Xie, Yun

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1a6b6916-6761-4c95-8a21-8e16e88cc92f
  • Xie, Yun (5)
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Author's Bibliography

Excited-State Hydroxide Ion Release From a Series of Acridinol Photobases

Xie, Yun; Ilic, Stefan; Škaro, Sanja; Maslak, Veselin; Glusac, Ksenija D.

(Amer Chemical Soc, Washington, 2017)

TY  - JOUR
AU  - Xie, Yun
AU  - Ilic, Stefan
AU  - Škaro, Sanja
AU  - Maslak, Veselin
AU  - Glusac, Ksenija D.
PY  - 2017
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/2977
AB  - The excited-state heterolysis of acridinol-based derivatives leads to the release of the OH- ion and the formation of the corresponding acridinium cations. To evaluate the parameters that control the reaction barriers, the kinetics of excited-state OH- release from a series of acridinol photobases were studied using transient absorption spectroscopy. The rate constants were obtained in three solvents (methanol, butanol, and isobutanol), and the data were modeled using Marcus theory. The intrinsic reorganization energies obtained from these fits were found to correlate well with the solvent reorganization energies calculated using dielectric continuum model, suggesting that the excited-state OH- release occurs along the solvent reaction coordinate. Furthermore, the ability of acridinol photobases to photoinitiate chemical reactions was demonstrated using the Michael reaction between dimethylmalonate and nitrostyrene.
PB  - Amer Chemical Soc, Washington
T2  - Journal of Physical Chemistry. Part A: Molecules, Spectroscopy, Kinetics, Environment and General Theory
T1  - Excited-State Hydroxide Ion Release From a Series of Acridinol Photobases
VL  - 121
IS  - 2
SP  - 448
EP  - 457
DO  - 10.1021/acs.jpca.6b10980
ER  - 
@article{
author = "Xie, Yun and Ilic, Stefan and Škaro, Sanja and Maslak, Veselin and Glusac, Ksenija D.",
year = "2017",
abstract = "The excited-state heterolysis of acridinol-based derivatives leads to the release of the OH- ion and the formation of the corresponding acridinium cations. To evaluate the parameters that control the reaction barriers, the kinetics of excited-state OH- release from a series of acridinol photobases were studied using transient absorption spectroscopy. The rate constants were obtained in three solvents (methanol, butanol, and isobutanol), and the data were modeled using Marcus theory. The intrinsic reorganization energies obtained from these fits were found to correlate well with the solvent reorganization energies calculated using dielectric continuum model, suggesting that the excited-state OH- release occurs along the solvent reaction coordinate. Furthermore, the ability of acridinol photobases to photoinitiate chemical reactions was demonstrated using the Michael reaction between dimethylmalonate and nitrostyrene.",
publisher = "Amer Chemical Soc, Washington",
journal = "Journal of Physical Chemistry. Part A: Molecules, Spectroscopy, Kinetics, Environment and General Theory",
title = "Excited-State Hydroxide Ion Release From a Series of Acridinol Photobases",
volume = "121",
number = "2",
pages = "448-457",
doi = "10.1021/acs.jpca.6b10980"
}
Xie, Y., Ilic, S., Škaro, S., Maslak, V.,& Glusac, K. D.. (2017). Excited-State Hydroxide Ion Release From a Series of Acridinol Photobases. in Journal of Physical Chemistry. Part A: Molecules, Spectroscopy, Kinetics, Environment and General Theory
Amer Chemical Soc, Washington., 121(2), 448-457.
https://doi.org/10.1021/acs.jpca.6b10980
Xie Y, Ilic S, Škaro S, Maslak V, Glusac KD. Excited-State Hydroxide Ion Release From a Series of Acridinol Photobases. in Journal of Physical Chemistry. Part A: Molecules, Spectroscopy, Kinetics, Environment and General Theory. 2017;121(2):448-457.
doi:10.1021/acs.jpca.6b10980 .
Xie, Yun, Ilic, Stefan, Škaro, Sanja, Maslak, Veselin, Glusac, Ksenija D., "Excited-State Hydroxide Ion Release From a Series of Acridinol Photobases" in Journal of Physical Chemistry. Part A: Molecules, Spectroscopy, Kinetics, Environment and General Theory, 121, no. 2 (2017):448-457,
https://doi.org/10.1021/acs.jpca.6b10980 . .
1
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Excited-State Hydroxide Ion Release From a Series of Acridinol Photobases

Xie, Yun; Ilic, Stefan; Škaro, Sanja; Maslak, Veselin; Glusac, Ksenija D.

(Amer Chemical Soc, Washington, 2017)

TY  - JOUR
AU  - Xie, Yun
AU  - Ilic, Stefan
AU  - Škaro, Sanja
AU  - Maslak, Veselin
AU  - Glusac, Ksenija D.
PY  - 2017
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/2382
AB  - The excited-state heterolysis of acridinol-based derivatives leads to the release of the OH- ion and the formation of the corresponding acridinium cations. To evaluate the parameters that control the reaction barriers, the kinetics of excited-state OH- release from a series of acridinol photobases were studied using transient absorption spectroscopy. The rate constants were obtained in three solvents (methanol, butanol, and isobutanol), and the data were modeled using Marcus theory. The intrinsic reorganization energies obtained from these fits were found to correlate well with the solvent reorganization energies calculated using dielectric continuum model, suggesting that the excited-state OH- release occurs along the solvent reaction coordinate. Furthermore, the ability of acridinol photobases to photoinitiate chemical reactions was demonstrated using the Michael reaction between dimethylmalonate and nitrostyrene.
PB  - Amer Chemical Soc, Washington
T2  - Journal of Physical Chemistry. Part A: Molecules, Spectroscopy, Kinetics, Environment and General Th
T1  - Excited-State Hydroxide Ion Release From a Series of Acridinol Photobases
VL  - 121
IS  - 2
SP  - 448
EP  - 457
DO  - 10.1021/acs.jpca.6b10980
UR  - Kon_3198
ER  - 
@article{
author = "Xie, Yun and Ilic, Stefan and Škaro, Sanja and Maslak, Veselin and Glusac, Ksenija D.",
year = "2017",
abstract = "The excited-state heterolysis of acridinol-based derivatives leads to the release of the OH- ion and the formation of the corresponding acridinium cations. To evaluate the parameters that control the reaction barriers, the kinetics of excited-state OH- release from a series of acridinol photobases were studied using transient absorption spectroscopy. The rate constants were obtained in three solvents (methanol, butanol, and isobutanol), and the data were modeled using Marcus theory. The intrinsic reorganization energies obtained from these fits were found to correlate well with the solvent reorganization energies calculated using dielectric continuum model, suggesting that the excited-state OH- release occurs along the solvent reaction coordinate. Furthermore, the ability of acridinol photobases to photoinitiate chemical reactions was demonstrated using the Michael reaction between dimethylmalonate and nitrostyrene.",
publisher = "Amer Chemical Soc, Washington",
journal = "Journal of Physical Chemistry. Part A: Molecules, Spectroscopy, Kinetics, Environment and General Th",
title = "Excited-State Hydroxide Ion Release From a Series of Acridinol Photobases",
volume = "121",
number = "2",
pages = "448-457",
doi = "10.1021/acs.jpca.6b10980",
url = "Kon_3198"
}
Xie, Y., Ilic, S., Škaro, S., Maslak, V.,& Glusac, K. D.. (2017). Excited-State Hydroxide Ion Release From a Series of Acridinol Photobases. in Journal of Physical Chemistry. Part A: Molecules, Spectroscopy, Kinetics, Environment and General Th
Amer Chemical Soc, Washington., 121(2), 448-457.
https://doi.org/10.1021/acs.jpca.6b10980
Kon_3198
Xie Y, Ilic S, Škaro S, Maslak V, Glusac KD. Excited-State Hydroxide Ion Release From a Series of Acridinol Photobases. in Journal of Physical Chemistry. Part A: Molecules, Spectroscopy, Kinetics, Environment and General Th. 2017;121(2):448-457.
doi:10.1021/acs.jpca.6b10980
Kon_3198 .
Xie, Yun, Ilic, Stefan, Škaro, Sanja, Maslak, Veselin, Glusac, Ksenija D., "Excited-State Hydroxide Ion Release From a Series of Acridinol Photobases" in Journal of Physical Chemistry. Part A: Molecules, Spectroscopy, Kinetics, Environment and General Th, 121, no. 2 (2017):448-457,
https://doi.org/10.1021/acs.jpca.6b10980 .,
Kon_3198 .
1
7
7
7

Improved Flavin-Based Catalytic Photooxidation of Alcohols through Intersystem Crossing Rate Enhancement

Korvinson, Kirill A.; Hargenrader, George N.; Stevanović, Jelena; Xie, Yun; Joseph, Jojo; Maslak, Veselin; Hadad, Christopher M.; Glusac, Ksenija D.

(Amer Chemical Soc, Washington, 2016)

TY  - JOUR
AU  - Korvinson, Kirill A.
AU  - Hargenrader, George N.
AU  - Stevanović, Jelena
AU  - Xie, Yun
AU  - Joseph, Jojo
AU  - Maslak, Veselin
AU  - Hadad, Christopher M.
AU  - Glusac, Ksenija D.
PY  - 2016
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3541
AB  - The triplet excited-state formation efficiency in a flavin derivative was increased by the introduction of iodine into the molecular framework. The transient absorption measurements showed that the intersystem crossing rate was 1.1 X 10(10) s(-1) significantly faster than in the parent flavin compound. Furthermore, the photocatalytic efficiency of iodoflavin was evaluated using the oxidation of benzyl alcohol as a model reaction. The benzaldehyde product yields were higher when iodoflavin was used as a photocatalyst, showing that the increased triplet yield directly translates into improved photocatalysis. The iodoflavin catalyst also allowed the use of higher substrate concentrations (since the undesired electron transfer from singlet excited state was minimized), which is expected to improve the practical aspects of photocatalysis by flavins.
PB  - Amer Chemical Soc, Washington
T2  - Journal of Physical Chemistry. Part A: Molecules, Spectroscopy, Kinetics, Environment and General Th
T1  - Improved Flavin-Based Catalytic Photooxidation of Alcohols through Intersystem Crossing Rate Enhancement
VL  - 120
IS  - 37
SP  - 7294
EP  - 7300
DO  - 10.1021/acs.jpca.6b08405
UR  - Kon_3131
ER  - 
@article{
author = "Korvinson, Kirill A. and Hargenrader, George N. and Stevanović, Jelena and Xie, Yun and Joseph, Jojo and Maslak, Veselin and Hadad, Christopher M. and Glusac, Ksenija D.",
year = "2016",
abstract = "The triplet excited-state formation efficiency in a flavin derivative was increased by the introduction of iodine into the molecular framework. The transient absorption measurements showed that the intersystem crossing rate was 1.1 X 10(10) s(-1) significantly faster than in the parent flavin compound. Furthermore, the photocatalytic efficiency of iodoflavin was evaluated using the oxidation of benzyl alcohol as a model reaction. The benzaldehyde product yields were higher when iodoflavin was used as a photocatalyst, showing that the increased triplet yield directly translates into improved photocatalysis. The iodoflavin catalyst also allowed the use of higher substrate concentrations (since the undesired electron transfer from singlet excited state was minimized), which is expected to improve the practical aspects of photocatalysis by flavins.",
publisher = "Amer Chemical Soc, Washington",
journal = "Journal of Physical Chemistry. Part A: Molecules, Spectroscopy, Kinetics, Environment and General Th",
title = "Improved Flavin-Based Catalytic Photooxidation of Alcohols through Intersystem Crossing Rate Enhancement",
volume = "120",
number = "37",
pages = "7294-7300",
doi = "10.1021/acs.jpca.6b08405",
url = "Kon_3131"
}
Korvinson, K. A., Hargenrader, G. N., Stevanović, J., Xie, Y., Joseph, J., Maslak, V., Hadad, C. M.,& Glusac, K. D.. (2016). Improved Flavin-Based Catalytic Photooxidation of Alcohols through Intersystem Crossing Rate Enhancement. in Journal of Physical Chemistry. Part A: Molecules, Spectroscopy, Kinetics, Environment and General Th
Amer Chemical Soc, Washington., 120(37), 7294-7300.
https://doi.org/10.1021/acs.jpca.6b08405
Kon_3131
Korvinson KA, Hargenrader GN, Stevanović J, Xie Y, Joseph J, Maslak V, Hadad CM, Glusac KD. Improved Flavin-Based Catalytic Photooxidation of Alcohols through Intersystem Crossing Rate Enhancement. in Journal of Physical Chemistry. Part A: Molecules, Spectroscopy, Kinetics, Environment and General Th. 2016;120(37):7294-7300.
doi:10.1021/acs.jpca.6b08405
Kon_3131 .
Korvinson, Kirill A., Hargenrader, George N., Stevanović, Jelena, Xie, Yun, Joseph, Jojo, Maslak, Veselin, Hadad, Christopher M., Glusac, Ksenija D., "Improved Flavin-Based Catalytic Photooxidation of Alcohols through Intersystem Crossing Rate Enhancement" in Journal of Physical Chemistry. Part A: Molecules, Spectroscopy, Kinetics, Environment and General Th, 120, no. 37 (2016):7294-7300,
https://doi.org/10.1021/acs.jpca.6b08405 .,
Kon_3131 .
27
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Supplementary material for the article: Korvinson, K. A.; Hargenrader, G. N.; Stevanovic, J.; Xie, Y.; Joseph, J.; Maslak, V.; Hadad, C. M.; Glusac, K. D. Improved Flavin-Based Catalytic Photooxidation of Alcohols through Intersystem Crossing Rate Enhancement. Journal of Physical Chemistry A 2016, 120 (37), 7294–7300. https://doi.org/10.1021/acs.jpca.6b08405

Korvinson, Kirill A.; Hargenrader, George N.; Stevanović, Jelena; Xie, Yun; Joseph, Jojo; Maslak, Veselin; Hadad, Christopher M.; Glusac, Ksenija D.

(Amer Chemical Soc, Washington, 2016)

TY  - DATA
AU  - Korvinson, Kirill A.
AU  - Hargenrader, George N.
AU  - Stevanović, Jelena
AU  - Xie, Yun
AU  - Joseph, Jojo
AU  - Maslak, Veselin
AU  - Hadad, Christopher M.
AU  - Glusac, Ksenija D.
PY  - 2016
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3542
PB  - Amer Chemical Soc, Washington
T2  - Journal of Physical Chemistry. Part A: Molecules, Spectroscopy, Kinetics, Environment and General Th
T1  - Supplementary material for the article: Korvinson, K. A.; Hargenrader, G. N.; Stevanovic, J.; Xie, Y.; Joseph, J.; Maslak, V.; Hadad, 
C. M.; Glusac, K. D. Improved Flavin-Based Catalytic Photooxidation of Alcohols through 
Intersystem Crossing Rate Enhancement. Journal of Physical Chemistry A 2016, 120 (37), 
7294–7300. https://doi.org/10.1021/acs.jpca.6b08405
ER  - 
@misc{
author = "Korvinson, Kirill A. and Hargenrader, George N. and Stevanović, Jelena and Xie, Yun and Joseph, Jojo and Maslak, Veselin and Hadad, Christopher M. and Glusac, Ksenija D.",
year = "2016",
publisher = "Amer Chemical Soc, Washington",
journal = "Journal of Physical Chemistry. Part A: Molecules, Spectroscopy, Kinetics, Environment and General Th",
title = "Supplementary material for the article: Korvinson, K. A.; Hargenrader, G. N.; Stevanovic, J.; Xie, Y.; Joseph, J.; Maslak, V.; Hadad, 
C. M.; Glusac, K. D. Improved Flavin-Based Catalytic Photooxidation of Alcohols through 
Intersystem Crossing Rate Enhancement. Journal of Physical Chemistry A 2016, 120 (37), 
7294–7300. https://doi.org/10.1021/acs.jpca.6b08405"
}
Korvinson, K. A., Hargenrader, G. N., Stevanović, J., Xie, Y., Joseph, J., Maslak, V., Hadad, C. M.,& Glusac, K. D.. (2016). Supplementary material for the article: Korvinson, K. A.; Hargenrader, G. N.; Stevanovic, J.; Xie, Y.; Joseph, J.; Maslak, V.; Hadad, 
C. M.; Glusac, K. D. Improved Flavin-Based Catalytic Photooxidation of Alcohols through 
Intersystem Crossing Rate Enhancement. Journal of Physical Chemistry A 2016, 120 (37), 
7294–7300. https://doi.org/10.1021/acs.jpca.6b08405. in Journal of Physical Chemistry. Part A: Molecules, Spectroscopy, Kinetics, Environment and General Th
Amer Chemical Soc, Washington..
Korvinson KA, Hargenrader GN, Stevanović J, Xie Y, Joseph J, Maslak V, Hadad CM, Glusac KD. Supplementary material for the article: Korvinson, K. A.; Hargenrader, G. N.; Stevanovic, J.; Xie, Y.; Joseph, J.; Maslak, V.; Hadad, 
C. M.; Glusac, K. D. Improved Flavin-Based Catalytic Photooxidation of Alcohols through 
Intersystem Crossing Rate Enhancement. Journal of Physical Chemistry A 2016, 120 (37), 
7294–7300. https://doi.org/10.1021/acs.jpca.6b08405. in Journal of Physical Chemistry. Part A: Molecules, Spectroscopy, Kinetics, Environment and General Th. 2016;..
Korvinson, Kirill A., Hargenrader, George N., Stevanović, Jelena, Xie, Yun, Joseph, Jojo, Maslak, Veselin, Hadad, Christopher M., Glusac, Ksenija D., "Supplementary material for the article: Korvinson, K. A.; Hargenrader, G. N.; Stevanovic, J.; Xie, Y.; Joseph, J.; Maslak, V.; Hadad, 
C. M.; Glusac, K. D. Improved Flavin-Based Catalytic Photooxidation of Alcohols through 
Intersystem Crossing Rate Enhancement. Journal of Physical Chemistry A 2016, 120 (37), 
7294–7300. https://doi.org/10.1021/acs.jpca.6b08405" in Journal of Physical Chemistry. Part A: Molecules, Spectroscopy, Kinetics, Environment and General Th (2016).

Improved Flavin-Based Catalytic Photooxidation of Alcohols through Intersystem Crossing Rate Enhancement

Korvinson, Kirill A.; Hargenrader, George N.; Stevanović, Jelena; Xie, Yun; Joseph, Jojo; Maslak, Veselin; Hadad, Christopher M.; Glusac, Ksenija D.

(Amer Chemical Soc, Washington, 2016)

TY  - JOUR
AU  - Korvinson, Kirill A.
AU  - Hargenrader, George N.
AU  - Stevanović, Jelena
AU  - Xie, Yun
AU  - Joseph, Jojo
AU  - Maslak, Veselin
AU  - Hadad, Christopher M.
AU  - Glusac, Ksenija D.
PY  - 2016
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/2315
AB  - The triplet excited-state formation efficiency in a flavin derivative was increased by the introduction of iodine into the molecular framework. The transient absorption measurements showed that the intersystem crossing rate was 1.1 X 10(10) s(-1) significantly faster than in the parent flavin compound. Furthermore, the photocatalytic efficiency of iodoflavin was evaluated using the oxidation of benzyl alcohol as a model reaction. The benzaldehyde product yields were higher when iodoflavin was used as a photocatalyst, showing that the increased triplet yield directly translates into improved photocatalysis. The iodoflavin catalyst also allowed the use of higher substrate concentrations (since the undesired electron transfer from singlet excited state was minimized), which is expected to improve the practical aspects of photocatalysis by flavins.
PB  - Amer Chemical Soc, Washington
T2  - Journal of Physical Chemistry. Part A: Molecules, Spectroscopy, Kinetics, Environment and General Th
T1  - Improved Flavin-Based Catalytic Photooxidation of Alcohols through Intersystem Crossing Rate Enhancement
VL  - 120
IS  - 37
SP  - 7294
EP  - 7300
DO  - 10.1021/acs.jpca.6b08405
UR  - Kon_3131
ER  - 
@article{
author = "Korvinson, Kirill A. and Hargenrader, George N. and Stevanović, Jelena and Xie, Yun and Joseph, Jojo and Maslak, Veselin and Hadad, Christopher M. and Glusac, Ksenija D.",
year = "2016",
abstract = "The triplet excited-state formation efficiency in a flavin derivative was increased by the introduction of iodine into the molecular framework. The transient absorption measurements showed that the intersystem crossing rate was 1.1 X 10(10) s(-1) significantly faster than in the parent flavin compound. Furthermore, the photocatalytic efficiency of iodoflavin was evaluated using the oxidation of benzyl alcohol as a model reaction. The benzaldehyde product yields were higher when iodoflavin was used as a photocatalyst, showing that the increased triplet yield directly translates into improved photocatalysis. The iodoflavin catalyst also allowed the use of higher substrate concentrations (since the undesired electron transfer from singlet excited state was minimized), which is expected to improve the practical aspects of photocatalysis by flavins.",
publisher = "Amer Chemical Soc, Washington",
journal = "Journal of Physical Chemistry. Part A: Molecules, Spectroscopy, Kinetics, Environment and General Th",
title = "Improved Flavin-Based Catalytic Photooxidation of Alcohols through Intersystem Crossing Rate Enhancement",
volume = "120",
number = "37",
pages = "7294-7300",
doi = "10.1021/acs.jpca.6b08405",
url = "Kon_3131"
}
Korvinson, K. A., Hargenrader, G. N., Stevanović, J., Xie, Y., Joseph, J., Maslak, V., Hadad, C. M.,& Glusac, K. D.. (2016). Improved Flavin-Based Catalytic Photooxidation of Alcohols through Intersystem Crossing Rate Enhancement. in Journal of Physical Chemistry. Part A: Molecules, Spectroscopy, Kinetics, Environment and General Th
Amer Chemical Soc, Washington., 120(37), 7294-7300.
https://doi.org/10.1021/acs.jpca.6b08405
Kon_3131
Korvinson KA, Hargenrader GN, Stevanović J, Xie Y, Joseph J, Maslak V, Hadad CM, Glusac KD. Improved Flavin-Based Catalytic Photooxidation of Alcohols through Intersystem Crossing Rate Enhancement. in Journal of Physical Chemistry. Part A: Molecules, Spectroscopy, Kinetics, Environment and General Th. 2016;120(37):7294-7300.
doi:10.1021/acs.jpca.6b08405
Kon_3131 .
Korvinson, Kirill A., Hargenrader, George N., Stevanović, Jelena, Xie, Yun, Joseph, Jojo, Maslak, Veselin, Hadad, Christopher M., Glusac, Ksenija D., "Improved Flavin-Based Catalytic Photooxidation of Alcohols through Intersystem Crossing Rate Enhancement" in Journal of Physical Chemistry. Part A: Molecules, Spectroscopy, Kinetics, Environment and General Th, 120, no. 37 (2016):7294-7300,
https://doi.org/10.1021/acs.jpca.6b08405 .,
Kon_3131 .
27
22
24