TY  - JOUR
AU  - Milovanovic, Milos B.
AU  - Trifunović, Snežana S.
AU  - Katsikas, Lynne
AU  - Popović, Ivanka G.
PY  - 2007
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/908
AB  - The free radical copolymerisation of itaconic anhydride and methyl methacrylate in solution was studied at 60 C. The copolymer composition was determined by H-1-NMR spectroscopy and the obtained monomer reactivity ratios were calculated, r(ITA) = 1.35 +/- 0.11; r(MMA) = 0.22 +/- 0.22 (by the Fineman-Ross method) and r(ITA) = 1.27 +/- 0.38; rMMA = 0.10 +/- 0.05 (by the Mayo-Lewis method). The synthesised copolymers were modified by reaction with di-n-butyl amine. The copolymer composition after amidation was determined by elemental analysis via the nitrogen content. Amidation of the anhydride units in the copolymers with di-n-butyl amine resulted in complete conversion to itaconamic acid.
AB  - Ispitivana je radikalna kopolimerizacija anhidrida itakonske kiseline i metil-metakrilata u rastvoru na 60 °C. Sastav kopolimera određen je 1H-NMR spektroskopijom i izračunati su odnosi reaktivnosti monomera, rITA = 1.35±0.11; rMMA = 0.22±0.22 (metodom Fajnman-Ros) i rITA = 1.27±0.38; rMMA = 0.10±0.05 (metodom Mejo-Luis). Sintetizovani kopolimeri su modifikovani reakcijom sa dibutil-aminom. Nakon amidacije sastav kopolimera određen je elementalnom analizom na osnovu sadržaja azota. Amidacijom anhidridnih jedinica u kopolimerima dibutil-aminom nastale su komonomerne jedinice itakonamične kiseline.
PB  - Serbian Chemical Soc, Belgrade
T2  - Journal of the Serbian Chemical Society
T1  - Preparation and modification of itaconic anhydride-methyl methacrylate copolymers
T1  - Sinteza i modifikacija kopolimera anhidrida itakonske kiseline i metil-metakrilata
VL  - 72
IS  - 12
SP  - 1507
EP  - 1514
DO  - 10.2298/JSC0712507M
ER  - 

@article{
author = "Milovanovic, Milos B. and Trifunović, Snežana S. and Katsikas, Lynne and Popović, Ivanka G.",
year = "2007",
abstract = "The free radical copolymerisation of itaconic anhydride and methyl methacrylate in solution was studied at 60 C. The copolymer composition was determined by H-1-NMR spectroscopy and the obtained monomer reactivity ratios were calculated, r(ITA) = 1.35 +/- 0.11; r(MMA) = 0.22 +/- 0.22 (by the Fineman-Ross method) and r(ITA) = 1.27 +/- 0.38; rMMA = 0.10 +/- 0.05 (by the Mayo-Lewis method). The synthesised copolymers were modified by reaction with di-n-butyl amine. The copolymer composition after amidation was determined by elemental analysis via the nitrogen content. Amidation of the anhydride units in the copolymers with di-n-butyl amine resulted in complete conversion to itaconamic acid., Ispitivana je radikalna kopolimerizacija anhidrida itakonske kiseline i metil-metakrilata u rastvoru na 60 °C. Sastav kopolimera određen je 1H-NMR spektroskopijom i izračunati su odnosi reaktivnosti monomera, rITA = 1.35±0.11; rMMA = 0.22±0.22 (metodom Fajnman-Ros) i rITA = 1.27±0.38; rMMA = 0.10±0.05 (metodom Mejo-Luis). Sintetizovani kopolimeri su modifikovani reakcijom sa dibutil-aminom. Nakon amidacije sastav kopolimera određen je elementalnom analizom na osnovu sadržaja azota. Amidacijom anhidridnih jedinica u kopolimerima dibutil-aminom nastale su komonomerne jedinice itakonamične kiseline.",
publisher = "Serbian Chemical Soc, Belgrade",
journal = "Journal of the Serbian Chemical Society",
title = "Preparation and modification of itaconic anhydride-methyl methacrylate copolymers, Sinteza i modifikacija kopolimera anhidrida itakonske kiseline i metil-metakrilata",
volume = "72",
number = "12",
pages = "1507-1514",
doi = "10.2298/JSC0712507M"
}

Milovanovic, M. B., Trifunović, S. S., Katsikas, L.,& Popović, I. G.. (2007). Preparation and modification of itaconic anhydride-methyl methacrylate copolymers. in Journal of the Serbian Chemical Society
Serbian Chemical Soc, Belgrade., 72(12), 1507-1514.
https://doi.org/10.2298/JSC0712507M

Milovanovic MB, Trifunović SS, Katsikas L, Popović IG. Preparation and modification of itaconic anhydride-methyl methacrylate copolymers. in Journal of the Serbian Chemical Society. 2007;72(12):1507-1514.
doi:10.2298/JSC0712507M .

Milovanovic, Milos B., Trifunović, Snežana S., Katsikas, Lynne, Popović, Ivanka G., "Preparation and modification of itaconic anhydride-methyl methacrylate copolymers" in Journal of the Serbian Chemical Society, 72, no. 12 (2007):1507-1514,
https://doi.org/10.2298/JSC0712507M . .