olivera R., Todorović, Tamara, "2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior" in CrystEngComm, 23, no. 27 (2021):4799-4815, https://doi.org/10.1039/d1ce00394a . .