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1,3-Migration of phenylthio group in the rearrangement of tertiary cyclopropylmethanols possessing an α-phenylthio group
dc.creator | Saičić, Radomir | |
dc.creator | Badić, J. | |
dc.creator | Čeković, Živorad | |
dc.date.accessioned | 2018-11-22T00:00:59Z | |
dc.date.available | 2018-11-22T00:00:59Z | |
dc.date.issued | 1996 | |
dc.identifier.issn | 0352-5139 | |
dc.identifier.uri | https://cherry.chem.bg.ac.rs/handle/123456789/61 | |
dc.description.abstract | The acid catalysed ring opening of tertiary cyclopropylmethanols 1 (R = H, vinyl, Ph), possessing a phenylthio group on the adjacent carbon atom proceeds, regioselectively and homoallylic halides 2 are obtained in 49 - 86% yields. Depending on the structure of 1 (R= Ph, SPh) and the acid used the cyclopropane ring opening follows the 1,3-migration of phenylthio group and the corresponding 1-halo-3-phenylthio-4-pentene derivatives 3 are obtained in 54-76% yields. | en |
dc.rights | restrictedAccess | |
dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/4.0/ | |
dc.source | Journal of the Serbian Chemical Society | |
dc.subject | 1,3-migration of phenylthio group | en |
dc.subject | Cyclopropane ring opening | en |
dc.subject | Cyclopropylcarbinyl carbocation | en |
dc.title | 1,3-Migration of phenylthio group in the rearrangement of tertiary cyclopropylmethanols possessing an α-phenylthio group | en |
dc.type | article | |
dc.rights.license | BY-NC-ND | |
dc.citation.volume | 61 | |
dc.citation.issue | 10 | |
dc.citation.spage | 841 | |
dc.citation.epage | 848 | |
dc.citation.other | 61(10): 841-848 | |
dc.type.version | publishedVersion | en |
dc.identifier.scopus | 2-s2.0-0040649974 | |
dc.identifier.rcub | https://hdl.handle.net/21.15107/rcub_cherry_61 |
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