TY  - CHAP
AU  - Liu, X.
AU  - Qiao, S.
AU  - Wang, R.
AU  - Jovančićević, Branimir
PY  - 2017
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/327
AB  - With the development of global economy, the combustion of a large number of fossil fuels leads to the emission of large amounts of carbon dioxide. Although CO2 is the main greenhouse gas, CO2 is also an abundant carbon resource with great application potential. A series of methods for CO2 fixation and conversion have been developed. Among these methods, electrochemical reduction of CO2 is one of the most efficient ways which could be achieved at normal temperature and pressure. However, there are some difficulties for electrochemical reduction of CO2 such as the solubility of CO2 in electrolyte, low energy efficiency and selectivity of reduction product. Ionic liquids have been proved to be excellent electrolytes or electrocatalysts for electrochemical reduction of CO2 due to their negligible vapor pressure, good electrochemical property and high solubility of CO2. According to literatures, ionic liquid could efficiently reduce the overpotential of the electrochemical reduction of CO2. Currently, there are many studies on the electrochemical reduction of CO2 using ionic liquids as electrolytes or electrocatalysts. The specific applications of ionic liquids on the electrochemical reduction of CO2 are reorganized in this chapter. © 2017 by Nova Science Publishers, Inc. All rights reserved.
T2  - Ionic Liquids: Electrochemistry, Uses and Challenges
T1  - The application of ionic liquids in the electrochemical reduction of CO2
SP  - 83
EP  - 104
UR  - https://hdl.handle.net/21.15107/rcub_cherry_327
ER  - 

@inbook{
author = "Liu, X. and Qiao, S. and Wang, R. and Jovančićević, Branimir",
year = "2017",
abstract = "With the development of global economy, the combustion of a large number of fossil fuels leads to the emission of large amounts of carbon dioxide. Although CO2 is the main greenhouse gas, CO2 is also an abundant carbon resource with great application potential. A series of methods for CO2 fixation and conversion have been developed. Among these methods, electrochemical reduction of CO2 is one of the most efficient ways which could be achieved at normal temperature and pressure. However, there are some difficulties for electrochemical reduction of CO2 such as the solubility of CO2 in electrolyte, low energy efficiency and selectivity of reduction product. Ionic liquids have been proved to be excellent electrolytes or electrocatalysts for electrochemical reduction of CO2 due to their negligible vapor pressure, good electrochemical property and high solubility of CO2. According to literatures, ionic liquid could efficiently reduce the overpotential of the electrochemical reduction of CO2. Currently, there are many studies on the electrochemical reduction of CO2 using ionic liquids as electrolytes or electrocatalysts. The specific applications of ionic liquids on the electrochemical reduction of CO2 are reorganized in this chapter. © 2017 by Nova Science Publishers, Inc. All rights reserved.",
journal = "Ionic Liquids: Electrochemistry, Uses and Challenges",
booktitle = "The application of ionic liquids in the electrochemical reduction of CO2",
pages = "83-104",
url = "https://hdl.handle.net/21.15107/rcub_cherry_327"
}

Liu, X., Qiao, S., Wang, R.,& Jovančićević, B.. (2017). The application of ionic liquids in the electrochemical reduction of CO2. in Ionic Liquids: Electrochemistry, Uses and Challenges, 83-104.
https://hdl.handle.net/21.15107/rcub_cherry_327

Liu X, Qiao S, Wang R, Jovančićević B. The application of ionic liquids in the electrochemical reduction of CO2. in Ionic Liquids: Electrochemistry, Uses and Challenges. 2017;:83-104.
https://hdl.handle.net/21.15107/rcub_cherry_327 .

Liu, X., Qiao, S., Wang, R., Jovančićević, Branimir, "The application of ionic liquids in the electrochemical reduction of CO2" in Ionic Liquids: Electrochemistry, Uses and Challenges (2017):83-104,
https://hdl.handle.net/21.15107/rcub_cherry_327 .

TY  - CHAP
AU  - Li, J.
AU  - Wang, R.
AU  - Jovančićević, Branimir
PY  - 2017
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/326
AB  - Dimethyl carbonate (DMC) is a rapidly developing green chemical product. It can be used as substitutes for basic organic chemical raw materials to replace toxic phosgene, methyl chloride, methyl chloroformate and other substances, which has important meaning for environmental protection. On one hand, CO2 is the most important greenhouse gas, causing environmental problems. On the other hand, it is also a rich and cheap carbon source. The synthesis of dimethyl carbonate from CO2 and methanol has received much attention in the past years. However, due to the thermodynamic stability and kinetic inertness of CO2, the direct synthesis of dimethyl carbonate from CO2 and methanol can only be carried out under the conditions of high temperature and high pressure or in the presence of catalysts, and even so the yield is not high. Electrochemical fixation of CO2 to dimethyl carbonate can improve the utilization of CO2 and enable the reaction to proceed under mild condition. Especially the use of green solvent ionic liquids in the study of CO2 fixation has more practical significance. Here we will introduce the process and mechanism of electrochemical synthesis of DMC in ionic liquids. The yield of DMC is affected by various factors such as ionic liquids, cathode materials, temperature, reaction time, working potential and the types of electrolytic cell. We reviewed herein the influence of several factors on the yield of DMC. © 2017 by Nova Science Publishers, Inc. All rights reserved.
T2  - Ionic Liquids: Electrochemistry, Uses and Challenges
T1  - The application of ionic liquids in the electrochemical synthesis of dimethyl carbonate from CO2 and methanol
SP  - 63
EP  - 82
UR  - https://hdl.handle.net/21.15107/rcub_cherry_326
ER  - 

@inbook{
author = "Li, J. and Wang, R. and Jovančićević, Branimir",
year = "2017",
abstract = "Dimethyl carbonate (DMC) is a rapidly developing green chemical product. It can be used as substitutes for basic organic chemical raw materials to replace toxic phosgene, methyl chloride, methyl chloroformate and other substances, which has important meaning for environmental protection. On one hand, CO2 is the most important greenhouse gas, causing environmental problems. On the other hand, it is also a rich and cheap carbon source. The synthesis of dimethyl carbonate from CO2 and methanol has received much attention in the past years. However, due to the thermodynamic stability and kinetic inertness of CO2, the direct synthesis of dimethyl carbonate from CO2 and methanol can only be carried out under the conditions of high temperature and high pressure or in the presence of catalysts, and even so the yield is not high. Electrochemical fixation of CO2 to dimethyl carbonate can improve the utilization of CO2 and enable the reaction to proceed under mild condition. Especially the use of green solvent ionic liquids in the study of CO2 fixation has more practical significance. Here we will introduce the process and mechanism of electrochemical synthesis of DMC in ionic liquids. The yield of DMC is affected by various factors such as ionic liquids, cathode materials, temperature, reaction time, working potential and the types of electrolytic cell. We reviewed herein the influence of several factors on the yield of DMC. © 2017 by Nova Science Publishers, Inc. All rights reserved.",
journal = "Ionic Liquids: Electrochemistry, Uses and Challenges",
booktitle = "The application of ionic liquids in the electrochemical synthesis of dimethyl carbonate from CO2 and methanol",
pages = "63-82",
url = "https://hdl.handle.net/21.15107/rcub_cherry_326"
}

Li, J., Wang, R.,& Jovančićević, B.. (2017). The application of ionic liquids in the electrochemical synthesis of dimethyl carbonate from CO2 and methanol. in Ionic Liquids: Electrochemistry, Uses and Challenges, 63-82.
https://hdl.handle.net/21.15107/rcub_cherry_326

Li J, Wang R, Jovančićević B. The application of ionic liquids in the electrochemical synthesis of dimethyl carbonate from CO2 and methanol. in Ionic Liquids: Electrochemistry, Uses and Challenges. 2017;:63-82.
https://hdl.handle.net/21.15107/rcub_cherry_326 .

Li, J., Wang, R., Jovančićević, Branimir, "The application of ionic liquids in the electrochemical synthesis of dimethyl carbonate from CO2 and methanol" in Ionic Liquids: Electrochemistry, Uses and Challenges (2017):63-82,
https://hdl.handle.net/21.15107/rcub_cherry_326 .