Quantitative Structure-Retention Relationships of Mixed Tris-beta-Diketonato Complexes on Polyacrylonitrile Sorbent
Само за регистроване кориснике
2008
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Quantitative structure-retention relationships models have been developed for thin-layer chromatographic parameters of 30 mixed beta-diketonato complexes. In order to obtain predictive and interpretative models, we chromatographed a series of beta-diketonato complexes of cobalt(III), chromium(III) and ruthenium(III) on thin-layer polyacrylonitrile sorbent. Chemical descriptors: volume, surface area, energy of the highest occupied molecular orbital, energy of the lowest unoccupied molecular orbital, dipole moment, refractivity and polarizability were calculated from the structure and related to their chromatographic retention parameters by multiple linear regression analysis. The obtained models were used for interpretation of the retention behaviour of the investigated beta-diketonato complexes.
Кључне речи:
Thin-layer chromatography / Quantitative structure-retention relationship / Molecular descriptors / beta-Diketonato complexesИзвор:
Chromatographia, 2008, 68, 9-10, 797-802Издавач:
- Vieweg, Wiesbaden
Финансирање / пројекти:
- Синтеза, анализа и активност нових органских полидентатних лиганада и њихових комплекса са d-металима (RS-142062)
DOI: 10.1365/s10337-008-0759-3
ISSN: 0009-5893
WoS: 000260524400015
Scopus: 2-s2.0-55349087220
Колекције
Институција/група
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Baošić, Rada AU - Radojevic, Ana AU - Tešić, Živoslav Lj. PY - 2008 UR - https://cherry.chem.bg.ac.rs/handle/123456789/980 AB - Quantitative structure-retention relationships models have been developed for thin-layer chromatographic parameters of 30 mixed beta-diketonato complexes. In order to obtain predictive and interpretative models, we chromatographed a series of beta-diketonato complexes of cobalt(III), chromium(III) and ruthenium(III) on thin-layer polyacrylonitrile sorbent. Chemical descriptors: volume, surface area, energy of the highest occupied molecular orbital, energy of the lowest unoccupied molecular orbital, dipole moment, refractivity and polarizability were calculated from the structure and related to their chromatographic retention parameters by multiple linear regression analysis. The obtained models were used for interpretation of the retention behaviour of the investigated beta-diketonato complexes. PB - Vieweg, Wiesbaden T2 - Chromatographia T1 - Quantitative Structure-Retention Relationships of Mixed Tris-beta-Diketonato Complexes on Polyacrylonitrile Sorbent VL - 68 IS - 9-10 SP - 797 EP - 802 DO - 10.1365/s10337-008-0759-3 ER -
@article{ author = "Baošić, Rada and Radojevic, Ana and Tešić, Živoslav Lj.", year = "2008", abstract = "Quantitative structure-retention relationships models have been developed for thin-layer chromatographic parameters of 30 mixed beta-diketonato complexes. In order to obtain predictive and interpretative models, we chromatographed a series of beta-diketonato complexes of cobalt(III), chromium(III) and ruthenium(III) on thin-layer polyacrylonitrile sorbent. Chemical descriptors: volume, surface area, energy of the highest occupied molecular orbital, energy of the lowest unoccupied molecular orbital, dipole moment, refractivity and polarizability were calculated from the structure and related to their chromatographic retention parameters by multiple linear regression analysis. The obtained models were used for interpretation of the retention behaviour of the investigated beta-diketonato complexes.", publisher = "Vieweg, Wiesbaden", journal = "Chromatographia", title = "Quantitative Structure-Retention Relationships of Mixed Tris-beta-Diketonato Complexes on Polyacrylonitrile Sorbent", volume = "68", number = "9-10", pages = "797-802", doi = "10.1365/s10337-008-0759-3" }
Baošić, R., Radojevic, A.,& Tešić, Ž. Lj.. (2008). Quantitative Structure-Retention Relationships of Mixed Tris-beta-Diketonato Complexes on Polyacrylonitrile Sorbent. in Chromatographia Vieweg, Wiesbaden., 68(9-10), 797-802. https://doi.org/10.1365/s10337-008-0759-3
Baošić R, Radojevic A, Tešić ŽL. Quantitative Structure-Retention Relationships of Mixed Tris-beta-Diketonato Complexes on Polyacrylonitrile Sorbent. in Chromatographia. 2008;68(9-10):797-802. doi:10.1365/s10337-008-0759-3 .
Baošić, Rada, Radojevic, Ana, Tešić, Živoslav Lj., "Quantitative Structure-Retention Relationships of Mixed Tris-beta-Diketonato Complexes on Polyacrylonitrile Sorbent" in Chromatographia, 68, no. 9-10 (2008):797-802, https://doi.org/10.1365/s10337-008-0759-3 . .