Ethylenediammonium aquabis(malonato)oxovanadate(IV)
Апстракт
In the anion of the title compound, (C2H10N2)[VO(H2O)(C3H2O4)(2)] or H(2)en[VO(mal)(2)H2O], vanadium(IV) is distorted-octahedrally coordinated by six donor O atoms. The two malonate ligands are situated in the equatorial plane, whereas the oxo and the water ligand occupy axial positions. The apical V=O bond exhibits a strong trans influence. The anion possesses crystallographically imposed C-2 symmetry, with the central V atom, the oxo and the water ligand lying on the twofold axis.
Извор:
Acta Crystallographica. Section E: Structure Reports Online, 2003, 59, 7Издавач:
- Blackwell Munksgaard, Copenhagen
DOI: 10.1107/S160053680301417X
ISSN: 1600-5368
WoS: 000183875000061
Scopus: 2-s2.0-18444368732
Колекције
Институција/група
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Kaludjerovic, GN AU - Heinemann, FW AU - Leovac, Vukadin M. AU - Trifunović, Srećko R. AU - Sabo, Tibor PY - 2003 UR - https://cherry.chem.bg.ac.rs/handle/123456789/562 AB - In the anion of the title compound, (C2H10N2)[VO(H2O)(C3H2O4)(2)] or H(2)en[VO(mal)(2)H2O], vanadium(IV) is distorted-octahedrally coordinated by six donor O atoms. The two malonate ligands are situated in the equatorial plane, whereas the oxo and the water ligand occupy axial positions. The apical V=O bond exhibits a strong trans influence. The anion possesses crystallographically imposed C-2 symmetry, with the central V atom, the oxo and the water ligand lying on the twofold axis. PB - Blackwell Munksgaard, Copenhagen T2 - Acta Crystallographica. Section E: Structure Reports Online T1 - Ethylenediammonium aquabis(malonato)oxovanadate(IV) VL - 59 IS - 7 DO - 10.1107/S160053680301417X ER -
@article{ author = "Kaludjerovic, GN and Heinemann, FW and Leovac, Vukadin M. and Trifunović, Srećko R. and Sabo, Tibor", year = "2003", abstract = "In the anion of the title compound, (C2H10N2)[VO(H2O)(C3H2O4)(2)] or H(2)en[VO(mal)(2)H2O], vanadium(IV) is distorted-octahedrally coordinated by six donor O atoms. The two malonate ligands are situated in the equatorial plane, whereas the oxo and the water ligand occupy axial positions. The apical V=O bond exhibits a strong trans influence. The anion possesses crystallographically imposed C-2 symmetry, with the central V atom, the oxo and the water ligand lying on the twofold axis.", publisher = "Blackwell Munksgaard, Copenhagen", journal = "Acta Crystallographica. Section E: Structure Reports Online", title = "Ethylenediammonium aquabis(malonato)oxovanadate(IV)", volume = "59", number = "7", doi = "10.1107/S160053680301417X" }
Kaludjerovic, G., Heinemann, F., Leovac, V. M., Trifunović, S. R.,& Sabo, T.. (2003). Ethylenediammonium aquabis(malonato)oxovanadate(IV). in Acta Crystallographica. Section E: Structure Reports Online Blackwell Munksgaard, Copenhagen., 59(7). https://doi.org/10.1107/S160053680301417X
Kaludjerovic G, Heinemann F, Leovac VM, Trifunović SR, Sabo T. Ethylenediammonium aquabis(malonato)oxovanadate(IV). in Acta Crystallographica. Section E: Structure Reports Online. 2003;59(7). doi:10.1107/S160053680301417X .
Kaludjerovic, GN, Heinemann, FW, Leovac, Vukadin M., Trifunović, Srećko R., Sabo, Tibor, "Ethylenediammonium aquabis(malonato)oxovanadate(IV)" in Acta Crystallographica. Section E: Structure Reports Online, 59, no. 7 (2003), https://doi.org/10.1107/S160053680301417X . .