Regioselective synthesis of a stereodefined heterocyclic push-pull alkene - H-1 NMR studies and two-dimensional TLC illustrating Z/E isomerization
Само за регистроване кориснике
2004
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Introducing students to the regioselective synthesis of a stereodefined push-pull alkene from inexpensive chemicals can be facilicated through experiment. In the experiment, preparation of the precursor, such as diethyl mercaptosuccinate from mercaptosuccinic acid and ethanol in toluene as a cosolvent, demonstrates the educational significance of binary and tertiary azeotropes in practical organic synthesis. The utility of 1H NMR spectroscopy is illustrated as a tool to identify the configurational isomers and to study the stereodynamic behavior of the isolated heterocyclic product.
Извор:
Journal of Chemical Education, 2004, 81, 7, 1026-1029Издавач:
- Amer Chemical Soc, Washington
Колекције
Институција/група
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Marković, R. AU - Baranac-Stojanović, Marija AU - Jovanović, Vesna B. AU - Džambaski, Z. PY - 2004 UR - https://cherry.chem.bg.ac.rs/handle/123456789/646 AB - Introducing students to the regioselective synthesis of a stereodefined push-pull alkene from inexpensive chemicals can be facilicated through experiment. In the experiment, preparation of the precursor, such as diethyl mercaptosuccinate from mercaptosuccinic acid and ethanol in toluene as a cosolvent, demonstrates the educational significance of binary and tertiary azeotropes in practical organic synthesis. The utility of 1H NMR spectroscopy is illustrated as a tool to identify the configurational isomers and to study the stereodynamic behavior of the isolated heterocyclic product. PB - Amer Chemical Soc, Washington T2 - Journal of Chemical Education T1 - Regioselective synthesis of a stereodefined heterocyclic push-pull alkene - H-1 NMR studies and two-dimensional TLC illustrating Z/E isomerization VL - 81 IS - 7 SP - 1026 EP - 1029 UR - https://hdl.handle.net/21.15107/rcub_cherry_646 ER -
@article{ author = "Marković, R. and Baranac-Stojanović, Marija and Jovanović, Vesna B. and Džambaski, Z.", year = "2004", abstract = "Introducing students to the regioselective synthesis of a stereodefined push-pull alkene from inexpensive chemicals can be facilicated through experiment. In the experiment, preparation of the precursor, such as diethyl mercaptosuccinate from mercaptosuccinic acid and ethanol in toluene as a cosolvent, demonstrates the educational significance of binary and tertiary azeotropes in practical organic synthesis. The utility of 1H NMR spectroscopy is illustrated as a tool to identify the configurational isomers and to study the stereodynamic behavior of the isolated heterocyclic product.", publisher = "Amer Chemical Soc, Washington", journal = "Journal of Chemical Education", title = "Regioselective synthesis of a stereodefined heterocyclic push-pull alkene - H-1 NMR studies and two-dimensional TLC illustrating Z/E isomerization", volume = "81", number = "7", pages = "1026-1029", url = "https://hdl.handle.net/21.15107/rcub_cherry_646" }
Marković, R., Baranac-Stojanović, M., Jovanović, V. B.,& Džambaski, Z.. (2004). Regioselective synthesis of a stereodefined heterocyclic push-pull alkene - H-1 NMR studies and two-dimensional TLC illustrating Z/E isomerization. in Journal of Chemical Education Amer Chemical Soc, Washington., 81(7), 1026-1029. https://hdl.handle.net/21.15107/rcub_cherry_646
Marković R, Baranac-Stojanović M, Jovanović VB, Džambaski Z. Regioselective synthesis of a stereodefined heterocyclic push-pull alkene - H-1 NMR studies and two-dimensional TLC illustrating Z/E isomerization. in Journal of Chemical Education. 2004;81(7):1026-1029. https://hdl.handle.net/21.15107/rcub_cherry_646 .
Marković, R., Baranac-Stojanović, Marija, Jovanović, Vesna B., Džambaski, Z., "Regioselective synthesis of a stereodefined heterocyclic push-pull alkene - H-1 NMR studies and two-dimensional TLC illustrating Z/E isomerization" in Journal of Chemical Education, 81, no. 7 (2004):1026-1029, https://hdl.handle.net/21.15107/rcub_cherry_646 .