@conference{
author = "Predrag, Ristić and Ivana, Marjanović and Olivera, Klisurić and Nenad, Filipović and Tamara, Todorović",
year = "2019",
abstract = "Despite the variety in coordination polymers’ (CP) structure their characteristic architecture is based on relatively small organic molecules, which are most often O or N donors [1]. The ligand piperazine 1,4-dicarbonitrile (L) is used for synthesis of novel Ag(I) 3D CP with general formula {[Ag(L)2]ClO4}n. The obtained complex crystallizes in the orthorhombic crystal system, space group Pnnn. The structure of CP consists of one metal center, two L ligands coordinated bismonodentately via N atom and one perchlorate anion (Figure 1). Each Ag(I) is in tetrahedral environment, coordinated to four nitgoren atoms from four different L ligands. The geometric index of distortion is 0.956 [2]. Topological analysis [3] showed that there are two crystallographically different Ag(I) ions. The first one builds two interpenetrating networks which are related by 12.61 Å translations along the a-axis direction (class Ia). The second Ag(I) ion gives four interpenetrating networks related by 12.61 Å translations along the a-axis direction and by an inversion centre (class IIIa).",
publisher = "Belgrade: Serbian Crystallographic Society",
journal = "XXVI Conference of the Serbian Crystallographic Society, Srebrno jezero, June 27–28, 2019, Book of abstracts",
title = "Ag(I) 3D coordination polymer with piperazine",
pages = "64-65",
url = "https://hdl.handle.net/21.15107/rcub_cherry_6204"
}