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Intramolecular C-H⋯π interactions in metal-porphyrin complexes
dc.creator | Bogdanović, Goran A. | |
dc.creator | Medaković, Vesna | |
dc.creator | Milčić, Miloš K. | |
dc.creator | Zarić, Snežana D. | |
dc.date.accessioned | 2018-11-22T00:06:21Z | |
dc.date.available | 2018-11-22T00:06:21Z | |
dc.date.issued | 2004 | |
dc.identifier.issn | 1422-0067 | |
dc.identifier.uri | https://cherry.chem.bg.ac.rs/handle/123456789/66 | |
dc.description.abstract | Cambridge Structural Database (CSD) was screened in order to find intramolecular C-H⋯π interactions with a chelate ring of coordinated porphyrin. It was found 154 crystal structures with 244 intramolecular C-H⋯π interactions in transition metal complexes with derivatives of porphyrin. Comparison of interacting distances indicates that interactions of hydrogen atoms in positions 2 and 6 of axially coordinated pyridine are more favorable with ruffled than with planar porphyrin. | en |
dc.rights | openAccess | |
dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | |
dc.source | International Journal of Molecular Sciences | |
dc.subject | Axial ligands | en |
dc.subject | C-H⋯π interactions | en |
dc.subject | Chelate ring | en |
dc.subject | Porphyrin | en |
dc.subject | Transition metal complexes | en |
dc.title | Intramolecular C-H⋯π interactions in metal-porphyrin complexes | en |
dc.type | conferenceObject | |
dc.rights.license | BY | |
dc.citation.volume | 5 | |
dc.citation.issue | SPEC ISS | |
dc.citation.spage | 174 | |
dc.citation.epage | 185 | |
dc.citation.other | 5(SPEC ISS): 174-185 | |
dc.type.version | publishedVersion | |
dc.identifier.scopus | 2-s2.0-19744364416 | |
dc.identifier.fulltext | https://cherry.chem.bg.ac.rs/bitstream/id/9897/64.pdf | |
dc.identifier.rcub | https://hdl.handle.net/21.15107/rcub_cherry_66 |