Sokic, Miroslav

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  • Sokic, Miroslav (5)
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Author's Bibliography

Ni-Pd/Al(2)O(3) Catalyst Supported on Reticulated Ceramic Foam for Dry Methane Reforming

Nikolić, Vesna; Kamberović, Željko; Korać, Marija; Sokic, Miroslav; Anđić, Zoran; Tomovic, Aleksandar

(Assoc Metallurgical Engineers Serbia, Belgrade, 2015)

TY  - JOUR
AU  - Nikolić, Vesna
AU  - Kamberović, Željko
AU  - Korać, Marija
AU  - Sokic, Miroslav
AU  - Anđić, Zoran
AU  - Tomovic, Aleksandar
PY  - 2015
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/578
AB  - In the present study, Ni-Pd/Al2O3 catalyst supported on alpha-Al2O3 based foam was prepared and evaluated in the dry methane reforming process. Corresponding metal chlorides were deposited to the foam surface by impregnation of the foam with ultrasonically aerosolized salt solutions at 473 K and drying at that temperature. Calcination step was excluded and the catalyst was reduced at very low temperature 533 K. The reforming experiment lasted for 3 h, with standing time of 1 h at the following temperatures: 873, 973 and 1023 K. Conclusions on selectivity, catalytic activity and stability were reached on the basis of CO and H-2 yields.
PB  - Assoc Metallurgical Engineers Serbia, Belgrade
T2  - Metallurgical and Materials Engineering
T1  - Ni-Pd/Al(2)O(3) Catalyst Supported on Reticulated Ceramic Foam for Dry Methane Reforming
VL  - 21
IS  - 1
SP  - 57
EP  - 63
DO  - 10.30544/133
ER  - 
@article{
author = "Nikolić, Vesna and Kamberović, Željko and Korać, Marija and Sokic, Miroslav and Anđić, Zoran and Tomovic, Aleksandar",
year = "2015",
abstract = "In the present study, Ni-Pd/Al2O3 catalyst supported on alpha-Al2O3 based foam was prepared and evaluated in the dry methane reforming process. Corresponding metal chlorides were deposited to the foam surface by impregnation of the foam with ultrasonically aerosolized salt solutions at 473 K and drying at that temperature. Calcination step was excluded and the catalyst was reduced at very low temperature 533 K. The reforming experiment lasted for 3 h, with standing time of 1 h at the following temperatures: 873, 973 and 1023 K. Conclusions on selectivity, catalytic activity and stability were reached on the basis of CO and H-2 yields.",
publisher = "Assoc Metallurgical Engineers Serbia, Belgrade",
journal = "Metallurgical and Materials Engineering",
title = "Ni-Pd/Al(2)O(3) Catalyst Supported on Reticulated Ceramic Foam for Dry Methane Reforming",
volume = "21",
number = "1",
pages = "57-63",
doi = "10.30544/133"
}
Nikolić, V., Kamberović, Ž., Korać, M., Sokic, M., Anđić, Z.,& Tomovic, A.. (2015). Ni-Pd/Al(2)O(3) Catalyst Supported on Reticulated Ceramic Foam for Dry Methane Reforming. in Metallurgical and Materials Engineering
Assoc Metallurgical Engineers Serbia, Belgrade., 21(1), 57-63.
https://doi.org/10.30544/133
Nikolić V, Kamberović Ž, Korać M, Sokic M, Anđić Z, Tomovic A. Ni-Pd/Al(2)O(3) Catalyst Supported on Reticulated Ceramic Foam for Dry Methane Reforming. in Metallurgical and Materials Engineering. 2015;21(1):57-63.
doi:10.30544/133 .
Nikolić, Vesna, Kamberović, Željko, Korać, Marija, Sokic, Miroslav, Anđić, Zoran, Tomovic, Aleksandar, "Ni-Pd/Al(2)O(3) Catalyst Supported on Reticulated Ceramic Foam for Dry Methane Reforming" in Metallurgical and Materials Engineering, 21, no. 1 (2015):57-63,
https://doi.org/10.30544/133 . .
1

Exploitation Properties of Ni-Pd/Al2o3 Catalyst Supported on Ceramic Foam

Nikolić, Vesna; Kamberović, Željko; Anđić, Zoran; Korać, Marija; Sokic, Miroslav; Gajić, Nataša; Jovanovic, Nikola

(Assoc Metallurgical Engineers Serbia, Belgrade, 2015)

TY  - JOUR
AU  - Nikolić, Vesna
AU  - Kamberović, Željko
AU  - Anđić, Zoran
AU  - Korać, Marija
AU  - Sokic, Miroslav
AU  - Gajić, Nataša
AU  - Jovanovic, Nikola
PY  - 2015
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/579
AB  - The goal of this research was to examine exploitation properties of Ni-Pd/Al2O3 catalyst supported on alpha-Al2O3 based foam in the dry methane reforming. The catalyst was prepared by using aerosol method. Chloride precursors for Ni and Pd were reduced by hydrogen at low temperature of 533 K, without previous calcination. The reforming experiment was performed for 3 h, with standing time of 1 h for each of the following temperatures: 873, 973 and 1023 K. Conclusions on selectivity, catalytic activity and stability were made on the basis of CO and H-2 yields.
PB  - Assoc Metallurgical Engineers Serbia, Belgrade
T2  - Metallurgical and Materials Engineering
T1  - Exploitation Properties of Ni-Pd/Al2o3 Catalyst Supported on Ceramic Foam
VL  - 21
IS  - 4
SP  - 277
EP  - 282
DO  - 10.30544/74
ER  - 
@article{
author = "Nikolić, Vesna and Kamberović, Željko and Anđić, Zoran and Korać, Marija and Sokic, Miroslav and Gajić, Nataša and Jovanovic, Nikola",
year = "2015",
abstract = "The goal of this research was to examine exploitation properties of Ni-Pd/Al2O3 catalyst supported on alpha-Al2O3 based foam in the dry methane reforming. The catalyst was prepared by using aerosol method. Chloride precursors for Ni and Pd were reduced by hydrogen at low temperature of 533 K, without previous calcination. The reforming experiment was performed for 3 h, with standing time of 1 h for each of the following temperatures: 873, 973 and 1023 K. Conclusions on selectivity, catalytic activity and stability were made on the basis of CO and H-2 yields.",
publisher = "Assoc Metallurgical Engineers Serbia, Belgrade",
journal = "Metallurgical and Materials Engineering",
title = "Exploitation Properties of Ni-Pd/Al2o3 Catalyst Supported on Ceramic Foam",
volume = "21",
number = "4",
pages = "277-282",
doi = "10.30544/74"
}
Nikolić, V., Kamberović, Ž., Anđić, Z., Korać, M., Sokic, M., Gajić, N.,& Jovanovic, N.. (2015). Exploitation Properties of Ni-Pd/Al2o3 Catalyst Supported on Ceramic Foam. in Metallurgical and Materials Engineering
Assoc Metallurgical Engineers Serbia, Belgrade., 21(4), 277-282.
https://doi.org/10.30544/74
Nikolić V, Kamberović Ž, Anđić Z, Korać M, Sokic M, Gajić N, Jovanovic N. Exploitation Properties of Ni-Pd/Al2o3 Catalyst Supported on Ceramic Foam. in Metallurgical and Materials Engineering. 2015;21(4):277-282.
doi:10.30544/74 .
Nikolić, Vesna, Kamberović, Željko, Anđić, Zoran, Korać, Marija, Sokic, Miroslav, Gajić, Nataša, Jovanovic, Nikola, "Exploitation Properties of Ni-Pd/Al2o3 Catalyst Supported on Ceramic Foam" in Metallurgical and Materials Engineering, 21, no. 4 (2015):277-282,
https://doi.org/10.30544/74 . .

Synthesis of Alpha-Al2o3 Based Foams with Improved Properties as Catalyst Carriers

Nikolić, Vesna; Kamberović, Željko; Anđić, Zoran; Korać, Marija; Sokic, Miroslav

(Inst Za Kovinske Materiale I In Tehnologie, Ljubjana, 2014)

TY  - JOUR
AU  - Nikolić, Vesna
AU  - Kamberović, Željko
AU  - Anđić, Zoran
AU  - Korać, Marija
AU  - Sokic, Miroslav
PY  - 2014
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1505
AB  - This paper explores the possibility of synthesising catalyst supports with improved properties. Alumina foams were produced with the polymer replication technique. Representative high- and low-temperature sintering ceramics were selected. Suitable suspension amounts, the clay addition and sintering temperature were determined. A lower sintering temperature was used for an economic enhancement of the process. The sintering was conducted at the temperatures from 1573 K to 1773 K for 60 min. A comparative analysis of the studied systems shows that the best compressive strength of 6.2 MPa was achieved with the system based on the alpha-Al2O3-25 clay (mass fractions, w/%), polyester foam with 10 PPI, sintered at 1673 K.
PB  - Inst Za Kovinske Materiale I In Tehnologie, Ljubjana
T2  - Materials and Technology = Materiali in Tehnologije
T1  - Synthesis of Alpha-Al2o3 Based Foams with Improved Properties as Catalyst Carriers
VL  - 48
IS  - 1
SP  - 45
EP  - 50
UR  - https://hdl.handle.net/21.15107/rcub_cherry_1505
ER  - 
@article{
author = "Nikolić, Vesna and Kamberović, Željko and Anđić, Zoran and Korać, Marija and Sokic, Miroslav",
year = "2014",
abstract = "This paper explores the possibility of synthesising catalyst supports with improved properties. Alumina foams were produced with the polymer replication technique. Representative high- and low-temperature sintering ceramics were selected. Suitable suspension amounts, the clay addition and sintering temperature were determined. A lower sintering temperature was used for an economic enhancement of the process. The sintering was conducted at the temperatures from 1573 K to 1773 K for 60 min. A comparative analysis of the studied systems shows that the best compressive strength of 6.2 MPa was achieved with the system based on the alpha-Al2O3-25 clay (mass fractions, w/%), polyester foam with 10 PPI, sintered at 1673 K.",
publisher = "Inst Za Kovinske Materiale I In Tehnologie, Ljubjana",
journal = "Materials and Technology = Materiali in Tehnologije",
title = "Synthesis of Alpha-Al2o3 Based Foams with Improved Properties as Catalyst Carriers",
volume = "48",
number = "1",
pages = "45-50",
url = "https://hdl.handle.net/21.15107/rcub_cherry_1505"
}
Nikolić, V., Kamberović, Ž., Anđić, Z., Korać, M.,& Sokic, M.. (2014). Synthesis of Alpha-Al2o3 Based Foams with Improved Properties as Catalyst Carriers. in Materials and Technology = Materiali in Tehnologije
Inst Za Kovinske Materiale I In Tehnologie, Ljubjana., 48(1), 45-50.
https://hdl.handle.net/21.15107/rcub_cherry_1505
Nikolić V, Kamberović Ž, Anđić Z, Korać M, Sokic M. Synthesis of Alpha-Al2o3 Based Foams with Improved Properties as Catalyst Carriers. in Materials and Technology = Materiali in Tehnologije. 2014;48(1):45-50.
https://hdl.handle.net/21.15107/rcub_cherry_1505 .
Nikolić, Vesna, Kamberović, Željko, Anđić, Zoran, Korać, Marija, Sokic, Miroslav, "Synthesis of Alpha-Al2o3 Based Foams with Improved Properties as Catalyst Carriers" in Materials and Technology = Materiali in Tehnologije, 48, no. 1 (2014):45-50,
https://hdl.handle.net/21.15107/rcub_cherry_1505 .
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Influences of synthesis methods and modifier addition on the properties of Ni-based catalysts supported on reticulated ceramic foams

Nikolić, Vesna; Kamberović, Željko; Anđić, Zoran; Korać, Marija; Sokic, Miroslav; Maksimovic, Vesna

(Springer, New York, 2014)

TY  - JOUR
AU  - Nikolić, Vesna
AU  - Kamberović, Željko
AU  - Anđić, Zoran
AU  - Korać, Marija
AU  - Sokic, Miroslav
AU  - Maksimovic, Vesna
PY  - 2014
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1826
AB  - A method of synthesizing Ni-based catalysts supported on alpha-Al2O3-based foams was developed. The foams were impregnated with aqueous solutions of metal chlorides under an air atmosphere using an aerosol route. Separate procedures involved calcination to form oxides and drying to obtain chlorides on the foam surface. The synthesized samples were subsequently reduced with hydrogen. With respect to the Ni/Al2O3 catalysts, the chloride reduction route enabled the formation of a Ni coating without agglomerates or cracks. Further research included catalyst modification by the addition of Pd, Cu, and Fe. The influences of the additives on the degree of reduction and on the low-temperature reduction effectiveness (533 and 633 K) were examined and compared for the catalysts obtained from oxides and chlorides. Greater degrees of reduction were achieved with chlorides, whereas Pd was the most effective modifier among those investigated. The reduction process was nearly complete at 533 K in the sample that contained 0.1wt% Pd. A lower reduction temperature was utilized, and the calcination step was avoided, which may enhance the economical and technological aspects of the developed catalyst production method.
PB  - Springer, New York
T2  - International Journal of Minerals, Metallurgy and Materials
T1  - Influences of synthesis methods and modifier addition on the properties of Ni-based catalysts supported on reticulated ceramic foams
VL  - 21
IS  - 8
SP  - 806
EP  - 812
DO  - 10.1007/s12613-014-0974-x
ER  - 
@article{
author = "Nikolić, Vesna and Kamberović, Željko and Anđić, Zoran and Korać, Marija and Sokic, Miroslav and Maksimovic, Vesna",
year = "2014",
abstract = "A method of synthesizing Ni-based catalysts supported on alpha-Al2O3-based foams was developed. The foams were impregnated with aqueous solutions of metal chlorides under an air atmosphere using an aerosol route. Separate procedures involved calcination to form oxides and drying to obtain chlorides on the foam surface. The synthesized samples were subsequently reduced with hydrogen. With respect to the Ni/Al2O3 catalysts, the chloride reduction route enabled the formation of a Ni coating without agglomerates or cracks. Further research included catalyst modification by the addition of Pd, Cu, and Fe. The influences of the additives on the degree of reduction and on the low-temperature reduction effectiveness (533 and 633 K) were examined and compared for the catalysts obtained from oxides and chlorides. Greater degrees of reduction were achieved with chlorides, whereas Pd was the most effective modifier among those investigated. The reduction process was nearly complete at 533 K in the sample that contained 0.1wt% Pd. A lower reduction temperature was utilized, and the calcination step was avoided, which may enhance the economical and technological aspects of the developed catalyst production method.",
publisher = "Springer, New York",
journal = "International Journal of Minerals, Metallurgy and Materials",
title = "Influences of synthesis methods and modifier addition on the properties of Ni-based catalysts supported on reticulated ceramic foams",
volume = "21",
number = "8",
pages = "806-812",
doi = "10.1007/s12613-014-0974-x"
}
Nikolić, V., Kamberović, Ž., Anđić, Z., Korać, M., Sokic, M.,& Maksimovic, V.. (2014). Influences of synthesis methods and modifier addition on the properties of Ni-based catalysts supported on reticulated ceramic foams. in International Journal of Minerals, Metallurgy and Materials
Springer, New York., 21(8), 806-812.
https://doi.org/10.1007/s12613-014-0974-x
Nikolić V, Kamberović Ž, Anđić Z, Korać M, Sokic M, Maksimovic V. Influences of synthesis methods and modifier addition on the properties of Ni-based catalysts supported on reticulated ceramic foams. in International Journal of Minerals, Metallurgy and Materials. 2014;21(8):806-812.
doi:10.1007/s12613-014-0974-x .
Nikolić, Vesna, Kamberović, Željko, Anđić, Zoran, Korać, Marija, Sokic, Miroslav, Maksimovic, Vesna, "Influences of synthesis methods and modifier addition on the properties of Ni-based catalysts supported on reticulated ceramic foams" in International Journal of Minerals, Metallurgy and Materials, 21, no. 8 (2014):806-812,
https://doi.org/10.1007/s12613-014-0974-x . .
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Effects of Additives on Nickel (Ii)-Chloride Hydrogen Reduction for Production of Nanocomposite Catalysts

Kamberović, Željko; Sokic, Miroslav; Matkovic, Vladislav; Anđić, Zoran; Korać, Marija; Nikolić, Vesna

(Editura Stiintifica Fmr, Bucharest, 2012)

TY  - JOUR
AU  - Kamberović, Željko
AU  - Sokic, Miroslav
AU  - Matkovic, Vladislav
AU  - Anđić, Zoran
AU  - Korać, Marija
AU  - Nikolić, Vesna
PY  - 2012
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1269
AB  - Catalysts based on nickel, as active component, exhibit suitable properties in various heterogeneous catalysis processes; however, they quickly deactivate due to deposits formation during exploitation and sintering at elevated temperatures. Considering that catalysts with several catalytic components possess enhanced catalytic properties, in present study the influence of temperature, time and additives (PdCl2, FeCl2 and CuCl2) on the reduction degree of nickel(II)-chloride by hydrogen have been investigated. The objectives of the study were selection of an appropriate catalytic activity modifier and development of a new synthesis method for nanocomposite catalysts production, which are characterized by enhanced properties compared to the commercial Ni/Al2O3 catalysts. Obtained experimental results clearly indicate that the best effect was achieved with addition of 0.1 wt. % PdCl2, whereby NiCl2, reduction degree was 58.16% at 653 K and Pd significantly increased the reduction rate. According to the obtained results., new technological synthesis method of nanocomposite Ni-Pd/Al2O3 catalysis was proposed, where Ni and Pd. as catalytically active components, are homogeneously dispersed in monolithic Al2O3 based ceramic foam.
PB  - Editura Stiintifica Fmr, Bucharest
T2  - Metalurgia International
T1  - Effects of Additives on Nickel (Ii)-Chloride Hydrogen Reduction for Production of Nanocomposite Catalysts
VL  - 17
IS  - 5
SP  - 37
EP  - 41
UR  - https://hdl.handle.net/21.15107/rcub_cherry_1269
ER  - 
@article{
author = "Kamberović, Željko and Sokic, Miroslav and Matkovic, Vladislav and Anđić, Zoran and Korać, Marija and Nikolić, Vesna",
year = "2012",
abstract = "Catalysts based on nickel, as active component, exhibit suitable properties in various heterogeneous catalysis processes; however, they quickly deactivate due to deposits formation during exploitation and sintering at elevated temperatures. Considering that catalysts with several catalytic components possess enhanced catalytic properties, in present study the influence of temperature, time and additives (PdCl2, FeCl2 and CuCl2) on the reduction degree of nickel(II)-chloride by hydrogen have been investigated. The objectives of the study were selection of an appropriate catalytic activity modifier and development of a new synthesis method for nanocomposite catalysts production, which are characterized by enhanced properties compared to the commercial Ni/Al2O3 catalysts. Obtained experimental results clearly indicate that the best effect was achieved with addition of 0.1 wt. % PdCl2, whereby NiCl2, reduction degree was 58.16% at 653 K and Pd significantly increased the reduction rate. According to the obtained results., new technological synthesis method of nanocomposite Ni-Pd/Al2O3 catalysis was proposed, where Ni and Pd. as catalytically active components, are homogeneously dispersed in monolithic Al2O3 based ceramic foam.",
publisher = "Editura Stiintifica Fmr, Bucharest",
journal = "Metalurgia International",
title = "Effects of Additives on Nickel (Ii)-Chloride Hydrogen Reduction for Production of Nanocomposite Catalysts",
volume = "17",
number = "5",
pages = "37-41",
url = "https://hdl.handle.net/21.15107/rcub_cherry_1269"
}
Kamberović, Ž., Sokic, M., Matkovic, V., Anđić, Z., Korać, M.,& Nikolić, V.. (2012). Effects of Additives on Nickel (Ii)-Chloride Hydrogen Reduction for Production of Nanocomposite Catalysts. in Metalurgia International
Editura Stiintifica Fmr, Bucharest., 17(5), 37-41.
https://hdl.handle.net/21.15107/rcub_cherry_1269
Kamberović Ž, Sokic M, Matkovic V, Anđić Z, Korać M, Nikolić V. Effects of Additives on Nickel (Ii)-Chloride Hydrogen Reduction for Production of Nanocomposite Catalysts. in Metalurgia International. 2012;17(5):37-41.
https://hdl.handle.net/21.15107/rcub_cherry_1269 .
Kamberović, Željko, Sokic, Miroslav, Matkovic, Vladislav, Anđić, Zoran, Korać, Marija, Nikolić, Vesna, "Effects of Additives on Nickel (Ii)-Chloride Hydrogen Reduction for Production of Nanocomposite Catalysts" in Metalurgia International, 17, no. 5 (2012):37-41,
https://hdl.handle.net/21.15107/rcub_cherry_1269 .
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