Hirsch, Andreas

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Authority KeyName Variants
cb28d9d0-a5a0-42fe-892f-84c998a43dac
  • Hirsch, Andreas (6)
Projects
Deutsche Forschungsgemeinschaft (DFG, FLAG-ERA AB694/2-1) European Research Council (ERC Advanced Grant 742145 B-PhosphoChem to A.H.)
European Research Council (ERC Starting Grant 2D-PnictoChem 804110 to G.A.) European Union Seventh Framework Programme (agreement No. 604391) Graphene Flagship
Generalitat Valenciana (CIDEGENT/2018/001and iDiFEDER/2018/061 co-financed by FEDER) Innovation Office of Hungary (NKFIH) Grant Nos. K119442 and 2017-1.2.1-NKP-2017-00001
Spanish MICINN (PID2019-111742GA-I00 and Excellence Unit María de Maeztu (CEX2019-000919-M)) Alexander von Humboldt (AvH) Foundation for a postdoctoral fellowship.
Cluster of Excellence “Engineering of Advanced Materials”. Deutsche Forschungsgemeinschaft
European Commission (742145,604391) European Research Council (ERC Advanced Grant 742145 B-PhosphoChem to A.H., and ERC Starting Grant 2D-PnictoChem 804110 to G.A.).
European Research Council (ERC) No. 804110 European Union Seventh Framework Programme under grant agreement No. 604391 Graphene Flagship.
FAU (Emerging Talents Initiative grant #WS16-17_Nat_04). Free State of Bavaria (Research Network “Solar Technologies go Hybrid”).
Generalitat Valenciana (CIDEGENT/2018/001 and iDiFEDER/2018/061) Generalitat Valenciana (SEJI/2018/034 grant).
German Research Foundation (DFG) No. FLAG-ERA AB694/2-1 and SFB 953 Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200168 (University of Belgrade, Faculty of Chemistry)
SFB 953 “Synthetic Carbon Allotropes” funded by the DFG. Spanish Government (CEX2019-000919-M, PID2019-111742GA-I00)
This work was supported by the MINECO (Spain) through the Excellence Unit Mar&a de Maeztu (MDM-2015-0538) and the Project CTQ2017-86735-P. Тhe Deutsche Forschungsgemeinschaft (DFG; FLAGERA AB694/2-1).
Тhe Postdoctoral Junior Leader Fellowship Programme from “la Caixa” Banking Foundation (LCF/BQ/PI18/11630018).

Author's Bibliography

Sugar-Bridged Fullerene Dumbbells and Their Interaction with the [10]Cycloparaphenylene Nanoring

Jakšić, Jovana; Solymosi, Iris; Hirsch, Andreas; Pérez-Ojeda, M. Eugenia; Mitrović, Aleksandra D.; Maslak, Veselin

(John Wiley and Sons Inc, 2023)

TY  - JOUR
AU  - Jakšić, Jovana
AU  - Solymosi, Iris
AU  - Hirsch, Andreas
AU  - Pérez-Ojeda, M. Eugenia
AU  - Mitrović, Aleksandra D.
AU  - Maslak, Veselin
PY  - 2023
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/6272
AB  - The synthesis and characterization of four dumbbell-shaped fullerene molecules connected by isosorbide and isomannide moieties is presented. Additionally, their electrochemical behavior and their ability to form complexes with [10]cycloparaphenylene ([10]CPP) were investigated. The cyclic voltammetry (CV) results of the fullerene dumbbells demonstrate a high electron affinity, indicating their strong interaction with electron-donating counterparts such as carbon nanorings, which possess complementary charge and shape properties. To study the thermodynamic and kinetic parameters of complexation, isothermal titration calorimetry (ITC) was employed. NMR titration experiments provided further insights into the binding stoichiometries. Two distinct approaches were utilized to create bridged structures: one based on cyclopropane and the other based on furan. Regardless of the type of linker used, all derivatives formed conventional 2 : 1 complexes denoted as [10]CPP2 ⊃C60derivative . However, the methano-dumbbell molecules exhibited distinct binding behavior, resulting in the formation of mono- and bis-pseudorotaxanes, as well as oligomers (polymers). The formation of linear polymers holds significant potential for applications in solar energy conversion processes.
PB  - John Wiley and Sons Inc
T2  - Chemistry (Weinheim an Der Bergstrasse, Germany)
T1  - Sugar-Bridged Fullerene Dumbbells and Their Interaction with the [10]Cycloparaphenylene Nanoring
VL  - 29
IS  - 44
SP  - e202301061
DO  - 10.1002/chem.202301061
ER  - 
@article{
author = "Jakšić, Jovana and Solymosi, Iris and Hirsch, Andreas and Pérez-Ojeda, M. Eugenia and Mitrović, Aleksandra D. and Maslak, Veselin",
year = "2023",
abstract = "The synthesis and characterization of four dumbbell-shaped fullerene molecules connected by isosorbide and isomannide moieties is presented. Additionally, their electrochemical behavior and their ability to form complexes with [10]cycloparaphenylene ([10]CPP) were investigated. The cyclic voltammetry (CV) results of the fullerene dumbbells demonstrate a high electron affinity, indicating their strong interaction with electron-donating counterparts such as carbon nanorings, which possess complementary charge and shape properties. To study the thermodynamic and kinetic parameters of complexation, isothermal titration calorimetry (ITC) was employed. NMR titration experiments provided further insights into the binding stoichiometries. Two distinct approaches were utilized to create bridged structures: one based on cyclopropane and the other based on furan. Regardless of the type of linker used, all derivatives formed conventional 2 : 1 complexes denoted as [10]CPP2 ⊃C60derivative . However, the methano-dumbbell molecules exhibited distinct binding behavior, resulting in the formation of mono- and bis-pseudorotaxanes, as well as oligomers (polymers). The formation of linear polymers holds significant potential for applications in solar energy conversion processes.",
publisher = "John Wiley and Sons Inc",
journal = "Chemistry (Weinheim an Der Bergstrasse, Germany)",
title = "Sugar-Bridged Fullerene Dumbbells and Their Interaction with the [10]Cycloparaphenylene Nanoring",
volume = "29",
number = "44",
pages = "e202301061",
doi = "10.1002/chem.202301061"
}
Jakšić, J., Solymosi, I., Hirsch, A., Pérez-Ojeda, M. E., Mitrović, A. D.,& Maslak, V.. (2023). Sugar-Bridged Fullerene Dumbbells and Their Interaction with the [10]Cycloparaphenylene Nanoring. in Chemistry (Weinheim an Der Bergstrasse, Germany)
John Wiley and Sons Inc., 29(44), e202301061.
https://doi.org/10.1002/chem.202301061
Jakšić J, Solymosi I, Hirsch A, Pérez-Ojeda ME, Mitrović AD, Maslak V. Sugar-Bridged Fullerene Dumbbells and Their Interaction with the [10]Cycloparaphenylene Nanoring. in Chemistry (Weinheim an Der Bergstrasse, Germany). 2023;29(44):e202301061.
doi:10.1002/chem.202301061 .
Jakšić, Jovana, Solymosi, Iris, Hirsch, Andreas, Pérez-Ojeda, M. Eugenia, Mitrović, Aleksandra D., Maslak, Veselin, "Sugar-Bridged Fullerene Dumbbells and Their Interaction with the [10]Cycloparaphenylene Nanoring" in Chemistry (Weinheim an Der Bergstrasse, Germany), 29, no. 44 (2023):e202301061,
https://doi.org/10.1002/chem.202301061 . .
17
3
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Interface Amorphization of Two-Dimensional Black Phosphorus upon Treatment with Diazonium Salts

Mitrović, Aleksandra D.; Wild, Stefan; Lloret, Vicent; Fickert, Michael; Assebban, Mhamed; Márkus, Bence Gábor; Simon, Ferenc; Hauke, Frank; Abellán, Gonzalo; Hirsch, Andreas

(Wiley-VCH Verlag, 2021)

TY  - JOUR
AU  - Mitrović, Aleksandra D.
AU  - Wild, Stefan
AU  - Lloret, Vicent
AU  - Fickert, Michael
AU  - Assebban, Mhamed
AU  - Márkus, Bence Gábor
AU  - Simon, Ferenc
AU  - Hauke, Frank
AU  - Abellán, Gonzalo
AU  - Hirsch, Andreas
PY  - 2021
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/4501
AB  - Two-dimensional (2D) black phosphorus (BP) represents one of the most appealing 2D materials due to its electronic, optical, and chemical properties. Many strategies have been pursued to face its environmental instability, covalent functionalization being one of the most promising. However, the extremely low functionalization degrees and the limitations in proving the nature of the covalent functionalization still represent challenges in many of these sheet architectures reported to date. Here we shine light on the structural evolution of 2D-BP upon the addition of electrophilic diazonium salts. We demonstrated the absence of covalent functionalization in both the neutral and the reductive routes, observing in the latter case an unexpected interface conversion of BP to red phosphorus (RP), as characterized by Raman, 31P-MAS NMR, and X-ray photoelectron spectroscopies (XPS). Furthermore, thermogravimetric analysis coupled to gas chromatography and mass spectrometry (TG-GC-MS), as well as electron paramagnetic resonance (EPR) gave insights into the potential underlying radical mechanism, suggesting a Sandmeyer-like reaction.
PB  - Wiley-VCH Verlag
T2  - European Chemical Societies
T1  - Interface Amorphization of Two-Dimensional Black Phosphorus upon Treatment with Diazonium Salts
VL  - 27
SP  - 3361
EP  - 3366
DO  - 10.1002/chem.202003584
ER  - 
@article{
author = "Mitrović, Aleksandra D. and Wild, Stefan and Lloret, Vicent and Fickert, Michael and Assebban, Mhamed and Márkus, Bence Gábor and Simon, Ferenc and Hauke, Frank and Abellán, Gonzalo and Hirsch, Andreas",
year = "2021",
abstract = "Two-dimensional (2D) black phosphorus (BP) represents one of the most appealing 2D materials due to its electronic, optical, and chemical properties. Many strategies have been pursued to face its environmental instability, covalent functionalization being one of the most promising. However, the extremely low functionalization degrees and the limitations in proving the nature of the covalent functionalization still represent challenges in many of these sheet architectures reported to date. Here we shine light on the structural evolution of 2D-BP upon the addition of electrophilic diazonium salts. We demonstrated the absence of covalent functionalization in both the neutral and the reductive routes, observing in the latter case an unexpected interface conversion of BP to red phosphorus (RP), as characterized by Raman, 31P-MAS NMR, and X-ray photoelectron spectroscopies (XPS). Furthermore, thermogravimetric analysis coupled to gas chromatography and mass spectrometry (TG-GC-MS), as well as electron paramagnetic resonance (EPR) gave insights into the potential underlying radical mechanism, suggesting a Sandmeyer-like reaction.",
publisher = "Wiley-VCH Verlag",
journal = "European Chemical Societies",
title = "Interface Amorphization of Two-Dimensional Black Phosphorus upon Treatment with Diazonium Salts",
volume = "27",
pages = "3361-3366",
doi = "10.1002/chem.202003584"
}
Mitrović, A. D., Wild, S., Lloret, V., Fickert, M., Assebban, M., Márkus, B. G., Simon, F., Hauke, F., Abellán, G.,& Hirsch, A.. (2021). Interface Amorphization of Two-Dimensional Black Phosphorus upon Treatment with Diazonium Salts. in European Chemical Societies
Wiley-VCH Verlag., 27, 3361-3366.
https://doi.org/10.1002/chem.202003584
Mitrović AD, Wild S, Lloret V, Fickert M, Assebban M, Márkus BG, Simon F, Hauke F, Abellán G, Hirsch A. Interface Amorphization of Two-Dimensional Black Phosphorus upon Treatment with Diazonium Salts. in European Chemical Societies. 2021;27:3361-3366.
doi:10.1002/chem.202003584 .
Mitrović, Aleksandra D., Wild, Stefan, Lloret, Vicent, Fickert, Michael, Assebban, Mhamed, Márkus, Bence Gábor, Simon, Ferenc, Hauke, Frank, Abellán, Gonzalo, Hirsch, Andreas, "Interface Amorphization of Two-Dimensional Black Phosphorus upon Treatment with Diazonium Salts" in European Chemical Societies, 27 (2021):3361-3366,
https://doi.org/10.1002/chem.202003584 . .
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Supplementary data for the article: Mitrović, A.; Wild, S.; Lloret, V.; Fickert, M.; Assebban, M.; Márkus, B. G.; Simon, F.; Hauke, F.; Abellán, G.; Hirsch, A. Interface Amorphization of Two-Dimensional Black Phosphorus upon Treatment with Diazonium Salts. Chemistry – A European Journal 2021, 27 (10), 3361–3366. https://doi.org/10.1002/chem.202003584.

Mitrović, Aleksandra D.; Wild, Stefan; Lloret, Vicent; Fickert, Michael; Assebban, Mhamed; Márkus, Bence Gábor; Simon, Ferenc; Hauke, Frank; Abellán, Gonzalo; Hirsch, Andreas

(Wiley-VCH Verlag, 2021)

TY  - DATA
AU  - Mitrović, Aleksandra D.
AU  - Wild, Stefan
AU  - Lloret, Vicent
AU  - Fickert, Michael
AU  - Assebban, Mhamed
AU  - Márkus, Bence Gábor
AU  - Simon, Ferenc
AU  - Hauke, Frank
AU  - Abellán, Gonzalo
AU  - Hirsch, Andreas
PY  - 2021
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/4501
PB  - Wiley-VCH Verlag
T2  - European Chemical Societies
T1  - Supplementary data for the article: Mitrović, A.; Wild, S.; Lloret, V.; Fickert, M.; Assebban, M.; Márkus, B. G.; Simon, F.; Hauke, F.; Abellán, G.; Hirsch, A. Interface Amorphization of Two-Dimensional Black Phosphorus upon Treatment with Diazonium Salts. Chemistry – A European Journal 2021, 27 (10), 3361–3366. https://doi.org/10.1002/chem.202003584.
UR  - https://hdl.handle.net/21.15107/rcub_cherry_4502
ER  - 
@misc{
author = "Mitrović, Aleksandra D. and Wild, Stefan and Lloret, Vicent and Fickert, Michael and Assebban, Mhamed and Márkus, Bence Gábor and Simon, Ferenc and Hauke, Frank and Abellán, Gonzalo and Hirsch, Andreas",
year = "2021",
publisher = "Wiley-VCH Verlag",
journal = "European Chemical Societies",
title = "Supplementary data for the article: Mitrović, A.; Wild, S.; Lloret, V.; Fickert, M.; Assebban, M.; Márkus, B. G.; Simon, F.; Hauke, F.; Abellán, G.; Hirsch, A. Interface Amorphization of Two-Dimensional Black Phosphorus upon Treatment with Diazonium Salts. Chemistry – A European Journal 2021, 27 (10), 3361–3366. https://doi.org/10.1002/chem.202003584.",
url = "https://hdl.handle.net/21.15107/rcub_cherry_4502"
}
Mitrović, A. D., Wild, S., Lloret, V., Fickert, M., Assebban, M., Márkus, B. G., Simon, F., Hauke, F., Abellán, G.,& Hirsch, A.. (2021). Supplementary data for the article: Mitrović, A.; Wild, S.; Lloret, V.; Fickert, M.; Assebban, M.; Márkus, B. G.; Simon, F.; Hauke, F.; Abellán, G.; Hirsch, A. Interface Amorphization of Two-Dimensional Black Phosphorus upon Treatment with Diazonium Salts. Chemistry – A European Journal 2021, 27 (10), 3361–3366. https://doi.org/10.1002/chem.202003584.. in European Chemical Societies
Wiley-VCH Verlag..
https://hdl.handle.net/21.15107/rcub_cherry_4502
Mitrović AD, Wild S, Lloret V, Fickert M, Assebban M, Márkus BG, Simon F, Hauke F, Abellán G, Hirsch A. Supplementary data for the article: Mitrović, A.; Wild, S.; Lloret, V.; Fickert, M.; Assebban, M.; Márkus, B. G.; Simon, F.; Hauke, F.; Abellán, G.; Hirsch, A. Interface Amorphization of Two-Dimensional Black Phosphorus upon Treatment with Diazonium Salts. Chemistry – A European Journal 2021, 27 (10), 3361–3366. https://doi.org/10.1002/chem.202003584.. in European Chemical Societies. 2021;.
https://hdl.handle.net/21.15107/rcub_cherry_4502 .
Mitrović, Aleksandra D., Wild, Stefan, Lloret, Vicent, Fickert, Michael, Assebban, Mhamed, Márkus, Bence Gábor, Simon, Ferenc, Hauke, Frank, Abellán, Gonzalo, Hirsch, Andreas, "Supplementary data for the article: Mitrović, A.; Wild, S.; Lloret, V.; Fickert, M.; Assebban, M.; Márkus, B. G.; Simon, F.; Hauke, F.; Abellán, G.; Hirsch, A. Interface Amorphization of Two-Dimensional Black Phosphorus upon Treatment with Diazonium Salts. Chemistry – A European Journal 2021, 27 (10), 3361–3366. https://doi.org/10.1002/chem.202003584." in European Chemical Societies (2021),
https://hdl.handle.net/21.15107/rcub_cherry_4502 .

Covalent and non-covalent chemistry of 2D black phosphorus

Mitrović, Aleksandra D.; Abellán, Gonzalo; Hirsch, Andreas

(Royal Society of Chemistry, 2021)

TY  - JOUR
AU  - Mitrović, Aleksandra D.
AU  - Abellán, Gonzalo
AU  - Hirsch, Andreas
PY  - 2021
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/4741
AB  - The post-graphene era is undoubtedly marked by two-dimensional (2D) sheet polymers, such as black phosphorus (BP). This emerging material has a fascinating structure and outstanding electronic properties and has been postulated for a plethora of applications. The need to circumvent the pronounced oxophilicity of P atoms has dominated the research on this material in recent years, with the objective of finding the most effective method to improve its environmental stability. When it comes to chemical functionalization, the few approaches reported so far involve some drawbacks such as low degree of addition and low production ability. This review presents the concepts and strategies of our studies on the chemical functionalization of BP, both non-covalent and covalent, emphazising the current synthetic challenges. Moreover, we also provide some effective pathways for the chemical activation of the unreactive basal plane, the identification of the effective binding strategies, and the concept to overcome hurdles associated with characterization tools. This work will provide fundamental insights into the controlled chemical functionalization and characterization of BP, fostering the research on this appealing 2D material.
PB  - Royal Society of Chemistry
T2  - RSC Advances
T2  - RSC AdvancesRSC Adv.
T1  - Covalent and non-covalent chemistry of 2D black phosphorus
VL  - 11
IS  - 42
SP  - 26093
EP  - 26101
DO  - 10.1039/D1RA04416H
ER  - 
@article{
author = "Mitrović, Aleksandra D. and Abellán, Gonzalo and Hirsch, Andreas",
year = "2021",
abstract = "The post-graphene era is undoubtedly marked by two-dimensional (2D) sheet polymers, such as black phosphorus (BP). This emerging material has a fascinating structure and outstanding electronic properties and has been postulated for a plethora of applications. The need to circumvent the pronounced oxophilicity of P atoms has dominated the research on this material in recent years, with the objective of finding the most effective method to improve its environmental stability. When it comes to chemical functionalization, the few approaches reported so far involve some drawbacks such as low degree of addition and low production ability. This review presents the concepts and strategies of our studies on the chemical functionalization of BP, both non-covalent and covalent, emphazising the current synthetic challenges. Moreover, we also provide some effective pathways for the chemical activation of the unreactive basal plane, the identification of the effective binding strategies, and the concept to overcome hurdles associated with characterization tools. This work will provide fundamental insights into the controlled chemical functionalization and characterization of BP, fostering the research on this appealing 2D material.",
publisher = "Royal Society of Chemistry",
journal = "RSC Advances, RSC AdvancesRSC Adv.",
title = "Covalent and non-covalent chemistry of 2D black phosphorus",
volume = "11",
number = "42",
pages = "26093-26101",
doi = "10.1039/D1RA04416H"
}
Mitrović, A. D., Abellán, G.,& Hirsch, A.. (2021). Covalent and non-covalent chemistry of 2D black phosphorus. in RSC Advances
Royal Society of Chemistry., 11(42), 26093-26101.
https://doi.org/10.1039/D1RA04416H
Mitrović AD, Abellán G, Hirsch A. Covalent and non-covalent chemistry of 2D black phosphorus. in RSC Advances. 2021;11(42):26093-26101.
doi:10.1039/D1RA04416H .
Mitrović, Aleksandra D., Abellán, Gonzalo, Hirsch, Andreas, "Covalent and non-covalent chemistry of 2D black phosphorus" in RSC Advances, 11, no. 42 (2021):26093-26101,
https://doi.org/10.1039/D1RA04416H . .
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Interface Amorphization of Two‐Dimensional Black Phosphorus upon Treatment with Diazonium Salts

Mitrović, Aleksandra D.; Wild, Stefan; Lloret, Vicent; Fickert, Michael; Assebban, Mhamed; Márkus, Bence G.; Simon, Ferenc; Hauke, Frank; Abellan, Gonzalo; Hirsch, Andreas

(Wiley, 2020)

TY  - JOUR
AU  - Mitrović, Aleksandra D.
AU  - Wild, Stefan
AU  - Lloret, Vicent
AU  - Fickert, Michael
AU  - Assebban, Mhamed
AU  - Márkus, Bence G.
AU  - Simon, Ferenc
AU  - Hauke, Frank
AU  - Abellan, Gonzalo
AU  - Hirsch, Andreas
PY  - 2020
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5350
AB  - Two‐dimensional (2D) black phosphorus (BP) represents one of the most appealing 2D materials due to its electronic, optical, and chemical properties. Many strategies have been pursued to face its environmental instability, covalent functionalization being one of the most promising. However, the extremely low functionalization degrees and the limitations in proving the nature of the covalent functionalization still represent challenges in many of these sheet architectures reported to date. Here we shine light on the structural evolution of 2D‐BP upon the addition of electrophilic diazonium salts. We demonstrated the absence of covalent functionalization in both the neutral and the reductive routes, observing in the latter case an unexpected interface conversion of BP to red phosphorus (RP), as characterized by Raman, 31P‐MAS NMR, and X‐ray photoelectron spectroscopies (XPS). Furthermore, thermogravimetric analysis coupled to gas chromatography and mass spectrometry (TG‐GC‐MS), as well as electron paramagnetic resonance (EPR) gave insights into the potential underlying radical mechanism, suggesting a Sandmeyer‐like reaction.
PB  - Wiley
T2  - Chemistry - A European Journal
T1  - Interface Amorphization of Two‐Dimensional Black Phosphorus upon Treatment with Diazonium Salts
VL  - 27
DO  - 10.1002/chem.202003584
ER  - 
@article{
author = "Mitrović, Aleksandra D. and Wild, Stefan and Lloret, Vicent and Fickert, Michael and Assebban, Mhamed and Márkus, Bence G. and Simon, Ferenc and Hauke, Frank and Abellan, Gonzalo and Hirsch, Andreas",
year = "2020",
abstract = "Two‐dimensional (2D) black phosphorus (BP) represents one of the most appealing 2D materials due to its electronic, optical, and chemical properties. Many strategies have been pursued to face its environmental instability, covalent functionalization being one of the most promising. However, the extremely low functionalization degrees and the limitations in proving the nature of the covalent functionalization still represent challenges in many of these sheet architectures reported to date. Here we shine light on the structural evolution of 2D‐BP upon the addition of electrophilic diazonium salts. We demonstrated the absence of covalent functionalization in both the neutral and the reductive routes, observing in the latter case an unexpected interface conversion of BP to red phosphorus (RP), as characterized by Raman, 31P‐MAS NMR, and X‐ray photoelectron spectroscopies (XPS). Furthermore, thermogravimetric analysis coupled to gas chromatography and mass spectrometry (TG‐GC‐MS), as well as electron paramagnetic resonance (EPR) gave insights into the potential underlying radical mechanism, suggesting a Sandmeyer‐like reaction.",
publisher = "Wiley",
journal = "Chemistry - A European Journal",
title = "Interface Amorphization of Two‐Dimensional Black Phosphorus upon Treatment with Diazonium Salts",
volume = "27",
doi = "10.1002/chem.202003584"
}
Mitrović, A. D., Wild, S., Lloret, V., Fickert, M., Assebban, M., Márkus, B. G., Simon, F., Hauke, F., Abellan, G.,& Hirsch, A.. (2020). Interface Amorphization of Two‐Dimensional Black Phosphorus upon Treatment with Diazonium Salts. in Chemistry - A European Journal
Wiley., 27.
https://doi.org/10.1002/chem.202003584
Mitrović AD, Wild S, Lloret V, Fickert M, Assebban M, Márkus BG, Simon F, Hauke F, Abellan G, Hirsch A. Interface Amorphization of Two‐Dimensional Black Phosphorus upon Treatment with Diazonium Salts. in Chemistry - A European Journal. 2020;27.
doi:10.1002/chem.202003584 .
Mitrović, Aleksandra D., Wild, Stefan, Lloret, Vicent, Fickert, Michael, Assebban, Mhamed, Márkus, Bence G., Simon, Ferenc, Hauke, Frank, Abellan, Gonzalo, Hirsch, Andreas, "Interface Amorphization of Two‐Dimensional Black Phosphorus upon Treatment with Diazonium Salts" in Chemistry - A European Journal, 27 (2020),
https://doi.org/10.1002/chem.202003584 . .
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14
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Lattice Opening upon Bulk Reductive Covalent Functionalization of Black Phosphorus

Wild, Stefan; Fickert, Michael; Mitrović, Aleksandra D.; Lloret, Vicent; Neiss, Christian; Vidal‐Moya, Jose Alejandro; Rivero‐Crespo, Miguel Angel; Leyva‐Pérez, Antonio; Werbach, Katharina; Peterlik, Herwig; Grabau, Mathias; Wittkämper, Haiko; Papp, Christian; Steinrück, Hans-Peter; Pichler, Thomas; Görling, Andreas; Hauke, Frank; Abellán, Gonzalo; Hirsch, Andreas

(Wiley, 2019)

TY  - JOUR
AU  - Wild, Stefan
AU  - Fickert, Michael
AU  - Mitrović, Aleksandra D.
AU  - Lloret, Vicent
AU  - Neiss, Christian
AU  - Vidal‐Moya, Jose Alejandro
AU  - Rivero‐Crespo, Miguel Angel
AU  - Leyva‐Pérez, Antonio
AU  - Werbach, Katharina
AU  - Peterlik, Herwig
AU  - Grabau, Mathias
AU  - Wittkämper, Haiko
AU  - Papp, Christian
AU  - Steinrück, Hans-Peter
AU  - Pichler, Thomas
AU  - Görling, Andreas
AU  - Hauke, Frank
AU  - Abellán, Gonzalo
AU  - Hirsch, Andreas
PY  - 2019
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3936
AB  - The chemical bulk reductive covalent functionalization of thin‐layer black phosphorus (BP) using BP intercalation compounds has been developed. Through effective reductive activation, covalent functionalization of the charged BP by reaction with organic alkyl halides is achieved. Functionalization was extensively demonstrated by means of several spectroscopic techniques and DFT calculations; the products showed higher functionalization degrees than those obtained by neutral routes
PB  - Wiley
T2  - Angewandte Chemie International Edition
T1  - Lattice Opening upon Bulk Reductive Covalent Functionalization of Black Phosphorus
VL  - 58
IS  - 17
SP  - 5763
EP  - 5768
DO  - 10.1002/anie.201811181
ER  - 
@article{
author = "Wild, Stefan and Fickert, Michael and Mitrović, Aleksandra D. and Lloret, Vicent and Neiss, Christian and Vidal‐Moya, Jose Alejandro and Rivero‐Crespo, Miguel Angel and Leyva‐Pérez, Antonio and Werbach, Katharina and Peterlik, Herwig and Grabau, Mathias and Wittkämper, Haiko and Papp, Christian and Steinrück, Hans-Peter and Pichler, Thomas and Görling, Andreas and Hauke, Frank and Abellán, Gonzalo and Hirsch, Andreas",
year = "2019",
abstract = "The chemical bulk reductive covalent functionalization of thin‐layer black phosphorus (BP) using BP intercalation compounds has been developed. Through effective reductive activation, covalent functionalization of the charged BP by reaction with organic alkyl halides is achieved. Functionalization was extensively demonstrated by means of several spectroscopic techniques and DFT calculations; the products showed higher functionalization degrees than those obtained by neutral routes",
publisher = "Wiley",
journal = "Angewandte Chemie International Edition",
title = "Lattice Opening upon Bulk Reductive Covalent Functionalization of Black Phosphorus",
volume = "58",
number = "17",
pages = "5763-5768",
doi = "10.1002/anie.201811181"
}
Wild, S., Fickert, M., Mitrović, A. D., Lloret, V., Neiss, C., Vidal‐Moya, J. A., Rivero‐Crespo, M. A., Leyva‐Pérez, A., Werbach, K., Peterlik, H., Grabau, M., Wittkämper, H., Papp, C., Steinrück, H., Pichler, T., Görling, A., Hauke, F., Abellán, G.,& Hirsch, A.. (2019). Lattice Opening upon Bulk Reductive Covalent Functionalization of Black Phosphorus. in Angewandte Chemie International Edition
Wiley., 58(17), 5763-5768.
https://doi.org/10.1002/anie.201811181
Wild S, Fickert M, Mitrović AD, Lloret V, Neiss C, Vidal‐Moya JA, Rivero‐Crespo MA, Leyva‐Pérez A, Werbach K, Peterlik H, Grabau M, Wittkämper H, Papp C, Steinrück H, Pichler T, Görling A, Hauke F, Abellán G, Hirsch A. Lattice Opening upon Bulk Reductive Covalent Functionalization of Black Phosphorus. in Angewandte Chemie International Edition. 2019;58(17):5763-5768.
doi:10.1002/anie.201811181 .
Wild, Stefan, Fickert, Michael, Mitrović, Aleksandra D., Lloret, Vicent, Neiss, Christian, Vidal‐Moya, Jose Alejandro, Rivero‐Crespo, Miguel Angel, Leyva‐Pérez, Antonio, Werbach, Katharina, Peterlik, Herwig, Grabau, Mathias, Wittkämper, Haiko, Papp, Christian, Steinrück, Hans-Peter, Pichler, Thomas, Görling, Andreas, Hauke, Frank, Abellán, Gonzalo, Hirsch, Andreas, "Lattice Opening upon Bulk Reductive Covalent Functionalization of Black Phosphorus" in Angewandte Chemie International Edition, 58, no. 17 (2019):5763-5768,
https://doi.org/10.1002/anie.201811181 . .
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