Low-Valent Cobalt-Catalyzed Deprotection of Allyloxyarenes
Samo za registrovane korisnike
2022
Autori
Kokić, BranislavSelaković, Života
Nikolić, Andrea M.
Andrijević, Ana
Anđelković, Boban D.
Ajdačić, Vladimir
Opsenica, Igor
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
Herein, we report a low-valent cobalt-catalyzed deprotection of allyloxyarenes. The method displays a broad substrate scope and good functional group tolerance, granting its utilization on more complex substrates, including O-allylated derivatives of natural products and drugs. Based on comprehensive experiments, a plausible mechanistic pathway for the low-valent cobalt-catalyzed O-deallylation of allyloxyarenes is proposed.
Ključne reči:
allyloxyarenes / cobalt / deprotection / drugs / natural productsIzvor:
European Journal of Organic Chemistry, 2022, 43, e202201112-Izdavač:
- Wiley
Finansiranje / projekti:
- Ministarstvo nauke, tehnološkog razvoja i inovacija Republike Srbije, institucionalno finansiranje - 200168 (Univerzitet u Beogradu, Hemijski fakultet) (RS-MESTD-inst-2020-200168)
- Ministarstvo nauke, tehnološkog razvoja i inovacija Republike Srbije, institucionalno finansiranje - 200288 (Inovacioni centar Hemijskog fakulteta u Beogradu doo) (RS-MESTD-inst-2020-200288)
- Serbian Academy of Sciences and Arts grant F-80
Napomena:
- Supplementary material: https://cherry.chem.bg.ac.rs/handle/123456789/5706
Povezane informacije:
Institucija/grupa
Inovacioni centar / Innovation CentreTY - JOUR AU - Kokić, Branislav AU - Selaković, Života AU - Nikolić, Andrea M. AU - Andrijević, Ana AU - Anđelković, Boban D. AU - Ajdačić, Vladimir AU - Opsenica, Igor PY - 2022 UR - http://cherry.chem.bg.ac.rs/handle/123456789/5680 AB - Herein, we report a low-valent cobalt-catalyzed deprotection of allyloxyarenes. The method displays a broad substrate scope and good functional group tolerance, granting its utilization on more complex substrates, including O-allylated derivatives of natural products and drugs. Based on comprehensive experiments, a plausible mechanistic pathway for the low-valent cobalt-catalyzed O-deallylation of allyloxyarenes is proposed. PB - Wiley T2 - European Journal of Organic Chemistry T1 - Low-Valent Cobalt-Catalyzed Deprotection of Allyloxyarenes VL - 43 SP - e202201112 DO - 10.1002/ejoc.202201112 ER -
@article{ author = "Kokić, Branislav and Selaković, Života and Nikolić, Andrea M. and Andrijević, Ana and Anđelković, Boban D. and Ajdačić, Vladimir and Opsenica, Igor", year = "2022", abstract = "Herein, we report a low-valent cobalt-catalyzed deprotection of allyloxyarenes. The method displays a broad substrate scope and good functional group tolerance, granting its utilization on more complex substrates, including O-allylated derivatives of natural products and drugs. Based on comprehensive experiments, a plausible mechanistic pathway for the low-valent cobalt-catalyzed O-deallylation of allyloxyarenes is proposed.", publisher = "Wiley", journal = "European Journal of Organic Chemistry", title = "Low-Valent Cobalt-Catalyzed Deprotection of Allyloxyarenes", volume = "43", pages = "e202201112", doi = "10.1002/ejoc.202201112" }
Kokić, B., Selaković, Ž., Nikolić, A. M., Andrijević, A., Anđelković, B. D., Ajdačić, V.,& Opsenica, I.. (2022). Low-Valent Cobalt-Catalyzed Deprotection of Allyloxyarenes. in European Journal of Organic Chemistry Wiley., 43, e202201112. https://doi.org/10.1002/ejoc.202201112
Kokić B, Selaković Ž, Nikolić AM, Andrijević A, Anđelković BD, Ajdačić V, Opsenica I. Low-Valent Cobalt-Catalyzed Deprotection of Allyloxyarenes. in European Journal of Organic Chemistry. 2022;43:e202201112. doi:10.1002/ejoc.202201112 .
Kokić, Branislav, Selaković, Života, Nikolić, Andrea M., Andrijević, Ana, Anđelković, Boban D., Ajdačić, Vladimir, Opsenica, Igor, "Low-Valent Cobalt-Catalyzed Deprotection of Allyloxyarenes" in European Journal of Organic Chemistry, 43 (2022):e202201112, https://doi.org/10.1002/ejoc.202201112 . .