Crystal Structure of 2-{1-[(1-(2-Pyridinio)ethylidene) hydrazono]ethyl}pyridinium diperchlorate, the Product of Template Condensation in the Presence of Cr(III)
Само за регистроване кориснике
2009
Аутори
Radanović, Dušanka D.Kaluđerović, Goran N.
Gomez-Ruiz, Santiago
Sladić, Dušan
Šumar-Ristović, Maja
Brčeski, Ilija
Anđelković, Katarina K.
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
In an attempt to synthesize a Cr(III) complex of 20-[1-(2-pyridinyl)ethylidene]oxamohydrazide an azine product 2-{1-[(1-(2-pyridinio)ethylidene)hydrazono]ethyl} pyridinium diperchlorate was obtained by an electrophilic acyl substitution catalyzed by Cr(III). Its structure was determined by X-ray crystal analysis and showed significant changes in comparison to the corresponding unprotonated compound. The 2-{1-[(1-(2-pyridinio)ethylidene)hydrazono] ethyl}pyridinium diperchlorate crystallizes in the space group P2(1)/n of the monoclinic crystal system with unit cell parameters a = 14.3809(3) angstrom, b = 24.1516(5) angstrom, c = 15.4471(3) angstrom, beta = 99.930(2)degrees, V = 5284.74(19) angstrom(3) and Z = 12, i.e. three molecules per asymmetric unit.
Кључне речи:
X-ray structure determination / Template synthesis / AzinesИзвор:
Journal of Chemical Crystallography, 2009, 39, 2, 138-142Издавач:
- Springer/Plenum Publishers, New York
Финансирање / пројекти:
- Интеракције природних производа и њихових аналога са протеинима и нуклеинским киселинама (RS-MESTD-MPN2006-2010-142026)
DOI: 10.1007/s10870-008-9443-6
ISSN: 1074-1542
WoS: 000263056300012
Scopus: 2-s2.0-59849119841
Колекције
Институција/група
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Radanović, Dušanka D. AU - Kaluđerović, Goran N. AU - Gomez-Ruiz, Santiago AU - Sladić, Dušan AU - Šumar-Ristović, Maja AU - Brčeski, Ilija AU - Anđelković, Katarina K. PY - 2009 UR - https://cherry.chem.bg.ac.rs/handle/123456789/603 AB - In an attempt to synthesize a Cr(III) complex of 20-[1-(2-pyridinyl)ethylidene]oxamohydrazide an azine product 2-{1-[(1-(2-pyridinio)ethylidene)hydrazono]ethyl} pyridinium diperchlorate was obtained by an electrophilic acyl substitution catalyzed by Cr(III). Its structure was determined by X-ray crystal analysis and showed significant changes in comparison to the corresponding unprotonated compound. The 2-{1-[(1-(2-pyridinio)ethylidene)hydrazono] ethyl}pyridinium diperchlorate crystallizes in the space group P2(1)/n of the monoclinic crystal system with unit cell parameters a = 14.3809(3) angstrom, b = 24.1516(5) angstrom, c = 15.4471(3) angstrom, beta = 99.930(2)degrees, V = 5284.74(19) angstrom(3) and Z = 12, i.e. three molecules per asymmetric unit. PB - Springer/Plenum Publishers, New York T2 - Journal of Chemical Crystallography T1 - Crystal Structure of 2-{1-[(1-(2-Pyridinio)ethylidene) hydrazono]ethyl}pyridinium diperchlorate, the Product of Template Condensation in the Presence of Cr(III) VL - 39 IS - 2 SP - 138 EP - 142 DO - 10.1007/s10870-008-9443-6 ER -
@article{ author = "Radanović, Dušanka D. and Kaluđerović, Goran N. and Gomez-Ruiz, Santiago and Sladić, Dušan and Šumar-Ristović, Maja and Brčeski, Ilija and Anđelković, Katarina K.", year = "2009", abstract = "In an attempt to synthesize a Cr(III) complex of 20-[1-(2-pyridinyl)ethylidene]oxamohydrazide an azine product 2-{1-[(1-(2-pyridinio)ethylidene)hydrazono]ethyl} pyridinium diperchlorate was obtained by an electrophilic acyl substitution catalyzed by Cr(III). Its structure was determined by X-ray crystal analysis and showed significant changes in comparison to the corresponding unprotonated compound. The 2-{1-[(1-(2-pyridinio)ethylidene)hydrazono] ethyl}pyridinium diperchlorate crystallizes in the space group P2(1)/n of the monoclinic crystal system with unit cell parameters a = 14.3809(3) angstrom, b = 24.1516(5) angstrom, c = 15.4471(3) angstrom, beta = 99.930(2)degrees, V = 5284.74(19) angstrom(3) and Z = 12, i.e. three molecules per asymmetric unit.", publisher = "Springer/Plenum Publishers, New York", journal = "Journal of Chemical Crystallography", title = "Crystal Structure of 2-{1-[(1-(2-Pyridinio)ethylidene) hydrazono]ethyl}pyridinium diperchlorate, the Product of Template Condensation in the Presence of Cr(III)", volume = "39", number = "2", pages = "138-142", doi = "10.1007/s10870-008-9443-6" }
Radanović, D. D., Kaluđerović, G. N., Gomez-Ruiz, S., Sladić, D., Šumar-Ristović, M., Brčeski, I.,& Anđelković, K. K.. (2009). Crystal Structure of 2-{1-[(1-(2-Pyridinio)ethylidene) hydrazono]ethyl}pyridinium diperchlorate, the Product of Template Condensation in the Presence of Cr(III). in Journal of Chemical Crystallography Springer/Plenum Publishers, New York., 39(2), 138-142. https://doi.org/10.1007/s10870-008-9443-6
Radanović DD, Kaluđerović GN, Gomez-Ruiz S, Sladić D, Šumar-Ristović M, Brčeski I, Anđelković KK. Crystal Structure of 2-{1-[(1-(2-Pyridinio)ethylidene) hydrazono]ethyl}pyridinium diperchlorate, the Product of Template Condensation in the Presence of Cr(III). in Journal of Chemical Crystallography. 2009;39(2):138-142. doi:10.1007/s10870-008-9443-6 .
Radanović, Dušanka D., Kaluđerović, Goran N., Gomez-Ruiz, Santiago, Sladić, Dušan, Šumar-Ristović, Maja, Brčeski, Ilija, Anđelković, Katarina K., "Crystal Structure of 2-{1-[(1-(2-Pyridinio)ethylidene) hydrazono]ethyl}pyridinium diperchlorate, the Product of Template Condensation in the Presence of Cr(III)" in Journal of Chemical Crystallography, 39, no. 2 (2009):138-142, https://doi.org/10.1007/s10870-008-9443-6 . .