TY  - JOUR
AU  - Milutinovic, Milena
AU  - Sallard, Sebastien
AU  - Manojlović, Dragan D.
AU  - Mano, Nicolas
AU  - Šojić, Nešo
PY  - 2011
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1203
AB  - In this work, we report a new sensing approach based on electrogenerated chemiluminescence (ECL) in an electrodeposited redox hydrogel using glucose dehydrogenase as a model system. The ECL-hydrogel films were electrodeposited by potential cycling of a PBS solution containing [poly(4-vinylpyridine)Ru(2,2'-bipyridine)(2) Cl-](+/2+). The film was easily prepared in a rapid, reproducible and well-controlled one-step procedure. The deposited hydrogel film is permeable to water-soluble chemicals and biochemicals, like enzyme substrates and coenzymes. Electrochemistry and ECL of NADH were studied at the level of the hydrogel film. Results indicate that ECL emission occurs at a relatively low anodic potential compared to the classical Ru(bipy)(3)(2+) complex. This is an important advantage since the measurements performed with the ECL hydrogel are thus less sensitive to interfering species. An ECL oxidative-reductive mechanism is presented for the ECL-hydrogel. Then we showed that the intensity of the ECL of NADH produced by the enzymatic activity varies with the enzyme substrate concentration. Such sensing approach combines enzymatic selectivity with the ECL advantages at low oxidation potential. (C) 2011 Elsevier B.V. All rights reserved.
PB  - Elsevier Science Sa, Lausanne
T2  - Bioelectrochemistry
T1  - Glucose sensing by electrogenerated chemiluminescence of glucose-dehydrogenase produced NADH on electrodeposited redox hydrogel
VL  - 82
IS  - 1
SP  - 63
EP  - 68
DO  - 10.1016/j.bioelechem.2011.05.005
ER  - 

@article{
author = "Milutinovic, Milena and Sallard, Sebastien and Manojlović, Dragan D. and Mano, Nicolas and Šojić, Nešo",
year = "2011",
abstract = "In this work, we report a new sensing approach based on electrogenerated chemiluminescence (ECL) in an electrodeposited redox hydrogel using glucose dehydrogenase as a model system. The ECL-hydrogel films were electrodeposited by potential cycling of a PBS solution containing [poly(4-vinylpyridine)Ru(2,2'-bipyridine)(2) Cl-](+/2+). The film was easily prepared in a rapid, reproducible and well-controlled one-step procedure. The deposited hydrogel film is permeable to water-soluble chemicals and biochemicals, like enzyme substrates and coenzymes. Electrochemistry and ECL of NADH were studied at the level of the hydrogel film. Results indicate that ECL emission occurs at a relatively low anodic potential compared to the classical Ru(bipy)(3)(2+) complex. This is an important advantage since the measurements performed with the ECL hydrogel are thus less sensitive to interfering species. An ECL oxidative-reductive mechanism is presented for the ECL-hydrogel. Then we showed that the intensity of the ECL of NADH produced by the enzymatic activity varies with the enzyme substrate concentration. Such sensing approach combines enzymatic selectivity with the ECL advantages at low oxidation potential. (C) 2011 Elsevier B.V. All rights reserved.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Bioelectrochemistry",
title = "Glucose sensing by electrogenerated chemiluminescence of glucose-dehydrogenase produced NADH on electrodeposited redox hydrogel",
volume = "82",
number = "1",
pages = "63-68",
doi = "10.1016/j.bioelechem.2011.05.005"
}

Milutinovic, M., Sallard, S., Manojlović, D. D., Mano, N.,& Šojić, N.. (2011). Glucose sensing by electrogenerated chemiluminescence of glucose-dehydrogenase produced NADH on electrodeposited redox hydrogel. in Bioelectrochemistry
Elsevier Science Sa, Lausanne., 82(1), 63-68.
https://doi.org/10.1016/j.bioelechem.2011.05.005

Milutinovic M, Sallard S, Manojlović DD, Mano N, Šojić N. Glucose sensing by electrogenerated chemiluminescence of glucose-dehydrogenase produced NADH on electrodeposited redox hydrogel. in Bioelectrochemistry. 2011;82(1):63-68.
doi:10.1016/j.bioelechem.2011.05.005 .

Milutinovic, Milena, Sallard, Sebastien, Manojlović, Dragan D., Mano, Nicolas, Šojić, Nešo, "Glucose sensing by electrogenerated chemiluminescence of glucose-dehydrogenase produced NADH on electrodeposited redox hydrogel" in Bioelectrochemistry, 82, no. 1 (2011):63-68,
https://doi.org/10.1016/j.bioelechem.2011.05.005 . .

TY  - JOUR
AU  - Milutinovic, Milena
AU  - Suraniti, Emmanuel
AU  - Studer, Vincent
AU  - Mano, Nicolas
AU  - Manojlović, Dragan D.
AU  - Šojić, Nešo
PY  - 2011
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1185
AB  - Photoinitiated polymerisation is efficiently and rapidly carried out to immobilise ultrathin electrochemiluminescent redox hydrogel films. Microscale patterns are fabricated on an electrode surface by a simple photolithographic procedure and revealed by ECL imaging.
PB  - Royal Soc Chemistry, Cambridge
T2  - Chemical Communications
T1  - Photopatterning of ultrathin electrochemiluminescent redox hydrogel films
VL  - 47
IS  - 32
SP  - 9125
EP  - 9127
DO  - 10.1039/c1cc12724a
ER  - 

@article{
author = "Milutinovic, Milena and Suraniti, Emmanuel and Studer, Vincent and Mano, Nicolas and Manojlović, Dragan D. and Šojić, Nešo",
year = "2011",
abstract = "Photoinitiated polymerisation is efficiently and rapidly carried out to immobilise ultrathin electrochemiluminescent redox hydrogel films. Microscale patterns are fabricated on an electrode surface by a simple photolithographic procedure and revealed by ECL imaging.",
publisher = "Royal Soc Chemistry, Cambridge",
journal = "Chemical Communications",
title = "Photopatterning of ultrathin electrochemiluminescent redox hydrogel films",
volume = "47",
number = "32",
pages = "9125-9127",
doi = "10.1039/c1cc12724a"
}

Milutinovic, M., Suraniti, E., Studer, V., Mano, N., Manojlović, D. D.,& Šojić, N.. (2011). Photopatterning of ultrathin electrochemiluminescent redox hydrogel films. in Chemical Communications
Royal Soc Chemistry, Cambridge., 47(32), 9125-9127.
https://doi.org/10.1039/c1cc12724a

Milutinovic M, Suraniti E, Studer V, Mano N, Manojlović DD, Šojić N. Photopatterning of ultrathin electrochemiluminescent redox hydrogel films. in Chemical Communications. 2011;47(32):9125-9127.
doi:10.1039/c1cc12724a .

Milutinovic, Milena, Suraniti, Emmanuel, Studer, Vincent, Mano, Nicolas, Manojlović, Dragan D., Šojić, Nešo, "Photopatterning of ultrathin electrochemiluminescent redox hydrogel films" in Chemical Communications, 47, no. 32 (2011):9125-9127,
https://doi.org/10.1039/c1cc12724a . .