Sulfur retention by ash during coal combustion. Part II. A model of the process
Zadržavanje sumpora u pepelu tokom sagorevanja uglja - deo II - model procesa
Abstract
An overall model for sulfur self-retention in ash during coal particle combustion is developed in this paper. It is assumed that sulfur retention during char combustion occurs due to the reaction between SO2 and CaO in the form of uniformly distributed non-porous grains. Parametric analysis shows that the process of sulfur self-retention is limited by solid difussion through the non-porous product layer formed on the CaO grains and that the most important coal characteristics which influence sulfur self-retention are coal rank. content of sulfur forms. molar Ca/S ratio and particle radius. A comparison with the experimentally obtained values in a FB reactor showed that die model can adequately predict the kinetics of the process, the levels of the obtained values of the SSR efficiencies, as well as the influence of temperature and coal particle size.
U radu je prikazan razvijeni model zadržavanja sumpora u pepelu tokom sagorevanja uglja. Pretpostavka modela je da se zadržavanje sumpora tokom sagorevanja koksnog ostatka odigrava usled reakcije SO2 i CaO koji je u obliku ravnomerno raspoređenih zrna. Parametarska analiza je pokazala da je proces zadržavanja sumpora kontrolisan difuzijom kroz formirani sloj čvrstog produkta na zrnima CaO, kao i da su rang uglja, sadržaj formi sumpora molarni Ca/S odnos i veličina čestice važne osobine uglja koje utiču na proces. Poređenje sa eksperimentalnim rezultatima dobijenim u reaktoru sa fluidizovanim slojem je pokazalo da model može adekvatno da predvidi kinetiku procesa, efikasnost zadržavanja sumpora u pepelu, kao i uticaj temperature i veličine čestice uglja.
Keywords:
coal combustion / sulfur retention by ash / sulfur retention by ash / modelling / modellingSource:
Journal of the Serbian Chemical Society, 2003, 68, 3, 171-182Publisher:
- Serbian Chemical Soc, Belgrade
DOI: 10.2298/JSC0303171M
ISSN: 0352-5139
WoS: 000181865100003
Scopus: 2-s2.0-0037704458
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Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Manovic, V AU - Grubor, B AU - Ilić, Mladen AU - Jovančićević, Branimir PY - 2003 UR - https://cherry.chem.bg.ac.rs/handle/123456789/546 AB - An overall model for sulfur self-retention in ash during coal particle combustion is developed in this paper. It is assumed that sulfur retention during char combustion occurs due to the reaction between SO2 and CaO in the form of uniformly distributed non-porous grains. Parametric analysis shows that the process of sulfur self-retention is limited by solid difussion through the non-porous product layer formed on the CaO grains and that the most important coal characteristics which influence sulfur self-retention are coal rank. content of sulfur forms. molar Ca/S ratio and particle radius. A comparison with the experimentally obtained values in a FB reactor showed that die model can adequately predict the kinetics of the process, the levels of the obtained values of the SSR efficiencies, as well as the influence of temperature and coal particle size. AB - U radu je prikazan razvijeni model zadržavanja sumpora u pepelu tokom sagorevanja uglja. Pretpostavka modela je da se zadržavanje sumpora tokom sagorevanja koksnog ostatka odigrava usled reakcije SO2 i CaO koji je u obliku ravnomerno raspoređenih zrna. Parametarska analiza je pokazala da je proces zadržavanja sumpora kontrolisan difuzijom kroz formirani sloj čvrstog produkta na zrnima CaO, kao i da su rang uglja, sadržaj formi sumpora molarni Ca/S odnos i veličina čestice važne osobine uglja koje utiču na proces. Poređenje sa eksperimentalnim rezultatima dobijenim u reaktoru sa fluidizovanim slojem je pokazalo da model može adekvatno da predvidi kinetiku procesa, efikasnost zadržavanja sumpora u pepelu, kao i uticaj temperature i veličine čestice uglja. PB - Serbian Chemical Soc, Belgrade T2 - Journal of the Serbian Chemical Society T1 - Sulfur retention by ash during coal combustion. Part II. A model of the process T1 - Zadržavanje sumpora u pepelu tokom sagorevanja uglja - deo II - model procesa VL - 68 IS - 3 SP - 171 EP - 182 DO - 10.2298/JSC0303171M ER -
@article{ author = "Manovic, V and Grubor, B and Ilić, Mladen and Jovančićević, Branimir", year = "2003", abstract = "An overall model for sulfur self-retention in ash during coal particle combustion is developed in this paper. It is assumed that sulfur retention during char combustion occurs due to the reaction between SO2 and CaO in the form of uniformly distributed non-porous grains. Parametric analysis shows that the process of sulfur self-retention is limited by solid difussion through the non-porous product layer formed on the CaO grains and that the most important coal characteristics which influence sulfur self-retention are coal rank. content of sulfur forms. molar Ca/S ratio and particle radius. A comparison with the experimentally obtained values in a FB reactor showed that die model can adequately predict the kinetics of the process, the levels of the obtained values of the SSR efficiencies, as well as the influence of temperature and coal particle size., U radu je prikazan razvijeni model zadržavanja sumpora u pepelu tokom sagorevanja uglja. Pretpostavka modela je da se zadržavanje sumpora tokom sagorevanja koksnog ostatka odigrava usled reakcije SO2 i CaO koji je u obliku ravnomerno raspoređenih zrna. Parametarska analiza je pokazala da je proces zadržavanja sumpora kontrolisan difuzijom kroz formirani sloj čvrstog produkta na zrnima CaO, kao i da su rang uglja, sadržaj formi sumpora molarni Ca/S odnos i veličina čestice važne osobine uglja koje utiču na proces. Poređenje sa eksperimentalnim rezultatima dobijenim u reaktoru sa fluidizovanim slojem je pokazalo da model može adekvatno da predvidi kinetiku procesa, efikasnost zadržavanja sumpora u pepelu, kao i uticaj temperature i veličine čestice uglja.", publisher = "Serbian Chemical Soc, Belgrade", journal = "Journal of the Serbian Chemical Society", title = "Sulfur retention by ash during coal combustion. Part II. A model of the process, Zadržavanje sumpora u pepelu tokom sagorevanja uglja - deo II - model procesa", volume = "68", number = "3", pages = "171-182", doi = "10.2298/JSC0303171M" }
Manovic, V., Grubor, B., Ilić, M.,& Jovančićević, B.. (2003). Sulfur retention by ash during coal combustion. Part II. A model of the process. in Journal of the Serbian Chemical Society Serbian Chemical Soc, Belgrade., 68(3), 171-182. https://doi.org/10.2298/JSC0303171M
Manovic V, Grubor B, Ilić M, Jovančićević B. Sulfur retention by ash during coal combustion. Part II. A model of the process. in Journal of the Serbian Chemical Society. 2003;68(3):171-182. doi:10.2298/JSC0303171M .
Manovic, V, Grubor, B, Ilić, Mladen, Jovančićević, Branimir, "Sulfur retention by ash during coal combustion. Part II. A model of the process" in Journal of the Serbian Chemical Society, 68, no. 3 (2003):171-182, https://doi.org/10.2298/JSC0303171M . .