An Fe(III) complex with the dianionic form of 2,6-diacetylpyridine bis(acylhydrazone). The crystal structure of [diaqua-2 ',2 ''-(2,6-pyridinediyldiethylidyne)dioxamo-hydrazide]iron(III) perchlorate trihydrate, [Fe(dapsox)(H2O)(2)]ClO4 center dot 3H(2)O
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Anđelković, Katarina K.Bacchi, Alessia
Pelizzi, G
Jeremić, Dejan
Ivanović-Burmazović, Ivana
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The title compound was prepared by a template synthesis from 2,6-diacetylpyridine, dioxamohydrazide and Fe(ClO4)(3) . 6H(2)O (mol ratio 1: 2: 1) in MeOH/H2O (3:1) solution and its structure determined by single-crystal X-ray diffraction; triclinic, space group P (1) over bar, a= 7.5186(7), b = 10.9730(9), c = 14.6110(10) Angstrom, alpha = 95.866(1), beta = 100.252(1), gamma = 92.895(1), z = 2. The polydentate ligand is coordinated as a dianionic pentadentate while water molecules occupy apical positions in the structure. This is the first example of a monomeric, pentagonal bipyramidal structure of an Fe(III) complex with a dianionic bis(acylhydrazone) derivative of 2,6-diacetylpyridine.
Keywords:
Fe(III) / bis(acylhydrazone) / X-ray structureSource:
Journal of Coordination Chemistry, 2002, 55, 12, 1385-1392Publisher:
- Taylor & Francis Ltd, Abingdon
DOI: 10.1080/0095897021000058600
ISSN: 0095-8972
WoS: 000180964400003
Scopus: 2-s2.0-0036975358
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Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Anđelković, Katarina K. AU - Bacchi, Alessia AU - Pelizzi, G AU - Jeremić, Dejan AU - Ivanović-Burmazović, Ivana PY - 2002 UR - https://cherry.chem.bg.ac.rs/handle/123456789/539 AB - The title compound was prepared by a template synthesis from 2,6-diacetylpyridine, dioxamohydrazide and Fe(ClO4)(3) . 6H(2)O (mol ratio 1: 2: 1) in MeOH/H2O (3:1) solution and its structure determined by single-crystal X-ray diffraction; triclinic, space group P (1) over bar, a= 7.5186(7), b = 10.9730(9), c = 14.6110(10) Angstrom, alpha = 95.866(1), beta = 100.252(1), gamma = 92.895(1), z = 2. The polydentate ligand is coordinated as a dianionic pentadentate while water molecules occupy apical positions in the structure. This is the first example of a monomeric, pentagonal bipyramidal structure of an Fe(III) complex with a dianionic bis(acylhydrazone) derivative of 2,6-diacetylpyridine. PB - Taylor & Francis Ltd, Abingdon T2 - Journal of Coordination Chemistry T1 - An Fe(III) complex with the dianionic form of 2,6-diacetylpyridine bis(acylhydrazone). The crystal structure of [diaqua-2 ',2 ''-(2,6-pyridinediyldiethylidyne)dioxamo-hydrazide]iron(III) perchlorate trihydrate, [Fe(dapsox)(H2O)(2)]ClO4 center dot 3H(2)O VL - 55 IS - 12 SP - 1385 EP - 1392 DO - 10.1080/0095897021000058600 ER -
@article{ author = "Anđelković, Katarina K. and Bacchi, Alessia and Pelizzi, G and Jeremić, Dejan and Ivanović-Burmazović, Ivana", year = "2002", abstract = "The title compound was prepared by a template synthesis from 2,6-diacetylpyridine, dioxamohydrazide and Fe(ClO4)(3) . 6H(2)O (mol ratio 1: 2: 1) in MeOH/H2O (3:1) solution and its structure determined by single-crystal X-ray diffraction; triclinic, space group P (1) over bar, a= 7.5186(7), b = 10.9730(9), c = 14.6110(10) Angstrom, alpha = 95.866(1), beta = 100.252(1), gamma = 92.895(1), z = 2. The polydentate ligand is coordinated as a dianionic pentadentate while water molecules occupy apical positions in the structure. This is the first example of a monomeric, pentagonal bipyramidal structure of an Fe(III) complex with a dianionic bis(acylhydrazone) derivative of 2,6-diacetylpyridine.", publisher = "Taylor & Francis Ltd, Abingdon", journal = "Journal of Coordination Chemistry", title = "An Fe(III) complex with the dianionic form of 2,6-diacetylpyridine bis(acylhydrazone). The crystal structure of [diaqua-2 ',2 ''-(2,6-pyridinediyldiethylidyne)dioxamo-hydrazide]iron(III) perchlorate trihydrate, [Fe(dapsox)(H2O)(2)]ClO4 center dot 3H(2)O", volume = "55", number = "12", pages = "1385-1392", doi = "10.1080/0095897021000058600" }
Anđelković, K. K., Bacchi, A., Pelizzi, G., Jeremić, D.,& Ivanović-Burmazović, I.. (2002). An Fe(III) complex with the dianionic form of 2,6-diacetylpyridine bis(acylhydrazone). The crystal structure of [diaqua-2 ',2 ''-(2,6-pyridinediyldiethylidyne)dioxamo-hydrazide]iron(III) perchlorate trihydrate, [Fe(dapsox)(H2O)(2)]ClO4 center dot 3H(2)O. in Journal of Coordination Chemistry Taylor & Francis Ltd, Abingdon., 55(12), 1385-1392. https://doi.org/10.1080/0095897021000058600
Anđelković KK, Bacchi A, Pelizzi G, Jeremić D, Ivanović-Burmazović I. An Fe(III) complex with the dianionic form of 2,6-diacetylpyridine bis(acylhydrazone). The crystal structure of [diaqua-2 ',2 ''-(2,6-pyridinediyldiethylidyne)dioxamo-hydrazide]iron(III) perchlorate trihydrate, [Fe(dapsox)(H2O)(2)]ClO4 center dot 3H(2)O. in Journal of Coordination Chemistry. 2002;55(12):1385-1392. doi:10.1080/0095897021000058600 .
Anđelković, Katarina K., Bacchi, Alessia, Pelizzi, G, Jeremić, Dejan, Ivanović-Burmazović, Ivana, "An Fe(III) complex with the dianionic form of 2,6-diacetylpyridine bis(acylhydrazone). The crystal structure of [diaqua-2 ',2 ''-(2,6-pyridinediyldiethylidyne)dioxamo-hydrazide]iron(III) perchlorate trihydrate, [Fe(dapsox)(H2O)(2)]ClO4 center dot 3H(2)O" in Journal of Coordination Chemistry, 55, no. 12 (2002):1385-1392, https://doi.org/10.1080/0095897021000058600 . .