Relić, Dubravka

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Authority KeyName Variants
orcid::0000-0002-0876-4561
  • Relić, Dubravka (71)
Projects
The study of physicochemical and biochemical processes in living environment that have impacts on pollution and the investigation of possibilities for minimizing the consequences Studying climate change and its influence on environment: impacts, adaptation and mitigation
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200168 (University of Belgrade, Faculty of Chemistry) Structure-properties relationships of natural and synthetic molecules and their metal complexes
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200017 (University of Belgrade, Institute of Nuclear Sciences 'Vinča', Belgrade-Vinča) Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200116 (University of Belgrade, Faculty of Agriculture)
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200288 (Innovation Center of the Faculty of Chemistry) Osmotic dehydration of food - energy and ecological aspects of sustainable production
OTKA [K119269] Bilateral contract between Institute of Physics and Institute for Medical Research and Occupational Health (337-00-205/2019–09/22).
Croatian Science Foundation, Croatia (Project OPENTOX, No. 8366). ERASMUS + programme
European Commission Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200007 (University of Belgrade, Institute for Biological Research 'Siniša Stanković')
Improvement and development of hygienic and technological procedures in production of animal originating foodstuffs with the aim of producing high-quality and safe products competetive on the global market Institute of Physics Belgrade (document number: 0801–116/1).
Joint Institute for Nuclear Research, Dubna, Russia Ministry of Education and Science of the Republic of Serbia (contract number: 451- 03-1338/2020–14) for postdoctoral investigation for Dr. Tijana Milićević.
Ministry of Education, Science and Technological Development of Serbiа (No. 337–00-107/2019–09/17) Ministry of Education, Science, Research and Sport of the Slovak Republic VEGA 1/0326/18
Ministry of Education, Science, Research and Sport of the Slovak Republic VEGA 1/0591/18 Project “Persistent Organic Pollutants - Environmental Impact Assessment and Stability of Human Genetic Material” at Institute for Medical Research and Occupational Health- Zagreb.
Slovak Research and Development Agency (No. SK-SRB-18-0038) Bilateral contract between Institute of Physics and Institute for Medical Research.
Croatian Science Foundation (Project OPENTOX, No. 8366), institutional financing 2018–2021 Project “Persistent Organic Pollutants – Environmental Impact Assessment and Stability of Human Genetic Material”. Grant for postdoctoral investigation for Dr. Tijana Milićević (contract No. 451-03- 1338/2020-14).
PFAStwin - Twinning to address the PFAS challenge in Serbia Meteorological extremes and climatic change in Serbia
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200026 (University of Belgrade, Institute of Chemistry, Technology and Metallurgy - IChTM) Geohemijska ispitivanja u funkciji pronalaženja novih ležišta fosilnih goriva i zaštite životne sredine

Author's Bibliography

Health risk assessment of heavy metals in soil, plant, and water samples near “Gacko” power plant, in Bosnia and Herzegovina

Antunović, Vesna; Blagojević, Dragana; Baošić, Rada; Relić, Dubravka; Lolić, Aleksandar

(Springer, 2023)

TY  - JOUR
AU  - Antunović, Vesna
AU  - Blagojević, Dragana
AU  - Baošić, Rada
AU  - Relić, Dubravka
AU  - Lolić, Aleksandar
PY  - 2023
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/6252
AB  - This study assesses heavy metal content in soil, water, and plant material from sites located around the lignite mine and the power plant “Gacko”, Bosnia and Herzegovina. The samples were collected, prepared, and analyzed for heavy metals content using the flame atomic absorption spectrophotometer. Samples were analyzed for cadmium, lead, copper, zinc, manganese, and iron. To identify the relationship among the metals in samples and their possible sources, Pearson’s correlation and principal component analysis were performed. Health risk assessment was applied to establish potential health risks posed to humans caused by contaminants in different environmental compartments. The results of our analyses show that most soil samples contain copper, and one of those samples had a copper concentration of more than 70 µg/g, which is a critical upper value for agricultural use. In the soil samples that were analyzed, cadmium was also detected, and its concentration was greater than 2 µg/g. Lead, on the other hand, had a concentration that was higher than the maximum permissible for unpolluted soils in 40% of the soil samples that were analyzed. Lead and cadmium concentrations in surface waters mostly contribute to a non-carcinogenic risk in the scenario of recreational swimming exposure. The presence of Cd, a highly toxic element in water, may be explained by the leaching of artificial fertilizers used in the study area, whereas Pb’s origin may be geological. The results of this study recommend routine heavy metal monitoring in samples of soil, water, and plants from the examined area so that, if metal concentrations continue increasing, remedial action should be advised to prevent accumulation in the food chain.
PB  - Springer
T2  - Environmental Monitoring and Assessment
T1  - Health risk assessment of heavy metals in soil, plant, and water samples near “Gacko” power plant, in Bosnia and Herzegovina
VL  - 195
IS  - 5
SP  - 596
DO  - 10.1007/s10661-023-11232-7
ER  - 
@article{
author = "Antunović, Vesna and Blagojević, Dragana and Baošić, Rada and Relić, Dubravka and Lolić, Aleksandar",
year = "2023",
abstract = "This study assesses heavy metal content in soil, water, and plant material from sites located around the lignite mine and the power plant “Gacko”, Bosnia and Herzegovina. The samples were collected, prepared, and analyzed for heavy metals content using the flame atomic absorption spectrophotometer. Samples were analyzed for cadmium, lead, copper, zinc, manganese, and iron. To identify the relationship among the metals in samples and their possible sources, Pearson’s correlation and principal component analysis were performed. Health risk assessment was applied to establish potential health risks posed to humans caused by contaminants in different environmental compartments. The results of our analyses show that most soil samples contain copper, and one of those samples had a copper concentration of more than 70 µg/g, which is a critical upper value for agricultural use. In the soil samples that were analyzed, cadmium was also detected, and its concentration was greater than 2 µg/g. Lead, on the other hand, had a concentration that was higher than the maximum permissible for unpolluted soils in 40% of the soil samples that were analyzed. Lead and cadmium concentrations in surface waters mostly contribute to a non-carcinogenic risk in the scenario of recreational swimming exposure. The presence of Cd, a highly toxic element in water, may be explained by the leaching of artificial fertilizers used in the study area, whereas Pb’s origin may be geological. The results of this study recommend routine heavy metal monitoring in samples of soil, water, and plants from the examined area so that, if metal concentrations continue increasing, remedial action should be advised to prevent accumulation in the food chain.",
publisher = "Springer",
journal = "Environmental Monitoring and Assessment",
title = "Health risk assessment of heavy metals in soil, plant, and water samples near “Gacko” power plant, in Bosnia and Herzegovina",
volume = "195",
number = "5",
pages = "596",
doi = "10.1007/s10661-023-11232-7"
}
Antunović, V., Blagojević, D., Baošić, R., Relić, D.,& Lolić, A.. (2023). Health risk assessment of heavy metals in soil, plant, and water samples near “Gacko” power plant, in Bosnia and Herzegovina. in Environmental Monitoring and Assessment
Springer., 195(5), 596.
https://doi.org/10.1007/s10661-023-11232-7
Antunović V, Blagojević D, Baošić R, Relić D, Lolić A. Health risk assessment of heavy metals in soil, plant, and water samples near “Gacko” power plant, in Bosnia and Herzegovina. in Environmental Monitoring and Assessment. 2023;195(5):596.
doi:10.1007/s10661-023-11232-7 .
Antunović, Vesna, Blagojević, Dragana, Baošić, Rada, Relić, Dubravka, Lolić, Aleksandar, "Health risk assessment of heavy metals in soil, plant, and water samples near “Gacko” power plant, in Bosnia and Herzegovina" in Environmental Monitoring and Assessment, 195, no. 5 (2023):596,
https://doi.org/10.1007/s10661-023-11232-7 . .
3
3
2

In Silico Guided Design of Metal/Semiconductor Photocatalysts: A Case of Cu-Modified TiO2 for Ciprofloxacin Degradation

Kovačević, Marija; Živković, Sanja; Ognjanović, Miloš; Momčilović, Miloš; Relić, Dubravka; Vasić Anićijević, Dragana

(2023)

TY  - JOUR
AU  - Kovačević, Marija
AU  - Živković, Sanja
AU  - Ognjanović, Miloš
AU  - Momčilović, Miloš
AU  - Relić, Dubravka
AU  - Vasić Anićijević, Dragana
PY  - 2023
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/6328
AB  - (1) Background: An increasing use of pharmaceutics imposes a need for the permanent development of efficient strategies, including the tailoring of highly specific new materials for their removal from the environment. Photocatalytic degradation has been the subject of increasing interest of the researchers in the field. (2) Methods: This paper is focused on the investigation of the possibility to deposit a thin metal layer on a TiO2 surface and study its photocatalytic performance for the degradation of ciprofloxacin using a combination of theoretical and experimental methods. (3) Results: Based on the extensive DFT screening of 24 d-metals’ adhesion on TiO2, Cu was selected for further work, due to the satisfactory expected stability and good availability. The (Cu)TiO2 was successfully synthesized and characterized with XRD, SEM+EDS and UV-Vis spectrophotometry. The uniformly distributed copper on the TiO2 surface corresponds to the binding on high-affinity oxygen-rich sites, as proposed with DFT calculations. The photocatalytic degradation rate of ciprofloxacin was improved by about a factor of 1.5 compared to the bare non-modified TiO2. (4) Conclusions: The observed result was ascribed to the ability of adsorbed Cu to impede the agglomeration of TiO2 and increase the active catalytic area, and bandgap narrowing predicted with DFT calculations.
T2  - Materials
T1  - In Silico Guided Design of Metal/Semiconductor Photocatalysts: A Case of Cu-Modified TiO2 for Ciprofloxacin Degradation
VL  - 16
IS  - 16
SP  - 5708
DO  - 10.3390/ma16165708
ER  - 
@article{
author = "Kovačević, Marija and Živković, Sanja and Ognjanović, Miloš and Momčilović, Miloš and Relić, Dubravka and Vasić Anićijević, Dragana",
year = "2023",
abstract = "(1) Background: An increasing use of pharmaceutics imposes a need for the permanent development of efficient strategies, including the tailoring of highly specific new materials for their removal from the environment. Photocatalytic degradation has been the subject of increasing interest of the researchers in the field. (2) Methods: This paper is focused on the investigation of the possibility to deposit a thin metal layer on a TiO2 surface and study its photocatalytic performance for the degradation of ciprofloxacin using a combination of theoretical and experimental methods. (3) Results: Based on the extensive DFT screening of 24 d-metals’ adhesion on TiO2, Cu was selected for further work, due to the satisfactory expected stability and good availability. The (Cu)TiO2 was successfully synthesized and characterized with XRD, SEM+EDS and UV-Vis spectrophotometry. The uniformly distributed copper on the TiO2 surface corresponds to the binding on high-affinity oxygen-rich sites, as proposed with DFT calculations. The photocatalytic degradation rate of ciprofloxacin was improved by about a factor of 1.5 compared to the bare non-modified TiO2. (4) Conclusions: The observed result was ascribed to the ability of adsorbed Cu to impede the agglomeration of TiO2 and increase the active catalytic area, and bandgap narrowing predicted with DFT calculations.",
journal = "Materials",
title = "In Silico Guided Design of Metal/Semiconductor Photocatalysts: A Case of Cu-Modified TiO2 for Ciprofloxacin Degradation",
volume = "16",
number = "16",
pages = "5708",
doi = "10.3390/ma16165708"
}
Kovačević, M., Živković, S., Ognjanović, M., Momčilović, M., Relić, D.,& Vasić Anićijević, D.. (2023). In Silico Guided Design of Metal/Semiconductor Photocatalysts: A Case of Cu-Modified TiO2 for Ciprofloxacin Degradation. in Materials, 16(16), 5708.
https://doi.org/10.3390/ma16165708
Kovačević M, Živković S, Ognjanović M, Momčilović M, Relić D, Vasić Anićijević D. In Silico Guided Design of Metal/Semiconductor Photocatalysts: A Case of Cu-Modified TiO2 for Ciprofloxacin Degradation. in Materials. 2023;16(16):5708.
doi:10.3390/ma16165708 .
Kovačević, Marija, Živković, Sanja, Ognjanović, Miloš, Momčilović, Miloš, Relić, Dubravka, Vasić Anićijević, Dragana, "In Silico Guided Design of Metal/Semiconductor Photocatalysts: A Case of Cu-Modified TiO2 for Ciprofloxacin Degradation" in Materials, 16, no. 16 (2023):5708,
https://doi.org/10.3390/ma16165708 . .
1
1

Persistent organic pollutants in Croatian breast milk: An overview of pollutant levels and infant health risk assessment from 1976 to the present

Herceg Romanić, Snježana; Milićević, Tijana; Jovanović, Gordana; Matek Sarić, Marijana; Mendaš, Gordana; Fingler, Sanja; Jakšić, Goran; Popović, Aleksandar R.; Relić, Dubravka

(Elsevier, 2023)

TY  - JOUR
AU  - Herceg Romanić, Snježana
AU  - Milićević, Tijana
AU  - Jovanović, Gordana
AU  - Matek Sarić, Marijana
AU  - Mendaš, Gordana
AU  - Fingler, Sanja
AU  - Jakšić, Goran
AU  - Popović, Aleksandar R.
AU  - Relić, Dubravka
PY  - 2023
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/6323
AB  - This review article summarizes our research of persistent organic pollutants (POPs) in human milk from Croatian mothers over the last few decades. Our studies make up the bulk of all POPs research in human milk in Croatia and show a state-of-the art in the research area. The first investigations were made in 1970's. Aim of our review article is to document the comprehensive results over several decades as the best tool to: 1.) contribute to understanding of POPs and their potential health risks, 2.) evaluate effectiveness of legislative bans and restrictions on human exposure to POPs in Croatia, and 3.) to suggest further actions. In our review we discuss: 1.) Human milk between 2011 and 2014 - evaluation of interrelations of organochlorine pesticides (OCP) and polychlorinated biphenyls (PCB) in human milk and their association with the mother's age and parity using artificial intelligence methods; and our yet unpublished research data on health risks for infants assessed through daily PCB and OCP intake. 2.) Time trends of PCB and OCP in human milk between 1976 and 2014. 3.) polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofuran (PCDD/F) in human milk in 2000., and yet unpublished data on PCDD/F and polybrominated diphenyl ethers (PBDE) in 2014.
PB  - Elsevier
T2  - Food and Chemical Toxicology
T1  - Persistent organic pollutants in Croatian breast milk: An overview of pollutant levels and infant health risk assessment from 1976 to the present
VL  - 179
SP  - 113990
DO  - 10.1016/j.fct.2023.113990
ER  - 
@article{
author = "Herceg Romanić, Snježana and Milićević, Tijana and Jovanović, Gordana and Matek Sarić, Marijana and Mendaš, Gordana and Fingler, Sanja and Jakšić, Goran and Popović, Aleksandar R. and Relić, Dubravka",
year = "2023",
abstract = "This review article summarizes our research of persistent organic pollutants (POPs) in human milk from Croatian mothers over the last few decades. Our studies make up the bulk of all POPs research in human milk in Croatia and show a state-of-the art in the research area. The first investigations were made in 1970's. Aim of our review article is to document the comprehensive results over several decades as the best tool to: 1.) contribute to understanding of POPs and their potential health risks, 2.) evaluate effectiveness of legislative bans and restrictions on human exposure to POPs in Croatia, and 3.) to suggest further actions. In our review we discuss: 1.) Human milk between 2011 and 2014 - evaluation of interrelations of organochlorine pesticides (OCP) and polychlorinated biphenyls (PCB) in human milk and their association with the mother's age and parity using artificial intelligence methods; and our yet unpublished research data on health risks for infants assessed through daily PCB and OCP intake. 2.) Time trends of PCB and OCP in human milk between 1976 and 2014. 3.) polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofuran (PCDD/F) in human milk in 2000., and yet unpublished data on PCDD/F and polybrominated diphenyl ethers (PBDE) in 2014.",
publisher = "Elsevier",
journal = "Food and Chemical Toxicology",
title = "Persistent organic pollutants in Croatian breast milk: An overview of pollutant levels and infant health risk assessment from 1976 to the present",
volume = "179",
pages = "113990",
doi = "10.1016/j.fct.2023.113990"
}
Herceg Romanić, S., Milićević, T., Jovanović, G., Matek Sarić, M., Mendaš, G., Fingler, S., Jakšić, G., Popović, A. R.,& Relić, D.. (2023). Persistent organic pollutants in Croatian breast milk: An overview of pollutant levels and infant health risk assessment from 1976 to the present. in Food and Chemical Toxicology
Elsevier., 179, 113990.
https://doi.org/10.1016/j.fct.2023.113990
Herceg Romanić S, Milićević T, Jovanović G, Matek Sarić M, Mendaš G, Fingler S, Jakšić G, Popović AR, Relić D. Persistent organic pollutants in Croatian breast milk: An overview of pollutant levels and infant health risk assessment from 1976 to the present. in Food and Chemical Toxicology. 2023;179:113990.
doi:10.1016/j.fct.2023.113990 .
Herceg Romanić, Snježana, Milićević, Tijana, Jovanović, Gordana, Matek Sarić, Marijana, Mendaš, Gordana, Fingler, Sanja, Jakšić, Goran, Popović, Aleksandar R., Relić, Dubravka, "Persistent organic pollutants in Croatian breast milk: An overview of pollutant levels and infant health risk assessment from 1976 to the present" in Food and Chemical Toxicology, 179 (2023):113990,
https://doi.org/10.1016/j.fct.2023.113990 . .

Non-destructive techniques for the determination of magnetic particle and element contents in grapevine leaves and soil as an eco-sustainable tool for environmental pollution assessment in the agricultural areas

Milićević, Tijana; Relić, Dubravka; Aničić Urošević, Mira; Castanheiro, Ana; Roganović, Jovana; Samson, Roeland; Popović, Aleksandar R.

(Springer Science and Business Media Deutschland GmbH, 2023)

TY  - JOUR
AU  - Milićević, Tijana
AU  - Relić, Dubravka
AU  -  Aničić Urošević, Mira
AU  - Castanheiro, Ana
AU  - Roganović, Jovana
AU  - Samson, Roeland
AU  - Popović, Aleksandar R.
PY  - 2023
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/6267
AB  - The concentration of magnetic particulate matter (PM) on the leaf surface (an indicator of current pollution) and topsoil (an indicator of magnetic PMs which have geogenic natural signal or historical pollution origin) was assessed in agricultural areas (conventional and organic vineyards). The main aim of this study was to explore whether magnetic parameters such as saturation isothermal remanent magnetization (SIRM) and mass-specific magnetic susceptibility (χ) can be a proxy for magnetic particulate matter (PM) pollution and associated potentially toxic elements (PTEs) in agricultural areas. Besides, wavelength dispersive X-ray fluorescence spectroscopy (WD-XRF) was investigated as a screening method for total PTE content in soil and leaf samples. Both magnetic parameters (SIRM and χ) pinpoint soil pollution, while SIRM was more suitable for evaluating magnetic PM accumulated on leaves. The values of both magnetic parameters were significantly (p < 0.01) correlated within the same type of sample (soil-soil or leaf-leaf), but not between different matrixes (soil-leaf). Differences between magnetic particles’ grain sizes among vegetation seasons in vineyards were obtained by observing the SIRM/χ ratio. WD-XRF was revealed to be an appropriate screening method for soil and leaf total element contents in agricultural ambient. For a more precise application of WD-XRF leaf measurements, specific calibration using a similar matrix to plant material is required. In parallel, measurements of SIRM, χ, and element content (by WD-XRF) can be recommended as user-friendly, fast, and eco-sustainable techniques for determining magnetic PM and PTE pollution hotspots in agricultural ambient.
PB  - Springer Science and Business Media Deutschland GmbH
T2  - Environmental Monitoring and Assessment
T1  - Non-destructive techniques for the determination of magnetic particle and element contents in grapevine leaves and soil as an eco-sustainable tool for environmental pollution assessment in the agricultural areas
VL  - 195
IS  - 7
SP  - 858
DO  - 10.1007/s10661-023-11402-7
ER  - 
@article{
author = "Milićević, Tijana and Relić, Dubravka and  Aničić Urošević, Mira and Castanheiro, Ana and Roganović, Jovana and Samson, Roeland and Popović, Aleksandar R.",
year = "2023",
abstract = "The concentration of magnetic particulate matter (PM) on the leaf surface (an indicator of current pollution) and topsoil (an indicator of magnetic PMs which have geogenic natural signal or historical pollution origin) was assessed in agricultural areas (conventional and organic vineyards). The main aim of this study was to explore whether magnetic parameters such as saturation isothermal remanent magnetization (SIRM) and mass-specific magnetic susceptibility (χ) can be a proxy for magnetic particulate matter (PM) pollution and associated potentially toxic elements (PTEs) in agricultural areas. Besides, wavelength dispersive X-ray fluorescence spectroscopy (WD-XRF) was investigated as a screening method for total PTE content in soil and leaf samples. Both magnetic parameters (SIRM and χ) pinpoint soil pollution, while SIRM was more suitable for evaluating magnetic PM accumulated on leaves. The values of both magnetic parameters were significantly (p < 0.01) correlated within the same type of sample (soil-soil or leaf-leaf), but not between different matrixes (soil-leaf). Differences between magnetic particles’ grain sizes among vegetation seasons in vineyards were obtained by observing the SIRM/χ ratio. WD-XRF was revealed to be an appropriate screening method for soil and leaf total element contents in agricultural ambient. For a more precise application of WD-XRF leaf measurements, specific calibration using a similar matrix to plant material is required. In parallel, measurements of SIRM, χ, and element content (by WD-XRF) can be recommended as user-friendly, fast, and eco-sustainable techniques for determining magnetic PM and PTE pollution hotspots in agricultural ambient.",
publisher = "Springer Science and Business Media Deutschland GmbH",
journal = "Environmental Monitoring and Assessment",
title = "Non-destructive techniques for the determination of magnetic particle and element contents in grapevine leaves and soil as an eco-sustainable tool for environmental pollution assessment in the agricultural areas",
volume = "195",
number = "7",
pages = "858",
doi = "10.1007/s10661-023-11402-7"
}
Milićević, T., Relić, D.,  Aničić Urošević, M., Castanheiro, A., Roganović, J., Samson, R.,& Popović, A. R.. (2023). Non-destructive techniques for the determination of magnetic particle and element contents in grapevine leaves and soil as an eco-sustainable tool for environmental pollution assessment in the agricultural areas. in Environmental Monitoring and Assessment
Springer Science and Business Media Deutschland GmbH., 195(7), 858.
https://doi.org/10.1007/s10661-023-11402-7
Milićević T, Relić D,  Aničić Urošević M, Castanheiro A, Roganović J, Samson R, Popović AR. Non-destructive techniques for the determination of magnetic particle and element contents in grapevine leaves and soil as an eco-sustainable tool for environmental pollution assessment in the agricultural areas. in Environmental Monitoring and Assessment. 2023;195(7):858.
doi:10.1007/s10661-023-11402-7 .
Milićević, Tijana, Relić, Dubravka,  Aničić Urošević, Mira, Castanheiro, Ana, Roganović, Jovana, Samson, Roeland, Popović, Aleksandar R., "Non-destructive techniques for the determination of magnetic particle and element contents in grapevine leaves and soil as an eco-sustainable tool for environmental pollution assessment in the agricultural areas" in Environmental Monitoring and Assessment, 195, no. 7 (2023):858,
https://doi.org/10.1007/s10661-023-11402-7 . .

Scientifc Strategy for PFAS Analysis and Bioremediation at UBFC (2023-2033)

Beškoski, Vladimir; Lješević, Marija; Lončarević, Branka; Božić, Tatjana T.; Relić, Dubravka; Vujisić, Ljubodrag V.; Gruden-Pavlović, Maja; Lugonja, Nikoleta; Jiménez, Begoña; Colomer Vidal, Pere; Muñoz Arnanz, Juan; Battaglia, Fabienne; Crampon, Marc

(University of Belgrade – Faculty of Chemistry, 2023)

TY  - GEN
AU  - Beškoski, Vladimir
AU  - Lješević, Marija
AU  - Lončarević, Branka
AU  - Božić, Tatjana T.
AU  - Relić, Dubravka
AU  - Vujisić, Ljubodrag V.
AU  - Gruden-Pavlović, Maja
AU  - Lugonja, Nikoleta
AU  - Jiménez, Begoña
AU  - Colomer Vidal, Pere
AU  - Muñoz Arnanz, Juan
AU  - Battaglia, Fabienne
AU  - Crampon, Marc
PY  - 2023
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/6048
AB  - Per- and polyfluoroalkyl substances (PFAS) are a group of synthetic chemicals that have been widely used in various industrial and consumer products due to their unique properties, such as oil and water repellency, thermal stability, and durability. However, the persistence and mobility of these chemicals in the environment have raised concerns about their potential adverse effects on human health and the environment. PFAS have been detected on a global scale in various environmental media, such as soil, water, air, and biota. As a country undergoing economic development and transition, Serbia faces the challenge of managing and addressing the PFAS contamination in its environment. This challenge requires a comprehensive and science-based strategy that can effectively reduce the exposure and risks of PFAS to human health and the environment. This document aims to provide a scientific strategy for solving the PFAS challenge in Serbia. Firstly, it is important to acknowledge that PFAS are persistent and bioaccumulative in the environment, which means that they do not break down easily and can accumulate in the food chain, posing a long-term risk to human health and the environment. Therefore, a precautionary approach is necessary to minimize the exposure and risks of PFAS. International experience and cooperation are very important for developing an effective scientifc strategy for addressing the PFAS challenge in Serbia. PFAS are a global issue, and many countries have already implemented measures to manage and reduce the exposure and risks of PFAS. Therefore, it is important to draw on international experience and best practices when developing the strategy for Serbia. International experience can provide valuable insights into the sources, pathways, and fate of PFAS, as well as the e"ectiveness of various risk management measures. For example, the United States, Canada, and some European countries have established regulatory frameworks for PFAS, which can serve as a model for Serbia. Other countries have implemented remediation measures for contaminated sites, which can provide valuable insights for selecting appropriate remediation technologies in Serbia. Moreover, international experience can provide access to the latest scientific knowledge, methods, and technologies for assessing and managing PFAS contamination. For example, international organizations such as the United Nations Environment Programme (UNEP) and the Organization for Economic Co-operation and Development (OECD) have developed guidance documents and tools for assessing and managing PFAS contamination. The scientific strategy for solving the PFAS challenge in Serbia is based on a thorough understanding of the sources, pathways, and fate of PFAS in the environment. It is also based on a comprehensive and systematic approach, including risk assessment, monitoring, regulation, remediation, and communication. This strategy is tailored to the specific context and needs of Serbia. It is based on the latest scientifc knowledge and practical experience from other countries and regions, focusing on the European Union, USA, China and Japan. The cultural, social, economic, and political factors can affect the implementation and effectiveness of the strategy, and therefore, the strategy is developed through a collaborative and participatory process involving stakeholders from different sectors and levels. The international experience provided helpful guidance and lessons learned, but ultimately, the strategy is based on local knowledge, priorities, and capacities. By implementing this strategy, we aim to contribute to that Serbia can protect its citizens and environment from the potential harm of PFAS and achieve sustainable development.
PB  - University of Belgrade – Faculty of Chemistry
T1  - Scientifc Strategy for PFAS Analysis and Bioremediation at UBFC  (2023-2033)
UR  - https://hdl.handle.net/21.15107/rcub_cherry_6048
ER  - 
@misc{
author = "Beškoski, Vladimir and Lješević, Marija and Lončarević, Branka and Božić, Tatjana T. and Relić, Dubravka and Vujisić, Ljubodrag V. and Gruden-Pavlović, Maja and Lugonja, Nikoleta and Jiménez, Begoña and Colomer Vidal, Pere and Muñoz Arnanz, Juan and Battaglia, Fabienne and Crampon, Marc",
year = "2023",
abstract = "Per- and polyfluoroalkyl substances (PFAS) are a group of synthetic chemicals that have been widely used in various industrial and consumer products due to their unique properties, such as oil and water repellency, thermal stability, and durability. However, the persistence and mobility of these chemicals in the environment have raised concerns about their potential adverse effects on human health and the environment. PFAS have been detected on a global scale in various environmental media, such as soil, water, air, and biota. As a country undergoing economic development and transition, Serbia faces the challenge of managing and addressing the PFAS contamination in its environment. This challenge requires a comprehensive and science-based strategy that can effectively reduce the exposure and risks of PFAS to human health and the environment. This document aims to provide a scientific strategy for solving the PFAS challenge in Serbia. Firstly, it is important to acknowledge that PFAS are persistent and bioaccumulative in the environment, which means that they do not break down easily and can accumulate in the food chain, posing a long-term risk to human health and the environment. Therefore, a precautionary approach is necessary to minimize the exposure and risks of PFAS. International experience and cooperation are very important for developing an effective scientifc strategy for addressing the PFAS challenge in Serbia. PFAS are a global issue, and many countries have already implemented measures to manage and reduce the exposure and risks of PFAS. Therefore, it is important to draw on international experience and best practices when developing the strategy for Serbia. International experience can provide valuable insights into the sources, pathways, and fate of PFAS, as well as the e"ectiveness of various risk management measures. For example, the United States, Canada, and some European countries have established regulatory frameworks for PFAS, which can serve as a model for Serbia. Other countries have implemented remediation measures for contaminated sites, which can provide valuable insights for selecting appropriate remediation technologies in Serbia. Moreover, international experience can provide access to the latest scientific knowledge, methods, and technologies for assessing and managing PFAS contamination. For example, international organizations such as the United Nations Environment Programme (UNEP) and the Organization for Economic Co-operation and Development (OECD) have developed guidance documents and tools for assessing and managing PFAS contamination. The scientific strategy for solving the PFAS challenge in Serbia is based on a thorough understanding of the sources, pathways, and fate of PFAS in the environment. It is also based on a comprehensive and systematic approach, including risk assessment, monitoring, regulation, remediation, and communication. This strategy is tailored to the specific context and needs of Serbia. It is based on the latest scientifc knowledge and practical experience from other countries and regions, focusing on the European Union, USA, China and Japan. The cultural, social, economic, and political factors can affect the implementation and effectiveness of the strategy, and therefore, the strategy is developed through a collaborative and participatory process involving stakeholders from different sectors and levels. The international experience provided helpful guidance and lessons learned, but ultimately, the strategy is based on local knowledge, priorities, and capacities. By implementing this strategy, we aim to contribute to that Serbia can protect its citizens and environment from the potential harm of PFAS and achieve sustainable development.",
publisher = "University of Belgrade – Faculty of Chemistry",
title = "Scientifc Strategy for PFAS Analysis and Bioremediation at UBFC  (2023-2033)",
url = "https://hdl.handle.net/21.15107/rcub_cherry_6048"
}
Beškoski, V., Lješević, M., Lončarević, B., Božić, T. T., Relić, D., Vujisić, L. V., Gruden-Pavlović, M., Lugonja, N., Jiménez, B., Colomer Vidal, P., Muñoz Arnanz, J., Battaglia, F.,& Crampon, M.. (2023). Scientifc Strategy for PFAS Analysis and Bioremediation at UBFC  (2023-2033). 
University of Belgrade – Faculty of Chemistry..
https://hdl.handle.net/21.15107/rcub_cherry_6048
Beškoski V, Lješević M, Lončarević B, Božić TT, Relić D, Vujisić LV, Gruden-Pavlović M, Lugonja N, Jiménez B, Colomer Vidal P, Muñoz Arnanz J, Battaglia F, Crampon M. Scientifc Strategy for PFAS Analysis and Bioremediation at UBFC  (2023-2033). 2023;.
https://hdl.handle.net/21.15107/rcub_cherry_6048 .
Beškoski, Vladimir, Lješević, Marija, Lončarević, Branka, Božić, Tatjana T., Relić, Dubravka, Vujisić, Ljubodrag V., Gruden-Pavlović, Maja, Lugonja, Nikoleta, Jiménez, Begoña, Colomer Vidal, Pere, Muñoz Arnanz, Juan, Battaglia, Fabienne, Crampon, Marc, "Scientifc Strategy for PFAS Analysis and Bioremediation at UBFC  (2023-2033)" (2023),
https://hdl.handle.net/21.15107/rcub_cherry_6048 .

Degradation of bisphenol A on SnO2-MWCNT electrode using electrochemical oxidation

Simić, Marija; Savić, Branislava; Ognjanović, Miloš; Stanković, Dalibor; Relić, Dubravka; Aćimović, Danka; Brdarić, Tanja

(Elsevier, 2023)

TY  - JOUR
AU  - Simić, Marija
AU  - Savić, Branislava
AU  - Ognjanović, Miloš
AU  - Stanković, Dalibor
AU  - Relić, Dubravka
AU  - Aćimović, Danka
AU  - Brdarić, Tanja
PY  - 2023
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5693
AB  - Bisphenol A (BPA) is an organic pollutant that is widely spread in waterbody with effluents as a result of its extensive use in the plastics industry. It posses to the class of compounds that are endocrine disruptors and has a great negative impact on living organisms. Therefore, the progress in development of green technology for BPA removal from the aquatic media is crucial for environmental protection. This paper presents BPA removal by electrochemical oxidation on SnO2-MWCNT (tin dioxide-multi walled carbon nanotube) nanocomposite anode. The nanocomposite was structural and morphological characterized by X-ray powder diffraction and transmission electron microscopy. Electrochemical properties of the SnO2-MWCNT anode were investigated using cyclic voltammetry, linear sweep voltammetry and electrical impedance spectroscopy. The electrochemical behavior of anodes toward BPA in sodium sulfate solutions has shown that BPA is oxidized by indirectly mechanism via hydroxyl radicals (verified by quenching tests). Electrolysis of BPA has been done in galvanostatic regime at current densities 2.5, 5.0, 10.0, 15.0 and 20.0 mA cm−2 in 0.1 M sodium sulfate supported electrolyte pH 4.0. Complete degradation of BPA was accomplished after 5 h of electrolysis at a current density of 20 mA cm−2. The proposed electrochemical technology using a low-cost SnO2-MWCNT electrode is promising for wastewater BPA removal.
PB  - Elsevier
T2  - Journal of Water Process Engineering
T1  - Degradation of bisphenol A on SnO2-MWCNT electrode using electrochemical oxidation
VL  - 51
SP  - 103416
DO  - 10.1016/j.jwpe.2022.103416
ER  - 
@article{
author = "Simić, Marija and Savić, Branislava and Ognjanović, Miloš and Stanković, Dalibor and Relić, Dubravka and Aćimović, Danka and Brdarić, Tanja",
year = "2023",
abstract = "Bisphenol A (BPA) is an organic pollutant that is widely spread in waterbody with effluents as a result of its extensive use in the plastics industry. It posses to the class of compounds that are endocrine disruptors and has a great negative impact on living organisms. Therefore, the progress in development of green technology for BPA removal from the aquatic media is crucial for environmental protection. This paper presents BPA removal by electrochemical oxidation on SnO2-MWCNT (tin dioxide-multi walled carbon nanotube) nanocomposite anode. The nanocomposite was structural and morphological characterized by X-ray powder diffraction and transmission electron microscopy. Electrochemical properties of the SnO2-MWCNT anode were investigated using cyclic voltammetry, linear sweep voltammetry and electrical impedance spectroscopy. The electrochemical behavior of anodes toward BPA in sodium sulfate solutions has shown that BPA is oxidized by indirectly mechanism via hydroxyl radicals (verified by quenching tests). Electrolysis of BPA has been done in galvanostatic regime at current densities 2.5, 5.0, 10.0, 15.0 and 20.0 mA cm−2 in 0.1 M sodium sulfate supported electrolyte pH 4.0. Complete degradation of BPA was accomplished after 5 h of electrolysis at a current density of 20 mA cm−2. The proposed electrochemical technology using a low-cost SnO2-MWCNT electrode is promising for wastewater BPA removal.",
publisher = "Elsevier",
journal = "Journal of Water Process Engineering",
title = "Degradation of bisphenol A on SnO2-MWCNT electrode using electrochemical oxidation",
volume = "51",
pages = "103416",
doi = "10.1016/j.jwpe.2022.103416"
}
Simić, M., Savić, B., Ognjanović, M., Stanković, D., Relić, D., Aćimović, D.,& Brdarić, T.. (2023). Degradation of bisphenol A on SnO2-MWCNT electrode using electrochemical oxidation. in Journal of Water Process Engineering
Elsevier., 51, 103416.
https://doi.org/10.1016/j.jwpe.2022.103416
Simić M, Savić B, Ognjanović M, Stanković D, Relić D, Aćimović D, Brdarić T. Degradation of bisphenol A on SnO2-MWCNT electrode using electrochemical oxidation. in Journal of Water Process Engineering. 2023;51:103416.
doi:10.1016/j.jwpe.2022.103416 .
Simić, Marija, Savić, Branislava, Ognjanović, Miloš, Stanković, Dalibor, Relić, Dubravka, Aćimović, Danka, Brdarić, Tanja, "Degradation of bisphenol A on SnO2-MWCNT electrode using electrochemical oxidation" in Journal of Water Process Engineering, 51 (2023):103416,
https://doi.org/10.1016/j.jwpe.2022.103416 . .
7
4

To Professor Petar Pfendt, In calidum, et plurium retributivus memoriae: FTIR-ATR analysis of post stamps of the Principality of Serbia issued in 1866 and 1868 and their forgeries

Popović, Aleksandar R.; Anđelković, Boban D.; Đorđević, Dragana S.; Sakan, Sanja M.; Vujisić, Ljubodrag V.; Veličković, Sava; Relić, Dubravka

(2022)

TY  - JOUR
AU  - Popović, Aleksandar R.
AU  - Anđelković, Boban D.
AU  - Đorđević, Dragana S.
AU  - Sakan, Sanja M.
AU  - Vujisić, Ljubodrag V.
AU  - Veličković, Sava
AU  - Relić, Dubravka
PY  - 2022
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/4942
AB  - In order to further define the potential use of FTIR-ATR spectroscopy, as a non-destructive and reliable technique, for the analysis of the characteristics of post stamps, certified originals of the Principality of Serbia stamps (“Prince Michael issues”) issued in 1866 and 1868 as well as their forgeries were ana­lyzed. Spectra enabling the comparison of the paper, dye and glue of stamps of so-called “Vienna issues”, having denominations of 10 (orange-yellow), 20 (pink) and 40 para (blue) and “Belgrade issues” (1 para-green and 2 para-reddish brown), as well as 24 expert-certified forgeries, were taken. It was shown that the applied technology was, in most of the cases, a fast and suitable technique for establishing clear differences between the spectral characteristics of the paper and dye used for the original stamps, and forgeries that were most probably made decades after the printing of the genuine stamps. The differences between print­ings of the same issues of the genuine stamps were also elaborated. It is pro­posed, for the first time in philatelic history, the possibility that “Vienna issues” stamps may have been printed on two different papers, and, having in mind the technology of printing in the 19th century, potentially, not even at the same time or in the same printing house.
T2  - Journal of the Serbian Chemical Society
T1  - To Professor Petar Pfendt, In calidum, et plurium retributivus memoriae: FTIR-ATR analysis of post stamps of the Principality of Serbia issued in 1866 and 1868 and their forgeries
VL  - 87
IS  - 1
SP  - 27
EP  - 40
DO  - 10.2298/JSC210901090P
ER  - 
@article{
author = "Popović, Aleksandar R. and Anđelković, Boban D. and Đorđević, Dragana S. and Sakan, Sanja M. and Vujisić, Ljubodrag V. and Veličković, Sava and Relić, Dubravka",
year = "2022",
abstract = "In order to further define the potential use of FTIR-ATR spectroscopy, as a non-destructive and reliable technique, for the analysis of the characteristics of post stamps, certified originals of the Principality of Serbia stamps (“Prince Michael issues”) issued in 1866 and 1868 as well as their forgeries were ana­lyzed. Spectra enabling the comparison of the paper, dye and glue of stamps of so-called “Vienna issues”, having denominations of 10 (orange-yellow), 20 (pink) and 40 para (blue) and “Belgrade issues” (1 para-green and 2 para-reddish brown), as well as 24 expert-certified forgeries, were taken. It was shown that the applied technology was, in most of the cases, a fast and suitable technique for establishing clear differences between the spectral characteristics of the paper and dye used for the original stamps, and forgeries that were most probably made decades after the printing of the genuine stamps. The differences between print­ings of the same issues of the genuine stamps were also elaborated. It is pro­posed, for the first time in philatelic history, the possibility that “Vienna issues” stamps may have been printed on two different papers, and, having in mind the technology of printing in the 19th century, potentially, not even at the same time or in the same printing house.",
journal = "Journal of the Serbian Chemical Society",
title = "To Professor Petar Pfendt, In calidum, et plurium retributivus memoriae: FTIR-ATR analysis of post stamps of the Principality of Serbia issued in 1866 and 1868 and their forgeries",
volume = "87",
number = "1",
pages = "27-40",
doi = "10.2298/JSC210901090P"
}
Popović, A. R., Anđelković, B. D., Đorđević, D. S., Sakan, S. M., Vujisić, L. V., Veličković, S.,& Relić, D.. (2022). To Professor Petar Pfendt, In calidum, et plurium retributivus memoriae: FTIR-ATR analysis of post stamps of the Principality of Serbia issued in 1866 and 1868 and their forgeries. in Journal of the Serbian Chemical Society, 87(1), 27-40.
https://doi.org/10.2298/JSC210901090P
Popović AR, Anđelković BD, Đorđević DS, Sakan SM, Vujisić LV, Veličković S, Relić D. To Professor Petar Pfendt, In calidum, et plurium retributivus memoriae: FTIR-ATR analysis of post stamps of the Principality of Serbia issued in 1866 and 1868 and their forgeries. in Journal of the Serbian Chemical Society. 2022;87(1):27-40.
doi:10.2298/JSC210901090P .
Popović, Aleksandar R., Anđelković, Boban D., Đorđević, Dragana S., Sakan, Sanja M., Vujisić, Ljubodrag V., Veličković, Sava, Relić, Dubravka, "To Professor Petar Pfendt, In calidum, et plurium retributivus memoriae: FTIR-ATR analysis of post stamps of the Principality of Serbia issued in 1866 and 1868 and their forgeries" in Journal of the Serbian Chemical Society, 87, no. 1 (2022):27-40,
https://doi.org/10.2298/JSC210901090P . .

Removal of heavy metals from aqueous media by sunflower husk: A comparative study of biosorption efficiency by using ICP-OES and LIBS

Radenković, Marina; Momčilović, Miloš; Petrović, Jelena; Mraković, Ana; Relić, Dubravka; Popović, Aleksandar R.; Živković, Sanja

(Serbian Chemical Society, 2022)

TY  - JOUR
AU  - Radenković, Marina
AU  - Momčilović, Miloš
AU  - Petrović, Jelena
AU  - Mraković, Ana
AU  - Relić, Dubravka
AU  - Popović, Aleksandar R.
AU  - Živković, Sanja
PY  - 2022
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5663
AB  - Presented research aimed to develop an alternative approach for the estimation of biosorption capability of sunflower husk. The acid-pretreated sunflower biomass was characterized by scanning electron microscopy combined with energy dispersive X-Ray spectroscopy (SEM-EDX) analysis and Fourier transform infrared (FTIR) spectroscopy. Biosorption efficiency has been evaluated using inductively coupled plasma optical emission spectroscopy (ICP-OES) and laser-induced breakdown spectroscopy (LIBS). The adsorption capacity of the adsorbent was determined as the function of the pH of the solution, the initial concentration of heavy metal solutions, and contact time. The optimal conditions were achieved after 15 min of contact at pH 6, while the percentage of the removal was from 80.0–98.7 %, depending on the element. The results obtained from the kinetic and isotherm studies show that maximum adsorption of ions was quickly reached and followed the pseudo-second-order kinetic model. Real samples were tested and obtained Ni values by LIBS method were 3100±200 and 1240±100 mg kg-1, while estimated values by the ICP-OES were 2995±20 and 1130±10 mg kg-1, respectively. The obtained results prove that LIBS method can be used as a “green alternative“for the evaluation of biosorption efficiency.
PB  - Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - Removal of heavy metals from aqueous media by sunflower husk: A comparative study of biosorption efficiency by using ICP-OES and LIBS
VL  - 87
IS  - 7-8
SP  - 939
EP  - 952
DO  - 10.2298/JSC220105022R
ER  - 
@article{
author = "Radenković, Marina and Momčilović, Miloš and Petrović, Jelena and Mraković, Ana and Relić, Dubravka and Popović, Aleksandar R. and Živković, Sanja",
year = "2022",
abstract = "Presented research aimed to develop an alternative approach for the estimation of biosorption capability of sunflower husk. The acid-pretreated sunflower biomass was characterized by scanning electron microscopy combined with energy dispersive X-Ray spectroscopy (SEM-EDX) analysis and Fourier transform infrared (FTIR) spectroscopy. Biosorption efficiency has been evaluated using inductively coupled plasma optical emission spectroscopy (ICP-OES) and laser-induced breakdown spectroscopy (LIBS). The adsorption capacity of the adsorbent was determined as the function of the pH of the solution, the initial concentration of heavy metal solutions, and contact time. The optimal conditions were achieved after 15 min of contact at pH 6, while the percentage of the removal was from 80.0–98.7 %, depending on the element. The results obtained from the kinetic and isotherm studies show that maximum adsorption of ions was quickly reached and followed the pseudo-second-order kinetic model. Real samples were tested and obtained Ni values by LIBS method were 3100±200 and 1240±100 mg kg-1, while estimated values by the ICP-OES were 2995±20 and 1130±10 mg kg-1, respectively. The obtained results prove that LIBS method can be used as a “green alternative“for the evaluation of biosorption efficiency.",
publisher = "Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "Removal of heavy metals from aqueous media by sunflower husk: A comparative study of biosorption efficiency by using ICP-OES and LIBS",
volume = "87",
number = "7-8",
pages = "939-952",
doi = "10.2298/JSC220105022R"
}
Radenković, M., Momčilović, M., Petrović, J., Mraković, A., Relić, D., Popović, A. R.,& Živković, S.. (2022). Removal of heavy metals from aqueous media by sunflower husk: A comparative study of biosorption efficiency by using ICP-OES and LIBS. in Journal of the Serbian Chemical Society
Serbian Chemical Society., 87(7-8), 939-952.
https://doi.org/10.2298/JSC220105022R
Radenković M, Momčilović M, Petrović J, Mraković A, Relić D, Popović AR, Živković S. Removal of heavy metals from aqueous media by sunflower husk: A comparative study of biosorption efficiency by using ICP-OES and LIBS. in Journal of the Serbian Chemical Society. 2022;87(7-8):939-952.
doi:10.2298/JSC220105022R .
Radenković, Marina, Momčilović, Miloš, Petrović, Jelena, Mraković, Ana, Relić, Dubravka, Popović, Aleksandar R., Živković, Sanja, "Removal of heavy metals from aqueous media by sunflower husk: A comparative study of biosorption efficiency by using ICP-OES and LIBS" in Journal of the Serbian Chemical Society, 87, no. 7-8 (2022):939-952,
https://doi.org/10.2298/JSC220105022R . .
2
2
1

Human health risks and benefits assessment based on OCPs, PCBs, toxic elements and fatty acids in the pelagic fish species from the Adriatic Sea

Milićević, Tijana; Herceg Romanić, Snježana; Popović, Aleksandar R.; Mustać, Bosiljka; Đinović-Stojanović, Jasna; Jovanović, Gordana; Relić, Dubravka

(Elsevier, 2022)

TY  - JOUR
AU  - Milićević, Tijana
AU  - Herceg Romanić, Snježana
AU  - Popović, Aleksandar R.
AU  - Mustać, Bosiljka
AU  - Đinović-Stojanović, Jasna
AU  - Jovanović, Gordana
AU  - Relić, Dubravka
PY  - 2022
UR  - https://www.sciencedirect.com/science/article/pii/S0045653521025406
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/4664
AB  - Benefits and risks of the fish consumption should be assessed to balance the ingestion of healthy omega-3 fatty acids and adverse chemicals. Persistent organic pollutants-POPs (organochlorine pesticides-OCPs and polychlorinated biphenyls-PCB), macro- and micro-elements and fatty acid contents were determined in six fish species from the Adriatic Sea to assess health risks for consumers (worst-case scenario, diseases development risks and benefit-risk). 16 element, 24 POPs and 14 fatty acid contents were determined in six pelagic species which can be used in human diet. Element concentrations were determined by inductively coupled plasma mass spectrometry (ICP-MS), POPs by high-resolution gas chromatography and fatty acid content by gas–liquid chromatography. Diet based on chub mackerel and round sardinella showed lower daily intake (DI) of POPs and highest DI of essential omega-3 fatty acids than other investigated species. Lower ingestion of toxic elements can be observed by consuming anchovy and round sardinella. Based on POP concentrations, there was not observed non-carcinogenic (HI) nor carcinogenic (CR) risks for consumers. Based on element concentrations, there was low HI (0.1 ≥ HI ≥ 1), while the maximum HIs and outlier values (horse mackerel and anchovy samples) implied the presence of HI (HI > 1). The most significant contributor to total non-carcinogenic and carcinogenic risks was inorganic arsenic (inorganic As). Acceptable CR for consumers was assessed, but maximum CR for consumers of horse mackerel and anchovy (CR ≥ 1 × 10–6) showed adverse effects on human health. There were low HIs for developing cardiovascular, nervous, and reproductive diseases, and maximum HIs were higher than 1. Acceptable (1 × 10−4≥CR ≥ 1 × 10−6) risks were observed for developing cancer of nervous system and reproductive organs. Among investigated fish samples, those with higher ƩBR (benefit-risks) and BR for arsenic (As) than median value have a higher risk than benefits in the human diet.
PB  - Elsevier
T2  - Chemosphere
T1  - Human health risks and benefits assessment based on OCPs, PCBs, toxic elements and fatty acids in the pelagic fish species from the Adriatic Sea
VL  - 287
SP  - 132068
DO  - 10.1016/j.chemosphere.2021.132068
ER  - 
@article{
author = "Milićević, Tijana and Herceg Romanić, Snježana and Popović, Aleksandar R. and Mustać, Bosiljka and Đinović-Stojanović, Jasna and Jovanović, Gordana and Relić, Dubravka",
year = "2022",
abstract = "Benefits and risks of the fish consumption should be assessed to balance the ingestion of healthy omega-3 fatty acids and adverse chemicals. Persistent organic pollutants-POPs (organochlorine pesticides-OCPs and polychlorinated biphenyls-PCB), macro- and micro-elements and fatty acid contents were determined in six fish species from the Adriatic Sea to assess health risks for consumers (worst-case scenario, diseases development risks and benefit-risk). 16 element, 24 POPs and 14 fatty acid contents were determined in six pelagic species which can be used in human diet. Element concentrations were determined by inductively coupled plasma mass spectrometry (ICP-MS), POPs by high-resolution gas chromatography and fatty acid content by gas–liquid chromatography. Diet based on chub mackerel and round sardinella showed lower daily intake (DI) of POPs and highest DI of essential omega-3 fatty acids than other investigated species. Lower ingestion of toxic elements can be observed by consuming anchovy and round sardinella. Based on POP concentrations, there was not observed non-carcinogenic (HI) nor carcinogenic (CR) risks for consumers. Based on element concentrations, there was low HI (0.1 ≥ HI ≥ 1), while the maximum HIs and outlier values (horse mackerel and anchovy samples) implied the presence of HI (HI > 1). The most significant contributor to total non-carcinogenic and carcinogenic risks was inorganic arsenic (inorganic As). Acceptable CR for consumers was assessed, but maximum CR for consumers of horse mackerel and anchovy (CR ≥ 1 × 10–6) showed adverse effects on human health. There were low HIs for developing cardiovascular, nervous, and reproductive diseases, and maximum HIs were higher than 1. Acceptable (1 × 10−4≥CR ≥ 1 × 10−6) risks were observed for developing cancer of nervous system and reproductive organs. Among investigated fish samples, those with higher ƩBR (benefit-risks) and BR for arsenic (As) than median value have a higher risk than benefits in the human diet.",
publisher = "Elsevier",
journal = "Chemosphere",
title = "Human health risks and benefits assessment based on OCPs, PCBs, toxic elements and fatty acids in the pelagic fish species from the Adriatic Sea",
volume = "287",
pages = "132068",
doi = "10.1016/j.chemosphere.2021.132068"
}
Milićević, T., Herceg Romanić, S., Popović, A. R., Mustać, B., Đinović-Stojanović, J., Jovanović, G.,& Relić, D.. (2022). Human health risks and benefits assessment based on OCPs, PCBs, toxic elements and fatty acids in the pelagic fish species from the Adriatic Sea. in Chemosphere
Elsevier., 287, 132068.
https://doi.org/10.1016/j.chemosphere.2021.132068
Milićević T, Herceg Romanić S, Popović AR, Mustać B, Đinović-Stojanović J, Jovanović G, Relić D. Human health risks and benefits assessment based on OCPs, PCBs, toxic elements and fatty acids in the pelagic fish species from the Adriatic Sea. in Chemosphere. 2022;287:132068.
doi:10.1016/j.chemosphere.2021.132068 .
Milićević, Tijana, Herceg Romanić, Snježana, Popović, Aleksandar R., Mustać, Bosiljka, Đinović-Stojanović, Jasna, Jovanović, Gordana, Relić, Dubravka, "Human health risks and benefits assessment based on OCPs, PCBs, toxic elements and fatty acids in the pelagic fish species from the Adriatic Sea" in Chemosphere, 287 (2022):132068,
https://doi.org/10.1016/j.chemosphere.2021.132068 . .
14
1
10
10

Supplementary data for the article: Milićević, T.; Romanić, S. H.; Popović, A.; Mustać, B.; Đinović-Stojanović, J.; Jovanović, G.; Relić, D. Human Health Risks and Benefits Assessment Based on OCPs, PCBs, Toxic Elements and Fatty Acids in the Pelagic Fish Species from the Adriatic Sea. Chemosphere 2022, 287, 132068. https://doi.org/10.1016/j.chemosphere.2021.132068.

Milićević, Tijana; Herceg Romanić, Snježana; Popović, Aleksandar R.; Mustać, Bosiljka; Đinović-Stojanović, Jasna; Jovanović, Gordana; Relić, Dubravka

(Elsevier, 2022)

TY  - DATA
AU  - Milićević, Tijana
AU  - Herceg Romanić, Snježana
AU  - Popović, Aleksandar R.
AU  - Mustać, Bosiljka
AU  - Đinović-Stojanović, Jasna
AU  - Jovanović, Gordana
AU  - Relić, Dubravka
PY  - 2022
UR  - https://www.sciencedirect.com/science/article/pii/S0045653521025406
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/4665
PB  - Elsevier
T2  - Chemosphere
T1  - Supplementary data for the article: Milićević, T.; Romanić, S. H.; Popović, A.; Mustać, B.; Đinović-Stojanović, J.; Jovanović, G.; Relić, D. Human Health Risks and Benefits Assessment Based on OCPs, PCBs, Toxic Elements and Fatty Acids in the Pelagic Fish Species from the Adriatic Sea. Chemosphere 2022, 287, 132068. https://doi.org/10.1016/j.chemosphere.2021.132068.
UR  - https://hdl.handle.net/21.15107/rcub_cherry_4665
ER  - 
@misc{
author = "Milićević, Tijana and Herceg Romanić, Snježana and Popović, Aleksandar R. and Mustać, Bosiljka and Đinović-Stojanović, Jasna and Jovanović, Gordana and Relić, Dubravka",
year = "2022",
publisher = "Elsevier",
journal = "Chemosphere",
title = "Supplementary data for the article: Milićević, T.; Romanić, S. H.; Popović, A.; Mustać, B.; Đinović-Stojanović, J.; Jovanović, G.; Relić, D. Human Health Risks and Benefits Assessment Based on OCPs, PCBs, Toxic Elements and Fatty Acids in the Pelagic Fish Species from the Adriatic Sea. Chemosphere 2022, 287, 132068. https://doi.org/10.1016/j.chemosphere.2021.132068.",
url = "https://hdl.handle.net/21.15107/rcub_cherry_4665"
}
Milićević, T., Herceg Romanić, S., Popović, A. R., Mustać, B., Đinović-Stojanović, J., Jovanović, G.,& Relić, D.. (2022). Supplementary data for the article: Milićević, T.; Romanić, S. H.; Popović, A.; Mustać, B.; Đinović-Stojanović, J.; Jovanović, G.; Relić, D. Human Health Risks and Benefits Assessment Based on OCPs, PCBs, Toxic Elements and Fatty Acids in the Pelagic Fish Species from the Adriatic Sea. Chemosphere 2022, 287, 132068. https://doi.org/10.1016/j.chemosphere.2021.132068.. in Chemosphere
Elsevier..
https://hdl.handle.net/21.15107/rcub_cherry_4665
Milićević T, Herceg Romanić S, Popović AR, Mustać B, Đinović-Stojanović J, Jovanović G, Relić D. Supplementary data for the article: Milićević, T.; Romanić, S. H.; Popović, A.; Mustać, B.; Đinović-Stojanović, J.; Jovanović, G.; Relić, D. Human Health Risks and Benefits Assessment Based on OCPs, PCBs, Toxic Elements and Fatty Acids in the Pelagic Fish Species from the Adriatic Sea. Chemosphere 2022, 287, 132068. https://doi.org/10.1016/j.chemosphere.2021.132068.. in Chemosphere. 2022;.
https://hdl.handle.net/21.15107/rcub_cherry_4665 .
Milićević, Tijana, Herceg Romanić, Snježana, Popović, Aleksandar R., Mustać, Bosiljka, Đinović-Stojanović, Jasna, Jovanović, Gordana, Relić, Dubravka, "Supplementary data for the article: Milićević, T.; Romanić, S. H.; Popović, A.; Mustać, B.; Đinović-Stojanović, J.; Jovanović, G.; Relić, D. Human Health Risks and Benefits Assessment Based on OCPs, PCBs, Toxic Elements and Fatty Acids in the Pelagic Fish Species from the Adriatic Sea. Chemosphere 2022, 287, 132068. https://doi.org/10.1016/j.chemosphere.2021.132068." in Chemosphere (2022),
https://hdl.handle.net/21.15107/rcub_cherry_4665 .

Mercury in scarletina bolete mushroom (Neoboletus luridiformis): Intake, spatial distribution in the fruiting body, accumulation ability and health risk assessment

Árvay, Július; Hauptvogl, Martin; Demková, Lenka; Harangozo, Ľuboš; Šnirc, Marek; Bobuľská, Lenka; Štefániková, Jana; Kováčik, Anton; Jakabová, Silvia; Jančo, Ivona; Kunca, Vladimír; Relić, Dubravka

(Elsevier, 2022)

TY  - JOUR
AU  - Árvay, Július
AU  - Hauptvogl, Martin
AU  - Demková, Lenka
AU  - Harangozo, Ľuboš
AU  - Šnirc, Marek
AU  - Bobuľská, Lenka
AU  - Štefániková, Jana
AU  - Kováčik, Anton
AU  - Jakabová, Silvia
AU  - Jančo, Ivona
AU  - Kunca, Vladimír
AU  - Relić, Dubravka
PY  - 2022
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/4875
AB  - In the present work, we focused on two aspects of mercury (Hg) bioconcentration in the above-ground parts of Neoboletus luridiformis. In the first part, we monitored the bioconcentration potential of individual anatomical parts of a particular fruiting body and evaluated the obtained data by the spline interpolation method. In the second part, we focused on assessing the mercury content in 378 samples of N. luridiformis and associated samples of substrates from 38 localities with different levels of Hg content in Slovakia. From the obtained data of Hg content in samples of substrate and fungi, we evaluated ecological indicators (geoaccumulation index – Igeo, contamination factor – Cf a potential ecological risk – PER), bioconcentration indicators (bioconcentration factor – BCF; cap/stipe quotient – Qc/s) and health indicators (percentage of provisional tolerable weekly intake – %PTWI a target hazard quotient – THQ). Based on the Hg distribution results, the highest Hg content was found in the tubes & pores (3.86 mg/kg DW), followed by the flesh of cap (1.82 mg/kg DW). The lowest Hg content was in the stipe (1.23 mg/kg DW). The results of the BCF values indicate that the studied species can be included in the category of mercury accumulators. The results of the ecological indices representing the state of soil pollution pointed out that two localities (Malachov and Nižná Slaná) stood apart from all monitored localities and showed a state of an extremely disturbed environment. This fact was also reflected in the values of Hg content in the fruiting bodies of the studied mushroom species. In the case of the consumption of mushrooms from these localities, it can be stated that long-term and regular consumption could have a negative non-carcinogenic effect on the health of consumers. It was confirmed by the %PTWI (Malachov: 57.8%; Nižná Slaná: 53.2%) and THQ (Malachov: 1.11 Nižná Slaná: 1.02). The locality Čačín-Jelšovec is interesting from the bioconcentration characteristics point of view, where the level of environmental pollution was the lowest (Hg content in the soil was below the background value) compared to other localities, however, the THQ value was the highest (1.29).
PB  - Elsevier
T2  - Ecotoxicology and Environmental Safety
T1  - Mercury in scarletina bolete mushroom (Neoboletus luridiformis): Intake, spatial distribution in the fruiting body, accumulation ability and health risk assessment
VL  - 232
SP  - 113235
DO  - 10.1016/j.ecoenv.2022.113235
ER  - 
@article{
author = "Árvay, Július and Hauptvogl, Martin and Demková, Lenka and Harangozo, Ľuboš and Šnirc, Marek and Bobuľská, Lenka and Štefániková, Jana and Kováčik, Anton and Jakabová, Silvia and Jančo, Ivona and Kunca, Vladimír and Relić, Dubravka",
year = "2022",
abstract = "In the present work, we focused on two aspects of mercury (Hg) bioconcentration in the above-ground parts of Neoboletus luridiformis. In the first part, we monitored the bioconcentration potential of individual anatomical parts of a particular fruiting body and evaluated the obtained data by the spline interpolation method. In the second part, we focused on assessing the mercury content in 378 samples of N. luridiformis and associated samples of substrates from 38 localities with different levels of Hg content in Slovakia. From the obtained data of Hg content in samples of substrate and fungi, we evaluated ecological indicators (geoaccumulation index – Igeo, contamination factor – Cf a potential ecological risk – PER), bioconcentration indicators (bioconcentration factor – BCF; cap/stipe quotient – Qc/s) and health indicators (percentage of provisional tolerable weekly intake – %PTWI a target hazard quotient – THQ). Based on the Hg distribution results, the highest Hg content was found in the tubes & pores (3.86 mg/kg DW), followed by the flesh of cap (1.82 mg/kg DW). The lowest Hg content was in the stipe (1.23 mg/kg DW). The results of the BCF values indicate that the studied species can be included in the category of mercury accumulators. The results of the ecological indices representing the state of soil pollution pointed out that two localities (Malachov and Nižná Slaná) stood apart from all monitored localities and showed a state of an extremely disturbed environment. This fact was also reflected in the values of Hg content in the fruiting bodies of the studied mushroom species. In the case of the consumption of mushrooms from these localities, it can be stated that long-term and regular consumption could have a negative non-carcinogenic effect on the health of consumers. It was confirmed by the %PTWI (Malachov: 57.8%; Nižná Slaná: 53.2%) and THQ (Malachov: 1.11 Nižná Slaná: 1.02). The locality Čačín-Jelšovec is interesting from the bioconcentration characteristics point of view, where the level of environmental pollution was the lowest (Hg content in the soil was below the background value) compared to other localities, however, the THQ value was the highest (1.29).",
publisher = "Elsevier",
journal = "Ecotoxicology and Environmental Safety",
title = "Mercury in scarletina bolete mushroom (Neoboletus luridiformis): Intake, spatial distribution in the fruiting body, accumulation ability and health risk assessment",
volume = "232",
pages = "113235",
doi = "10.1016/j.ecoenv.2022.113235"
}
Árvay, J., Hauptvogl, M., Demková, L., Harangozo, Ľ., Šnirc, M., Bobuľská, L., Štefániková, J., Kováčik, A., Jakabová, S., Jančo, I., Kunca, V.,& Relić, D.. (2022). Mercury in scarletina bolete mushroom (Neoboletus luridiformis): Intake, spatial distribution in the fruiting body, accumulation ability and health risk assessment. in Ecotoxicology and Environmental Safety
Elsevier., 232, 113235.
https://doi.org/10.1016/j.ecoenv.2022.113235
Árvay J, Hauptvogl M, Demková L, Harangozo Ľ, Šnirc M, Bobuľská L, Štefániková J, Kováčik A, Jakabová S, Jančo I, Kunca V, Relić D. Mercury in scarletina bolete mushroom (Neoboletus luridiformis): Intake, spatial distribution in the fruiting body, accumulation ability and health risk assessment. in Ecotoxicology and Environmental Safety. 2022;232:113235.
doi:10.1016/j.ecoenv.2022.113235 .
Árvay, Július, Hauptvogl, Martin, Demková, Lenka, Harangozo, Ľuboš, Šnirc, Marek, Bobuľská, Lenka, Štefániková, Jana, Kováčik, Anton, Jakabová, Silvia, Jančo, Ivona, Kunca, Vladimír, Relić, Dubravka, "Mercury in scarletina bolete mushroom (Neoboletus luridiformis): Intake, spatial distribution in the fruiting body, accumulation ability and health risk assessment" in Ecotoxicology and Environmental Safety, 232 (2022):113235,
https://doi.org/10.1016/j.ecoenv.2022.113235 . .
1
6
6
5

Supplementary data for article: Árvay, J.; Hauptvogl, M.; Demková, L.; Harangozo, Ľ.; Šnirc, M.; Bobuľská, L.; Štefániková, J.; Kováčik, A.; Jakabová, S.; Jančo, I.; Kunca, V.; Relić, D. Mercury in Scarletina Bolete Mushroom (Neoboletus Luridiformis): Intake, Spatial Distribution in the Fruiting Body, Accumulation Ability and Health Risk Assessment. Ecotoxicology and Environmental Safety 2022, 232, 113235. https://doi.org/10.1016/j.ecoenv.2022.113235.

Árvay, Július; Hauptvogl, Martin; Demková, Lenka; Harangozo, Ľuboš; Šnirc, Marek; Bobuľská, Lenka; Štefániková, Jana; Kováčik, Anton; Jakabová, Silvia; Jančo, Ivona; Kunca, Vladimír; Relić, Dubravka

(Elsevier, 2022)

TY  - DATA
AU  - Árvay, Július
AU  - Hauptvogl, Martin
AU  - Demková, Lenka
AU  - Harangozo, Ľuboš
AU  - Šnirc, Marek
AU  - Bobuľská, Lenka
AU  - Štefániková, Jana
AU  - Kováčik, Anton
AU  - Jakabová, Silvia
AU  - Jančo, Ivona
AU  - Kunca, Vladimír
AU  - Relić, Dubravka
PY  - 2022
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/4876
PB  - Elsevier
T2  - Ecotoxicology and Environmental Safety
T1  - Supplementary data for article: Árvay, J.; Hauptvogl, M.; Demková, L.; Harangozo, Ľ.; Šnirc, M.; Bobuľská, L.; Štefániková, J.; Kováčik, A.; Jakabová, S.; Jančo, I.; Kunca, V.; Relić, D. Mercury in Scarletina Bolete Mushroom (Neoboletus Luridiformis): Intake, Spatial Distribution in the Fruiting Body, Accumulation Ability and Health Risk Assessment. Ecotoxicology and Environmental Safety 2022, 232, 113235. https://doi.org/10.1016/j.ecoenv.2022.113235.
UR  - https://hdl.handle.net/21.15107/rcub_cherry_4876
ER  - 
@misc{
author = "Árvay, Július and Hauptvogl, Martin and Demková, Lenka and Harangozo, Ľuboš and Šnirc, Marek and Bobuľská, Lenka and Štefániková, Jana and Kováčik, Anton and Jakabová, Silvia and Jančo, Ivona and Kunca, Vladimír and Relić, Dubravka",
year = "2022",
publisher = "Elsevier",
journal = "Ecotoxicology and Environmental Safety",
title = "Supplementary data for article: Árvay, J.; Hauptvogl, M.; Demková, L.; Harangozo, Ľ.; Šnirc, M.; Bobuľská, L.; Štefániková, J.; Kováčik, A.; Jakabová, S.; Jančo, I.; Kunca, V.; Relić, D. Mercury in Scarletina Bolete Mushroom (Neoboletus Luridiformis): Intake, Spatial Distribution in the Fruiting Body, Accumulation Ability and Health Risk Assessment. Ecotoxicology and Environmental Safety 2022, 232, 113235. https://doi.org/10.1016/j.ecoenv.2022.113235.",
url = "https://hdl.handle.net/21.15107/rcub_cherry_4876"
}
Árvay, J., Hauptvogl, M., Demková, L., Harangozo, Ľ., Šnirc, M., Bobuľská, L., Štefániková, J., Kováčik, A., Jakabová, S., Jančo, I., Kunca, V.,& Relić, D.. (2022). Supplementary data for article: Árvay, J.; Hauptvogl, M.; Demková, L.; Harangozo, Ľ.; Šnirc, M.; Bobuľská, L.; Štefániková, J.; Kováčik, A.; Jakabová, S.; Jančo, I.; Kunca, V.; Relić, D. Mercury in Scarletina Bolete Mushroom (Neoboletus Luridiformis): Intake, Spatial Distribution in the Fruiting Body, Accumulation Ability and Health Risk Assessment. Ecotoxicology and Environmental Safety 2022, 232, 113235. https://doi.org/10.1016/j.ecoenv.2022.113235.. in Ecotoxicology and Environmental Safety
Elsevier..
https://hdl.handle.net/21.15107/rcub_cherry_4876
Árvay J, Hauptvogl M, Demková L, Harangozo Ľ, Šnirc M, Bobuľská L, Štefániková J, Kováčik A, Jakabová S, Jančo I, Kunca V, Relić D. Supplementary data for article: Árvay, J.; Hauptvogl, M.; Demková, L.; Harangozo, Ľ.; Šnirc, M.; Bobuľská, L.; Štefániková, J.; Kováčik, A.; Jakabová, S.; Jančo, I.; Kunca, V.; Relić, D. Mercury in Scarletina Bolete Mushroom (Neoboletus Luridiformis): Intake, Spatial Distribution in the Fruiting Body, Accumulation Ability and Health Risk Assessment. Ecotoxicology and Environmental Safety 2022, 232, 113235. https://doi.org/10.1016/j.ecoenv.2022.113235.. in Ecotoxicology and Environmental Safety. 2022;.
https://hdl.handle.net/21.15107/rcub_cherry_4876 .
Árvay, Július, Hauptvogl, Martin, Demková, Lenka, Harangozo, Ľuboš, Šnirc, Marek, Bobuľská, Lenka, Štefániková, Jana, Kováčik, Anton, Jakabová, Silvia, Jančo, Ivona, Kunca, Vladimír, Relić, Dubravka, "Supplementary data for article: Árvay, J.; Hauptvogl, M.; Demková, L.; Harangozo, Ľ.; Šnirc, M.; Bobuľská, L.; Štefániková, J.; Kováčik, A.; Jakabová, S.; Jančo, I.; Kunca, V.; Relić, D. Mercury in Scarletina Bolete Mushroom (Neoboletus Luridiformis): Intake, Spatial Distribution in the Fruiting Body, Accumulation Ability and Health Risk Assessment. Ecotoxicology and Environmental Safety 2022, 232, 113235. https://doi.org/10.1016/j.ecoenv.2022.113235." in Ecotoxicology and Environmental Safety (2022),
https://hdl.handle.net/21.15107/rcub_cherry_4876 .

Autochthonous and international grape varieties grown in Serbia - Phenolic and elemental composition

Natić, Maja; Dabić Zagorac, Dragana; Gašić, Uroš M.; Dojčinović, Biljana P.; Ćirić, Ivanka; Relić, Dubravka; Todić, Slavica; Sredojević, Milica

(Elsevier, 2021)

TY  - JOUR
AU  - Natić, Maja
AU  - Dabić Zagorac, Dragana
AU  - Gašić, Uroš M.
AU  - Dojčinović, Biljana P.
AU  - Ćirić, Ivanka
AU  - Relić, Dubravka
AU  - Todić, Slavica
AU  - Sredojević, Milica
PY  - 2021
UR  - https://www.sciencedirect.com/science/article/pii/S2212429221000146
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/4487
AB  - The phenolic and elemental profiles of Serbian autochthonous grape varieties ‘Smederevka’ and ‘Plovdina’ were studied and compared with some international varieties. Total phenolic content and radical scavenging activity were highest in seeds of ‘Plovdina’, and in ‘Smederevka’ skins, which also had the highest contents of ferulic, chlorogenic and caffeic acids (16.0, 1.44 and 0.98 mg/kg, respectively). Protocatechuic acid was quantified only in the seeds of these varieties. Untypically for Vitis vinifera L. species, the presence of malvidin 3,5-O-dihexoside was found in the skins of ‘Vranac’ and ‘Muscat Hamburg’. In ‘Plovdina’ skins among the anthocyanins, hexosides of peonidin and delphinidin were prevalent. ‘Plovdina’ grapes had lower quantities of Al, Ni and Na in comparison to the other varieties intended for white wine production. Significant correlations among the most abundant elements, such as K, P, Ca, Mg, S, Fe, Cu, and Zn, pointed to potential positive interactions. For elements that have toxicological reference values, the health risk assessment was calculated for adults and children, and suggested that all samples were safe for human consumption.
PB  - Elsevier
T2  - Food Bioscience
T2  - Food BioscienceFood Bioscience
T1  - Autochthonous and international grape varieties grown in Serbia - Phenolic and elemental composition
VL  - 40
SP  - 100889
DO  - 10.1016/j.fbio.2021.100889
ER  - 
@article{
author = "Natić, Maja and Dabić Zagorac, Dragana and Gašić, Uroš M. and Dojčinović, Biljana P. and Ćirić, Ivanka and Relić, Dubravka and Todić, Slavica and Sredojević, Milica",
year = "2021",
abstract = "The phenolic and elemental profiles of Serbian autochthonous grape varieties ‘Smederevka’ and ‘Plovdina’ were studied and compared with some international varieties. Total phenolic content and radical scavenging activity were highest in seeds of ‘Plovdina’, and in ‘Smederevka’ skins, which also had the highest contents of ferulic, chlorogenic and caffeic acids (16.0, 1.44 and 0.98 mg/kg, respectively). Protocatechuic acid was quantified only in the seeds of these varieties. Untypically for Vitis vinifera L. species, the presence of malvidin 3,5-O-dihexoside was found in the skins of ‘Vranac’ and ‘Muscat Hamburg’. In ‘Plovdina’ skins among the anthocyanins, hexosides of peonidin and delphinidin were prevalent. ‘Plovdina’ grapes had lower quantities of Al, Ni and Na in comparison to the other varieties intended for white wine production. Significant correlations among the most abundant elements, such as K, P, Ca, Mg, S, Fe, Cu, and Zn, pointed to potential positive interactions. For elements that have toxicological reference values, the health risk assessment was calculated for adults and children, and suggested that all samples were safe for human consumption.",
publisher = "Elsevier",
journal = "Food Bioscience, Food BioscienceFood Bioscience",
title = "Autochthonous and international grape varieties grown in Serbia - Phenolic and elemental composition",
volume = "40",
pages = "100889",
doi = "10.1016/j.fbio.2021.100889"
}
Natić, M., Dabić Zagorac, D., Gašić, U. M., Dojčinović, B. P., Ćirić, I., Relić, D., Todić, S.,& Sredojević, M.. (2021). Autochthonous and international grape varieties grown in Serbia - Phenolic and elemental composition. in Food Bioscience
Elsevier., 40, 100889.
https://doi.org/10.1016/j.fbio.2021.100889
Natić M, Dabić Zagorac D, Gašić UM, Dojčinović BP, Ćirić I, Relić D, Todić S, Sredojević M. Autochthonous and international grape varieties grown in Serbia - Phenolic and elemental composition. in Food Bioscience. 2021;40:100889.
doi:10.1016/j.fbio.2021.100889 .
Natić, Maja, Dabić Zagorac, Dragana, Gašić, Uroš M., Dojčinović, Biljana P., Ćirić, Ivanka, Relić, Dubravka, Todić, Slavica, Sredojević, Milica, "Autochthonous and international grape varieties grown in Serbia - Phenolic and elemental composition" in Food Bioscience, 40 (2021):100889,
https://doi.org/10.1016/j.fbio.2021.100889 . .
2
2
1

Supplementary data for the article: Natić, M.; Dabić Zagorac, D.; Gašić, U.; Dojčinović, B.; Ćirić, I.; Relić, D.; Todić, S.; Sredojević, M. Autochthonous and International Grape Varieties Grown in Serbia - Phenolic and Elemental Composition. Food Bioscience 2021, 40, 100889. https://doi.org/10.1016/j.fbio.2021.100889.

Natić, Maja; Dabić Zagorac, Dragana; Gašić, Uroš M.; Dojčinović, Biljana P.; Ćirić, Ivanka; Relić, Dubravka; Todić, Slavica; Sredojević, Milica

(Elsevier, 2021)

TY  - DATA
AU  - Natić, Maja
AU  - Dabić Zagorac, Dragana
AU  - Gašić, Uroš M.
AU  - Dojčinović, Biljana P.
AU  - Ćirić, Ivanka
AU  - Relić, Dubravka
AU  - Todić, Slavica
AU  - Sredojević, Milica
PY  - 2021
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/4487
UR  - https://www.sciencedirect.com/science/article/pii/S2212429221000146
PB  - Elsevier
T2  - Food Bioscience
T2  - Food BioscienceFood Bioscience
T1  - Supplementary data for the article: Natić, M.; Dabić Zagorac, D.; Gašić, U.; Dojčinović, B.; Ćirić, I.; Relić, D.; Todić, S.; Sredojević, M. Autochthonous and International Grape Varieties Grown in Serbia - Phenolic and Elemental Composition. Food Bioscience 2021, 40, 100889. https://doi.org/10.1016/j.fbio.2021.100889.
UR  - https://hdl.handle.net/21.15107/rcub_cherry_4488
ER  - 
@misc{
author = "Natić, Maja and Dabić Zagorac, Dragana and Gašić, Uroš M. and Dojčinović, Biljana P. and Ćirić, Ivanka and Relić, Dubravka and Todić, Slavica and Sredojević, Milica",
year = "2021",
publisher = "Elsevier",
journal = "Food Bioscience, Food BioscienceFood Bioscience",
title = "Supplementary data for the article: Natić, M.; Dabić Zagorac, D.; Gašić, U.; Dojčinović, B.; Ćirić, I.; Relić, D.; Todić, S.; Sredojević, M. Autochthonous and International Grape Varieties Grown in Serbia - Phenolic and Elemental Composition. Food Bioscience 2021, 40, 100889. https://doi.org/10.1016/j.fbio.2021.100889.",
url = "https://hdl.handle.net/21.15107/rcub_cherry_4488"
}
Natić, M., Dabić Zagorac, D., Gašić, U. M., Dojčinović, B. P., Ćirić, I., Relić, D., Todić, S.,& Sredojević, M.. (2021). Supplementary data for the article: Natić, M.; Dabić Zagorac, D.; Gašić, U.; Dojčinović, B.; Ćirić, I.; Relić, D.; Todić, S.; Sredojević, M. Autochthonous and International Grape Varieties Grown in Serbia - Phenolic and Elemental Composition. Food Bioscience 2021, 40, 100889. https://doi.org/10.1016/j.fbio.2021.100889.. in Food Bioscience
Elsevier..
https://hdl.handle.net/21.15107/rcub_cherry_4488
Natić M, Dabić Zagorac D, Gašić UM, Dojčinović BP, Ćirić I, Relić D, Todić S, Sredojević M. Supplementary data for the article: Natić, M.; Dabić Zagorac, D.; Gašić, U.; Dojčinović, B.; Ćirić, I.; Relić, D.; Todić, S.; Sredojević, M. Autochthonous and International Grape Varieties Grown in Serbia - Phenolic and Elemental Composition. Food Bioscience 2021, 40, 100889. https://doi.org/10.1016/j.fbio.2021.100889.. in Food Bioscience. 2021;.
https://hdl.handle.net/21.15107/rcub_cherry_4488 .
Natić, Maja, Dabić Zagorac, Dragana, Gašić, Uroš M., Dojčinović, Biljana P., Ćirić, Ivanka, Relić, Dubravka, Todić, Slavica, Sredojević, Milica, "Supplementary data for the article: Natić, M.; Dabić Zagorac, D.; Gašić, U.; Dojčinović, B.; Ćirić, I.; Relić, D.; Todić, S.; Sredojević, M. Autochthonous and International Grape Varieties Grown in Serbia - Phenolic and Elemental Composition. Food Bioscience 2021, 40, 100889. https://doi.org/10.1016/j.fbio.2021.100889." in Food Bioscience (2021),
https://hdl.handle.net/21.15107/rcub_cherry_4488 .

Health Risk Assessment for Residents and Workers Based on Toxic and Carcinogenic Element Content from PM2.5 in Belgrade Suburban Area

Mutavdžić, D.; Aničić Urošević, M.; Kuzmanoski, M.; Kodranov, Igor D.; Popović, Aleksandar R.; Relić, Dubravka

(Belgrade : Serbian Chemical Society, 2021)

TY  - CONF
AU  - Mutavdžić, D.
AU  - Aničić Urošević, M.
AU  - Kuzmanoski, M.
AU  - Kodranov, Igor D.
AU  - Popović, Aleksandar R.
AU  - Relić, Dubravka
PY  - 2021
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/4921
AB  - Particulate matter of diametar <2.5 µm (PM2.5) pollution is recognized as one of primary pollution contaminant which directly affect human health. Toxic and carcinogenic elements originating from different pollution sources can be constituents of PM2.5. Because of their small size, particles can penetrate deeper into the lungs and enter the bloodstream causing different disorders and threats to human health [1]. We performed elemental characterization of PM2.5 samples collected during the spring/summer season 2019 in a suburban part of Belgrade (in the inner courtyard of Institute of Physics Belgrade). The spring/ summer period was characterized by the industrial or different outdoor activities with several Saharan dust episodes. In addition, April and October were partly characterized by heating sources. The quartz filters with PM2.5 were digested by the microwave digestion system using 7 mL 65% HNO3 and 1 mL 30% H2 O2 . The concentrations of Al, B, Ba, Bi, Ca, K, Fe, Mn, Ni, P, S and Sr were measured using inductively coupled plasma-optical emission spectrometry (ICP-OES), while concentrations of Ag, As, Be, Cd, Co, Cu, Cr, Hg, Pb, Se, Sb and Tl were measured using inductively coupled plasma mass spectrometry (ICP-MS). The non-carcinogenic and carcinogenic risks for residents and for five different types of workers (outdoor, indoor, composite, construction and excavation workers) in this ambient were assessed by equations provided by The Risk Assessment Information System – RAIS [2]. Comparing the investigated scenarios, the highest non-carcinogenic and carcinogenic risks were observed for the residents. There were observed non-carcinogenic (HI>1) and carcinogenic (R≥1×10-5) risks for the residents from this area. The residents spent the most of their time in this ambient and they are most at the risk caused by the measured PM2.5 pollution (HImedian: 2.28; Rmedian: 1.25 × 10-4). Observing the scenarios for workers, the risk mostly depends on the time that workers spent outside during working hours. Similar non-carcinogenic risks were observed for outdoor, indoor and composite workers, slightly higher risk was observed for construction workers, while the lowest risk was obtained for an excavation worker who is less exposed to the PM2.5 atmospheric deposition than soil dust resuspension. The same was observed for the carcinogenic risk, while the similar risks were observed for all workers. Only for an excavation worker, the carcinogenic risk was significantly lower than for other workers. The most significant contributor to the non-carcinogenic risk in all scenarios was the concentration of Mn, and then the concentration of Be, while the most significant contributor to the carcinogenic risk was Cr6+. Observing the risks among the investigated period the highest non-carcinogenic and carcinogenic risks were observed in April and October based on the toxic and carcinogenic elements in PM2.5. In these months beside the influence of the industrial activities, dust episodes or activity of heating sorces possibly caused the increase of the toxic and carcinogenic elements in PM2.5.
PB  - Belgrade : Serbian Chemical Society
C3  - Book of Abstracts 21st; European Meeting on Environmental Chemistry
T1  - Health Risk Assessment for Residents and Workers Based on Toxic and Carcinogenic Element Content from PM2.5 in Belgrade Suburban Area
SP  - 134
EP  - 134
UR  - https://hdl.handle.net/21.15107/rcub_cherry_4921
ER  - 
@conference{
author = "Mutavdžić, D. and Aničić Urošević, M. and Kuzmanoski, M. and Kodranov, Igor D. and Popović, Aleksandar R. and Relić, Dubravka",
year = "2021",
abstract = "Particulate matter of diametar <2.5 µm (PM2.5) pollution is recognized as one of primary pollution contaminant which directly affect human health. Toxic and carcinogenic elements originating from different pollution sources can be constituents of PM2.5. Because of their small size, particles can penetrate deeper into the lungs and enter the bloodstream causing different disorders and threats to human health [1]. We performed elemental characterization of PM2.5 samples collected during the spring/summer season 2019 in a suburban part of Belgrade (in the inner courtyard of Institute of Physics Belgrade). The spring/ summer period was characterized by the industrial or different outdoor activities with several Saharan dust episodes. In addition, April and October were partly characterized by heating sources. The quartz filters with PM2.5 were digested by the microwave digestion system using 7 mL 65% HNO3 and 1 mL 30% H2 O2 . The concentrations of Al, B, Ba, Bi, Ca, K, Fe, Mn, Ni, P, S and Sr were measured using inductively coupled plasma-optical emission spectrometry (ICP-OES), while concentrations of Ag, As, Be, Cd, Co, Cu, Cr, Hg, Pb, Se, Sb and Tl were measured using inductively coupled plasma mass spectrometry (ICP-MS). The non-carcinogenic and carcinogenic risks for residents and for five different types of workers (outdoor, indoor, composite, construction and excavation workers) in this ambient were assessed by equations provided by The Risk Assessment Information System – RAIS [2]. Comparing the investigated scenarios, the highest non-carcinogenic and carcinogenic risks were observed for the residents. There were observed non-carcinogenic (HI>1) and carcinogenic (R≥1×10-5) risks for the residents from this area. The residents spent the most of their time in this ambient and they are most at the risk caused by the measured PM2.5 pollution (HImedian: 2.28; Rmedian: 1.25 × 10-4). Observing the scenarios for workers, the risk mostly depends on the time that workers spent outside during working hours. Similar non-carcinogenic risks were observed for outdoor, indoor and composite workers, slightly higher risk was observed for construction workers, while the lowest risk was obtained for an excavation worker who is less exposed to the PM2.5 atmospheric deposition than soil dust resuspension. The same was observed for the carcinogenic risk, while the similar risks were observed for all workers. Only for an excavation worker, the carcinogenic risk was significantly lower than for other workers. The most significant contributor to the non-carcinogenic risk in all scenarios was the concentration of Mn, and then the concentration of Be, while the most significant contributor to the carcinogenic risk was Cr6+. Observing the risks among the investigated period the highest non-carcinogenic and carcinogenic risks were observed in April and October based on the toxic and carcinogenic elements in PM2.5. In these months beside the influence of the industrial activities, dust episodes or activity of heating sorces possibly caused the increase of the toxic and carcinogenic elements in PM2.5.",
publisher = "Belgrade : Serbian Chemical Society",
journal = "Book of Abstracts 21st; European Meeting on Environmental Chemistry",
title = "Health Risk Assessment for Residents and Workers Based on Toxic and Carcinogenic Element Content from PM2.5 in Belgrade Suburban Area",
pages = "134-134",
url = "https://hdl.handle.net/21.15107/rcub_cherry_4921"
}
Mutavdžić, D., Aničić Urošević, M., Kuzmanoski, M., Kodranov, I. D., Popović, A. R.,& Relić, D.. (2021). Health Risk Assessment for Residents and Workers Based on Toxic and Carcinogenic Element Content from PM2.5 in Belgrade Suburban Area. in Book of Abstracts 21st; European Meeting on Environmental Chemistry
Belgrade : Serbian Chemical Society., 134-134.
https://hdl.handle.net/21.15107/rcub_cherry_4921
Mutavdžić D, Aničić Urošević M, Kuzmanoski M, Kodranov ID, Popović AR, Relić D. Health Risk Assessment for Residents and Workers Based on Toxic and Carcinogenic Element Content from PM2.5 in Belgrade Suburban Area. in Book of Abstracts 21st; European Meeting on Environmental Chemistry. 2021;:134-134.
https://hdl.handle.net/21.15107/rcub_cherry_4921 .
Mutavdžić, D., Aničić Urošević, M., Kuzmanoski, M., Kodranov, Igor D., Popović, Aleksandar R., Relić, Dubravka, "Health Risk Assessment for Residents and Workers Based on Toxic and Carcinogenic Element Content from PM2.5 in Belgrade Suburban Area" in Book of Abstracts 21st; European Meeting on Environmental Chemistry (2021):134-134,
https://hdl.handle.net/21.15107/rcub_cherry_4921 .

Release of wood extractable elements in experimental spirit model: Health risk assessment of the wood species generated in Balkan cooperage

Smailagić, Anita; Dabić Zagorac, Dragana; Veljović, Sonja; Sredojević, Milica; Relić, Dubravka; Fotirić-Akšić, Milica M.; Roglić, Goran; Natić, Maja

(Elsevier, 2021)

TY  - JOUR
AU  - Smailagić, Anita
AU  - Dabić Zagorac, Dragana
AU  - Veljović, Sonja
AU  - Sredojević, Milica
AU  - Relić, Dubravka
AU  - Fotirić-Akšić, Milica M.
AU  - Roglić, Goran
AU  - Natić, Maja
PY  - 2021
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/4105
AB  - This work investigates the release of toxic elements from wood into the experimental spirit models and the safety risks for consumers. The spirit models were prepared as ethanolic extracts using the procedure which reproduces maturation of spirits. Investigation included staves of wood species commonly used in Balkan cooperage: mulberry, Myrobalan plum, black locust, wild cherry, and various oaks. Potassium was the most abundant element, except in the wild cherry extract where calcium was dominant, and the Myrobalan plum extract where phosphorus was the most abundant. The parameters for the health risk assessment, such as hazard index (HI) and hazard quotient (HQ) were calculated for potentially toxic elements and indicated that all wood extracts would be safe for human consumption. Owing to the proven abundance of phenolics in the investigated wood extracts, relations among elements and phenolics were also studied and conclusions were made based on the statistically significant correlations.
PB  - Elsevier
T2  - Food Chemistry
T2  - Food ChemistryFood Chemistry
T1  - Release of wood extractable elements in experimental spirit model: Health risk assessment of the wood species generated in Balkan cooperage
VL  - 338
SP  - 127804
DO  - 10.1016/j.foodchem.2020.127804
ER  - 
@article{
author = "Smailagić, Anita and Dabić Zagorac, Dragana and Veljović, Sonja and Sredojević, Milica and Relić, Dubravka and Fotirić-Akšić, Milica M. and Roglić, Goran and Natić, Maja",
year = "2021",
abstract = "This work investigates the release of toxic elements from wood into the experimental spirit models and the safety risks for consumers. The spirit models were prepared as ethanolic extracts using the procedure which reproduces maturation of spirits. Investigation included staves of wood species commonly used in Balkan cooperage: mulberry, Myrobalan plum, black locust, wild cherry, and various oaks. Potassium was the most abundant element, except in the wild cherry extract where calcium was dominant, and the Myrobalan plum extract where phosphorus was the most abundant. The parameters for the health risk assessment, such as hazard index (HI) and hazard quotient (HQ) were calculated for potentially toxic elements and indicated that all wood extracts would be safe for human consumption. Owing to the proven abundance of phenolics in the investigated wood extracts, relations among elements and phenolics were also studied and conclusions were made based on the statistically significant correlations.",
publisher = "Elsevier",
journal = "Food Chemistry, Food ChemistryFood Chemistry",
title = "Release of wood extractable elements in experimental spirit model: Health risk assessment of the wood species generated in Balkan cooperage",
volume = "338",
pages = "127804",
doi = "10.1016/j.foodchem.2020.127804"
}
Smailagić, A., Dabić Zagorac, D., Veljović, S., Sredojević, M., Relić, D., Fotirić-Akšić, M. M., Roglić, G.,& Natić, M.. (2021). Release of wood extractable elements in experimental spirit model: Health risk assessment of the wood species generated in Balkan cooperage. in Food Chemistry
Elsevier., 338, 127804.
https://doi.org/10.1016/j.foodchem.2020.127804
Smailagić A, Dabić Zagorac D, Veljović S, Sredojević M, Relić D, Fotirić-Akšić MM, Roglić G, Natić M. Release of wood extractable elements in experimental spirit model: Health risk assessment of the wood species generated in Balkan cooperage. in Food Chemistry. 2021;338:127804.
doi:10.1016/j.foodchem.2020.127804 .
Smailagić, Anita, Dabić Zagorac, Dragana, Veljović, Sonja, Sredojević, Milica, Relić, Dubravka, Fotirić-Akšić, Milica M., Roglić, Goran, Natić, Maja, "Release of wood extractable elements in experimental spirit model: Health risk assessment of the wood species generated in Balkan cooperage" in Food Chemistry, 338 (2021):127804,
https://doi.org/10.1016/j.foodchem.2020.127804 . .
4
2
5
4

Supplementary data for the article: Smailagić, A.; Dabić Zagorac, D.; Veljović, S.; Sredojević, M.; Relić, D.; Fotirić Akšić, M.; Roglić, G.; Natić, M. Release of Wood Extractable Elements in Experimental Spirit Model: Health Risk Assessment of the Wood Species Generated in Balkan Cooperage. Food Chemistry 2021, 338, 127804. https://doi.org/10.1016/j.foodchem.2020.127804

Smailagić, Anita; Dabić Zagorac, Dragana; Veljović, Sonja; Sredojević, Milica; Relić, Dubravka; Fotirić-Akšić, Milica M.; Roglić, Goran; Natić, Maja

(Elsevier, 2021)

TY  - DATA
AU  - Smailagić, Anita
AU  - Dabić Zagorac, Dragana
AU  - Veljović, Sonja
AU  - Sredojević, Milica
AU  - Relić, Dubravka
AU  - Fotirić-Akšić, Milica M.
AU  - Roglić, Goran
AU  - Natić, Maja
PY  - 2021
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/4106
PB  - Elsevier
T2  - Food Chemistry
T1  - Supplementary data for the article: Smailagić, A.; Dabić Zagorac, D.; Veljović, S.; Sredojević, M.; Relić, D.; Fotirić Akšić, M.; Roglić, G.; Natić, M. Release of Wood Extractable Elements in Experimental Spirit Model: Health Risk Assessment of the Wood Species Generated in Balkan Cooperage. Food Chemistry 2021, 338, 127804. https://doi.org/10.1016/j.foodchem.2020.127804
UR  - https://hdl.handle.net/21.15107/rcub_cherry_4106
ER  - 
@misc{
author = "Smailagić, Anita and Dabić Zagorac, Dragana and Veljović, Sonja and Sredojević, Milica and Relić, Dubravka and Fotirić-Akšić, Milica M. and Roglić, Goran and Natić, Maja",
year = "2021",
publisher = "Elsevier",
journal = "Food Chemistry",
title = "Supplementary data for the article: Smailagić, A.; Dabić Zagorac, D.; Veljović, S.; Sredojević, M.; Relić, D.; Fotirić Akšić, M.; Roglić, G.; Natić, M. Release of Wood Extractable Elements in Experimental Spirit Model: Health Risk Assessment of the Wood Species Generated in Balkan Cooperage. Food Chemistry 2021, 338, 127804. https://doi.org/10.1016/j.foodchem.2020.127804",
url = "https://hdl.handle.net/21.15107/rcub_cherry_4106"
}
Smailagić, A., Dabić Zagorac, D., Veljović, S., Sredojević, M., Relić, D., Fotirić-Akšić, M. M., Roglić, G.,& Natić, M.. (2021). Supplementary data for the article: Smailagić, A.; Dabić Zagorac, D.; Veljović, S.; Sredojević, M.; Relić, D.; Fotirić Akšić, M.; Roglić, G.; Natić, M. Release of Wood Extractable Elements in Experimental Spirit Model: Health Risk Assessment of the Wood Species Generated in Balkan Cooperage. Food Chemistry 2021, 338, 127804. https://doi.org/10.1016/j.foodchem.2020.127804. in Food Chemistry
Elsevier..
https://hdl.handle.net/21.15107/rcub_cherry_4106
Smailagić A, Dabić Zagorac D, Veljović S, Sredojević M, Relić D, Fotirić-Akšić MM, Roglić G, Natić M. Supplementary data for the article: Smailagić, A.; Dabić Zagorac, D.; Veljović, S.; Sredojević, M.; Relić, D.; Fotirić Akšić, M.; Roglić, G.; Natić, M. Release of Wood Extractable Elements in Experimental Spirit Model: Health Risk Assessment of the Wood Species Generated in Balkan Cooperage. Food Chemistry 2021, 338, 127804. https://doi.org/10.1016/j.foodchem.2020.127804. in Food Chemistry. 2021;.
https://hdl.handle.net/21.15107/rcub_cherry_4106 .
Smailagić, Anita, Dabić Zagorac, Dragana, Veljović, Sonja, Sredojević, Milica, Relić, Dubravka, Fotirić-Akšić, Milica M., Roglić, Goran, Natić, Maja, "Supplementary data for the article: Smailagić, A.; Dabić Zagorac, D.; Veljović, S.; Sredojević, M.; Relić, D.; Fotirić Akšić, M.; Roglić, G.; Natić, M. Release of Wood Extractable Elements in Experimental Spirit Model: Health Risk Assessment of the Wood Species Generated in Balkan Cooperage. Food Chemistry 2021, 338, 127804. https://doi.org/10.1016/j.foodchem.2020.127804" in Food Chemistry (2021),
https://hdl.handle.net/21.15107/rcub_cherry_4106 .

Environmental pollution influence to soil–plant–air system in organic vineyard: bioavailability, environmental, and health risk assessment

Milićević, Tijana; Urošević-Aničić, Mira; Relić, Dubravka; Jovanović, Gordana; Nikolić, Dragica; Vergel, Konstantin; Popović, Aleksandar R.

(Springer, 2021)

TY  - JOUR
AU  - Milićević, Tijana
AU  - Urošević-Aničić, Mira
AU  - Relić, Dubravka
AU  - Jovanović, Gordana
AU  - Nikolić, Dragica
AU  - Vergel, Konstantin
AU  - Popović, Aleksandar R.
PY  - 2021
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/4807
AB  - This study was performed in organic vineyard to assess integrated pollution in soil–plant–air system by potentially toxic elements (PTE). Concentrations of 26 PTE were determined in soil, grapevine, and air biomonitors (moss bags) using ICP-OES and ICP-MS. Environmental implication assessment of soil did not show pollution by PTE, except for B in samples collected in the middle of grapevine season (July). Despite low total Cd concentrations in soil, it has the highest influence on increase of environmental risk. Based on biological accumulation concentration (BAC), grapevine is not hyperaccumulator of PTE from soil. Advanced classification algorithm, Kohonen self-organizing map (SOM), was applied to compare environmental implications in organic with conventional vineyards. PTE concentrations were significantly lower in organic than conventional grapevine. PTE concentrations were higher in the outer (leaf and petiole) than in the inner grapevine parts (skin, pulp, and seed). Some airborne elements have an influence on outer grapevine parts, especially on leaves (ratio factor—RF > 1). Moss bag technique testified about lower enrichment of airborne elements compared with the conventional vineyard and urban microenvironments. Environmental and health risk assessments confirmed that organic production is harmless for field workers and grape consumers.
PB  - Springer
T2  - Environmental Science and Pollution Research
T1  - Environmental pollution influence to soil–plant–air system in organic vineyard: bioavailability, environmental, and health risk assessment
VL  - 28
IS  - 3
SP  - 3361
EP  - 3374
DO  - 10.1007/s11356-020-10649-8
ER  - 
@article{
author = "Milićević, Tijana and Urošević-Aničić, Mira and Relić, Dubravka and Jovanović, Gordana and Nikolić, Dragica and Vergel, Konstantin and Popović, Aleksandar R.",
year = "2021",
abstract = "This study was performed in organic vineyard to assess integrated pollution in soil–plant–air system by potentially toxic elements (PTE). Concentrations of 26 PTE were determined in soil, grapevine, and air biomonitors (moss bags) using ICP-OES and ICP-MS. Environmental implication assessment of soil did not show pollution by PTE, except for B in samples collected in the middle of grapevine season (July). Despite low total Cd concentrations in soil, it has the highest influence on increase of environmental risk. Based on biological accumulation concentration (BAC), grapevine is not hyperaccumulator of PTE from soil. Advanced classification algorithm, Kohonen self-organizing map (SOM), was applied to compare environmental implications in organic with conventional vineyards. PTE concentrations were significantly lower in organic than conventional grapevine. PTE concentrations were higher in the outer (leaf and petiole) than in the inner grapevine parts (skin, pulp, and seed). Some airborne elements have an influence on outer grapevine parts, especially on leaves (ratio factor—RF > 1). Moss bag technique testified about lower enrichment of airborne elements compared with the conventional vineyard and urban microenvironments. Environmental and health risk assessments confirmed that organic production is harmless for field workers and grape consumers.",
publisher = "Springer",
journal = "Environmental Science and Pollution Research",
title = "Environmental pollution influence to soil–plant–air system in organic vineyard: bioavailability, environmental, and health risk assessment",
volume = "28",
number = "3",
pages = "3361-3374",
doi = "10.1007/s11356-020-10649-8"
}
Milićević, T., Urošević-Aničić, M., Relić, D., Jovanović, G., Nikolić, D., Vergel, K.,& Popović, A. R.. (2021). Environmental pollution influence to soil–plant–air system in organic vineyard: bioavailability, environmental, and health risk assessment. in Environmental Science and Pollution Research
Springer., 28(3), 3361-3374.
https://doi.org/10.1007/s11356-020-10649-8
Milićević T, Urošević-Aničić M, Relić D, Jovanović G, Nikolić D, Vergel K, Popović AR. Environmental pollution influence to soil–plant–air system in organic vineyard: bioavailability, environmental, and health risk assessment. in Environmental Science and Pollution Research. 2021;28(3):3361-3374.
doi:10.1007/s11356-020-10649-8 .
Milićević, Tijana, Urošević-Aničić, Mira, Relić, Dubravka, Jovanović, Gordana, Nikolić, Dragica, Vergel, Konstantin, Popović, Aleksandar R., "Environmental pollution influence to soil–plant–air system in organic vineyard: bioavailability, environmental, and health risk assessment" in Environmental Science and Pollution Research, 28, no. 3 (2021):3361-3374,
https://doi.org/10.1007/s11356-020-10649-8 . .
1
17
4
16
13

Supplementary data for the article: Milićević, T.; Aničić Urošević, M.; Relić, D.; Jovanović, G.; Nikolić, D.; Vergel, K.; Popović, A. Environmental Pollution Influence to Soil–Plant–Air System in Organic Vineyard: Bioavailability, Environmental, and Health Risk Assessment. Environ Sci Pollut Res 2021, 28 (3), 3361–3374. https://doi.org/10.1007/s11356-020-10649-8.

Milićević, Tijana; Urošević-Aničić, Mira; Relić, Dubravka; Jovanović, Gordana; Nikolić, Dragica; Vergel, Konstantin; Popović, Aleksandar R.

(Springer, 2021)

TY  - DATA
AU  - Milićević, Tijana
AU  - Urošević-Aničić, Mira
AU  - Relić, Dubravka
AU  - Jovanović, Gordana
AU  - Nikolić, Dragica
AU  - Vergel, Konstantin
AU  - Popović, Aleksandar R.
PY  - 2021
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/4808
PB  - Springer
T2  - Environmental Science and Pollution Research
T1  - Supplementary data for the article: Milićević, T.; Aničić Urošević, M.; Relić, D.; Jovanović, G.; Nikolić, D.; Vergel, K.; Popović, A. Environmental Pollution Influence to Soil–Plant–Air System in Organic Vineyard: Bioavailability, Environmental, and Health Risk Assessment. Environ Sci Pollut Res 2021, 28 (3), 3361–3374. https://doi.org/10.1007/s11356-020-10649-8.
UR  - https://hdl.handle.net/21.15107/rcub_cherry_4808
ER  - 
@misc{
author = "Milićević, Tijana and Urošević-Aničić, Mira and Relić, Dubravka and Jovanović, Gordana and Nikolić, Dragica and Vergel, Konstantin and Popović, Aleksandar R.",
year = "2021",
publisher = "Springer",
journal = "Environmental Science and Pollution Research",
title = "Supplementary data for the article: Milićević, T.; Aničić Urošević, M.; Relić, D.; Jovanović, G.; Nikolić, D.; Vergel, K.; Popović, A. Environmental Pollution Influence to Soil–Plant–Air System in Organic Vineyard: Bioavailability, Environmental, and Health Risk Assessment. Environ Sci Pollut Res 2021, 28 (3), 3361–3374. https://doi.org/10.1007/s11356-020-10649-8.",
url = "https://hdl.handle.net/21.15107/rcub_cherry_4808"
}
Milićević, T., Urošević-Aničić, M., Relić, D., Jovanović, G., Nikolić, D., Vergel, K.,& Popović, A. R.. (2021). Supplementary data for the article: Milićević, T.; Aničić Urošević, M.; Relić, D.; Jovanović, G.; Nikolić, D.; Vergel, K.; Popović, A. Environmental Pollution Influence to Soil–Plant–Air System in Organic Vineyard: Bioavailability, Environmental, and Health Risk Assessment. Environ Sci Pollut Res 2021, 28 (3), 3361–3374. https://doi.org/10.1007/s11356-020-10649-8.. in Environmental Science and Pollution Research
Springer..
https://hdl.handle.net/21.15107/rcub_cherry_4808
Milićević T, Urošević-Aničić M, Relić D, Jovanović G, Nikolić D, Vergel K, Popović AR. Supplementary data for the article: Milićević, T.; Aničić Urošević, M.; Relić, D.; Jovanović, G.; Nikolić, D.; Vergel, K.; Popović, A. Environmental Pollution Influence to Soil–Plant–Air System in Organic Vineyard: Bioavailability, Environmental, and Health Risk Assessment. Environ Sci Pollut Res 2021, 28 (3), 3361–3374. https://doi.org/10.1007/s11356-020-10649-8.. in Environmental Science and Pollution Research. 2021;.
https://hdl.handle.net/21.15107/rcub_cherry_4808 .
Milićević, Tijana, Urošević-Aničić, Mira, Relić, Dubravka, Jovanović, Gordana, Nikolić, Dragica, Vergel, Konstantin, Popović, Aleksandar R., "Supplementary data for the article: Milićević, T.; Aničić Urošević, M.; Relić, D.; Jovanović, G.; Nikolić, D.; Vergel, K.; Popović, A. Environmental Pollution Influence to Soil–Plant–Air System in Organic Vineyard: Bioavailability, Environmental, and Health Risk Assessment. Environ Sci Pollut Res 2021, 28 (3), 3361–3374. https://doi.org/10.1007/s11356-020-10649-8." in Environmental Science and Pollution Research (2021),
https://hdl.handle.net/21.15107/rcub_cherry_4808 .

Comparative Study of Removal Efficiency for Ni and Cd from Industrial Wastewater and Aqueous Solution by Sunflower Husk Using ICP-OES and LIBS

Radenković, M.; Petrović, J.; Momčilović, M.; Živković, S.; Relić, Dubravka; Popović, Aleksandar R.

(Belgrade : Serbian Chemical Society, 2021)

TY  - CONF
AU  - Radenković, M.
AU  - Petrović, J.
AU  - Momčilović, M.
AU  - Živković, S.
AU  - Relić, Dubravka
AU  - Popović, Aleksandar R.
PY  - 2021
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/4914
AB  - With the growth of the industrial world and the rise of anthropogenic activities, environmental challenges have also increased. Wastewater, especially from industrial sources can contain a wide variety of heavy metals [1]. The presence of heavy metals in water resources is a cause for concern due to their toxicity and tendency to bioaccumulation, which leads to significant problems for the environment as well as for animals and humans [2]. There are various conventional treatment technologies that are used for the removal of heavy metals from wastewater such as reverse osmosis, electrodialysis, ultrafiltration, industrial ion exchange process, and chemical precipitation. These techniques have some drawbacks such a being expensive due to high reagent and energy requirements, incomplete metal removal at low concentrations of heavy metals and generation of sludge [1]. Therefore, biosorption has been the subject of research by scientists for almost 70 years in order to find efficient, effective, and low-cost biomaterials for wastewater treatment [3]. In this study, a sunflower husk treated with 1% hydrochloric acid was used to evaluate removal efficiency for Ni from real wastewater samples, as well as to estimate the adsorption capacity as a function of contact time between the heavy metal ions such as Cd in the aqueous solution and the sunflower husk as a biosorbent. Two techniques were used for quantitative analysis, Inductively Coupled Plasma Optical Emission Spectrometry (ICP-OES) as a standard reference method and laser-induced plasma spectroscopy (LIBS) as an innovative non-standard analytical method. What makes the LIBS superior from the other standard optical techniques is that it allows fast multi-elemental analysis without prior sample preparation, leads to minimal sample damage, and is considered almost non-destructive, this method is also by the principles of green analytical chemistry, which means that it does not use toxic reagents and therefore no chemical waste [4]. The results of these two methods were compared, to examine the possibility of using laser-induced plasma spectroscopy as an alternative green analytical technology for quantitative analysis of sunflower husk as a biosorbent and evaluation of biosorption efficiency as a function of contact time.
PB  - Belgrade : Serbian Chemical Society
C3  - Book of Abstracts 21st; European Meeting on Environmental Chemistry
T1  - Comparative Study of Removal Efficiency for Ni and Cd from Industrial Wastewater and Aqueous Solution by Sunflower Husk Using ICP-OES and LIBS
SP  - 100
EP  - 100
UR  - https://hdl.handle.net/21.15107/rcub_cherry_4914
ER  - 
@conference{
author = "Radenković, M. and Petrović, J. and Momčilović, M. and Živković, S. and Relić, Dubravka and Popović, Aleksandar R.",
year = "2021",
abstract = "With the growth of the industrial world and the rise of anthropogenic activities, environmental challenges have also increased. Wastewater, especially from industrial sources can contain a wide variety of heavy metals [1]. The presence of heavy metals in water resources is a cause for concern due to their toxicity and tendency to bioaccumulation, which leads to significant problems for the environment as well as for animals and humans [2]. There are various conventional treatment technologies that are used for the removal of heavy metals from wastewater such as reverse osmosis, electrodialysis, ultrafiltration, industrial ion exchange process, and chemical precipitation. These techniques have some drawbacks such a being expensive due to high reagent and energy requirements, incomplete metal removal at low concentrations of heavy metals and generation of sludge [1]. Therefore, biosorption has been the subject of research by scientists for almost 70 years in order to find efficient, effective, and low-cost biomaterials for wastewater treatment [3]. In this study, a sunflower husk treated with 1% hydrochloric acid was used to evaluate removal efficiency for Ni from real wastewater samples, as well as to estimate the adsorption capacity as a function of contact time between the heavy metal ions such as Cd in the aqueous solution and the sunflower husk as a biosorbent. Two techniques were used for quantitative analysis, Inductively Coupled Plasma Optical Emission Spectrometry (ICP-OES) as a standard reference method and laser-induced plasma spectroscopy (LIBS) as an innovative non-standard analytical method. What makes the LIBS superior from the other standard optical techniques is that it allows fast multi-elemental analysis without prior sample preparation, leads to minimal sample damage, and is considered almost non-destructive, this method is also by the principles of green analytical chemistry, which means that it does not use toxic reagents and therefore no chemical waste [4]. The results of these two methods were compared, to examine the possibility of using laser-induced plasma spectroscopy as an alternative green analytical technology for quantitative analysis of sunflower husk as a biosorbent and evaluation of biosorption efficiency as a function of contact time.",
publisher = "Belgrade : Serbian Chemical Society",
journal = "Book of Abstracts 21st; European Meeting on Environmental Chemistry",
title = "Comparative Study of Removal Efficiency for Ni and Cd from Industrial Wastewater and Aqueous Solution by Sunflower Husk Using ICP-OES and LIBS",
pages = "100-100",
url = "https://hdl.handle.net/21.15107/rcub_cherry_4914"
}
Radenković, M., Petrović, J., Momčilović, M., Živković, S., Relić, D.,& Popović, A. R.. (2021). Comparative Study of Removal Efficiency for Ni and Cd from Industrial Wastewater and Aqueous Solution by Sunflower Husk Using ICP-OES and LIBS. in Book of Abstracts 21st; European Meeting on Environmental Chemistry
Belgrade : Serbian Chemical Society., 100-100.
https://hdl.handle.net/21.15107/rcub_cherry_4914
Radenković M, Petrović J, Momčilović M, Živković S, Relić D, Popović AR. Comparative Study of Removal Efficiency for Ni and Cd from Industrial Wastewater and Aqueous Solution by Sunflower Husk Using ICP-OES and LIBS. in Book of Abstracts 21st; European Meeting on Environmental Chemistry. 2021;:100-100.
https://hdl.handle.net/21.15107/rcub_cherry_4914 .
Radenković, M., Petrović, J., Momčilović, M., Živković, S., Relić, Dubravka, Popović, Aleksandar R., "Comparative Study of Removal Efficiency for Ni and Cd from Industrial Wastewater and Aqueous Solution by Sunflower Husk Using ICP-OES and LIBS" in Book of Abstracts 21st; European Meeting on Environmental Chemistry (2021):100-100,
https://hdl.handle.net/21.15107/rcub_cherry_4914 .

The Health Risk and Benefit Assessments for the Pelagic Fish Species’ Consumers

Milićević, T.; Herceg Romanić, S.; Popović, A.; Mustać, B.; Đinović-Stojanović, J.; Jovanović, G.; Relić, Dubravka

(Belgrade : Serbian Chemical Society, 2021)

TY  - CONF
AU  - Milićević, T.
AU  - Herceg Romanić, S.
AU  - Popović, A.
AU  - Mustać, B.
AU  - Đinović-Stojanović, J.
AU  - Jovanović, G.
AU  - Relić, Dubravka
PY  - 2021
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/4910
AB  - To balance the ingestion of healthy omega-3 and omega-6 fatty acids and adverse chemicals the assessments of benefits and risks of the fish consumption should be of the great importance. Elements, Persistent organic pollutants – POPs (organochlorine pesticides – OCPs and polychlorinated biphenyls – PCB), and omega-3 and omega-6 fatty acid contents were determined in six small pelagic fish species from the Adriatic Sea in Croatia to assess health risks for consumers. 16 element, 24 POPs and 14 fatty acid contents were determined in edible fishes to assess worst-case scenario, diseases development risks and benefit-risk for consumers. The results of this study were published in the scientific journal [1]. Element concentrations were measured by inductively coupled plasma mass spectrometry (ICP-MS), POPs by high-resolution gas chromatography (HRGC) and fatty acid content by gas–liquid partition chromatography (GLPC). The results of our study showed that diet based on chub mackerel and round sardinella have highest DI of essential omega-3 fatty acids and lower daily intake (DI) of POPs than other fishes. By consuming anchovy and round sardinella lower ingestion of toxic elements can be ingested. There was not observed non-carcinogenic (HI) nor carcinogenic (CR) risks based on POP concentrations, while based on element concentrations, there was low HI (0.1≥HI≥1) and the maximum HIs and outlier values (several horse mackerel and anchovy samples) showed the presence of HI (HI>1). The most significant contributor to total non-carcinogenic and carcinogenic risks was inorganic As. Acceptable CR for consumers was assessed, but maximum CR for consumers of horse mackerel and anchovy (CR≥1×10-6) showed adverse effects on human health. There were low HIs for developing cardiovascular, nervous, and reproductive diseases, and maximum HIs were higher than 1. Acceptable (1×10-4≥CR≥1×10- 6 ) risks were observed for developing cancer of nervous system and reproductive organs. Among investigated fish samples, those with higher ƩBR (benefit-risks) and BR for inorganic As than median value have a higher risk than benefits in the human diet (most of them were collected in 2015) [1].
PB  - Belgrade : Serbian Chemical Society
C3  - Book of Abstracts 21st; European Meeting on Environmental Chemistry
T1  - The Health Risk and Benefit Assessments for the Pelagic Fish Species’ Consumers
SP  - 80
EP  - 80
UR  - https://hdl.handle.net/21.15107/rcub_cherry_4910
ER  - 
@conference{
author = "Milićević, T. and Herceg Romanić, S. and Popović, A. and Mustać, B. and Đinović-Stojanović, J. and Jovanović, G. and Relić, Dubravka",
year = "2021",
abstract = "To balance the ingestion of healthy omega-3 and omega-6 fatty acids and adverse chemicals the assessments of benefits and risks of the fish consumption should be of the great importance. Elements, Persistent organic pollutants – POPs (organochlorine pesticides – OCPs and polychlorinated biphenyls – PCB), and omega-3 and omega-6 fatty acid contents were determined in six small pelagic fish species from the Adriatic Sea in Croatia to assess health risks for consumers. 16 element, 24 POPs and 14 fatty acid contents were determined in edible fishes to assess worst-case scenario, diseases development risks and benefit-risk for consumers. The results of this study were published in the scientific journal [1]. Element concentrations were measured by inductively coupled plasma mass spectrometry (ICP-MS), POPs by high-resolution gas chromatography (HRGC) and fatty acid content by gas–liquid partition chromatography (GLPC). The results of our study showed that diet based on chub mackerel and round sardinella have highest DI of essential omega-3 fatty acids and lower daily intake (DI) of POPs than other fishes. By consuming anchovy and round sardinella lower ingestion of toxic elements can be ingested. There was not observed non-carcinogenic (HI) nor carcinogenic (CR) risks based on POP concentrations, while based on element concentrations, there was low HI (0.1≥HI≥1) and the maximum HIs and outlier values (several horse mackerel and anchovy samples) showed the presence of HI (HI>1). The most significant contributor to total non-carcinogenic and carcinogenic risks was inorganic As. Acceptable CR for consumers was assessed, but maximum CR for consumers of horse mackerel and anchovy (CR≥1×10-6) showed adverse effects on human health. There were low HIs for developing cardiovascular, nervous, and reproductive diseases, and maximum HIs were higher than 1. Acceptable (1×10-4≥CR≥1×10- 6 ) risks were observed for developing cancer of nervous system and reproductive organs. Among investigated fish samples, those with higher ƩBR (benefit-risks) and BR for inorganic As than median value have a higher risk than benefits in the human diet (most of them were collected in 2015) [1].",
publisher = "Belgrade : Serbian Chemical Society",
journal = "Book of Abstracts 21st; European Meeting on Environmental Chemistry",
title = "The Health Risk and Benefit Assessments for the Pelagic Fish Species’ Consumers",
pages = "80-80",
url = "https://hdl.handle.net/21.15107/rcub_cherry_4910"
}
Milićević, T., Herceg Romanić, S., Popović, A., Mustać, B., Đinović-Stojanović, J., Jovanović, G.,& Relić, D.. (2021). The Health Risk and Benefit Assessments for the Pelagic Fish Species’ Consumers. in Book of Abstracts 21st; European Meeting on Environmental Chemistry
Belgrade : Serbian Chemical Society., 80-80.
https://hdl.handle.net/21.15107/rcub_cherry_4910
Milićević T, Herceg Romanić S, Popović A, Mustać B, Đinović-Stojanović J, Jovanović G, Relić D. The Health Risk and Benefit Assessments for the Pelagic Fish Species’ Consumers. in Book of Abstracts 21st; European Meeting on Environmental Chemistry. 2021;:80-80.
https://hdl.handle.net/21.15107/rcub_cherry_4910 .
Milićević, T., Herceg Romanić, S., Popović, A., Mustać, B., Đinović-Stojanović, J., Jovanović, G., Relić, Dubravka, "The Health Risk and Benefit Assessments for the Pelagic Fish Species’ Consumers" in Book of Abstracts 21st; European Meeting on Environmental Chemistry (2021):80-80,
https://hdl.handle.net/21.15107/rcub_cherry_4910 .

Pollution and health risk assessments of potentially toxic elements in soil and sediment samples in a petrochemical industry and surrounding area

Relić, Dubravka; Sakan, Sanja M.; Anđelković, Ivan; Popović, Aleksandar R.; Đorđević, Dragana S.

(MDPI, 2019)

TY  - JOUR
AU  - Relić, Dubravka
AU  - Sakan, Sanja M.
AU  - Anđelković, Ivan
AU  - Popović, Aleksandar R.
AU  - Đorđević, Dragana S.
PY  - 2019
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3146
AB  - The pollution state and health risk assessment of potentially toxic elements (PTE) in soil and sediment samples of the petrochemical industry and its surrounding area are evaluated in this study. The pseudo-total contents of Ba, Cd, Co, Cu, Cr, Mn, Ni, Pb, V, Zn, As, Hg, and Se were measured by inductively coupled plasma–optical emission spectrometry (ICP/OES) in analyzed samples. Instead of determining total content, we performed aqua regia of the samples. The silicate matrix remained, and the quantities of elements that are within the silicate matrix do not represent an environmental danger. The soils from the chlor–alkali plant are highly polluted by Hg (the enrichment factor values were above 6000), and by Cu, Cd, Pb, and Zn, while the sediment samples from the wastewater channel are polluted with Cr, Cd, and Hg. The measured element contents are used for calculating health risk criteria for a composite worker (a worker who is exposed, long-term, during the work day) and for residential people. Hg is the element that mainly contributes to non-carcinogenic risks within the petrochemical area. The highest value of total carcinogenic risk obtained in the sediment sample from the wastewater channel, and the metal that mostly contributes is Cr. The areas closest to the petrochemical industry have higher values of health risk criteria parameters and pollution indices. The areas that are located further to the north and south from the petrochemical industry are less burdened with the analyzed elements, which is significant because the closest city and village are situated in those directions.
PB  - MDPI
T2  - Molecules
T1  - Pollution and health risk assessments of potentially toxic elements in soil and sediment samples in a petrochemical industry and surrounding area
VL  - 24
IS  - 11
SP  - 1
EP  - 19
DO  - 10.3390/molecules24112139
ER  - 
@article{
author = "Relić, Dubravka and Sakan, Sanja M. and Anđelković, Ivan and Popović, Aleksandar R. and Đorđević, Dragana S.",
year = "2019",
abstract = "The pollution state and health risk assessment of potentially toxic elements (PTE) in soil and sediment samples of the petrochemical industry and its surrounding area are evaluated in this study. The pseudo-total contents of Ba, Cd, Co, Cu, Cr, Mn, Ni, Pb, V, Zn, As, Hg, and Se were measured by inductively coupled plasma–optical emission spectrometry (ICP/OES) in analyzed samples. Instead of determining total content, we performed aqua regia of the samples. The silicate matrix remained, and the quantities of elements that are within the silicate matrix do not represent an environmental danger. The soils from the chlor–alkali plant are highly polluted by Hg (the enrichment factor values were above 6000), and by Cu, Cd, Pb, and Zn, while the sediment samples from the wastewater channel are polluted with Cr, Cd, and Hg. The measured element contents are used for calculating health risk criteria for a composite worker (a worker who is exposed, long-term, during the work day) and for residential people. Hg is the element that mainly contributes to non-carcinogenic risks within the petrochemical area. The highest value of total carcinogenic risk obtained in the sediment sample from the wastewater channel, and the metal that mostly contributes is Cr. The areas closest to the petrochemical industry have higher values of health risk criteria parameters and pollution indices. The areas that are located further to the north and south from the petrochemical industry are less burdened with the analyzed elements, which is significant because the closest city and village are situated in those directions.",
publisher = "MDPI",
journal = "Molecules",
title = "Pollution and health risk assessments of potentially toxic elements in soil and sediment samples in a petrochemical industry and surrounding area",
volume = "24",
number = "11",
pages = "1-19",
doi = "10.3390/molecules24112139"
}
Relić, D., Sakan, S. M., Anđelković, I., Popović, A. R.,& Đorđević, D. S.. (2019). Pollution and health risk assessments of potentially toxic elements in soil and sediment samples in a petrochemical industry and surrounding area. in Molecules
MDPI., 24(11), 1-19.
https://doi.org/10.3390/molecules24112139
Relić D, Sakan SM, Anđelković I, Popović AR, Đorđević DS. Pollution and health risk assessments of potentially toxic elements in soil and sediment samples in a petrochemical industry and surrounding area. in Molecules. 2019;24(11):1-19.
doi:10.3390/molecules24112139 .
Relić, Dubravka, Sakan, Sanja M., Anđelković, Ivan, Popović, Aleksandar R., Đorđević, Dragana S., "Pollution and health risk assessments of potentially toxic elements in soil and sediment samples in a petrochemical industry and surrounding area" in Molecules, 24, no. 11 (2019):1-19,
https://doi.org/10.3390/molecules24112139 . .
1
19
8
20
16

Supplementary data for article: Relić, D.; Sakan, S.; Anđelković, I.; Popović, A.; Đorđević, D. Pollution and Health Risk Assessments of Potentially Toxic Elements in Soil and Sediment Samples in a Petrochemical Industry and Surrounding Area. Molecules 2019, 24 (11). https://doi.org/10.3390/molecules24112139

Relić, Dubravka; Sakan, Sanja M.; Anđelković, Ivan; Popović, Aleksandar R.; Đorđević, Dragana S.

(MDPI, 2019)

TY  - DATA
AU  - Relić, Dubravka
AU  - Sakan, Sanja M.
AU  - Anđelković, Ivan
AU  - Popović, Aleksandar R.
AU  - Đorđević, Dragana S.
PY  - 2019
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3147
PB  - MDPI
T2  - Molecules
T1  - Supplementary data for article: Relić, D.; Sakan, S.; Anđelković, I.; Popović, A.; Đorđević, D. Pollution and Health Risk Assessments of Potentially Toxic Elements in Soil and Sediment Samples in a Petrochemical Industry and Surrounding Area. Molecules 2019, 24 (11). https://doi.org/10.3390/molecules24112139
UR  - https://hdl.handle.net/21.15107/rcub_cherry_3147
ER  - 
@misc{
author = "Relić, Dubravka and Sakan, Sanja M. and Anđelković, Ivan and Popović, Aleksandar R. and Đorđević, Dragana S.",
year = "2019",
publisher = "MDPI",
journal = "Molecules",
title = "Supplementary data for article: Relić, D.; Sakan, S.; Anđelković, I.; Popović, A.; Đorđević, D. Pollution and Health Risk Assessments of Potentially Toxic Elements in Soil and Sediment Samples in a Petrochemical Industry and Surrounding Area. Molecules 2019, 24 (11). https://doi.org/10.3390/molecules24112139",
url = "https://hdl.handle.net/21.15107/rcub_cherry_3147"
}
Relić, D., Sakan, S. M., Anđelković, I., Popović, A. R.,& Đorđević, D. S.. (2019). Supplementary data for article: Relić, D.; Sakan, S.; Anđelković, I.; Popović, A.; Đorđević, D. Pollution and Health Risk Assessments of Potentially Toxic Elements in Soil and Sediment Samples in a Petrochemical Industry and Surrounding Area. Molecules 2019, 24 (11). https://doi.org/10.3390/molecules24112139. in Molecules
MDPI..
https://hdl.handle.net/21.15107/rcub_cherry_3147
Relić D, Sakan SM, Anđelković I, Popović AR, Đorđević DS. Supplementary data for article: Relić, D.; Sakan, S.; Anđelković, I.; Popović, A.; Đorđević, D. Pollution and Health Risk Assessments of Potentially Toxic Elements in Soil and Sediment Samples in a Petrochemical Industry and Surrounding Area. Molecules 2019, 24 (11). https://doi.org/10.3390/molecules24112139. in Molecules. 2019;.
https://hdl.handle.net/21.15107/rcub_cherry_3147 .
Relić, Dubravka, Sakan, Sanja M., Anđelković, Ivan, Popović, Aleksandar R., Đorđević, Dragana S., "Supplementary data for article: Relić, D.; Sakan, S.; Anđelković, I.; Popović, A.; Đorđević, D. Pollution and Health Risk Assessments of Potentially Toxic Elements in Soil and Sediment Samples in a Petrochemical Industry and Surrounding Area. Molecules 2019, 24 (11). https://doi.org/10.3390/molecules24112139" in Molecules (2019),
https://hdl.handle.net/21.15107/rcub_cherry_3147 .

Levels of toxic elements in canned fish from the Serbian markets and their health risks assessment

Popović, Aleksandar R.; Đinović-Stojanović, Jasna; Đorđević, Dragana S.; Relić, Dubravka; Vranić, Danijela; Milijašević, Milan P.; Pezo, Lato

(Academic Press Inc Elsevier Science, San Diego, 2018)

TY  - JOUR
AU  - Popović, Aleksandar R.
AU  - Đinović-Stojanović, Jasna
AU  - Đorđević, Dragana S.
AU  - Relić, Dubravka
AU  - Vranić, Danijela
AU  - Milijašević, Milan P.
AU  - Pezo, Lato
PY  - 2018
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3235
AB  - A total of 138 samples of canned tuna, sardines and mackerel from the Serbian market were analyzed for toxic (As, Cd, Pb, Hg) element levels using ICPMS. The highest average contents of toxic elements were found to be 1.70 mg kg(-1) for arsenic and 0.026 mg kg(-1) for cadmium in sardine and 0.068 mg kg(-1) for mercury in tuna. The lead content was very similar (similar to 0.048 mg kg(-1)) of the three types of canned fish. None of the fish analyzed contained toxic elements in levels exceeding the maximum allowable levels currently in force. Human health risk assessment of As, Cd, Pb and Hg in canned fish were investigated. A risk assessment based on the measured levels of examined elements indicated that consumption of canned fish according to current eating habits in Serbia presents little risk to human health since the carcinogenic risk is within the acceptable range, 10(-4)-10(-6).
PB  - Academic Press Inc Elsevier Science, San Diego
T2  - Journal of Food Composition and Analysis
T1  - Levels of toxic elements in canned fish from the Serbian markets and their health risks assessment
VL  - 67
SP  - 70
EP  - 76
DO  - 10.1016/j.jfca.2018.01.003
ER  - 
@article{
author = "Popović, Aleksandar R. and Đinović-Stojanović, Jasna and Đorđević, Dragana S. and Relić, Dubravka and Vranić, Danijela and Milijašević, Milan P. and Pezo, Lato",
year = "2018",
abstract = "A total of 138 samples of canned tuna, sardines and mackerel from the Serbian market were analyzed for toxic (As, Cd, Pb, Hg) element levels using ICPMS. The highest average contents of toxic elements were found to be 1.70 mg kg(-1) for arsenic and 0.026 mg kg(-1) for cadmium in sardine and 0.068 mg kg(-1) for mercury in tuna. The lead content was very similar (similar to 0.048 mg kg(-1)) of the three types of canned fish. None of the fish analyzed contained toxic elements in levels exceeding the maximum allowable levels currently in force. Human health risk assessment of As, Cd, Pb and Hg in canned fish were investigated. A risk assessment based on the measured levels of examined elements indicated that consumption of canned fish according to current eating habits in Serbia presents little risk to human health since the carcinogenic risk is within the acceptable range, 10(-4)-10(-6).",
publisher = "Academic Press Inc Elsevier Science, San Diego",
journal = "Journal of Food Composition and Analysis",
title = "Levels of toxic elements in canned fish from the Serbian markets and their health risks assessment",
volume = "67",
pages = "70-76",
doi = "10.1016/j.jfca.2018.01.003"
}
Popović, A. R., Đinović-Stojanović, J., Đorđević, D. S., Relić, D., Vranić, D., Milijašević, M. P.,& Pezo, L.. (2018). Levels of toxic elements in canned fish from the Serbian markets and their health risks assessment. in Journal of Food Composition and Analysis
Academic Press Inc Elsevier Science, San Diego., 67, 70-76.
https://doi.org/10.1016/j.jfca.2018.01.003
Popović AR, Đinović-Stojanović J, Đorđević DS, Relić D, Vranić D, Milijašević MP, Pezo L. Levels of toxic elements in canned fish from the Serbian markets and their health risks assessment. in Journal of Food Composition and Analysis. 2018;67:70-76.
doi:10.1016/j.jfca.2018.01.003 .
Popović, Aleksandar R., Đinović-Stojanović, Jasna, Đorđević, Dragana S., Relić, Dubravka, Vranić, Danijela, Milijašević, Milan P., Pezo, Lato, "Levels of toxic elements in canned fish from the Serbian markets and their health risks assessment" in Journal of Food Composition and Analysis, 67 (2018):70-76,
https://doi.org/10.1016/j.jfca.2018.01.003 . .
27
15
27
19

Ranking and similarity of conventional, microwave and ultrasound element sequential extraction methods

Héberger, Karoly; Sakan, Sanja M.; Škrbić, Biljana; Popović, Aleksandar R.; Đorđević, Dragana S.; Relić, Dubravka

(Pergamon-Elsevier Science Ltd, Oxford, 2018)

TY  - JOUR
AU  - Héberger, Karoly
AU  - Sakan, Sanja M.
AU  - Škrbić, Biljana
AU  - Popović, Aleksandar R.
AU  - Đorđević, Dragana S.
AU  - Relić, Dubravka
PY  - 2018
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3250
AB  - This study aims to compare three extraction techniques of four sequential element extraction steps from soil and sediment samples that were taken from the location of the Pancevo petrochemical industry (Serbia). Elements were extracted using three different techniques: conventional, microwave and ultrasound extraction. A novel procedure sum of the ranking differences (SRD) - was able to rank the techniques and elements, to see whether this method is a suitable tool to reveal the similarities and dissimilarities in element extraction techniques, provided that a proper ranking reference is available. The concentrations of the following elements Al, Ba, Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Na, Ni, Pb, Si, Sn, Sr, V and Zn were determined through ICP OES. The different efficiencies and recovery values of element concentrations using each of the three extraction techniques were examined by the CRM BCR-701. By using SRD, we obtained a better separation between the different extraction techniques and steps when we rank their differences among the samples while lower separation was obtained according to analysed elements. Appling this method for ordering the elements could be useful for three purposes: (i) to find possible associations among the elements; (ii) to find possible elements that have outlier concentrations or (iii) detect differences in geochemical origin or behaviour of elements. Cross-validation of the SRD values in combination with cluster and principal component analysis revealed the same groups of extraction steps and techniques. (C) 2018 Elsevier Ltd. All rights reserved.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - Chemosphere
T1  - Ranking and similarity of conventional, microwave and ultrasound element sequential extraction methods
VL  - 198
SP  - 103
EP  - 110
DO  - 10.1016/j.chemosphere.2017.12.200
ER  - 
@article{
author = "Héberger, Karoly and Sakan, Sanja M. and Škrbić, Biljana and Popović, Aleksandar R. and Đorđević, Dragana S. and Relić, Dubravka",
year = "2018",
abstract = "This study aims to compare three extraction techniques of four sequential element extraction steps from soil and sediment samples that were taken from the location of the Pancevo petrochemical industry (Serbia). Elements were extracted using three different techniques: conventional, microwave and ultrasound extraction. A novel procedure sum of the ranking differences (SRD) - was able to rank the techniques and elements, to see whether this method is a suitable tool to reveal the similarities and dissimilarities in element extraction techniques, provided that a proper ranking reference is available. The concentrations of the following elements Al, Ba, Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Na, Ni, Pb, Si, Sn, Sr, V and Zn were determined through ICP OES. The different efficiencies and recovery values of element concentrations using each of the three extraction techniques were examined by the CRM BCR-701. By using SRD, we obtained a better separation between the different extraction techniques and steps when we rank their differences among the samples while lower separation was obtained according to analysed elements. Appling this method for ordering the elements could be useful for three purposes: (i) to find possible associations among the elements; (ii) to find possible elements that have outlier concentrations or (iii) detect differences in geochemical origin or behaviour of elements. Cross-validation of the SRD values in combination with cluster and principal component analysis revealed the same groups of extraction steps and techniques. (C) 2018 Elsevier Ltd. All rights reserved.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Chemosphere",
title = "Ranking and similarity of conventional, microwave and ultrasound element sequential extraction methods",
volume = "198",
pages = "103-110",
doi = "10.1016/j.chemosphere.2017.12.200"
}
Héberger, K., Sakan, S. M., Škrbić, B., Popović, A. R., Đorđević, D. S.,& Relić, D.. (2018). Ranking and similarity of conventional, microwave and ultrasound element sequential extraction methods. in Chemosphere
Pergamon-Elsevier Science Ltd, Oxford., 198, 103-110.
https://doi.org/10.1016/j.chemosphere.2017.12.200
Héberger K, Sakan SM, Škrbić B, Popović AR, Đorđević DS, Relić D. Ranking and similarity of conventional, microwave and ultrasound element sequential extraction methods. in Chemosphere. 2018;198:103-110.
doi:10.1016/j.chemosphere.2017.12.200 .
Héberger, Karoly, Sakan, Sanja M., Škrbić, Biljana, Popović, Aleksandar R., Đorđević, Dragana S., Relić, Dubravka, "Ranking and similarity of conventional, microwave and ultrasound element sequential extraction methods" in Chemosphere, 198 (2018):103-110,
https://doi.org/10.1016/j.chemosphere.2017.12.200 . .
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