Panić, Vesna V.

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  • Panić, Vesna V. (5)
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Biobased thermo/pH sensitive poly(N-isopropylacrylamide-co-crotonic acid) hydrogels for targeted drug delivery

Marković, Maja D.; Panić, Vesna V.; Savić, Sanja I.; Ugrinović, Vukašin Đ.; Pjanović, Rada V.; Spasojević, Milica ; Spasojevic, Pavle M.

(Elsevier, 2022)

TY  - JOUR
AU  - Marković, Maja D.
AU  - Panić, Vesna V.
AU  - Savić, Sanja I.
AU  - Ugrinović, Vukašin Đ.
AU  - Pjanović, Rada V.
AU  - Spasojević, Milica 
AU  - Spasojevic, Pavle M.
PY  - 2022
UR  - https://www.sciencedirect.com/science/article/pii/S1387181122001366?pes=vor
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5148
AB  - Materials sensitive to external stimuli are recognized as safe and effective tool able to respond to specific demands in the therapy of various diseases. Thermo sensitive hydrogels based on poly(N-isopropylacrylamide) (P(NIPAAM)) are widely investigated for targeted drug delivery. Still, the abundance of the stimuli in the human body often requires more than one responsive group able to act simultaneously to achieve optimal therapeutic effects. Due to its pH sensitivity and bio-based production, crotonic acid (CA) was a monomer of choice for preparation of eco-friendly copolymer hydrogels based on NIPAAM and CA (P(NIPAAMcoCA)), which turned to be thermo and pH sensitive at the same time. The potential of the P(NIPAAMcoCA) system for encapsulation and controlled release of drugs with different solubility was investigated engaging water-soluble lidocaine hydrochloride and poorly water-soluble ibuprofen as model drugs. The hydrogels were characterized by various technics: FTIR, DSC, SEM and single compressive tests, while swelling behavior and controlled release of the drugs were analyzed with respect to the CA amount in two environments with different pH values at 25 °C and 37 °C. It was demonstrated that due to their dual responsiveness the P(NIPAAMcoCA) hydrogels have potential for controlled release of drugs with different solubility.
PB  - Elsevier
T2  - Microporous and Mesoporous Materials
T1  - Biobased thermo/pH sensitive poly(N-isopropylacrylamide-co-crotonic acid) hydrogels for targeted drug delivery
VL  - 335
SP  - 111817
DO  - 10.1016/j.micromeso.2022.111817
ER  - 
@article{
author = "Marković, Maja D. and Panić, Vesna V. and Savić, Sanja I. and Ugrinović, Vukašin Đ. and Pjanović, Rada V. and Spasojević, Milica  and Spasojevic, Pavle M.",
year = "2022",
abstract = "Materials sensitive to external stimuli are recognized as safe and effective tool able to respond to specific demands in the therapy of various diseases. Thermo sensitive hydrogels based on poly(N-isopropylacrylamide) (P(NIPAAM)) are widely investigated for targeted drug delivery. Still, the abundance of the stimuli in the human body often requires more than one responsive group able to act simultaneously to achieve optimal therapeutic effects. Due to its pH sensitivity and bio-based production, crotonic acid (CA) was a monomer of choice for preparation of eco-friendly copolymer hydrogels based on NIPAAM and CA (P(NIPAAMcoCA)), which turned to be thermo and pH sensitive at the same time. The potential of the P(NIPAAMcoCA) system for encapsulation and controlled release of drugs with different solubility was investigated engaging water-soluble lidocaine hydrochloride and poorly water-soluble ibuprofen as model drugs. The hydrogels were characterized by various technics: FTIR, DSC, SEM and single compressive tests, while swelling behavior and controlled release of the drugs were analyzed with respect to the CA amount in two environments with different pH values at 25 °C and 37 °C. It was demonstrated that due to their dual responsiveness the P(NIPAAMcoCA) hydrogels have potential for controlled release of drugs with different solubility.",
publisher = "Elsevier",
journal = "Microporous and Mesoporous Materials",
title = "Biobased thermo/pH sensitive poly(N-isopropylacrylamide-co-crotonic acid) hydrogels for targeted drug delivery",
volume = "335",
pages = "111817",
doi = "10.1016/j.micromeso.2022.111817"
}
Marković, M. D., Panić, V. V., Savić, S. I., Ugrinović, V. Đ., Pjanović, R. V., Spasojević, M.,& Spasojevic, P. M.. (2022). Biobased thermo/pH sensitive poly(N-isopropylacrylamide-co-crotonic acid) hydrogels for targeted drug delivery. in Microporous and Mesoporous Materials
Elsevier., 335, 111817.
https://doi.org/10.1016/j.micromeso.2022.111817
Marković MD, Panić VV, Savić SI, Ugrinović VĐ, Pjanović RV, Spasojević M, Spasojevic PM. Biobased thermo/pH sensitive poly(N-isopropylacrylamide-co-crotonic acid) hydrogels for targeted drug delivery. in Microporous and Mesoporous Materials. 2022;335:111817.
doi:10.1016/j.micromeso.2022.111817 .
Marković, Maja D., Panić, Vesna V., Savić, Sanja I., Ugrinović, Vukašin Đ., Pjanović, Rada V., Spasojević, Milica , Spasojevic, Pavle M., "Biobased thermo/pH sensitive poly(N-isopropylacrylamide-co-crotonic acid) hydrogels for targeted drug delivery" in Microporous and Mesoporous Materials, 335 (2022):111817,
https://doi.org/10.1016/j.micromeso.2022.111817 . .
10
1
10
9

Supplementary information for the article: Marković, M. D.; Panić, V. V.; Savić, S. I.; Ugrinović, V. Đ.; Pjanović, R. V.; Spasojević, M. M.; Spasojevic, P. M. Biobased Thermo/PH Sensitive Poly(N-Isopropylacrylamide-Co-Crotonic Acid) Hydrogels for Targeted Drug Delivery. Microporous and Mesoporous Materials 2022, 335. https://doi.org/10.1016.

Marković, Maja D.; Panić, Vesna V.; Savić, Sanja I.; Ugrinović, Vukašin Đ.; Pjanović, Rada V.; Spasojević, Milica ; Spasojevic, Pavle M.

(Elsevier, 2022)

TY  - DATA
AU  - Marković, Maja D.
AU  - Panić, Vesna V.
AU  - Savić, Sanja I.
AU  - Ugrinović, Vukašin Đ.
AU  - Pjanović, Rada V.
AU  - Spasojević, Milica 
AU  - Spasojevic, Pavle M.
PY  - 2022
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5148
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5150
AB  - Materials sensitive to external stimuli are recognized as safe and effective tool able to respond to specific demands in the therapy of various diseases. Thermo sensitive hydrogels based on poly(N-isopropylacrylamide) (P(NIPAAM)) are widely investigated for targeted drug delivery. Still, the abundance of the stimuli in the human body often requires more than one responsive group able to act simultaneously to achieve optimal therapeutic effects. Due to its pH sensitivity and bio-based production, crotonic acid (CA) was a monomer of choice for preparation of eco-friendly copolymer hydrogels based on NIPAAM and CA (P(NIPAAMcoCA)), which turned to be thermo and pH sensitive at the same time. The potential of the P(NIPAAMcoCA) system for encapsulation and controlled release of drugs with different solubility was investigated engaging water-soluble lidocaine hydrochloride and poorly water-soluble ibuprofen as model drugs. The hydrogels were characterized by various technics: FTIR, DSC, SEM and single compressive tests, while swelling behavior and controlled release of the drugs were analyzed with respect to the CA amount in two environments with different pH values at 25 °C and 37 °C. It was demonstrated that due to their dual responsiveness the P(NIPAAMcoCA) hydrogels have potential for controlled release of drugs with different solubility.
PB  - Elsevier
T2  - Microporous and Mesoporous Materials
T1  - Supplementary information for the article: Marković, M. D.; Panić, V. V.; Savić, S. I.; Ugrinović, V. Đ.; Pjanović, R. V.; Spasojević, M. M.; Spasojevic, P. M. Biobased Thermo/PH Sensitive Poly(N-Isopropylacrylamide-Co-Crotonic Acid) Hydrogels for Targeted Drug Delivery. Microporous and Mesoporous Materials 2022, 335. https://doi.org/10.1016.
VL  - 335
UR  - https://hdl.handle.net/21.15107/rcub_cherry_5150
ER  - 
@misc{
author = "Marković, Maja D. and Panić, Vesna V. and Savić, Sanja I. and Ugrinović, Vukašin Đ. and Pjanović, Rada V. and Spasojević, Milica  and Spasojevic, Pavle M.",
year = "2022",
abstract = "Materials sensitive to external stimuli are recognized as safe and effective tool able to respond to specific demands in the therapy of various diseases. Thermo sensitive hydrogels based on poly(N-isopropylacrylamide) (P(NIPAAM)) are widely investigated for targeted drug delivery. Still, the abundance of the stimuli in the human body often requires more than one responsive group able to act simultaneously to achieve optimal therapeutic effects. Due to its pH sensitivity and bio-based production, crotonic acid (CA) was a monomer of choice for preparation of eco-friendly copolymer hydrogels based on NIPAAM and CA (P(NIPAAMcoCA)), which turned to be thermo and pH sensitive at the same time. The potential of the P(NIPAAMcoCA) system for encapsulation and controlled release of drugs with different solubility was investigated engaging water-soluble lidocaine hydrochloride and poorly water-soluble ibuprofen as model drugs. The hydrogels were characterized by various technics: FTIR, DSC, SEM and single compressive tests, while swelling behavior and controlled release of the drugs were analyzed with respect to the CA amount in two environments with different pH values at 25 °C and 37 °C. It was demonstrated that due to their dual responsiveness the P(NIPAAMcoCA) hydrogels have potential for controlled release of drugs with different solubility.",
publisher = "Elsevier",
journal = "Microporous and Mesoporous Materials",
title = "Supplementary information for the article: Marković, M. D.; Panić, V. V.; Savić, S. I.; Ugrinović, V. Đ.; Pjanović, R. V.; Spasojević, M. M.; Spasojevic, P. M. Biobased Thermo/PH Sensitive Poly(N-Isopropylacrylamide-Co-Crotonic Acid) Hydrogels for Targeted Drug Delivery. Microporous and Mesoporous Materials 2022, 335. https://doi.org/10.1016.",
volume = "335",
url = "https://hdl.handle.net/21.15107/rcub_cherry_5150"
}
Marković, M. D., Panić, V. V., Savić, S. I., Ugrinović, V. Đ., Pjanović, R. V., Spasojević, M.,& Spasojevic, P. M.. (2022). Supplementary information for the article: Marković, M. D.; Panić, V. V.; Savić, S. I.; Ugrinović, V. Đ.; Pjanović, R. V.; Spasojević, M. M.; Spasojevic, P. M. Biobased Thermo/PH Sensitive Poly(N-Isopropylacrylamide-Co-Crotonic Acid) Hydrogels for Targeted Drug Delivery. Microporous and Mesoporous Materials 2022, 335. https://doi.org/10.1016.. in Microporous and Mesoporous Materials
Elsevier., 335.
https://hdl.handle.net/21.15107/rcub_cherry_5150
Marković MD, Panić VV, Savić SI, Ugrinović VĐ, Pjanović RV, Spasojević M, Spasojevic PM. Supplementary information for the article: Marković, M. D.; Panić, V. V.; Savić, S. I.; Ugrinović, V. Đ.; Pjanović, R. V.; Spasojević, M. M.; Spasojevic, P. M. Biobased Thermo/PH Sensitive Poly(N-Isopropylacrylamide-Co-Crotonic Acid) Hydrogels for Targeted Drug Delivery. Microporous and Mesoporous Materials 2022, 335. https://doi.org/10.1016.. in Microporous and Mesoporous Materials. 2022;335.
https://hdl.handle.net/21.15107/rcub_cherry_5150 .
Marković, Maja D., Panić, Vesna V., Savić, Sanja I., Ugrinović, Vukašin Đ., Pjanović, Rada V., Spasojević, Milica , Spasojevic, Pavle M., "Supplementary information for the article: Marković, M. D.; Panić, V. V.; Savić, S. I.; Ugrinović, V. Đ.; Pjanović, R. V.; Spasojević, M. M.; Spasojevic, P. M. Biobased Thermo/PH Sensitive Poly(N-Isopropylacrylamide-Co-Crotonic Acid) Hydrogels for Targeted Drug Delivery. Microporous and Mesoporous Materials 2022, 335. https://doi.org/10.1016." in Microporous and Mesoporous Materials, 335 (2022),
https://hdl.handle.net/21.15107/rcub_cherry_5150 .

Supplementary data for article : Panic, V. V.; Seslija, S. I.; Popovic, I. G.; Spasojevic, V. D.; Popovic, A. R.; Nikolic, V. B.; Spasojevic, P. M. Simple One-Pot Synthesis of Fully Biobased Unsaturated Polyester Resins Based on Itaconic Acid. Biomacromolecules 2017, 18 (12), 3881–3891. https://doi.org/10.1021/acs.biomac.7b00840

Panić, Vesna V.; Seslija, Sanja I.; Popović, Ivanka G.; Spasojević, Vuk D.; Popović, Aleksandar R.; Nikolić, Vladimir; Spasojević, Pavle M.

(Amer Chemical Soc, Washington, 2017)

TY  - DATA
AU  - Panić, Vesna V.
AU  - Seslija, Sanja I.
AU  - Popović, Ivanka G.
AU  - Spasojević, Vuk D.
AU  - Popović, Aleksandar R.
AU  - Nikolić, Vladimir
AU  - Spasojević, Pavle M.
PY  - 2017
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3059
PB  - Amer Chemical Soc, Washington
T2  - Biomacromolecules
T1  - Supplementary data for article : Panic, V. V.; Seslija, S. I.; Popovic, I. G.; Spasojevic, V. D.; Popovic, A. R.; Nikolic, V. B.; Spasojevic, P. M. Simple One-Pot Synthesis of Fully Biobased Unsaturated Polyester Resins Based on Itaconic Acid. Biomacromolecules 2017, 18 (12), 3881–3891. https://doi.org/10.1021/acs.biomac.7b00840
UR  - https://hdl.handle.net/21.15107/rcub_cherry_3059
ER  - 
@misc{
author = "Panić, Vesna V. and Seslija, Sanja I. and Popović, Ivanka G. and Spasojević, Vuk D. and Popović, Aleksandar R. and Nikolić, Vladimir and Spasojević, Pavle M.",
year = "2017",
publisher = "Amer Chemical Soc, Washington",
journal = "Biomacromolecules",
title = "Supplementary data for article : Panic, V. V.; Seslija, S. I.; Popovic, I. G.; Spasojevic, V. D.; Popovic, A. R.; Nikolic, V. B.; Spasojevic, P. M. Simple One-Pot Synthesis of Fully Biobased Unsaturated Polyester Resins Based on Itaconic Acid. Biomacromolecules 2017, 18 (12), 3881–3891. https://doi.org/10.1021/acs.biomac.7b00840",
url = "https://hdl.handle.net/21.15107/rcub_cherry_3059"
}
Panić, V. V., Seslija, S. I., Popović, I. G., Spasojević, V. D., Popović, A. R., Nikolić, V.,& Spasojević, P. M.. (2017). Supplementary data for article : Panic, V. V.; Seslija, S. I.; Popovic, I. G.; Spasojevic, V. D.; Popovic, A. R.; Nikolic, V. B.; Spasojevic, P. M. Simple One-Pot Synthesis of Fully Biobased Unsaturated Polyester Resins Based on Itaconic Acid. Biomacromolecules 2017, 18 (12), 3881–3891. https://doi.org/10.1021/acs.biomac.7b00840. in Biomacromolecules
Amer Chemical Soc, Washington..
https://hdl.handle.net/21.15107/rcub_cherry_3059
Panić VV, Seslija SI, Popović IG, Spasojević VD, Popović AR, Nikolić V, Spasojević PM. Supplementary data for article : Panic, V. V.; Seslija, S. I.; Popovic, I. G.; Spasojevic, V. D.; Popovic, A. R.; Nikolic, V. B.; Spasojevic, P. M. Simple One-Pot Synthesis of Fully Biobased Unsaturated Polyester Resins Based on Itaconic Acid. Biomacromolecules 2017, 18 (12), 3881–3891. https://doi.org/10.1021/acs.biomac.7b00840. in Biomacromolecules. 2017;.
https://hdl.handle.net/21.15107/rcub_cherry_3059 .
Panić, Vesna V., Seslija, Sanja I., Popović, Ivanka G., Spasojević, Vuk D., Popović, Aleksandar R., Nikolić, Vladimir, Spasojević, Pavle M., "Supplementary data for article : Panic, V. V.; Seslija, S. I.; Popovic, I. G.; Spasojevic, V. D.; Popovic, A. R.; Nikolic, V. B.; Spasojevic, P. M. Simple One-Pot Synthesis of Fully Biobased Unsaturated Polyester Resins Based on Itaconic Acid. Biomacromolecules 2017, 18 (12), 3881–3891. https://doi.org/10.1021/acs.biomac.7b00840" in Biomacromolecules (2017),
https://hdl.handle.net/21.15107/rcub_cherry_3059 .

Simple One-Pot Synthesis of Fully Biobased Unsaturated Polyester Resins Based on Itaconic Acid

Panić, Vesna V.; Seslija, Sanja I.; Popović, Ivanka G.; Spasojević, Vuk D.; Popović, Aleksandar R.; Nikolić, Vladimir; Spasojević, Pavle M.

(Amer Chemical Soc, Washington, 2017)

TY  - JOUR
AU  - Panić, Vesna V.
AU  - Seslija, Sanja I.
AU  - Popović, Ivanka G.
AU  - Spasojević, Vuk D.
AU  - Popović, Aleksandar R.
AU  - Nikolić, Vladimir
AU  - Spasojević, Pavle M.
PY  - 2017
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3058
AB  - For the preparation of fully biobased unsaturated polyester resins (UPRs), the replacement of styrene with alternate nonpetroleum-based monomers turned out to be one of the most challenging tasks. Its complexity lies in the fact that reactive diluents (RD) have to have low viscosity and volatility, good compatibility with prepolymer, and capability to homopolymerize and copolymerize with its unsaturations. In this context, we directed our efforts to develop fully biobased UPRs using the dialkyl itaconates as an alternative to styrene. Therefore, a series of 100% biobased UPRs were prepared from itaconic acid and 1,2-propandiol and diluted by dialkyl itaconates. The resins were characterized by Fourier transform infrared spectroscopy, NMR, volatility, and viscosity measurements, while the cured samples were characterized by dynamic mechanical properties, thermomechanical analysis, thermogravimetric analysis data, and tensile tests. The influence of RD structure on the properties of cured samples was discussed in detail. It was shown that the prepared resins had evaporation rates of dialkyl itaconates of several orders of magnitude less compared to styrene. The cured resins with dimethyl itaconate showed comparable or even better thermal and mechanical properties compared to the one with styrene. This investigation showed that itaconic acid and dialkyl itaconates are promising bioresources for the preparation of fully biobased UPRs for mass consumption.
PB  - Amer Chemical Soc, Washington
T2  - Biomacromolecules
T1  - Simple One-Pot Synthesis of Fully Biobased Unsaturated Polyester Resins Based on Itaconic Acid
VL  - 18
IS  - 12
SP  - 3881
EP  - 3891
DO  - 10.1021/acs.biomac.7b00840
ER  - 
@article{
author = "Panić, Vesna V. and Seslija, Sanja I. and Popović, Ivanka G. and Spasojević, Vuk D. and Popović, Aleksandar R. and Nikolić, Vladimir and Spasojević, Pavle M.",
year = "2017",
abstract = "For the preparation of fully biobased unsaturated polyester resins (UPRs), the replacement of styrene with alternate nonpetroleum-based monomers turned out to be one of the most challenging tasks. Its complexity lies in the fact that reactive diluents (RD) have to have low viscosity and volatility, good compatibility with prepolymer, and capability to homopolymerize and copolymerize with its unsaturations. In this context, we directed our efforts to develop fully biobased UPRs using the dialkyl itaconates as an alternative to styrene. Therefore, a series of 100% biobased UPRs were prepared from itaconic acid and 1,2-propandiol and diluted by dialkyl itaconates. The resins were characterized by Fourier transform infrared spectroscopy, NMR, volatility, and viscosity measurements, while the cured samples were characterized by dynamic mechanical properties, thermomechanical analysis, thermogravimetric analysis data, and tensile tests. The influence of RD structure on the properties of cured samples was discussed in detail. It was shown that the prepared resins had evaporation rates of dialkyl itaconates of several orders of magnitude less compared to styrene. The cured resins with dimethyl itaconate showed comparable or even better thermal and mechanical properties compared to the one with styrene. This investigation showed that itaconic acid and dialkyl itaconates are promising bioresources for the preparation of fully biobased UPRs for mass consumption.",
publisher = "Amer Chemical Soc, Washington",
journal = "Biomacromolecules",
title = "Simple One-Pot Synthesis of Fully Biobased Unsaturated Polyester Resins Based on Itaconic Acid",
volume = "18",
number = "12",
pages = "3881-3891",
doi = "10.1021/acs.biomac.7b00840"
}
Panić, V. V., Seslija, S. I., Popović, I. G., Spasojević, V. D., Popović, A. R., Nikolić, V.,& Spasojević, P. M.. (2017). Simple One-Pot Synthesis of Fully Biobased Unsaturated Polyester Resins Based on Itaconic Acid. in Biomacromolecules
Amer Chemical Soc, Washington., 18(12), 3881-3891.
https://doi.org/10.1021/acs.biomac.7b00840
Panić VV, Seslija SI, Popović IG, Spasojević VD, Popović AR, Nikolić V, Spasojević PM. Simple One-Pot Synthesis of Fully Biobased Unsaturated Polyester Resins Based on Itaconic Acid. in Biomacromolecules. 2017;18(12):3881-3891.
doi:10.1021/acs.biomac.7b00840 .
Panić, Vesna V., Seslija, Sanja I., Popović, Ivanka G., Spasojević, Vuk D., Popović, Aleksandar R., Nikolić, Vladimir, Spasojević, Pavle M., "Simple One-Pot Synthesis of Fully Biobased Unsaturated Polyester Resins Based on Itaconic Acid" in Biomacromolecules, 18, no. 12 (2017):3881-3891,
https://doi.org/10.1021/acs.biomac.7b00840 . .
62
26
57
52

Simple One-Pot Synthesis of Fully Biobased Unsaturated Polyester Resins Based on Itaconic Acid

Panić, Vesna V.; Seslija, Sanja I.; Popović, Ivanka G.; Spasojević, Vuk D.; Popović, Aleksandar R.; Nikolić, Vladimir; Spasojević, Pavle M.

(Amer Chemical Soc, Washington, 2017)

TY  - JOUR
AU  - Panić, Vesna V.
AU  - Seslija, Sanja I.
AU  - Popović, Ivanka G.
AU  - Spasojević, Vuk D.
AU  - Popović, Aleksandar R.
AU  - Nikolić, Vladimir
AU  - Spasojević, Pavle M.
PY  - 2017
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/2568
AB  - For the preparation of fully biobased unsaturated polyester resins (UPRs), the replacement of styrene with alternate nonpetroleum-based monomers turned out to be one of the most challenging tasks. Its complexity lies in the fact that reactive diluents (RD) have to have low viscosity and volatility, good compatibility with prepolymer, and capability to homopolymerize and copolymerize with its unsaturations. In this context, we directed our efforts to develop fully biobased UPRs using the dialkyl itaconates as an alternative to styrene. Therefore, a series of 100% biobased UPRs were prepared from itaconic acid and 1,2-propandiol and diluted by dialkyl itaconates. The resins were characterized by Fourier transform infrared spectroscopy, NMR, volatility, and viscosity measurements, while the cured samples were characterized by dynamic mechanical properties, thermomechanical analysis, thermogravimetric analysis data, and tensile tests. The influence of RD structure on the properties of cured samples was discussed in detail. It was shown that the prepared resins had evaporation rates of dialkyl itaconates of several orders of magnitude less compared to styrene. The cured resins with dimethyl itaconate showed comparable or even better thermal and mechanical properties compared to the one with styrene. This investigation showed that itaconic acid and dialkyl itaconates are promising bioresources for the preparation of fully biobased UPRs for mass consumption.
PB  - Amer Chemical Soc, Washington
T2  - Biomacromolecules
T1  - Simple One-Pot Synthesis of Fully Biobased Unsaturated Polyester Resins Based on Itaconic Acid
VL  - 18
IS  - 12
SP  - 3881
EP  - 3891
DO  - 10.1021/acs.biomac.7b00840
ER  - 
@article{
author = "Panić, Vesna V. and Seslija, Sanja I. and Popović, Ivanka G. and Spasojević, Vuk D. and Popović, Aleksandar R. and Nikolić, Vladimir and Spasojević, Pavle M.",
year = "2017",
abstract = "For the preparation of fully biobased unsaturated polyester resins (UPRs), the replacement of styrene with alternate nonpetroleum-based monomers turned out to be one of the most challenging tasks. Its complexity lies in the fact that reactive diluents (RD) have to have low viscosity and volatility, good compatibility with prepolymer, and capability to homopolymerize and copolymerize with its unsaturations. In this context, we directed our efforts to develop fully biobased UPRs using the dialkyl itaconates as an alternative to styrene. Therefore, a series of 100% biobased UPRs were prepared from itaconic acid and 1,2-propandiol and diluted by dialkyl itaconates. The resins were characterized by Fourier transform infrared spectroscopy, NMR, volatility, and viscosity measurements, while the cured samples were characterized by dynamic mechanical properties, thermomechanical analysis, thermogravimetric analysis data, and tensile tests. The influence of RD structure on the properties of cured samples was discussed in detail. It was shown that the prepared resins had evaporation rates of dialkyl itaconates of several orders of magnitude less compared to styrene. The cured resins with dimethyl itaconate showed comparable or even better thermal and mechanical properties compared to the one with styrene. This investigation showed that itaconic acid and dialkyl itaconates are promising bioresources for the preparation of fully biobased UPRs for mass consumption.",
publisher = "Amer Chemical Soc, Washington",
journal = "Biomacromolecules",
title = "Simple One-Pot Synthesis of Fully Biobased Unsaturated Polyester Resins Based on Itaconic Acid",
volume = "18",
number = "12",
pages = "3881-3891",
doi = "10.1021/acs.biomac.7b00840"
}
Panić, V. V., Seslija, S. I., Popović, I. G., Spasojević, V. D., Popović, A. R., Nikolić, V.,& Spasojević, P. M.. (2017). Simple One-Pot Synthesis of Fully Biobased Unsaturated Polyester Resins Based on Itaconic Acid. in Biomacromolecules
Amer Chemical Soc, Washington., 18(12), 3881-3891.
https://doi.org/10.1021/acs.biomac.7b00840
Panić VV, Seslija SI, Popović IG, Spasojević VD, Popović AR, Nikolić V, Spasojević PM. Simple One-Pot Synthesis of Fully Biobased Unsaturated Polyester Resins Based on Itaconic Acid. in Biomacromolecules. 2017;18(12):3881-3891.
doi:10.1021/acs.biomac.7b00840 .
Panić, Vesna V., Seslija, Sanja I., Popović, Ivanka G., Spasojević, Vuk D., Popović, Aleksandar R., Nikolić, Vladimir, Spasojević, Pavle M., "Simple One-Pot Synthesis of Fully Biobased Unsaturated Polyester Resins Based on Itaconic Acid" in Biomacromolecules, 18, no. 12 (2017):3881-3891,
https://doi.org/10.1021/acs.biomac.7b00840 . .
63
26
57
52