Photophysical, electrochemical, and mesomorphic properties of a liquid-crystalline [60]fullerene-peralkylated ferrocene dyad
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2008
Authors
Campidelli, StephaneSeverac, Marjorie
Scanu, David
Deschenaux, Robert
Vazquez, Ester
Milić, Dragana
Prato, Maurizio
Carano, Maurizio
Marcaccio, Massimo
Paolucci, Francesco
Rahman, G. M. Aminur
Guldi, Dirk M.
Article (Published version)
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Two fullerene-peralkylated ferrocene derivatives were synthesized: (1) a liquid-crystalline dyad (compound 1) was obtained by introduction of nonamethyl ferrocene into a liquid-crystalline fullerene derivative and (2) a reference compound (compound 2) was synthesized by attachment of nonamethyl ferrocene to a fulleropyrrolidine. The liquid-crystalline dyad displayed an enantiotropic smectic A phase from 57 to 155 degrees C. Oxidation and reduction processes were investigated by cyclic voltammetry, and were in agreement with the electrochemical characteristics of the redox-active units (peralkylated ferrocene, fullerene, dendrimer). Photoinduced electron transfer from ferrocene derivative to fullerene was identified.
Source:
Journal of Materials Chemistry, 2008, 18, 13, 1504-1509Publisher:
- Royal Soc Chemistry, Cambridge
DOI: 10.1039/b716806c
ISSN: 0959-9428
WoS: 000254386400009
Scopus: 2-s2.0-41149087372
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Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Campidelli, Stephane AU - Severac, Marjorie AU - Scanu, David AU - Deschenaux, Robert AU - Vazquez, Ester AU - Milić, Dragana AU - Prato, Maurizio AU - Carano, Maurizio AU - Marcaccio, Massimo AU - Paolucci, Francesco AU - Rahman, G. M. Aminur AU - Guldi, Dirk M. PY - 2008 UR - https://cherry.chem.bg.ac.rs/handle/123456789/925 AB - Two fullerene-peralkylated ferrocene derivatives were synthesized: (1) a liquid-crystalline dyad (compound 1) was obtained by introduction of nonamethyl ferrocene into a liquid-crystalline fullerene derivative and (2) a reference compound (compound 2) was synthesized by attachment of nonamethyl ferrocene to a fulleropyrrolidine. The liquid-crystalline dyad displayed an enantiotropic smectic A phase from 57 to 155 degrees C. Oxidation and reduction processes were investigated by cyclic voltammetry, and were in agreement with the electrochemical characteristics of the redox-active units (peralkylated ferrocene, fullerene, dendrimer). Photoinduced electron transfer from ferrocene derivative to fullerene was identified. PB - Royal Soc Chemistry, Cambridge T2 - Journal of Materials Chemistry T1 - Photophysical, electrochemical, and mesomorphic properties of a liquid-crystalline [60]fullerene-peralkylated ferrocene dyad VL - 18 IS - 13 SP - 1504 EP - 1509 DO - 10.1039/b716806c ER -
@article{ author = "Campidelli, Stephane and Severac, Marjorie and Scanu, David and Deschenaux, Robert and Vazquez, Ester and Milić, Dragana and Prato, Maurizio and Carano, Maurizio and Marcaccio, Massimo and Paolucci, Francesco and Rahman, G. M. Aminur and Guldi, Dirk M.", year = "2008", abstract = "Two fullerene-peralkylated ferrocene derivatives were synthesized: (1) a liquid-crystalline dyad (compound 1) was obtained by introduction of nonamethyl ferrocene into a liquid-crystalline fullerene derivative and (2) a reference compound (compound 2) was synthesized by attachment of nonamethyl ferrocene to a fulleropyrrolidine. The liquid-crystalline dyad displayed an enantiotropic smectic A phase from 57 to 155 degrees C. Oxidation and reduction processes were investigated by cyclic voltammetry, and were in agreement with the electrochemical characteristics of the redox-active units (peralkylated ferrocene, fullerene, dendrimer). Photoinduced electron transfer from ferrocene derivative to fullerene was identified.", publisher = "Royal Soc Chemistry, Cambridge", journal = "Journal of Materials Chemistry", title = "Photophysical, electrochemical, and mesomorphic properties of a liquid-crystalline [60]fullerene-peralkylated ferrocene dyad", volume = "18", number = "13", pages = "1504-1509", doi = "10.1039/b716806c" }
Campidelli, S., Severac, M., Scanu, D., Deschenaux, R., Vazquez, E., Milić, D., Prato, M., Carano, M., Marcaccio, M., Paolucci, F., Rahman, G. M. A.,& Guldi, D. M.. (2008). Photophysical, electrochemical, and mesomorphic properties of a liquid-crystalline [60]fullerene-peralkylated ferrocene dyad. in Journal of Materials Chemistry Royal Soc Chemistry, Cambridge., 18(13), 1504-1509. https://doi.org/10.1039/b716806c
Campidelli S, Severac M, Scanu D, Deschenaux R, Vazquez E, Milić D, Prato M, Carano M, Marcaccio M, Paolucci F, Rahman GMA, Guldi DM. Photophysical, electrochemical, and mesomorphic properties of a liquid-crystalline [60]fullerene-peralkylated ferrocene dyad. in Journal of Materials Chemistry. 2008;18(13):1504-1509. doi:10.1039/b716806c .
Campidelli, Stephane, Severac, Marjorie, Scanu, David, Deschenaux, Robert, Vazquez, Ester, Milić, Dragana, Prato, Maurizio, Carano, Maurizio, Marcaccio, Massimo, Paolucci, Francesco, Rahman, G. M. Aminur, Guldi, Dirk M., "Photophysical, electrochemical, and mesomorphic properties of a liquid-crystalline [60]fullerene-peralkylated ferrocene dyad" in Journal of Materials Chemistry, 18, no. 13 (2008):1504-1509, https://doi.org/10.1039/b716806c . .