TY  - JOUR
AU  - Korać Jačić, Jelena
AU  - Bajuk-Bogdanović, Danica
AU  - Savić, Slađana D.
AU  - Božić Cvijan, Bojana
AU  - Spasojević, Milica
AU  - MIlenković, Milica R.
PY  - 2023
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5881
AB  - Hydralazine (HL), a frequently prescribed oral antihypertensive drug, shows redox interactions with transition metals such as copper that are not fully understood. Copper may be present at high concentrations in the digestive tract and can affect oral drugs. An important parameter for such interactions is pH, which changes from acidic in the gastric juice to neutral pH in intestines. In this study, we examined interactions of HL with Cu2+ ions in conditions that mimic pH shift in the digestive tract using UV–Vis, Raman and EPR spectroscopy, cyclic voltammetry and oximetry. In the acidic solution, Cu2+ formed a stable mononuclear complex with two bidentate coordinated HL molecules. On the other hand, at neutral pH, Cu2+ initiated oxidation and degradation of HL. The degradation was more rapid in the HL-Cu2+ system that was initially prepared at acidic pH and then shifted to neutral pH. The formation of the complex at acidic pH increases the availability of Cu2+ for redox reactions after the shift to neutral pH at which Cu2+ is poorly soluble. These results imply that the change of pH along the digestive tract may promote HL degradation by allowing the formation of the complex at gastric pH which makes Cu2+ available for subsequent oxidation of HL at neutral pH.
PB  - Elsevier
T2  - Journal of Inorganic Biochemistry
T1  - Coordination of hydralazine with Cu2+ at acidic pH promotes its oxidative degradation at neutral pH
VL  - 243
SP  - 112181
DO  - 10.1016/j.jinorgbio.2023.112181
ER  - 

@article{
author = "Korać Jačić, Jelena and Bajuk-Bogdanović, Danica and Savić, Slađana D. and Božić Cvijan, Bojana and Spasojević, Milica and MIlenković, Milica R.",
year = "2023",
abstract = "Hydralazine (HL), a frequently prescribed oral antihypertensive drug, shows redox interactions with transition metals such as copper that are not fully understood. Copper may be present at high concentrations in the digestive tract and can affect oral drugs. An important parameter for such interactions is pH, which changes from acidic in the gastric juice to neutral pH in intestines. In this study, we examined interactions of HL with Cu2+ ions in conditions that mimic pH shift in the digestive tract using UV–Vis, Raman and EPR spectroscopy, cyclic voltammetry and oximetry. In the acidic solution, Cu2+ formed a stable mononuclear complex with two bidentate coordinated HL molecules. On the other hand, at neutral pH, Cu2+ initiated oxidation and degradation of HL. The degradation was more rapid in the HL-Cu2+ system that was initially prepared at acidic pH and then shifted to neutral pH. The formation of the complex at acidic pH increases the availability of Cu2+ for redox reactions after the shift to neutral pH at which Cu2+ is poorly soluble. These results imply that the change of pH along the digestive tract may promote HL degradation by allowing the formation of the complex at gastric pH which makes Cu2+ available for subsequent oxidation of HL at neutral pH.",
publisher = "Elsevier",
journal = "Journal of Inorganic Biochemistry",
title = "Coordination of hydralazine with Cu2+ at acidic pH promotes its oxidative degradation at neutral pH",
volume = "243",
pages = "112181",
doi = "10.1016/j.jinorgbio.2023.112181"
}

Korać Jačić, J., Bajuk-Bogdanović, D., Savić, S. D., Božić Cvijan, B., Spasojević, M.,& MIlenković, M. R.. (2023). Coordination of hydralazine with Cu2+ at acidic pH promotes its oxidative degradation at neutral pH. in Journal of Inorganic Biochemistry
Elsevier., 243, 112181.
https://doi.org/10.1016/j.jinorgbio.2023.112181

Korać Jačić J, Bajuk-Bogdanović D, Savić SD, Božić Cvijan B, Spasojević M, MIlenković MR. Coordination of hydralazine with Cu2+ at acidic pH promotes its oxidative degradation at neutral pH. in Journal of Inorganic Biochemistry. 2023;243:112181.
doi:10.1016/j.jinorgbio.2023.112181 .

Korać Jačić, Jelena, Bajuk-Bogdanović, Danica, Savić, Slađana D., Božić Cvijan, Bojana, Spasojević, Milica, MIlenković, Milica R., "Coordination of hydralazine with Cu2+ at acidic pH promotes its oxidative degradation at neutral pH" in Journal of Inorganic Biochemistry, 243 (2023):112181,
https://doi.org/10.1016/j.jinorgbio.2023.112181 . .

TY  - JOUR
AU  - Korać Jačić, Jelena
AU  - Bajuk-Bogdanović, Danica
AU  - Savić, Slađana D.
AU  - Božić Cvijan, Bojana
AU  - Spasojević, Milica
AU  - MIlenković, Milica R.
PY  - 2023
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5882
AB  - Hydralazine (HL), a frequently prescribed oral antihypertensive drug, shows redox interactions with transition metals such as copper that are not fully understood. Copper may be present at high concentrations in the digestive tract and can affect oral drugs. An important parameter for such interactions is pH, which changes from acidic in the gastric juice to neutral pH in intestines. In this study, we examined interactions of HL with Cu2+ ions in conditions that mimic pH shift in the digestive tract using UV–Vis, Raman and EPR spectroscopy, cyclic voltammetry and oximetry. In the acidic solution, Cu2+ formed a stable mononuclear complex with two bidentate coordinated HL molecules. On the other hand, at neutral pH, Cu2+ initiated oxidation and degradation of HL. The degradation was more rapid in the HL-Cu2+ system that was initially prepared at acidic pH and then shifted to neutral pH. The formation of the complex at acidic pH increases the availability of Cu2+ for redox reactions after the shift to neutral pH at which Cu2+ is poorly soluble. These results imply that the change of pH along the digestive tract may promote HL degradation by allowing the formation of the complex at gastric pH which makes Cu2+ available for subsequent oxidation of HL at neutral pH.
PB  - Elsevier
T2  - Journal of Inorganic Biochemistry
T1  - Coordination of hydralazine with Cu2+ at acidic pH promotes its oxidative degradation at neutral pH
VL  - 243
SP  - 112181
DO  - 10.1016/j.jinorgbio.2023.112181
ER  - 

@article{
author = "Korać Jačić, Jelena and Bajuk-Bogdanović, Danica and Savić, Slađana D. and Božić Cvijan, Bojana and Spasojević, Milica and MIlenković, Milica R.",
year = "2023",
abstract = "Hydralazine (HL), a frequently prescribed oral antihypertensive drug, shows redox interactions with transition metals such as copper that are not fully understood. Copper may be present at high concentrations in the digestive tract and can affect oral drugs. An important parameter for such interactions is pH, which changes from acidic in the gastric juice to neutral pH in intestines. In this study, we examined interactions of HL with Cu2+ ions in conditions that mimic pH shift in the digestive tract using UV–Vis, Raman and EPR spectroscopy, cyclic voltammetry and oximetry. In the acidic solution, Cu2+ formed a stable mononuclear complex with two bidentate coordinated HL molecules. On the other hand, at neutral pH, Cu2+ initiated oxidation and degradation of HL. The degradation was more rapid in the HL-Cu2+ system that was initially prepared at acidic pH and then shifted to neutral pH. The formation of the complex at acidic pH increases the availability of Cu2+ for redox reactions after the shift to neutral pH at which Cu2+ is poorly soluble. These results imply that the change of pH along the digestive tract may promote HL degradation by allowing the formation of the complex at gastric pH which makes Cu2+ available for subsequent oxidation of HL at neutral pH.",
publisher = "Elsevier",
journal = "Journal of Inorganic Biochemistry",
title = "Coordination of hydralazine with Cu2+ at acidic pH promotes its oxidative degradation at neutral pH",
volume = "243",
pages = "112181",
doi = "10.1016/j.jinorgbio.2023.112181"
}

Korać Jačić, J., Bajuk-Bogdanović, D., Savić, S. D., Božić Cvijan, B., Spasojević, M.,& MIlenković, M. R.. (2023). Coordination of hydralazine with Cu2+ at acidic pH promotes its oxidative degradation at neutral pH. in Journal of Inorganic Biochemistry
Elsevier., 243, 112181.
https://doi.org/10.1016/j.jinorgbio.2023.112181

Korać Jačić J, Bajuk-Bogdanović D, Savić SD, Božić Cvijan B, Spasojević M, MIlenković MR. Coordination of hydralazine with Cu2+ at acidic pH promotes its oxidative degradation at neutral pH. in Journal of Inorganic Biochemistry. 2023;243:112181.
doi:10.1016/j.jinorgbio.2023.112181 .

Korać Jačić, Jelena, Bajuk-Bogdanović, Danica, Savić, Slađana D., Božić Cvijan, Bojana, Spasojević, Milica, MIlenković, Milica R., "Coordination of hydralazine with Cu2+ at acidic pH promotes its oxidative degradation at neutral pH" in Journal of Inorganic Biochemistry, 243 (2023):112181,
https://doi.org/10.1016/j.jinorgbio.2023.112181 . .

TY  - JOUR
AU  - Dorontic, Sladjana
AU  - Bonasera, Aurelio
AU  - Scopelliti, Michelangelo
AU  - Marković, Olivera S.
AU  - Bajuk Bogdanović, Danica
AU  - Ciasca, Gabriele
AU  - Romanò, Sabrina
AU  - Dimkić, Ivica
AU  - Budimir, Milica
AU  - Marinković, Dragana
AU  - Jovanovic, Svetlana
PY  - 2022
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5883
AB  - Structural modification of different carbon-based nanomaterials is often necessary to
improve their morphology and optical properties, particularly the incorporation of N-atoms in
graphene quantum dots (GQDs). Here, a clean, simple, one-step, and eco-friendly method for
N-doping of GQDs using gamma irradiation is reported. GQDs were irradiated in the presence
of the different ethylenediamine (EDA) amounts (1 g, 5 g, and 10 g) and the highest % of N was
detected in the presence of 10 g. N-doped GQDs emitted strong, blue photoluminescence (PL).
Photoluminescence quantum yield was increased from 1.45, as obtained for non-irradiated dots,
to 7.24% for those irradiated in the presence of 1 g of EDA. Modified GQDs were investigated as
a PL probe for the detection of insecticide Carbofuran (2,2-Dimethyl-2,3-dihydro-1-benzofuran-7-
yl methylcarbamate) and herbicide Amitrole (3-amino-1,2,4-triazole). The limit of detection was
5.4 µmol L−1
for Carbofuran. For the first time, Amitrole was detected by GQDs in a turn-off/turn-on
mechanism using Pd(II) ions as a quenching agent. First, Pd(II) ions were quenched (turn-off) PL
of GQDs, while after Amitrole addition, PL was recovered linearly with Amitrole concentration
(turn-on). LOD was 2.03 µmol L−1
. These results suggest that modified GQDs can be used as an
efficient new material for Carbofuran and Amitrole detection. Furthermore, the phototoxicity of dots
was investigated on both Gram-positive and Gram-negative bacterial strains. When bacterial cells
were exposed to different GQD concentrations and illuminated with light of 470 nm wavelength, the
toxic effects were not observed.
PB  - MDPI
T2  - Nanomaterials
T1  - Gamma-ray-induced structural transformation of GQDs  towards the improvement of their optical properties, monitoring of selected toxic compounds,  and photo-induced effect on bacterial strains
VL  - 12
SP  - 2714
DO  - https://doi.org/10.3390/nano12152714
ER  - 

@article{
author = "Dorontic, Sladjana and Bonasera, Aurelio and Scopelliti, Michelangelo and Marković, Olivera S. and Bajuk Bogdanović, Danica and Ciasca, Gabriele and Romanò, Sabrina and Dimkić, Ivica and Budimir, Milica and Marinković, Dragana and Jovanovic, Svetlana",
year = "2022",
abstract = "Structural modification of different carbon-based nanomaterials is often necessary to
improve their morphology and optical properties, particularly the incorporation of N-atoms in
graphene quantum dots (GQDs). Here, a clean, simple, one-step, and eco-friendly method for
N-doping of GQDs using gamma irradiation is reported. GQDs were irradiated in the presence
of the different ethylenediamine (EDA) amounts (1 g, 5 g, and 10 g) and the highest % of N was
detected in the presence of 10 g. N-doped GQDs emitted strong, blue photoluminescence (PL).
Photoluminescence quantum yield was increased from 1.45, as obtained for non-irradiated dots,
to 7.24% for those irradiated in the presence of 1 g of EDA. Modified GQDs were investigated as
a PL probe for the detection of insecticide Carbofuran (2,2-Dimethyl-2,3-dihydro-1-benzofuran-7-
yl methylcarbamate) and herbicide Amitrole (3-amino-1,2,4-triazole). The limit of detection was
5.4 µmol L−1
for Carbofuran. For the first time, Amitrole was detected by GQDs in a turn-off/turn-on
mechanism using Pd(II) ions as a quenching agent. First, Pd(II) ions were quenched (turn-off) PL
of GQDs, while after Amitrole addition, PL was recovered linearly with Amitrole concentration
(turn-on). LOD was 2.03 µmol L−1
. These results suggest that modified GQDs can be used as an
efficient new material for Carbofuran and Amitrole detection. Furthermore, the phototoxicity of dots
was investigated on both Gram-positive and Gram-negative bacterial strains. When bacterial cells
were exposed to different GQD concentrations and illuminated with light of 470 nm wavelength, the
toxic effects were not observed.",
publisher = "MDPI",
journal = "Nanomaterials",
title = "Gamma-ray-induced structural transformation of GQDs  towards the improvement of their optical properties, monitoring of selected toxic compounds,  and photo-induced effect on bacterial strains",
volume = "12",
pages = "2714",
doi = "https://doi.org/10.3390/nano12152714"
}

Dorontic, S., Bonasera, A., Scopelliti, M., Marković, O. S., Bajuk Bogdanović, D., Ciasca, G., Romanò, S., Dimkić, I., Budimir, M., Marinković, D.,& Jovanovic, S.. (2022). Gamma-ray-induced structural transformation of GQDs  towards the improvement of their optical properties, monitoring of selected toxic compounds,  and photo-induced effect on bacterial strains. in Nanomaterials
MDPI., 12, 2714.
https://doi.org/https://doi.org/10.3390/nano12152714

Dorontic S, Bonasera A, Scopelliti M, Marković OS, Bajuk Bogdanović D, Ciasca G, Romanò S, Dimkić I, Budimir M, Marinković D, Jovanovic S. Gamma-ray-induced structural transformation of GQDs  towards the improvement of their optical properties, monitoring of selected toxic compounds,  and photo-induced effect on bacterial strains. in Nanomaterials. 2022;12:2714.
doi:https://doi.org/10.3390/nano12152714 .

Dorontic, Sladjana, Bonasera, Aurelio, Scopelliti, Michelangelo, Marković, Olivera S., Bajuk Bogdanović, Danica, Ciasca, Gabriele, Romanò, Sabrina, Dimkić, Ivica, Budimir, Milica, Marinković, Dragana, Jovanovic, Svetlana, "Gamma-ray-induced structural transformation of GQDs  towards the improvement of their optical properties, monitoring of selected toxic compounds,  and photo-induced effect on bacterial strains" in Nanomaterials, 12 (2022):2714,
https://doi.org/https://doi.org/10.3390/nano12152714 . .

TY  - JOUR
AU  - Korać Jačić, Jelena
AU  - Milenković, Milica R.
AU  - Bajuk-Bogdanović, Danica
AU  - Stanković, Dalibor
AU  - Dimitrijević, Milena
AU  - Spasojević, Ivan
PY  - 2022
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5511
AB  - There is a significant interest in understanding coordination and photo-chemistry of tetracycline antibiotics, primarily in relation to the development of advanced oxidation processes for degradation of these pollutants in water processing. Herein we analyzed the pH-dependence of interactions of tetracycline with ferric iron and photosensitivity of tetracycline to UV-A and UV-B, using a set of methods – UV–vis, Raman and electron paramagnetic resonance spectroscopy, MS spectrometry, HPLC, and cyclic voltammetry. Tetracycline and Fe3+ mainly bind through amide and OH groups in tricarbonylamide moiety to form a stable complex with 1:1 stoichiometry at pH ≤ 5. The interaction is reversible and tetracycline is released from the complex with pH increase. Tetracycline in the complex is stabilized and less susceptible than free tetracycline to oxidation by hydroxyl radical that is produced by UV-induced photolysis of Fe3+–OH- complexes. Redox properties of tetracycline were altered with increasing pH and it showed increased susceptibility to UV-induced degradation. In close, the system composed of tetracycline and ferric iron shows coordination and photo-redox chemistry that is dependent of pH in relation to the solubility of Fe3+ species and protonation of tetracycline. The development and optimization of advanced oxidation processes should take into account that iron may bind and stabilize pollutants and that the redox landscape of water changes drastically with pH.
PB  - Elsevier
T2  - Journal of Photochemistry & Photobiology, A: Chemistry
T1  - The impact of ferric iron and pH on photo-degradation of tetracycline in water
VL  - 433
SP  - 114155
DO  - 10.1016/j.jphotochem.2022.114155
ER  - 

@article{
author = "Korać Jačić, Jelena and Milenković, Milica R. and Bajuk-Bogdanović, Danica and Stanković, Dalibor and Dimitrijević, Milena and Spasojević, Ivan",
year = "2022",
abstract = "There is a significant interest in understanding coordination and photo-chemistry of tetracycline antibiotics, primarily in relation to the development of advanced oxidation processes for degradation of these pollutants in water processing. Herein we analyzed the pH-dependence of interactions of tetracycline with ferric iron and photosensitivity of tetracycline to UV-A and UV-B, using a set of methods – UV–vis, Raman and electron paramagnetic resonance spectroscopy, MS spectrometry, HPLC, and cyclic voltammetry. Tetracycline and Fe3+ mainly bind through amide and OH groups in tricarbonylamide moiety to form a stable complex with 1:1 stoichiometry at pH ≤ 5. The interaction is reversible and tetracycline is released from the complex with pH increase. Tetracycline in the complex is stabilized and less susceptible than free tetracycline to oxidation by hydroxyl radical that is produced by UV-induced photolysis of Fe3+–OH- complexes. Redox properties of tetracycline were altered with increasing pH and it showed increased susceptibility to UV-induced degradation. In close, the system composed of tetracycline and ferric iron shows coordination and photo-redox chemistry that is dependent of pH in relation to the solubility of Fe3+ species and protonation of tetracycline. The development and optimization of advanced oxidation processes should take into account that iron may bind and stabilize pollutants and that the redox landscape of water changes drastically with pH.",
publisher = "Elsevier",
journal = "Journal of Photochemistry & Photobiology, A: Chemistry",
title = "The impact of ferric iron and pH on photo-degradation of tetracycline in water",
volume = "433",
pages = "114155",
doi = "10.1016/j.jphotochem.2022.114155"
}

Korać Jačić, J., Milenković, M. R., Bajuk-Bogdanović, D., Stanković, D., Dimitrijević, M.,& Spasojević, I.. (2022). The impact of ferric iron and pH on photo-degradation of tetracycline in water. in Journal of Photochemistry & Photobiology, A: Chemistry
Elsevier., 433, 114155.
https://doi.org/10.1016/j.jphotochem.2022.114155

Korać Jačić J, Milenković MR, Bajuk-Bogdanović D, Stanković D, Dimitrijević M, Spasojević I. The impact of ferric iron and pH on photo-degradation of tetracycline in water. in Journal of Photochemistry & Photobiology, A: Chemistry. 2022;433:114155.
doi:10.1016/j.jphotochem.2022.114155 .

Korać Jačić, Jelena, Milenković, Milica R., Bajuk-Bogdanović, Danica, Stanković, Dalibor, Dimitrijević, Milena, Spasojević, Ivan, "The impact of ferric iron and pH on photo-degradation of tetracycline in water" in Journal of Photochemistry & Photobiology, A: Chemistry, 433 (2022):114155,
https://doi.org/10.1016/j.jphotochem.2022.114155 . .

TY  - DATA
AU  - Korać Jačić, Jelena
AU  - Milenković, Milica R.
AU  - Bajuk-Bogdanović, Danica
AU  - Stanković, Dalibor
AU  - Dimitrijević, Milena
AU  - Spasojević, Ivan
PY  - 2022
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5511
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5512
AB  - There is a significant interest in understanding coordination and photo-chemistry of tetracycline antibiotics, primarily in relation to the development of advanced oxidation processes for degradation of these pollutants in water processing. Herein we analyzed the pH-dependence of interactions of tetracycline with ferric iron and photosensitivity of tetracycline to UV-A and UV-B, using a set of methods – UV–vis, Raman and electron paramagnetic resonance spectroscopy, MS spectrometry, HPLC, and cyclic voltammetry. Tetracycline and Fe3+ mainly bind through amide and OH groups in tricarbonylamide moiety to form a stable complex with 1:1 stoichiometry at pH ≤ 5. The interaction is reversible and tetracycline is released from the complex with pH increase. Tetracycline in the complex is stabilized and less susceptible than free tetracycline to oxidation by hydroxyl radical that is produced by UV-induced photolysis of Fe3+–OH- complexes. Redox properties of tetracycline were altered with increasing pH and it showed increased susceptibility to UV-induced degradation. In close, the system composed of tetracycline and ferric iron shows coordination and photo-redox chemistry that is dependent of pH in relation to the solubility of Fe3+ species and protonation of tetracycline. The development and optimization of advanced oxidation processes should take into account that iron may bind and stabilize pollutants and that the redox landscape of water changes drastically with pH.
PB  - Elsevier
T2  - Journal of Photochemistry & Photobiology, A: Chemistry
T1  - Supplementary information for the article: Korać Jačić, J.; Milenković, M. R.; Bajuk-Bogdanović, D.; Stanković, D.; Dimitrijević, M.; Spasojević, I. The Impact of Ferric Iron and PH on Photo-Degradation of Tetracycline in Water. Journal of Photochemistry and Photobiology A: Chemistry 2022, 433, 114155. https://doi.org/10.1016/j.jphotochem.2022.114155.
VL  - 433
SP  - 114155
UR  - https://hdl.handle.net/21.15107/rcub_cherry_5512
ER  - 

@misc{
author = "Korać Jačić, Jelena and Milenković, Milica R. and Bajuk-Bogdanović, Danica and Stanković, Dalibor and Dimitrijević, Milena and Spasojević, Ivan",
year = "2022",
abstract = "There is a significant interest in understanding coordination and photo-chemistry of tetracycline antibiotics, primarily in relation to the development of advanced oxidation processes for degradation of these pollutants in water processing. Herein we analyzed the pH-dependence of interactions of tetracycline with ferric iron and photosensitivity of tetracycline to UV-A and UV-B, using a set of methods – UV–vis, Raman and electron paramagnetic resonance spectroscopy, MS spectrometry, HPLC, and cyclic voltammetry. Tetracycline and Fe3+ mainly bind through amide and OH groups in tricarbonylamide moiety to form a stable complex with 1:1 stoichiometry at pH ≤ 5. The interaction is reversible and tetracycline is released from the complex with pH increase. Tetracycline in the complex is stabilized and less susceptible than free tetracycline to oxidation by hydroxyl radical that is produced by UV-induced photolysis of Fe3+–OH- complexes. Redox properties of tetracycline were altered with increasing pH and it showed increased susceptibility to UV-induced degradation. In close, the system composed of tetracycline and ferric iron shows coordination and photo-redox chemistry that is dependent of pH in relation to the solubility of Fe3+ species and protonation of tetracycline. The development and optimization of advanced oxidation processes should take into account that iron may bind and stabilize pollutants and that the redox landscape of water changes drastically with pH.",
publisher = "Elsevier",
journal = "Journal of Photochemistry & Photobiology, A: Chemistry",
title = "Supplementary information for the article: Korać Jačić, J.; Milenković, M. R.; Bajuk-Bogdanović, D.; Stanković, D.; Dimitrijević, M.; Spasojević, I. The Impact of Ferric Iron and PH on Photo-Degradation of Tetracycline in Water. Journal of Photochemistry and Photobiology A: Chemistry 2022, 433, 114155. https://doi.org/10.1016/j.jphotochem.2022.114155.",
volume = "433",
pages = "114155",
url = "https://hdl.handle.net/21.15107/rcub_cherry_5512"
}

Korać Jačić, J., Milenković, M. R., Bajuk-Bogdanović, D., Stanković, D., Dimitrijević, M.,& Spasojević, I.. (2022). Supplementary information for the article: Korać Jačić, J.; Milenković, M. R.; Bajuk-Bogdanović, D.; Stanković, D.; Dimitrijević, M.; Spasojević, I. The Impact of Ferric Iron and PH on Photo-Degradation of Tetracycline in Water. Journal of Photochemistry and Photobiology A: Chemistry 2022, 433, 114155. https://doi.org/10.1016/j.jphotochem.2022.114155.. in Journal of Photochemistry & Photobiology, A: Chemistry
Elsevier., 433, 114155.
https://hdl.handle.net/21.15107/rcub_cherry_5512

Korać Jačić J, Milenković MR, Bajuk-Bogdanović D, Stanković D, Dimitrijević M, Spasojević I. Supplementary information for the article: Korać Jačić, J.; Milenković, M. R.; Bajuk-Bogdanović, D.; Stanković, D.; Dimitrijević, M.; Spasojević, I. The Impact of Ferric Iron and PH on Photo-Degradation of Tetracycline in Water. Journal of Photochemistry and Photobiology A: Chemistry 2022, 433, 114155. https://doi.org/10.1016/j.jphotochem.2022.114155.. in Journal of Photochemistry & Photobiology, A: Chemistry. 2022;433:114155.
https://hdl.handle.net/21.15107/rcub_cherry_5512 .

Korać Jačić, Jelena, Milenković, Milica R., Bajuk-Bogdanović, Danica, Stanković, Dalibor, Dimitrijević, Milena, Spasojević, Ivan, "Supplementary information for the article: Korać Jačić, J.; Milenković, M. R.; Bajuk-Bogdanović, D.; Stanković, D.; Dimitrijević, M.; Spasojević, I. The Impact of Ferric Iron and PH on Photo-Degradation of Tetracycline in Water. Journal of Photochemistry and Photobiology A: Chemistry 2022, 433, 114155. https://doi.org/10.1016/j.jphotochem.2022.114155." in Journal of Photochemistry & Photobiology, A: Chemistry, 433 (2022):114155,
https://hdl.handle.net/21.15107/rcub_cherry_5512 .

TY  - CONF
AU  - Bubanja, Itana Nuša
AU  - Lončarević, Branka D.
AU  - Lješević, Marija
AU  - Stanisavljev, Dragomir
AU  - Beškoski, Vladimir
AU  - Gojgić-Cvijović, Gordana D.
AU  - Bajuk-Bogdanović, Danica
AU  - Gizdavić-Nikolaidis, Marija
PY  - 2021
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5430
AB  - Microwave assisted synthesis of polyaniline modified by pullulan (PANI/Pull) composite wasperformed by aniline oxidation with potassium iodate. The PANI/Pull composite was characterizedusing ATR-FTIR technique. FTIR spectra confirm presence of both components in PANI/Pullcomposite. Antimicrobial evaluation of PANI/Pull material performed by using a qualitative diskdiffusion method on Candida albicans (C. albicans) culture showed very high sensitivity toPANI/Pull composite. Observed FTIR and antifungal activity represent a promising results especiallyfor potential biomedical applications of PANI/Pull composite.
PB  - Society of Physical Chemists of Serbia
C3  - Proceedings - Physical Chemistry 2021, 15th International Conference on Fundamental and Applied Aspects of Physical Chemistry
T1  - Microwave assisted synthesis of polyaniline/pullulan (pani/pull) composite
VL  - 2
SP  - 445
EP  - 448
UR  - https://hdl.handle.net/21.15107/rcub_cer_4955
ER  - 

@conference{
author = "Bubanja, Itana Nuša and Lončarević, Branka D. and Lješević, Marija and Stanisavljev, Dragomir and Beškoski, Vladimir and Gojgić-Cvijović, Gordana D. and Bajuk-Bogdanović, Danica and Gizdavić-Nikolaidis, Marija",
year = "2021",
abstract = "Microwave assisted synthesis of polyaniline modified by pullulan (PANI/Pull) composite wasperformed by aniline oxidation with potassium iodate. The PANI/Pull composite was characterizedusing ATR-FTIR technique. FTIR spectra confirm presence of both components in PANI/Pullcomposite. Antimicrobial evaluation of PANI/Pull material performed by using a qualitative diskdiffusion method on Candida albicans (C. albicans) culture showed very high sensitivity toPANI/Pull composite. Observed FTIR and antifungal activity represent a promising results especiallyfor potential biomedical applications of PANI/Pull composite.",
publisher = "Society of Physical Chemists of Serbia",
journal = "Proceedings - Physical Chemistry 2021, 15th International Conference on Fundamental and Applied Aspects of Physical Chemistry",
title = "Microwave assisted synthesis of polyaniline/pullulan (pani/pull) composite",
volume = "2",
pages = "445-448",
url = "https://hdl.handle.net/21.15107/rcub_cer_4955"
}

Bubanja, I. N., Lončarević, B. D., Lješević, M., Stanisavljev, D., Beškoski, V., Gojgić-Cvijović, G. D., Bajuk-Bogdanović, D.,& Gizdavić-Nikolaidis, M.. (2021). Microwave assisted synthesis of polyaniline/pullulan (pani/pull) composite. in Proceedings - Physical Chemistry 2021, 15th International Conference on Fundamental and Applied Aspects of Physical Chemistry
Society of Physical Chemists of Serbia., 2, 445-448.
https://hdl.handle.net/21.15107/rcub_cer_4955

Bubanja IN, Lončarević BD, Lješević M, Stanisavljev D, Beškoski V, Gojgić-Cvijović GD, Bajuk-Bogdanović D, Gizdavić-Nikolaidis M. Microwave assisted synthesis of polyaniline/pullulan (pani/pull) composite. in Proceedings - Physical Chemistry 2021, 15th International Conference on Fundamental and Applied Aspects of Physical Chemistry. 2021;2:445-448.
https://hdl.handle.net/21.15107/rcub_cer_4955 .

Bubanja, Itana Nuša, Lončarević, Branka D., Lješević, Marija, Stanisavljev, Dragomir, Beškoski, Vladimir, Gojgić-Cvijović, Gordana D., Bajuk-Bogdanović, Danica, Gizdavić-Nikolaidis, Marija, "Microwave assisted synthesis of polyaniline/pullulan (pani/pull) composite" in Proceedings - Physical Chemistry 2021, 15th International Conference on Fundamental and Applied Aspects of Physical Chemistry, 2 (2021):445-448,
https://hdl.handle.net/21.15107/rcub_cer_4955 .

TY  - CONF
AU  - Bubanja, Itana Nuša
AU  - Lončarević, Branka D.
AU  - Lješević, Marija
AU  - Stanisavljev, Dragomir
AU  - Beškoski, Vladimir
AU  - Gojgić-Cvijović, Gordana D.
AU  - Bajuk-Bogdanović, Danica
AU  - Gizdavić-Nikolaidis, Marija
PY  - 2021
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5431
AB  - Poster presented at Physical Chemistry 2021, 15th International Conference on Fundamental and Applied Aspects of Physical Chemistry
T1  - Microwave assisted synthesis of polyaniline/pullulan (pani/pull) composite
UR  - https://hdl.handle.net/21.15107/rcub_cer_4956
ER  - 

@conference{
author = "Bubanja, Itana Nuša and Lončarević, Branka D. and Lješević, Marija and Stanisavljev, Dragomir and Beškoski, Vladimir and Gojgić-Cvijović, Gordana D. and Bajuk-Bogdanović, Danica and Gizdavić-Nikolaidis, Marija",
year = "2021",
abstract = "Poster presented at Physical Chemistry 2021, 15th International Conference on Fundamental and Applied Aspects of Physical Chemistry",
title = "Microwave assisted synthesis of polyaniline/pullulan (pani/pull) composite",
url = "https://hdl.handle.net/21.15107/rcub_cer_4956"
}

Bubanja, I. N., Lončarević, B. D., Lješević, M., Stanisavljev, D., Beškoski, V., Gojgić-Cvijović, G. D., Bajuk-Bogdanović, D.,& Gizdavić-Nikolaidis, M.. (2021). Microwave assisted synthesis of polyaniline/pullulan (pani/pull) composite. .
https://hdl.handle.net/21.15107/rcub_cer_4956

Bubanja IN, Lončarević BD, Lješević M, Stanisavljev D, Beškoski V, Gojgić-Cvijović GD, Bajuk-Bogdanović D, Gizdavić-Nikolaidis M. Microwave assisted synthesis of polyaniline/pullulan (pani/pull) composite. 2021;.
https://hdl.handle.net/21.15107/rcub_cer_4956 .

Bubanja, Itana Nuša, Lončarević, Branka D., Lješević, Marija, Stanisavljev, Dragomir, Beškoski, Vladimir, Gojgić-Cvijović, Gordana D., Bajuk-Bogdanović, Danica, Gizdavić-Nikolaidis, Marija, "Microwave assisted synthesis of polyaniline/pullulan (pani/pull) composite" (2021),
https://hdl.handle.net/21.15107/rcub_cer_4956 .

TY  - DATA
AU  - Dimitrijević, Milena S.
AU  - Bogdanović Pristov, Jelena
AU  - Žižić, Milan
AU  - Stanković, Dalibor
AU  - Bajuk-Bogdanović, Danica
AU  - Stanić, Marina
AU  - Spasić, Snežana
AU  - Hagen, Wilfred
AU  - Spasojević, Ivan
PY  - 2019
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3069
T2  - Dalton Transactions
T1  - Supplementary data for article:
Dimitrijević, M. S.; Bogdanović Pristov, J.; Žižić, M.; Stanković, D. M.; Bajuk-Bogdanović, D.; Stanić, M.; Spasić, S.; Hagen, W.; Spasojević, I. Biliverdin-Copper Complex at Physiological PH. Dalton Transactions 2019, 48 (18), 6061–6070. https://doi.org/10.1039/c8dt04724c
VL  - 48
IS  - 18
SP  - 6061
EP  - 6070
UR  - https://hdl.handle.net/21.15107/rcub_cherry_3069
ER  - 

@misc{
author = "Dimitrijević, Milena S. and Bogdanović Pristov, Jelena and Žižić, Milan and Stanković, Dalibor and Bajuk-Bogdanović, Danica and Stanić, Marina and Spasić, Snežana and Hagen, Wilfred and Spasojević, Ivan",
year = "2019",
journal = "Dalton Transactions",
title = "Supplementary data for article:
Dimitrijević, M. S.; Bogdanović Pristov, J.; Žižić, M.; Stanković, D. M.; Bajuk-Bogdanović, D.; Stanić, M.; Spasić, S.; Hagen, W.; Spasojević, I. Biliverdin-Copper Complex at Physiological PH. Dalton Transactions 2019, 48 (18), 6061–6070. https://doi.org/10.1039/c8dt04724c",
volume = "48",
number = "18",
pages = "6061-6070",
url = "https://hdl.handle.net/21.15107/rcub_cherry_3069"
}

Dimitrijević, M. S., Bogdanović Pristov, J., Žižić, M., Stanković, D., Bajuk-Bogdanović, D., Stanić, M., Spasić, S., Hagen, W.,& Spasojević, I.. (2019). Supplementary data for article:
Dimitrijević, M. S.; Bogdanović Pristov, J.; Žižić, M.; Stanković, D. M.; Bajuk-Bogdanović, D.; Stanić, M.; Spasić, S.; Hagen, W.; Spasojević, I. Biliverdin-Copper Complex at Physiological PH. Dalton Transactions 2019, 48 (18), 6061–6070. https://doi.org/10.1039/c8dt04724c. in Dalton Transactions, 48(18), 6061-6070.
https://hdl.handle.net/21.15107/rcub_cherry_3069

Dimitrijević MS, Bogdanović Pristov J, Žižić M, Stanković D, Bajuk-Bogdanović D, Stanić M, Spasić S, Hagen W, Spasojević I. Supplementary data for article:
Dimitrijević, M. S.; Bogdanović Pristov, J.; Žižić, M.; Stanković, D. M.; Bajuk-Bogdanović, D.; Stanić, M.; Spasić, S.; Hagen, W.; Spasojević, I. Biliverdin-Copper Complex at Physiological PH. Dalton Transactions 2019, 48 (18), 6061–6070. https://doi.org/10.1039/c8dt04724c. in Dalton Transactions. 2019;48(18):6061-6070.
https://hdl.handle.net/21.15107/rcub_cherry_3069 .

Dimitrijević, Milena S., Bogdanović Pristov, Jelena, Žižić, Milan, Stanković, Dalibor, Bajuk-Bogdanović, Danica, Stanić, Marina, Spasić, Snežana, Hagen, Wilfred, Spasojević, Ivan, "Supplementary data for article:
Dimitrijević, M. S.; Bogdanović Pristov, J.; Žižić, M.; Stanković, D. M.; Bajuk-Bogdanović, D.; Stanić, M.; Spasić, S.; Hagen, W.; Spasojević, I. Biliverdin-Copper Complex at Physiological PH. Dalton Transactions 2019, 48 (18), 6061–6070. https://doi.org/10.1039/c8dt04724c" in Dalton Transactions, 48, no. 18 (2019):6061-6070,
https://hdl.handle.net/21.15107/rcub_cherry_3069 .

TY  - JOUR
AU  - Dimitrijević, Milena S.
AU  - Bogdanović Pristov, Jelena
AU  - Žižić, Milan
AU  - Stanković, Dalibor
AU  - Bajuk-Bogdanović, Danica
AU  - Stanić, Marina
AU  - Spasić, Snežana
AU  - Hagen, Wilfred
AU  - Spasojević, Ivan
PY  - 2019
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3068
AB  - Biliverdin (BV), a product of heme catabolism, is known to interact with transition metals, but the details of such interactions under physiological conditions are scarce. Herein, we examined coordinate/redox interactions of BV with Cu2+ in phosphate buffer at pH 7.4, using spectrophotometry, HESI-MS, Raman spectroscopy, 1 H NMR, EPR, fluorimetry, and electrochemical methods. BV formed a stable coordination complex with copper in 1 : 1 stoichiometry. The structure of BV was more planar and energetically stable in the complex. The complex showed strong paramagnetic effects that were attributed to an unpaired delocalized e−. The delocalized electron may come from BV or Cu2+, so the complex is formally composed either of BV radical cation and Cu1+ or of BV radical anion and Cu3+. The complex underwent oxidation only in the presence of both O2 and an excess of Cu2+, or a strong oxidizing agent, and it was resistant to reducing agents. The biological effects of the stable BV metallocomplex containing a delocalized unpaired electron should be further examined, and may provide an answer to the long-standing question of high energy investment in the catabolism of BV, which represents a relatively harmless molecule per se.
T2  - Dalton Transactions
T1  - Biliverdin-copper complex at physiological pH
VL  - 48
IS  - 18
SP  - 6061
EP  - 6070
DO  - 10.1039/c8dt04724c
ER  - 

@article{
author = "Dimitrijević, Milena S. and Bogdanović Pristov, Jelena and Žižić, Milan and Stanković, Dalibor and Bajuk-Bogdanović, Danica and Stanić, Marina and Spasić, Snežana and Hagen, Wilfred and Spasojević, Ivan",
year = "2019",
abstract = "Biliverdin (BV), a product of heme catabolism, is known to interact with transition metals, but the details of such interactions under physiological conditions are scarce. Herein, we examined coordinate/redox interactions of BV with Cu2+ in phosphate buffer at pH 7.4, using spectrophotometry, HESI-MS, Raman spectroscopy, 1 H NMR, EPR, fluorimetry, and electrochemical methods. BV formed a stable coordination complex with copper in 1 : 1 stoichiometry. The structure of BV was more planar and energetically stable in the complex. The complex showed strong paramagnetic effects that were attributed to an unpaired delocalized e−. The delocalized electron may come from BV or Cu2+, so the complex is formally composed either of BV radical cation and Cu1+ or of BV radical anion and Cu3+. The complex underwent oxidation only in the presence of both O2 and an excess of Cu2+, or a strong oxidizing agent, and it was resistant to reducing agents. The biological effects of the stable BV metallocomplex containing a delocalized unpaired electron should be further examined, and may provide an answer to the long-standing question of high energy investment in the catabolism of BV, which represents a relatively harmless molecule per se.",
journal = "Dalton Transactions",
title = "Biliverdin-copper complex at physiological pH",
volume = "48",
number = "18",
pages = "6061-6070",
doi = "10.1039/c8dt04724c"
}

Dimitrijević, M. S., Bogdanović Pristov, J., Žižić, M., Stanković, D., Bajuk-Bogdanović, D., Stanić, M., Spasić, S., Hagen, W.,& Spasojević, I.. (2019). Biliverdin-copper complex at physiological pH. in Dalton Transactions, 48(18), 6061-6070.
https://doi.org/10.1039/c8dt04724c

Dimitrijević MS, Bogdanović Pristov J, Žižić M, Stanković D, Bajuk-Bogdanović D, Stanić M, Spasić S, Hagen W, Spasojević I. Biliverdin-copper complex at physiological pH. in Dalton Transactions. 2019;48(18):6061-6070.
doi:10.1039/c8dt04724c .

Dimitrijević, Milena S., Bogdanović Pristov, Jelena, Žižić, Milan, Stanković, Dalibor, Bajuk-Bogdanović, Danica, Stanić, Marina, Spasić, Snežana, Hagen, Wilfred, Spasojević, Ivan, "Biliverdin-copper complex at physiological pH" in Dalton Transactions, 48, no. 18 (2019):6061-6070,
https://doi.org/10.1039/c8dt04724c . .

TY  - JOUR
AU  - Dimitrijević, Milena S.
AU  - Bogdanović Pristov, Jelena
AU  - Žižić, Milan
AU  - Stanković, Dalibor
AU  - Bajuk-Bogdanović, Danica
AU  - Stanić, Marina
AU  - Spasić, Snežana
AU  - Hagen, Wilfred
AU  - Spasojević, Ivan
PY  - 2019
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3066
AB  - Biliverdin (BV), a product of heme catabolism, is known to interact with transition metals, but the details of such interactions under physiological conditions are scarce. Herein, we examined coordinate/redox interactions of BV with Cu2+ in phosphate buffer at pH 7.4, using spectrophotometry, HESI-MS, Raman spectroscopy, 1 H NMR, EPR, fluorimetry, and electrochemical methods. BV formed a stable coordination complex with copper in 1 : 1 stoichiometry. The structure of BV was more planar and energetically stable in the complex. The complex showed strong paramagnetic effects that were attributed to an unpaired delocalized e−. The delocalized electron may come from BV or Cu2+, so the complex is formally composed either of BV radical cation and Cu1+ or of BV radical anion and Cu3+. The complex underwent oxidation only in the presence of both O2 and an excess of Cu2+, or a strong oxidizing agent, and it was resistant to reducing agents. The biological effects of the stable BV metallocomplex containing a delocalized unpaired electron should be further examined, and may provide an answer to the long-standing question of high energy investment in the catabolism of BV, which represents a relatively harmless molecule per se.
T2  - Dalton Transactions
T1  - Biliverdin-copper complex at physiological pH
VL  - 48
IS  - 18
SP  - 6061
EP  - 6070
DO  - 10.1039/c8dt04724c
ER  - 

@article{
author = "Dimitrijević, Milena S. and Bogdanović Pristov, Jelena and Žižić, Milan and Stanković, Dalibor and Bajuk-Bogdanović, Danica and Stanić, Marina and Spasić, Snežana and Hagen, Wilfred and Spasojević, Ivan",
year = "2019",
abstract = "Biliverdin (BV), a product of heme catabolism, is known to interact with transition metals, but the details of such interactions under physiological conditions are scarce. Herein, we examined coordinate/redox interactions of BV with Cu2+ in phosphate buffer at pH 7.4, using spectrophotometry, HESI-MS, Raman spectroscopy, 1 H NMR, EPR, fluorimetry, and electrochemical methods. BV formed a stable coordination complex with copper in 1 : 1 stoichiometry. The structure of BV was more planar and energetically stable in the complex. The complex showed strong paramagnetic effects that were attributed to an unpaired delocalized e−. The delocalized electron may come from BV or Cu2+, so the complex is formally composed either of BV radical cation and Cu1+ or of BV radical anion and Cu3+. The complex underwent oxidation only in the presence of both O2 and an excess of Cu2+, or a strong oxidizing agent, and it was resistant to reducing agents. The biological effects of the stable BV metallocomplex containing a delocalized unpaired electron should be further examined, and may provide an answer to the long-standing question of high energy investment in the catabolism of BV, which represents a relatively harmless molecule per se.",
journal = "Dalton Transactions",
title = "Biliverdin-copper complex at physiological pH",
volume = "48",
number = "18",
pages = "6061-6070",
doi = "10.1039/c8dt04724c"
}

Dimitrijević, M. S., Bogdanović Pristov, J., Žižić, M., Stanković, D., Bajuk-Bogdanović, D., Stanić, M., Spasić, S., Hagen, W.,& Spasojević, I.. (2019). Biliverdin-copper complex at physiological pH. in Dalton Transactions, 48(18), 6061-6070.
https://doi.org/10.1039/c8dt04724c

Dimitrijević MS, Bogdanović Pristov J, Žižić M, Stanković D, Bajuk-Bogdanović D, Stanić M, Spasić S, Hagen W, Spasojević I. Biliverdin-copper complex at physiological pH. in Dalton Transactions. 2019;48(18):6061-6070.
doi:10.1039/c8dt04724c .

Dimitrijević, Milena S., Bogdanović Pristov, Jelena, Žižić, Milan, Stanković, Dalibor, Bajuk-Bogdanović, Danica, Stanić, Marina, Spasić, Snežana, Hagen, Wilfred, Spasojević, Ivan, "Biliverdin-copper complex at physiological pH" in Dalton Transactions, 48, no. 18 (2019):6061-6070,
https://doi.org/10.1039/c8dt04724c . .

TY  - DATA
AU  - Korać, Jelena
AU  - Stanković, Dalibor
AU  - Stanić, Marina
AU  - Bajuk-Bogdanović, Danica
AU  - Žižić, Milan
AU  - Pristov-Bogdanović, Jelena
AU  - Grgurić-Šipka, Sanja
AU  - Popović-Bijelić, Ana
AU  - Spasojević, Ivan
PY  - 2018
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3040
PB  - Nature Publishing Group, London
T2  - Scientific Reports
T1  - Supplementary data for the article: Korać, J.; Stanković, D. M.; Stanić, M.; Bajuk-Bogdanović, D.; Žižić, M.; Pristov, J. B.; Grgurić-Šipka, S.; Popović-Bijelić, A.; Spasojević, I. Coordinate and Redox Interactions of Epinephrine with Ferric and Ferrous Iron at Physiological PH. Scientific Reports 2018, 8 (1). https://doi.org/10.1038/s41598-018-21940-7
UR  - https://hdl.handle.net/21.15107/rcub_cherry_3040
ER  - 

@misc{
author = "Korać, Jelena and Stanković, Dalibor and Stanić, Marina and Bajuk-Bogdanović, Danica and Žižić, Milan and Pristov-Bogdanović, Jelena and Grgurić-Šipka, Sanja and Popović-Bijelić, Ana and Spasojević, Ivan",
year = "2018",
publisher = "Nature Publishing Group, London",
journal = "Scientific Reports",
title = "Supplementary data for the article: Korać, J.; Stanković, D. M.; Stanić, M.; Bajuk-Bogdanović, D.; Žižić, M.; Pristov, J. B.; Grgurić-Šipka, S.; Popović-Bijelić, A.; Spasojević, I. Coordinate and Redox Interactions of Epinephrine with Ferric and Ferrous Iron at Physiological PH. Scientific Reports 2018, 8 (1). https://doi.org/10.1038/s41598-018-21940-7",
url = "https://hdl.handle.net/21.15107/rcub_cherry_3040"
}

Korać, J., Stanković, D., Stanić, M., Bajuk-Bogdanović, D., Žižić, M., Pristov-Bogdanović, J., Grgurić-Šipka, S., Popović-Bijelić, A.,& Spasojević, I.. (2018). Supplementary data for the article: Korać, J.; Stanković, D. M.; Stanić, M.; Bajuk-Bogdanović, D.; Žižić, M.; Pristov, J. B.; Grgurić-Šipka, S.; Popović-Bijelić, A.; Spasojević, I. Coordinate and Redox Interactions of Epinephrine with Ferric and Ferrous Iron at Physiological PH. Scientific Reports 2018, 8 (1). https://doi.org/10.1038/s41598-018-21940-7. in Scientific Reports
Nature Publishing Group, London..
https://hdl.handle.net/21.15107/rcub_cherry_3040

Korać J, Stanković D, Stanić M, Bajuk-Bogdanović D, Žižić M, Pristov-Bogdanović J, Grgurić-Šipka S, Popović-Bijelić A, Spasojević I. Supplementary data for the article: Korać, J.; Stanković, D. M.; Stanić, M.; Bajuk-Bogdanović, D.; Žižić, M.; Pristov, J. B.; Grgurić-Šipka, S.; Popović-Bijelić, A.; Spasojević, I. Coordinate and Redox Interactions of Epinephrine with Ferric and Ferrous Iron at Physiological PH. Scientific Reports 2018, 8 (1). https://doi.org/10.1038/s41598-018-21940-7. in Scientific Reports. 2018;.
https://hdl.handle.net/21.15107/rcub_cherry_3040 .

Korać, Jelena, Stanković, Dalibor, Stanić, Marina, Bajuk-Bogdanović, Danica, Žižić, Milan, Pristov-Bogdanović, Jelena, Grgurić-Šipka, Sanja, Popović-Bijelić, Ana, Spasojević, Ivan, "Supplementary data for the article: Korać, J.; Stanković, D. M.; Stanić, M.; Bajuk-Bogdanović, D.; Žižić, M.; Pristov, J. B.; Grgurić-Šipka, S.; Popović-Bijelić, A.; Spasojević, I. Coordinate and Redox Interactions of Epinephrine with Ferric and Ferrous Iron at Physiological PH. Scientific Reports 2018, 8 (1). https://doi.org/10.1038/s41598-018-21940-7" in Scientific Reports (2018),
https://hdl.handle.net/21.15107/rcub_cherry_3040 .

TY  - JOUR
AU  - Korać, Jelena
AU  - Stanković, Dalibor
AU  - Stanić, Marina
AU  - Bajuk-Bogdanović, Danica
AU  - Žižić, Milan
AU  - Pristov-Bogdanović, Jelena
AU  - Grgurić-Šipka, Sanja
AU  - Popović-Bijelić, Ana
AU  - Spasojević, Ivan
PY  - 2018
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/2097
AB  - Coordinate and redox interactions of epinephrine (Epi) with iron at physiological pH are essential for understanding two very different phenomena - the detrimental effects of chronic stress on the cardiovascular system and the cross-linking of catecholamine-rich biopolymers and frameworks. Here we show that Epi and Fe3+ form stable high-spin complexes in the 1:1 or 3:1 stoichiometry, depending on the Epi/Fe3+ concentration ratio (low or high). Oxygen atoms on the catechol ring represent the sites of coordinate bond formation within physiologically relevant bidentate 1:1 complex. Redox properties of Epi are slightly impacted by Fe3+. On the other hand, Epi and Fe2+ form a complex that acts as a strong reducing agent, which leads to the production of hydrogen peroxide via O-2 reduction, and to a facilitated formation of the Epi-Fe3+ complexes. Epi is not oxidized in this process, i.e. Fe2+ is not an electron shuttle, but the electron donor. Epi-catalyzed oxidation of Fe2+ represents a plausible chemical basis of stress-related damage to heart cells. In addition, our results support the previous findings on the interactions of catecholamine moieties in polymers with iron and provide a novel strategy for improving the efficiency of cross-linking.
PB  - Nature Publishing Group, London
T2  - Scientific Reports
T1  - Coordinate and redox interactions of epinephrine with ferric and ferrous iron at physiological pH
VL  - 8
DO  - 10.1038/s41598-018-21940-7
ER  - 

@article{
author = "Korać, Jelena and Stanković, Dalibor and Stanić, Marina and Bajuk-Bogdanović, Danica and Žižić, Milan and Pristov-Bogdanović, Jelena and Grgurić-Šipka, Sanja and Popović-Bijelić, Ana and Spasojević, Ivan",
year = "2018",
abstract = "Coordinate and redox interactions of epinephrine (Epi) with iron at physiological pH are essential for understanding two very different phenomena - the detrimental effects of chronic stress on the cardiovascular system and the cross-linking of catecholamine-rich biopolymers and frameworks. Here we show that Epi and Fe3+ form stable high-spin complexes in the 1:1 or 3:1 stoichiometry, depending on the Epi/Fe3+ concentration ratio (low or high). Oxygen atoms on the catechol ring represent the sites of coordinate bond formation within physiologically relevant bidentate 1:1 complex. Redox properties of Epi are slightly impacted by Fe3+. On the other hand, Epi and Fe2+ form a complex that acts as a strong reducing agent, which leads to the production of hydrogen peroxide via O-2 reduction, and to a facilitated formation of the Epi-Fe3+ complexes. Epi is not oxidized in this process, i.e. Fe2+ is not an electron shuttle, but the electron donor. Epi-catalyzed oxidation of Fe2+ represents a plausible chemical basis of stress-related damage to heart cells. In addition, our results support the previous findings on the interactions of catecholamine moieties in polymers with iron and provide a novel strategy for improving the efficiency of cross-linking.",
publisher = "Nature Publishing Group, London",
journal = "Scientific Reports",
title = "Coordinate and redox interactions of epinephrine with ferric and ferrous iron at physiological pH",
volume = "8",
doi = "10.1038/s41598-018-21940-7"
}

Korać, J., Stanković, D., Stanić, M., Bajuk-Bogdanović, D., Žižić, M., Pristov-Bogdanović, J., Grgurić-Šipka, S., Popović-Bijelić, A.,& Spasojević, I.. (2018). Coordinate and redox interactions of epinephrine with ferric and ferrous iron at physiological pH. in Scientific Reports
Nature Publishing Group, London., 8.
https://doi.org/10.1038/s41598-018-21940-7

Korać J, Stanković D, Stanić M, Bajuk-Bogdanović D, Žižić M, Pristov-Bogdanović J, Grgurić-Šipka S, Popović-Bijelić A, Spasojević I. Coordinate and redox interactions of epinephrine with ferric and ferrous iron at physiological pH. in Scientific Reports. 2018;8.
doi:10.1038/s41598-018-21940-7 .

Korać, Jelena, Stanković, Dalibor, Stanić, Marina, Bajuk-Bogdanović, Danica, Žižić, Milan, Pristov-Bogdanović, Jelena, Grgurić-Šipka, Sanja, Popović-Bijelić, Ana, Spasojević, Ivan, "Coordinate and redox interactions of epinephrine with ferric and ferrous iron at physiological pH" in Scientific Reports, 8 (2018),
https://doi.org/10.1038/s41598-018-21940-7 . .

TY  - JOUR
AU  - Sencanski, Jelena V.
AU  - Vujkovic, Milica J.
AU  - Stojkovic, Ivana B.
AU  - Majstorovic, Divna M.
AU  - Bajuk-Bogdanović, Danica
AU  - Pastor, Ferenc
AU  - Mentus, Slavko V.
PY  - 2017
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/2500
AB  - The Li-ion batteries are the main power source for the high technology devices, such as mobile phones and electric vehicles. Because of that, the number of spent Li-ion batteries significantly increases. Today, the number of active mobile phones crossed 7.19 billion. It is estimated that the mass of the spent lithium ion batteries in China will exceed 500,000 t by 2020. The trouble is in the ingredients of these batteries. They contain Li, Co, Mn, Ni, Cu, Al and toxic and flammable electrolytes which have a harmful affection to the environment. Because of that, the recycling procedure attracts raising attention of researches. Several commercial spent Li-ion batteries were recycled by the relatively fast, economic and simple procedure. The three ways of separating the cathode material from Al collector were examined after the manual dismantling of the components of batteries with the Li(Co-Mn-Ni)O-2 as cathode material. These were: 1. dissolution of the Al collector in the alkali medium, 2. peeling off with N-methyl-pyrrolidone and 3. thermal decomposition of the adhesive at 700 degrees C. The procedure with the highest yield was the one with the dissolution in alkali medium. The chemical analysis of the single batteries' components (the crust, Al/Cu collector, cathode material) were done by the atomic absorption spectrometry. The components, before the analysis, were dissolved. The re-synthesis of the cathode material by the method of the citrate gel combustion was done after the separating the cathode material and dissolving it in the nitric acid. The obtained product was, after annealing, characterized by the methods of X-ray diffraction and Raman spectroscopy. The recycled product was LiCo0.59Mn0.26Ni0.15O2 stoichiometry, with the hexagonal layered structure alpha-NaFeO2 type. The functionalization of the resynthesized material was examined in the 1 M solution LiClO4 in the propylene carbonate, by galvanostatic charging, with the current density of 0.7C. The recycled material showed relatively good capacities of charging and discharging which are 94.9 i 64.8 mA h g(-1), respectively.
PB  - Assoc Chemical Engineers Serbia, Belgrade
T2  - Hemijska industrija
T1  - Recycling of Lico0.59mn0.26ni0.15o2 Cathodic Material from  Spent Li-Ion Batteries by the Method of the Citrate Gel Combustion
VL  - 71
IS  - 3
SP  - 211
EP  - 220
DO  - 10.2298/HEMIND160418031S
ER  - 

@article{
author = "Sencanski, Jelena V. and Vujkovic, Milica J. and Stojkovic, Ivana B. and Majstorovic, Divna M. and Bajuk-Bogdanović, Danica and Pastor, Ferenc and Mentus, Slavko V.",
year = "2017",
abstract = "The Li-ion batteries are the main power source for the high technology devices, such as mobile phones and electric vehicles. Because of that, the number of spent Li-ion batteries significantly increases. Today, the number of active mobile phones crossed 7.19 billion. It is estimated that the mass of the spent lithium ion batteries in China will exceed 500,000 t by 2020. The trouble is in the ingredients of these batteries. They contain Li, Co, Mn, Ni, Cu, Al and toxic and flammable electrolytes which have a harmful affection to the environment. Because of that, the recycling procedure attracts raising attention of researches. Several commercial spent Li-ion batteries were recycled by the relatively fast, economic and simple procedure. The three ways of separating the cathode material from Al collector were examined after the manual dismantling of the components of batteries with the Li(Co-Mn-Ni)O-2 as cathode material. These were: 1. dissolution of the Al collector in the alkali medium, 2. peeling off with N-methyl-pyrrolidone and 3. thermal decomposition of the adhesive at 700 degrees C. The procedure with the highest yield was the one with the dissolution in alkali medium. The chemical analysis of the single batteries' components (the crust, Al/Cu collector, cathode material) were done by the atomic absorption spectrometry. The components, before the analysis, were dissolved. The re-synthesis of the cathode material by the method of the citrate gel combustion was done after the separating the cathode material and dissolving it in the nitric acid. The obtained product was, after annealing, characterized by the methods of X-ray diffraction and Raman spectroscopy. The recycled product was LiCo0.59Mn0.26Ni0.15O2 stoichiometry, with the hexagonal layered structure alpha-NaFeO2 type. The functionalization of the resynthesized material was examined in the 1 M solution LiClO4 in the propylene carbonate, by galvanostatic charging, with the current density of 0.7C. The recycled material showed relatively good capacities of charging and discharging which are 94.9 i 64.8 mA h g(-1), respectively.",
publisher = "Assoc Chemical Engineers Serbia, Belgrade",
journal = "Hemijska industrija",
title = "Recycling of Lico0.59mn0.26ni0.15o2 Cathodic Material from  Spent Li-Ion Batteries by the Method of the Citrate Gel Combustion",
volume = "71",
number = "3",
pages = "211-220",
doi = "10.2298/HEMIND160418031S"
}

Sencanski, J. V., Vujkovic, M. J., Stojkovic, I. B., Majstorovic, D. M., Bajuk-Bogdanović, D., Pastor, F.,& Mentus, S. V.. (2017). Recycling of Lico0.59mn0.26ni0.15o2 Cathodic Material from  Spent Li-Ion Batteries by the Method of the Citrate Gel Combustion. in Hemijska industrija
Assoc Chemical Engineers Serbia, Belgrade., 71(3), 211-220.
https://doi.org/10.2298/HEMIND160418031S

Sencanski JV, Vujkovic MJ, Stojkovic IB, Majstorovic DM, Bajuk-Bogdanović D, Pastor F, Mentus SV. Recycling of Lico0.59mn0.26ni0.15o2 Cathodic Material from  Spent Li-Ion Batteries by the Method of the Citrate Gel Combustion. in Hemijska industrija. 2017;71(3):211-220.
doi:10.2298/HEMIND160418031S .

Sencanski, Jelena V., Vujkovic, Milica J., Stojkovic, Ivana B., Majstorovic, Divna M., Bajuk-Bogdanović, Danica, Pastor, Ferenc, Mentus, Slavko V., "Recycling of Lico0.59mn0.26ni0.15o2 Cathodic Material from  Spent Li-Ion Batteries by the Method of the Citrate Gel Combustion" in Hemijska industrija, 71, no. 3 (2017):211-220,
https://doi.org/10.2298/HEMIND160418031S . .

TY  - JOUR
AU  - Ćirić-Marjanović, Gordana
AU  - Holclajtner-Antunović, Ivanka
AU  - Mentus, Slavko V.
AU  - Bajuk-Bogdanović, Danica
AU  - Jesic, Dragana
AU  - Manojlović, Dragan D.
AU  - Trifunović, Snežana S.
AU  - Stejskal, Jaroslav
PY  - 2010
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1096
AB  - Polyaniline (PANI) micro/nanostructures were synthesized by the external-template-free oxidative polymerization of aniline in aqueous solution of 12-tungstophosphoric acid (WPA), using ammonium peroxydisulfate (APS) as an oxidant and starting the oxidation of aniline from slightly acidic media (pH 5.4-5.9). The effect of the initial weight ratio of WPA to aniline on molecular structure, morphology, and physicochemical properties of polyaniline 12-tungstophosphate (PANI-WPA) was investigated by FTIR, Raman and inductively coupled plasma optical emission (ICP-OES) spectroscopies, elemental analysis, X-ray powder diffraction (XRPD), scanning and transmission electron microscopies (SEM and TEM), thermogravimetric analysis (TGA), differential thermal analysis (DTA), and conductivity measurements. The morphological change of polymerization products during a single polymerization process, from non-conducting submicro-/microspherical oligoaniline intermediates to semiconducting PANI-WPA consisted of self-assembled nanotubes and/or nanorods co-existing with submicro-/microspheres, has been revealed by SEM and TEM. The average diameter of nanorods in PANI-WPA samples decreased with increasing the initial WPA/aniline weight ratio. The incorporation of 12-tungstophosphate counter-ions into PANI matrix has been proved by FTIR. Raman and ICP-OES spectroscopies, TGA and DTA analysis. Electrical conductivity of PANI-WPA increased in the range (2.5-5.3) x 10(-3) S cm(-1) with the increase of the initial WPA/aniline weight ratio. The presence of branched structures and phenazine units besides the ordinary paramagnetic and diamagnetic emeraldine salt structural features in PANI-WPA was proved by FTIR and Raman spectroscopies. (C) 2010 Elsevier B.V. All rights reserved.
PB  - Elsevier Science Sa, Lausanne
T2  - Synthetic Metals
T1  - Self-assembled polyaniline 12-tungstophosphate micro/nanostructures
VL  - 160
IS  - 13-14
SP  - 1463
EP  - 1473
DO  - 10.1016/j.synthmet.2010.04.025
ER  - 

@article{
author = "Ćirić-Marjanović, Gordana and Holclajtner-Antunović, Ivanka and Mentus, Slavko V. and Bajuk-Bogdanović, Danica and Jesic, Dragana and Manojlović, Dragan D. and Trifunović, Snežana S. and Stejskal, Jaroslav",
year = "2010",
abstract = "Polyaniline (PANI) micro/nanostructures were synthesized by the external-template-free oxidative polymerization of aniline in aqueous solution of 12-tungstophosphoric acid (WPA), using ammonium peroxydisulfate (APS) as an oxidant and starting the oxidation of aniline from slightly acidic media (pH 5.4-5.9). The effect of the initial weight ratio of WPA to aniline on molecular structure, morphology, and physicochemical properties of polyaniline 12-tungstophosphate (PANI-WPA) was investigated by FTIR, Raman and inductively coupled plasma optical emission (ICP-OES) spectroscopies, elemental analysis, X-ray powder diffraction (XRPD), scanning and transmission electron microscopies (SEM and TEM), thermogravimetric analysis (TGA), differential thermal analysis (DTA), and conductivity measurements. The morphological change of polymerization products during a single polymerization process, from non-conducting submicro-/microspherical oligoaniline intermediates to semiconducting PANI-WPA consisted of self-assembled nanotubes and/or nanorods co-existing with submicro-/microspheres, has been revealed by SEM and TEM. The average diameter of nanorods in PANI-WPA samples decreased with increasing the initial WPA/aniline weight ratio. The incorporation of 12-tungstophosphate counter-ions into PANI matrix has been proved by FTIR. Raman and ICP-OES spectroscopies, TGA and DTA analysis. Electrical conductivity of PANI-WPA increased in the range (2.5-5.3) x 10(-3) S cm(-1) with the increase of the initial WPA/aniline weight ratio. The presence of branched structures and phenazine units besides the ordinary paramagnetic and diamagnetic emeraldine salt structural features in PANI-WPA was proved by FTIR and Raman spectroscopies. (C) 2010 Elsevier B.V. All rights reserved.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Synthetic Metals",
title = "Self-assembled polyaniline 12-tungstophosphate micro/nanostructures",
volume = "160",
number = "13-14",
pages = "1463-1473",
doi = "10.1016/j.synthmet.2010.04.025"
}

Ćirić-Marjanović, G., Holclajtner-Antunović, I., Mentus, S. V., Bajuk-Bogdanović, D., Jesic, D., Manojlović, D. D., Trifunović, S. S.,& Stejskal, J.. (2010). Self-assembled polyaniline 12-tungstophosphate micro/nanostructures. in Synthetic Metals
Elsevier Science Sa, Lausanne., 160(13-14), 1463-1473.
https://doi.org/10.1016/j.synthmet.2010.04.025

Ćirić-Marjanović G, Holclajtner-Antunović I, Mentus SV, Bajuk-Bogdanović D, Jesic D, Manojlović DD, Trifunović SS, Stejskal J. Self-assembled polyaniline 12-tungstophosphate micro/nanostructures. in Synthetic Metals. 2010;160(13-14):1463-1473.
doi:10.1016/j.synthmet.2010.04.025 .

Ćirić-Marjanović, Gordana, Holclajtner-Antunović, Ivanka, Mentus, Slavko V., Bajuk-Bogdanović, Danica, Jesic, Dragana, Manojlović, Dragan D., Trifunović, Snežana S., Stejskal, Jaroslav, "Self-assembled polyaniline 12-tungstophosphate micro/nanostructures" in Synthetic Metals, 160, no. 13-14 (2010):1463-1473,
https://doi.org/10.1016/j.synthmet.2010.04.025 . .