TY  - JOUR
AU  - Sredic, Svjetlana
AU  - Davidovic, Milorad
AU  - Spasjevic-de-Bire, Anne
AU  - Mioč, Ubavka B.
AU  - Todorović, Marija B.
AU  - Šegan, Dejan M.
AU  - Jovanović, Dušan
AU  - Polizos, George
AU  - Pissis, Polycarpos
PY  - 2008
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/968
AB  - Our previous experiences with incorporation of polyoxometalates (POMs) ill different substrates have been very successful, because new nanocomposites with better conductive, catalytical and biochemical characteristics have been obtained. The results of intercalation of different mass% of ammonium decavanadate (ADV) in Al-pillared interlayered clays (Al-PILCs) are presented. The Al-PILCs were prepared using natural raw material, bentonite, containing a high percentage of montmorillonite (MM). Synthesis of ADV has been described in a previous paper. The structure of ADV hexahydrate was determined at low temperature, 100 K. A kappa refinement was performed to estimate the atomic charges. A sol-gel procedure was applied to obtain Al-PILCs composite intercalated with ADV hexahydrate (from 2 to 5 mass% of ADV). Structure and morphological properties of the new material, a nanocomposite of Al-PILCs-ADV, were investigated by X-ray powder diffraction (XRPD) and atomic force microscopy (AFM). To understand better how ADV is incorporated in the MM substrate, specific surface areas, pore structures and pore distributions were determined. Electrical and dielectric properties of the new materials were investigated by thermally stimulated depolarization currents (TSDCs) and broadband dielectric relaxation spectroscopy (DRS). The electrical conductivity of the nanocomposite was found to increase, in relation to MM, by intercalating with a small amount of ADV. (C) 2008 Published by Elsevier Ltd.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - Journal of Physics and Chemistry of Solids
T1  - Inorganic-inorganic nanocomposite: Surface and conductive properties
VL  - 69
IS  - 8
SP  - 1883
EP  - 1890
DO  - 10.1016/j.jpcs.2007.12.023
ER  - 

@article{
author = "Sredic, Svjetlana and Davidovic, Milorad and Spasjevic-de-Bire, Anne and Mioč, Ubavka B. and Todorović, Marija B. and Šegan, Dejan M. and Jovanović, Dušan and Polizos, George and Pissis, Polycarpos",
year = "2008",
abstract = "Our previous experiences with incorporation of polyoxometalates (POMs) ill different substrates have been very successful, because new nanocomposites with better conductive, catalytical and biochemical characteristics have been obtained. The results of intercalation of different mass% of ammonium decavanadate (ADV) in Al-pillared interlayered clays (Al-PILCs) are presented. The Al-PILCs were prepared using natural raw material, bentonite, containing a high percentage of montmorillonite (MM). Synthesis of ADV has been described in a previous paper. The structure of ADV hexahydrate was determined at low temperature, 100 K. A kappa refinement was performed to estimate the atomic charges. A sol-gel procedure was applied to obtain Al-PILCs composite intercalated with ADV hexahydrate (from 2 to 5 mass% of ADV). Structure and morphological properties of the new material, a nanocomposite of Al-PILCs-ADV, were investigated by X-ray powder diffraction (XRPD) and atomic force microscopy (AFM). To understand better how ADV is incorporated in the MM substrate, specific surface areas, pore structures and pore distributions were determined. Electrical and dielectric properties of the new materials were investigated by thermally stimulated depolarization currents (TSDCs) and broadband dielectric relaxation spectroscopy (DRS). The electrical conductivity of the nanocomposite was found to increase, in relation to MM, by intercalating with a small amount of ADV. (C) 2008 Published by Elsevier Ltd.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Journal of Physics and Chemistry of Solids",
title = "Inorganic-inorganic nanocomposite: Surface and conductive properties",
volume = "69",
number = "8",
pages = "1883-1890",
doi = "10.1016/j.jpcs.2007.12.023"
}

Sredic, S., Davidovic, M., Spasjevic-de-Bire, A., Mioč, U. B., Todorović, M. B., Šegan, D. M., Jovanović, D., Polizos, G.,& Pissis, P.. (2008). Inorganic-inorganic nanocomposite: Surface and conductive properties. in Journal of Physics and Chemistry of Solids
Pergamon-Elsevier Science Ltd, Oxford., 69(8), 1883-1890.
https://doi.org/10.1016/j.jpcs.2007.12.023

Sredic S, Davidovic M, Spasjevic-de-Bire A, Mioč UB, Todorović MB, Šegan DM, Jovanović D, Polizos G, Pissis P. Inorganic-inorganic nanocomposite: Surface and conductive properties. in Journal of Physics and Chemistry of Solids. 2008;69(8):1883-1890.
doi:10.1016/j.jpcs.2007.12.023 .

Sredic, Svjetlana, Davidovic, Milorad, Spasjevic-de-Bire, Anne, Mioč, Ubavka B., Todorović, Marija B., Šegan, Dejan M., Jovanović, Dušan, Polizos, George, Pissis, Polycarpos, "Inorganic-inorganic nanocomposite: Surface and conductive properties" in Journal of Physics and Chemistry of Solids, 69, no. 8 (2008):1883-1890,
https://doi.org/10.1016/j.jpcs.2007.12.023 . .