Periodate oxidized horseradish peroxidase@ZIF-8 nanocomposite
Authors
Stanišić, Marija D.Ristić, Predrag
Đokić, Veljko
Balaž, Ana Marija
Prodanović, Radivoje
Todorović, Tamara
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Metal-organic frameworks (MOFs) are a class of materials well-known for their high degree of crystallinity and
ultrahigh porosity. Modular synthesis from organic linkers and metal nodes allows for precise control of structure,
pore size and chemical functionality of MOFs. Recently, MOFs have been explored for their potential to form novel
biocomposites with proteins by a process termed biomimetic mineralization. These novel MOF biocomposites show
great promise for application to industrial biocatalysis where strategies for enhancing enzyme stability are of
significant interest. The protective capacity and applications of biomimetically mineralized biomacromolecule zeolitic
imidazolate framework (ZIF-8) composites are likely dependent on the charge of the biomolecule and the topology
of the mineralized ZIF-8 coating. Herein, we identify conditions to reliably yield the porous periodate oxidized
horseradish peroxidase@ZIF-8 sodalite topology biocomposite in preference to other mo...re dense phases.
Keywords:
ZIF-8 / biomimetic mineralisation / horseradish peroxidase / topologySource:
19th International Conference on Nanosciences & Nanotechnologies, 5-8 July 2022, Thessaloniki, Greece, 2022, 138-138Funding / projects:
- SYMBIOSIS - Controllable Design of Efficient Enzyme"Mof Composites for Biocatalysis (RS-ScienceFundRS-Promis-6066997)
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Hemijski fakultet / Faculty of ChemistryTY - CONF AU - Stanišić, Marija D. AU - Ristić, Predrag AU - Đokić, Veljko AU - Balaž, Ana Marija AU - Prodanović, Radivoje AU - Todorović, Tamara PY - 2022 UR - http://cherry.chem.bg.ac.rs/handle/123456789/5752 AB - Metal-organic frameworks (MOFs) are a class of materials well-known for their high degree of crystallinity and ultrahigh porosity. Modular synthesis from organic linkers and metal nodes allows for precise control of structure, pore size and chemical functionality of MOFs. Recently, MOFs have been explored for their potential to form novel biocomposites with proteins by a process termed biomimetic mineralization. These novel MOF biocomposites show great promise for application to industrial biocatalysis where strategies for enhancing enzyme stability are of significant interest. The protective capacity and applications of biomimetically mineralized biomacromolecule zeolitic imidazolate framework (ZIF-8) composites are likely dependent on the charge of the biomolecule and the topology of the mineralized ZIF-8 coating. Herein, we identify conditions to reliably yield the porous periodate oxidized horseradish peroxidase@ZIF-8 sodalite topology biocomposite in preference to other more dense phases. C3 - 19th International Conference on Nanosciences & Nanotechnologies, 5-8 July 2022, Thessaloniki, Greece T1 - Periodate oxidized horseradish peroxidase@ZIF-8 nanocomposite SP - 138 EP - 138 UR - https://hdl.handle.net/21.15107/rcub_cherry_5752 ER -
@conference{ author = "Stanišić, Marija D. and Ristić, Predrag and Đokić, Veljko and Balaž, Ana Marija and Prodanović, Radivoje and Todorović, Tamara", year = "2022", abstract = "Metal-organic frameworks (MOFs) are a class of materials well-known for their high degree of crystallinity and ultrahigh porosity. Modular synthesis from organic linkers and metal nodes allows for precise control of structure, pore size and chemical functionality of MOFs. Recently, MOFs have been explored for their potential to form novel biocomposites with proteins by a process termed biomimetic mineralization. These novel MOF biocomposites show great promise for application to industrial biocatalysis where strategies for enhancing enzyme stability are of significant interest. The protective capacity and applications of biomimetically mineralized biomacromolecule zeolitic imidazolate framework (ZIF-8) composites are likely dependent on the charge of the biomolecule and the topology of the mineralized ZIF-8 coating. Herein, we identify conditions to reliably yield the porous periodate oxidized horseradish peroxidase@ZIF-8 sodalite topology biocomposite in preference to other more dense phases.", journal = "19th International Conference on Nanosciences & Nanotechnologies, 5-8 July 2022, Thessaloniki, Greece", title = "Periodate oxidized horseradish peroxidase@ZIF-8 nanocomposite", pages = "138-138", url = "https://hdl.handle.net/21.15107/rcub_cherry_5752" }
Stanišić, M. D., Ristić, P., Đokić, V., Balaž, A. M., Prodanović, R.,& Todorović, T.. (2022). Periodate oxidized horseradish peroxidase@ZIF-8 nanocomposite. in 19th International Conference on Nanosciences & Nanotechnologies, 5-8 July 2022, Thessaloniki, Greece, 138-138. https://hdl.handle.net/21.15107/rcub_cherry_5752
Stanišić MD, Ristić P, Đokić V, Balaž AM, Prodanović R, Todorović T. Periodate oxidized horseradish peroxidase@ZIF-8 nanocomposite. in 19th International Conference on Nanosciences & Nanotechnologies, 5-8 July 2022, Thessaloniki, Greece. 2022;:138-138. https://hdl.handle.net/21.15107/rcub_cherry_5752 .
Stanišić, Marija D., Ristić, Predrag, Đokić, Veljko, Balaž, Ana Marija, Prodanović, Radivoje, Todorović, Tamara, "Periodate oxidized horseradish peroxidase@ZIF-8 nanocomposite" in 19th International Conference on Nanosciences & Nanotechnologies, 5-8 July 2022, Thessaloniki, Greece (2022):138-138, https://hdl.handle.net/21.15107/rcub_cherry_5752 .