Highly exo selective, photochemically promoted cyclization of iodoallene derivatives
Authorized Users Only
2022
Authors
Jovanović, MilošSimić, Milena R.
Petković, Miloš
Tasić, Gordana
Maslak, Veselin
Jovanović, Predrag M.
Savić, Vladimir
Article (Published version)
Metadata
Show full item recordAbstract
A photochemically promoted intramolecular cyclization of aryl-, vinyl-, and alkyliodo allenes has been developed. The optimal conditions employed [Ir(ppy)2(dtbbpy)]PF6 (1 mol%) as catalyst affording products with high exo selectivity in moderate to good yields. Chiral substrates showed diastereoselectivity of up to 95/5 favoring trans product.
Source:
Journal of Heterocyclic Chemistry, 2022, 59, 8, 1435-1440Publisher:
- Wiley
Funding / projects:
DOI: 10.1002/jhet.4472
ISSN: 0022-152X
WoS: 000766376800001
Scopus: 2-s2.0-85125948339
URI
https://onlinelibrary.wiley.com/doi/abs/10.1002/jhet.4472http://cherry.chem.bg.ac.rs/handle/123456789/5204
Collections
Institution/Community
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Jovanović, Miloš AU - Simić, Milena R. AU - Petković, Miloš AU - Tasić, Gordana AU - Maslak, Veselin AU - Jovanović, Predrag M. AU - Savić, Vladimir PY - 2022 UR - https://onlinelibrary.wiley.com/doi/abs/10.1002/jhet.4472 UR - http://cherry.chem.bg.ac.rs/handle/123456789/5204 AB - A photochemically promoted intramolecular cyclization of aryl-, vinyl-, and alkyliodo allenes has been developed. The optimal conditions employed [Ir(ppy)2(dtbbpy)]PF6 (1 mol%) as catalyst affording products with high exo selectivity in moderate to good yields. Chiral substrates showed diastereoselectivity of up to 95/5 favoring trans product. PB - Wiley T2 - Journal of Heterocyclic Chemistry T1 - Highly exo selective, photochemically promoted cyclization of iodoallene derivatives VL - 59 IS - 8 SP - 1435 EP - 1440 DO - 10.1002/jhet.4472 ER -
@article{ author = "Jovanović, Miloš and Simić, Milena R. and Petković, Miloš and Tasić, Gordana and Maslak, Veselin and Jovanović, Predrag M. and Savić, Vladimir", year = "2022", abstract = "A photochemically promoted intramolecular cyclization of aryl-, vinyl-, and alkyliodo allenes has been developed. The optimal conditions employed [Ir(ppy)2(dtbbpy)]PF6 (1 mol%) as catalyst affording products with high exo selectivity in moderate to good yields. Chiral substrates showed diastereoselectivity of up to 95/5 favoring trans product.", publisher = "Wiley", journal = "Journal of Heterocyclic Chemistry", title = "Highly exo selective, photochemically promoted cyclization of iodoallene derivatives", volume = "59", number = "8", pages = "1435-1440", doi = "10.1002/jhet.4472" }
Jovanović, M., Simić, M. R., Petković, M., Tasić, G., Maslak, V., Jovanović, P. M.,& Savić, V.. (2022). Highly exo selective, photochemically promoted cyclization of iodoallene derivatives. in Journal of Heterocyclic Chemistry Wiley., 59(8), 1435-1440. https://doi.org/10.1002/jhet.4472
Jovanović M, Simić MR, Petković M, Tasić G, Maslak V, Jovanović PM, Savić V. Highly exo selective, photochemically promoted cyclization of iodoallene derivatives. in Journal of Heterocyclic Chemistry. 2022;59(8):1435-1440. doi:10.1002/jhet.4472 .
Jovanović, Miloš, Simić, Milena R., Petković, Miloš, Tasić, Gordana, Maslak, Veselin, Jovanović, Predrag M., Savić, Vladimir, "Highly exo selective, photochemically promoted cyclization of iodoallene derivatives" in Journal of Heterocyclic Chemistry, 59, no. 8 (2022):1435-1440, https://doi.org/10.1002/jhet.4472 . .