Kokić, Branislav

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  • Kokić, Branislav (10)
Projects

Author's Bibliography

Strategies for Carbon Electrophile Addition to Carbonyls and Imines by Cobalt Catalysis

Kokić, Branislav; Vulović, Bojan; Jović, Miloš; Andrijević, Ana; Ajdačić, Vladimir; Opsenica, Igor

(Wiley, 2023)

TY  - JOUR
AU  - Kokić, Branislav
AU  - Vulović, Bojan
AU  - Jović, Miloš
AU  - Andrijević, Ana
AU  - Ajdačić, Vladimir
AU  - Opsenica, Igor
PY  - 2023
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/6299
AB  - Прегледни чланак о до сад објављеним методама за кобалтом-катализовану адицију угљеничних електрофила на карбонилну и иминску функцију.
AB  - The addition of carbon electrophiles to carbonyls and imines has emerged as a valuable strategy for the construction of C−C bonds. The merger of this concept with sustainable cobalt catalysis has yielded numerous innovative methodologies. Remarkable functional group tolerance and selectivity have been observed in many cases, providing reliable methods for bond construction. The cobalt-catalyzed additions of carbon electrophiles to carbonyls, imines and carboxylic acid derivatives described in this review include the earliest reports, such as Takai-Utimoto Co/Cr co-catalyzed additions and their progression, as well as modern variants, exemplified by recent Co/photoredox co-catalyzed protocols. The systematic appraisal of this modern strategy provides a clearer perspective and inspiration for its further development.
PB  - Wiley
T2  - European Journal of Organic Chemistry
T1  - Strategies for Carbon Electrophile Addition to Carbonyls and Imines by Cobalt Catalysis
VL  - 26
IS  - 45
SP  - e202300997
DO  - 10.1002/ejoc.202300997
ER  - 
@article{
author = "Kokić, Branislav and Vulović, Bojan and Jović, Miloš and Andrijević, Ana and Ajdačić, Vladimir and Opsenica, Igor",
year = "2023",
abstract = "Прегледни чланак о до сад објављеним методама за кобалтом-катализовану адицију угљеничних електрофила на карбонилну и иминску функцију., The addition of carbon electrophiles to carbonyls and imines has emerged as a valuable strategy for the construction of C−C bonds. The merger of this concept with sustainable cobalt catalysis has yielded numerous innovative methodologies. Remarkable functional group tolerance and selectivity have been observed in many cases, providing reliable methods for bond construction. The cobalt-catalyzed additions of carbon electrophiles to carbonyls, imines and carboxylic acid derivatives described in this review include the earliest reports, such as Takai-Utimoto Co/Cr co-catalyzed additions and their progression, as well as modern variants, exemplified by recent Co/photoredox co-catalyzed protocols. The systematic appraisal of this modern strategy provides a clearer perspective and inspiration for its further development.",
publisher = "Wiley",
journal = "European Journal of Organic Chemistry",
title = "Strategies for Carbon Electrophile Addition to Carbonyls and Imines by Cobalt Catalysis",
volume = "26",
number = "45",
pages = "e202300997",
doi = "10.1002/ejoc.202300997"
}
Kokić, B., Vulović, B., Jović, M., Andrijević, A., Ajdačić, V.,& Opsenica, I.. (2023). Strategies for Carbon Electrophile Addition to Carbonyls and Imines by Cobalt Catalysis. in European Journal of Organic Chemistry
Wiley., 26(45), e202300997.
https://doi.org/10.1002/ejoc.202300997
Kokić B, Vulović B, Jović M, Andrijević A, Ajdačić V, Opsenica I. Strategies for Carbon Electrophile Addition to Carbonyls and Imines by Cobalt Catalysis. in European Journal of Organic Chemistry. 2023;26(45):e202300997.
doi:10.1002/ejoc.202300997 .
Kokić, Branislav, Vulović, Bojan, Jović, Miloš, Andrijević, Ana, Ajdačić, Vladimir, Opsenica, Igor, "Strategies for Carbon Electrophile Addition to Carbonyls and Imines by Cobalt Catalysis" in European Journal of Organic Chemistry, 26, no. 45 (2023):e202300997,
https://doi.org/10.1002/ejoc.202300997 . .
4
2

Introductory concept for teaching chirality – symmetry of the asymmetric (Animation5)

Kokić, Branislav

(2023)

TY  - DATA
AU  - Kokić, Branislav
PY  - 2023
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5949
AB  - Conformation energy diagram of 3'-isopropyl-2-methyl-1,1'-biphenyl along with the animation of conformational changes are presented. A cursor is pointing a spot on the diagram that corresponds to the conformation animated at that moment. After the animation, models (and their usual 2D representations) of conformational enantiomers are depicted. Software tool used for creation of the clip is referenced.
AB  - Prikazani su konformacioni dijagram 3’-izopropil-2-metil-1,1’-bifenila i animacija njegovih konformacionih promena. Kursor na dijagramu prati animaciju, prikazujući tačku na grafiku koja odgovara strukturi koja se animira u tom trenutku. Nakon toga, prikazani su modeli (i njihove uobičajene 2D prezentacije struktura) konformacionih enantiomera. Softver upotrebljen za pravljenje klipa je referenciran.
T1  - Introductory concept for teaching chirality – symmetry of the asymmetric (Animation5)
UR  - https://hdl.handle.net/21.15107/rcub_cherry_5949
ER  - 
@misc{
author = "Kokić, Branislav",
year = "2023",
abstract = "Conformation energy diagram of 3'-isopropyl-2-methyl-1,1'-biphenyl along with the animation of conformational changes are presented. A cursor is pointing a spot on the diagram that corresponds to the conformation animated at that moment. After the animation, models (and their usual 2D representations) of conformational enantiomers are depicted. Software tool used for creation of the clip is referenced., Prikazani su konformacioni dijagram 3’-izopropil-2-metil-1,1’-bifenila i animacija njegovih konformacionih promena. Kursor na dijagramu prati animaciju, prikazujući tačku na grafiku koja odgovara strukturi koja se animira u tom trenutku. Nakon toga, prikazani su modeli (i njihove uobičajene 2D prezentacije struktura) konformacionih enantiomera. Softver upotrebljen za pravljenje klipa je referenciran.",
title = "Introductory concept for teaching chirality – symmetry of the asymmetric (Animation5)",
url = "https://hdl.handle.net/21.15107/rcub_cherry_5949"
}
Kokić, B.. (2023). Introductory concept for teaching chirality – symmetry of the asymmetric (Animation5). .
https://hdl.handle.net/21.15107/rcub_cherry_5949
Kokić B. Introductory concept for teaching chirality – symmetry of the asymmetric (Animation5). 2023;.
https://hdl.handle.net/21.15107/rcub_cherry_5949 .
Kokić, Branislav, "Introductory concept for teaching chirality – symmetry of the asymmetric (Animation5)" (2023),
https://hdl.handle.net/21.15107/rcub_cherry_5949 .

Introductory concept for teaching chirality – symmetry of the asymmetric (Animation4)

Kokić, Branislav

(2023)

TY  - DATA
AU  - Kokić, Branislav
PY  - 2023
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5948
AB  - Conformation energy diagram of 2,2',3,5',6-pentachloro-1,1'-biphenyl along with the animation of conformational changes are presented. A cursor is pointing a spot on the diagram that corresponds to the conformation animated at that moment. After the animation, models (and their usual 2D representations) of conformational enantiomers are depicted. Software tool used for creation of the clip is referenced.
AB  - Prikazani su konformacioni dijagram 2,2’,3,5’,6-pentahlor-1,1’-bifenila i animacija njegovih konformacionih promena. Kursor na dijagramu prati animaciju, prikazujući tačku na grafiku koja odgovara strukturi koja se animira u tom trenutku. Nakon toga, prikazani su modeli (i njihove uobičajene 2D prezentacije struktura) konformacionih enantiomera. Softver upotrebljen za pravljenje klipa je referenciran.
T1  - Introductory concept for teaching chirality – symmetry of the asymmetric (Animation4)
UR  - https://hdl.handle.net/21.15107/rcub_cherry_5948
ER  - 
@misc{
author = "Kokić, Branislav",
year = "2023",
abstract = "Conformation energy diagram of 2,2',3,5',6-pentachloro-1,1'-biphenyl along with the animation of conformational changes are presented. A cursor is pointing a spot on the diagram that corresponds to the conformation animated at that moment. After the animation, models (and their usual 2D representations) of conformational enantiomers are depicted. Software tool used for creation of the clip is referenced., Prikazani su konformacioni dijagram 2,2’,3,5’,6-pentahlor-1,1’-bifenila i animacija njegovih konformacionih promena. Kursor na dijagramu prati animaciju, prikazujući tačku na grafiku koja odgovara strukturi koja se animira u tom trenutku. Nakon toga, prikazani su modeli (i njihove uobičajene 2D prezentacije struktura) konformacionih enantiomera. Softver upotrebljen za pravljenje klipa je referenciran.",
title = "Introductory concept for teaching chirality – symmetry of the asymmetric (Animation4)",
url = "https://hdl.handle.net/21.15107/rcub_cherry_5948"
}
Kokić, B.. (2023). Introductory concept for teaching chirality – symmetry of the asymmetric (Animation4). .
https://hdl.handle.net/21.15107/rcub_cherry_5948
Kokić B. Introductory concept for teaching chirality – symmetry of the asymmetric (Animation4). 2023;.
https://hdl.handle.net/21.15107/rcub_cherry_5948 .
Kokić, Branislav, "Introductory concept for teaching chirality – symmetry of the asymmetric (Animation4)" (2023),
https://hdl.handle.net/21.15107/rcub_cherry_5948 .

Introductory concept for teaching chirality – symmetry of the asymmetric (Animation3)

Kokić, Branislav

(2023)

TY  - DATA
AU  - Kokić, Branislav
PY  - 2023
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5947
AB  - Conformation energy diagram of 1,2-dibromoethane along with the animation of conformational changes are presented. A cursor is pointing a spot on the diagram that corresponds to the conformation animated at that moment. After the animation, models (and their usual 2D representations) of conformational enantiomers are depicted. Software tool used for creation of the clip is referenced.
AB  - Prikazani su konformacioni dijagram 1,2-dibrometana i animacija njegovih konformacionih promena. Kursor na dijagramu prati animaciju, prikazujući tačku na grafiku koja odgovara strukturi koja se animira u tom trenutku. Nakon toga, prikazani su modeli (i njihove uobičajene 2D prezentacije struktura) konformacionih enantiomera. Softver upotrebljen za pravljenje klipa je referenciran.
T1  - Introductory concept for teaching chirality – symmetry of the asymmetric (Animation3)
UR  - https://hdl.handle.net/21.15107/rcub_cherry_5947
ER  - 
@misc{
author = "Kokić, Branislav",
year = "2023",
abstract = "Conformation energy diagram of 1,2-dibromoethane along with the animation of conformational changes are presented. A cursor is pointing a spot on the diagram that corresponds to the conformation animated at that moment. After the animation, models (and their usual 2D representations) of conformational enantiomers are depicted. Software tool used for creation of the clip is referenced., Prikazani su konformacioni dijagram 1,2-dibrometana i animacija njegovih konformacionih promena. Kursor na dijagramu prati animaciju, prikazujući tačku na grafiku koja odgovara strukturi koja se animira u tom trenutku. Nakon toga, prikazani su modeli (i njihove uobičajene 2D prezentacije struktura) konformacionih enantiomera. Softver upotrebljen za pravljenje klipa je referenciran.",
title = "Introductory concept for teaching chirality – symmetry of the asymmetric (Animation3)",
url = "https://hdl.handle.net/21.15107/rcub_cherry_5947"
}
Kokić, B.. (2023). Introductory concept for teaching chirality – symmetry of the asymmetric (Animation3). .
https://hdl.handle.net/21.15107/rcub_cherry_5947
Kokić B. Introductory concept for teaching chirality – symmetry of the asymmetric (Animation3). 2023;.
https://hdl.handle.net/21.15107/rcub_cherry_5947 .
Kokić, Branislav, "Introductory concept for teaching chirality – symmetry of the asymmetric (Animation3)" (2023),
https://hdl.handle.net/21.15107/rcub_cherry_5947 .

Introductory concept for teaching chirality – symmetry of the asymmetric (Animation2)

Kokić, Branislav

(2023)

TY  - DATA
AU  - Kokić, Branislav
PY  - 2023
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5946
AB  - Animation of a bending vibration of bromochloromethane. After the animation, models of “bond angle enantiomers” (produced by the vibration) are depicted. Software tools used for creation of the animation are referenced.
AB  - Animacija savijajuće vibracije bromhlormetana. Nakon animacije, prikazani su modeli “enantiomera uglova veze“, proizišli iz vibracija. Referencirani su softverski alati upotrebljeni za generisanje animacije.
T1  - Introductory concept for teaching chirality – symmetry of the asymmetric (Animation2)
UR  - https://hdl.handle.net/21.15107/rcub_cherry_5946
ER  - 
@misc{
author = "Kokić, Branislav",
year = "2023",
abstract = "Animation of a bending vibration of bromochloromethane. After the animation, models of “bond angle enantiomers” (produced by the vibration) are depicted. Software tools used for creation of the animation are referenced., Animacija savijajuće vibracije bromhlormetana. Nakon animacije, prikazani su modeli “enantiomera uglova veze“, proizišli iz vibracija. Referencirani su softverski alati upotrebljeni za generisanje animacije.",
title = "Introductory concept for teaching chirality – symmetry of the asymmetric (Animation2)",
url = "https://hdl.handle.net/21.15107/rcub_cherry_5946"
}
Kokić, B.. (2023). Introductory concept for teaching chirality – symmetry of the asymmetric (Animation2). .
https://hdl.handle.net/21.15107/rcub_cherry_5946
Kokić B. Introductory concept for teaching chirality – symmetry of the asymmetric (Animation2). 2023;.
https://hdl.handle.net/21.15107/rcub_cherry_5946 .
Kokić, Branislav, "Introductory concept for teaching chirality – symmetry of the asymmetric (Animation2)" (2023),
https://hdl.handle.net/21.15107/rcub_cherry_5946 .

Introductory concept for teaching chirality – symmetry of the asymmetric (Animation1)

Kokić, Branislav

(2023)

TY  - DATA
AU  - Kokić, Branislav
PY  - 2023
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5945
AB  - Animation of an asymmetric C-H streching vibration of bromochloromethane. After the animation, models of “bond length enantiomers” (produced by the vibration) are depicted.
AB  - Animacija asimetrične C-H istežuće vibracije bromhlormetana. Nakon animacije, prikazani su modeli “enantiomera dužine veze“, proizišli iz vibracija.
T1  - Introductory concept for teaching chirality – symmetry of the asymmetric (Animation1)
UR  - https://hdl.handle.net/21.15107/rcub_cherry_5945
ER  - 
@misc{
author = "Kokić, Branislav",
year = "2023",
abstract = "Animation of an asymmetric C-H streching vibration of bromochloromethane. After the animation, models of “bond length enantiomers” (produced by the vibration) are depicted., Animacija asimetrične C-H istežuće vibracije bromhlormetana. Nakon animacije, prikazani su modeli “enantiomera dužine veze“, proizišli iz vibracija.",
title = "Introductory concept for teaching chirality – symmetry of the asymmetric (Animation1)",
url = "https://hdl.handle.net/21.15107/rcub_cherry_5945"
}
Kokić, B.. (2023). Introductory concept for teaching chirality – symmetry of the asymmetric (Animation1). .
https://hdl.handle.net/21.15107/rcub_cherry_5945
Kokić B. Introductory concept for teaching chirality – symmetry of the asymmetric (Animation1). 2023;.
https://hdl.handle.net/21.15107/rcub_cherry_5945 .
Kokić, Branislav, "Introductory concept for teaching chirality – symmetry of the asymmetric (Animation1)" (2023),
https://hdl.handle.net/21.15107/rcub_cherry_5945 .

Low-Valent Cobalt-Catalyzed Deprotection of Allyloxyarenes

Kokić, Branislav; Selaković, Života; Nikolić, Andrea M.; Andrijević, Ana; Anđelković, Boban D.; Ajdačić, Vladimir; Opsenica, Igor

(Wiley, 2022)

TY  - JOUR
AU  - Kokić, Branislav
AU  - Selaković, Života
AU  - Nikolić, Andrea M.
AU  - Andrijević, Ana
AU  - Anđelković, Boban D.
AU  - Ajdačić, Vladimir
AU  - Opsenica, Igor
PY  - 2022
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5680
AB  - Herein, we report a low-valent cobalt-catalyzed deprotection of allyloxyarenes. The method displays a broad substrate scope and good functional group tolerance, granting its utilization on more complex substrates, including O-allylated derivatives of natural products and drugs. Based on comprehensive experiments, a plausible mechanistic pathway for the low-valent cobalt-catalyzed O-deallylation of allyloxyarenes is proposed.
PB  - Wiley
T2  - European Journal of Organic Chemistry
T1  - Low-Valent Cobalt-Catalyzed Deprotection of Allyloxyarenes
VL  - 43
SP  - e202201112
DO  - 10.1002/ejoc.202201112
ER  - 
@article{
author = "Kokić, Branislav and Selaković, Života and Nikolić, Andrea M. and Andrijević, Ana and Anđelković, Boban D. and Ajdačić, Vladimir and Opsenica, Igor",
year = "2022",
abstract = "Herein, we report a low-valent cobalt-catalyzed deprotection of allyloxyarenes. The method displays a broad substrate scope and good functional group tolerance, granting its utilization on more complex substrates, including O-allylated derivatives of natural products and drugs. Based on comprehensive experiments, a plausible mechanistic pathway for the low-valent cobalt-catalyzed O-deallylation of allyloxyarenes is proposed.",
publisher = "Wiley",
journal = "European Journal of Organic Chemistry",
title = "Low-Valent Cobalt-Catalyzed Deprotection of Allyloxyarenes",
volume = "43",
pages = "e202201112",
doi = "10.1002/ejoc.202201112"
}
Kokić, B., Selaković, Ž., Nikolić, A. M., Andrijević, A., Anđelković, B. D., Ajdačić, V.,& Opsenica, I.. (2022). Low-Valent Cobalt-Catalyzed Deprotection of Allyloxyarenes. in European Journal of Organic Chemistry
Wiley., 43, e202201112.
https://doi.org/10.1002/ejoc.202201112
Kokić B, Selaković Ž, Nikolić AM, Andrijević A, Anđelković BD, Ajdačić V, Opsenica I. Low-Valent Cobalt-Catalyzed Deprotection of Allyloxyarenes. in European Journal of Organic Chemistry. 2022;43:e202201112.
doi:10.1002/ejoc.202201112 .
Kokić, Branislav, Selaković, Života, Nikolić, Andrea M., Andrijević, Ana, Anđelković, Boban D., Ajdačić, Vladimir, Opsenica, Igor, "Low-Valent Cobalt-Catalyzed Deprotection of Allyloxyarenes" in European Journal of Organic Chemistry, 43 (2022):e202201112,
https://doi.org/10.1002/ejoc.202201112 . .
8
2
1
1

Supplementary material for: Kokić, B., Selaković, Ž., Nikolić, A. M., Andrijević, A., Anđelković, B. D., Ajdačić, V., & Opsenica, I. (2022). Low-Valent Cobalt-Catalyzed Deprotection of Allyloxyarenes. European Journal of Organic Chemistry, 43, e202201112. https://doi.org/10.1002/ejoc.202201112

Kokić, Branislav; Selaković, Života; Nikolić, Andrea M.; Andrijević, Ana; Anđelković, Boban D.; Ajdačić, Vladimir; Opsenica, Igor

(Wiley, 2022)

TY  - DATA
AU  - Kokić, Branislav
AU  - Selaković, Života
AU  - Nikolić, Andrea M.
AU  - Andrijević, Ana
AU  - Anđelković, Boban D.
AU  - Ajdačić, Vladimir
AU  - Opsenica, Igor
PY  - 2022
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5706
AB  - Herein, we report a low-valent cobalt-catalyzed deprotection of allyloxyarenes. The method displays a broad substrate scope and good functional group tolerance, granting its utilization on more complex substrates, including O-allylated derivatives of natural products and drugs. Based on comprehensive experiments, a plausible mechanistic pathway for the low-valent cobalt-catalyzed O-deallylation of allyloxyarenes is proposed.
PB  - Wiley
T2  - European Journal of Organic Chemistry
T1  - Supplementary material for: Kokić, B., Selaković, Ž., Nikolić, A. M., Andrijević, A., Anđelković, B. D., Ajdačić, V., & Opsenica, I. (2022). Low-Valent Cobalt-Catalyzed Deprotection of Allyloxyarenes. European Journal of Organic Chemistry, 43, e202201112. https://doi.org/10.1002/ejoc.202201112
VL  - 43
SP  - e202201112
UR  - https://hdl.handle.net/21.15107/rcub_cherry_5706
ER  - 
@misc{
author = "Kokić, Branislav and Selaković, Života and Nikolić, Andrea M. and Andrijević, Ana and Anđelković, Boban D. and Ajdačić, Vladimir and Opsenica, Igor",
year = "2022",
abstract = "Herein, we report a low-valent cobalt-catalyzed deprotection of allyloxyarenes. The method displays a broad substrate scope and good functional group tolerance, granting its utilization on more complex substrates, including O-allylated derivatives of natural products and drugs. Based on comprehensive experiments, a plausible mechanistic pathway for the low-valent cobalt-catalyzed O-deallylation of allyloxyarenes is proposed.",
publisher = "Wiley",
journal = "European Journal of Organic Chemistry",
title = "Supplementary material for: Kokić, B., Selaković, Ž., Nikolić, A. M., Andrijević, A., Anđelković, B. D., Ajdačić, V., & Opsenica, I. (2022). Low-Valent Cobalt-Catalyzed Deprotection of Allyloxyarenes. European Journal of Organic Chemistry, 43, e202201112. https://doi.org/10.1002/ejoc.202201112",
volume = "43",
pages = "e202201112",
url = "https://hdl.handle.net/21.15107/rcub_cherry_5706"
}
Kokić, B., Selaković, Ž., Nikolić, A. M., Andrijević, A., Anđelković, B. D., Ajdačić, V.,& Opsenica, I.. (2022). Supplementary material for: Kokić, B., Selaković, Ž., Nikolić, A. M., Andrijević, A., Anđelković, B. D., Ajdačić, V., & Opsenica, I. (2022). Low-Valent Cobalt-Catalyzed Deprotection of Allyloxyarenes. European Journal of Organic Chemistry, 43, e202201112. https://doi.org/10.1002/ejoc.202201112. in European Journal of Organic Chemistry
Wiley., 43, e202201112.
https://hdl.handle.net/21.15107/rcub_cherry_5706
Kokić B, Selaković Ž, Nikolić AM, Andrijević A, Anđelković BD, Ajdačić V, Opsenica I. Supplementary material for: Kokić, B., Selaković, Ž., Nikolić, A. M., Andrijević, A., Anđelković, B. D., Ajdačić, V., & Opsenica, I. (2022). Low-Valent Cobalt-Catalyzed Deprotection of Allyloxyarenes. European Journal of Organic Chemistry, 43, e202201112. https://doi.org/10.1002/ejoc.202201112. in European Journal of Organic Chemistry. 2022;43:e202201112.
https://hdl.handle.net/21.15107/rcub_cherry_5706 .
Kokić, Branislav, Selaković, Života, Nikolić, Andrea M., Andrijević, Ana, Anđelković, Boban D., Ajdačić, Vladimir, Opsenica, Igor, "Supplementary material for: Kokić, B., Selaković, Ž., Nikolić, A. M., Andrijević, A., Anđelković, B. D., Ajdačić, V., & Opsenica, I. (2022). Low-Valent Cobalt-Catalyzed Deprotection of Allyloxyarenes. European Journal of Organic Chemistry, 43, e202201112. https://doi.org/10.1002/ejoc.202201112" in European Journal of Organic Chemistry, 43 (2022):e202201112,
https://hdl.handle.net/21.15107/rcub_cherry_5706 .
1

Dekarbonilativno acilovanje aril-bromida katalizovano kompleksnim jedinjenjima paladijuma

Kokić, Branislav

(2021)

TY  - THES
AU  - Kokić, Branislav
PY  - 2021
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/4467
AB  - U ovom master radu predstavljeno je ispitivanje uslova reakcije oksidativne
dehomologizacije difenilacetaldehida. Takođe, optimizovana je reakcija dekarbonilativnog
acilovanja, transformacija koja do sad nije prijavljena u literaturi, i primena te reakcije na
nekoliko različitih supstrata.
T1  - Dekarbonilativno acilovanje aril-bromida katalizovano kompleksnim jedinjenjima paladijuma
SP  - 1
EP  - 39
UR  - https://hdl.handle.net/21.15107/rcub_cherry_4467
ER  - 
@mastersthesis{
author = "Kokić, Branislav",
year = "2021",
abstract = "U ovom master radu predstavljeno je ispitivanje uslova reakcije oksidativne
dehomologizacije difenilacetaldehida. Takođe, optimizovana je reakcija dekarbonilativnog
acilovanja, transformacija koja do sad nije prijavljena u literaturi, i primena te reakcije na
nekoliko različitih supstrata.",
title = "Dekarbonilativno acilovanje aril-bromida katalizovano kompleksnim jedinjenjima paladijuma",
pages = "1-39",
url = "https://hdl.handle.net/21.15107/rcub_cherry_4467"
}
Kokić, B.. (2021). Dekarbonilativno acilovanje aril-bromida katalizovano kompleksnim jedinjenjima paladijuma. , 1-39.
https://hdl.handle.net/21.15107/rcub_cherry_4467
Kokić B. Dekarbonilativno acilovanje aril-bromida katalizovano kompleksnim jedinjenjima paladijuma. 2021;:1-39.
https://hdl.handle.net/21.15107/rcub_cherry_4467 .
Kokić, Branislav, "Dekarbonilativno acilovanje aril-bromida katalizovano kompleksnim jedinjenjima paladijuma" (2021):1-39,
https://hdl.handle.net/21.15107/rcub_cherry_4467 .

Sinteza i upotreba katalizatora na magnetnom nosaču u reakciji Suzuki-Miyaura ukrštenog kuplovanja

Kokić, Branislav

(2020)

TY  - THES
AU  - Kokić, Branislav
PY  - 2020
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/4071
AB  - Reakcija Suzuki-Miyaura kuplovanja je po prvi put predstavljena 1979.godine. Pre toga je Richard F. Heck uočio transmetalovanje boronske kiseline sa stehiometrijskom količinom paladijumskog katalizatora, dok je Ei-ichi Negishi primetio ukršteno kuplovanje između alkinil-borana i aril-halogenida i objavio u svom čuvenom radu u kom je proizvoljno ispitivao sklonost različitih organometala ka reakciji ukrštenog kuplovanja. Međutim, Heck-ovo zapažanje ima samo istorijski značaj, jer je jedna od najvećih prednosti ukrštenih kuplovanja upravo to što se radi o katalitičkom procesu, čime se postiže ekonomičnost procesa i olakšava eksperimentalini rad. Negishi svoje otkriće nije mogao da primeni na drugim supstratima, na kojima je Suzuki kasnije uspeo da izvrši transformaciju i predstavi temelje široke primenljivosti Suzuki-Miyaura reakcije, koji su proširivani daljim razvojem. Razlog za Negishi-jev neuspeh, Akira Suzuki uspeo je da pronađe i tako uđe u istoriju. Da bi se odigrala reakcija, neophodno je dodati bazu, što je osnovna razlika Suzuki-Miyaura reakcije u odnosu na ostale reakcije ukrštenog kuplovanja.
T1  - Sinteza i upotreba katalizatora na magnetnom nosaču u reakciji Suzuki-Miyaura ukrštenog kuplovanja
SP  - 4
EP  - 26
UR  - https://hdl.handle.net/21.15107/rcub_cherry_4071
ER  - 
@misc{
author = "Kokić, Branislav",
year = "2020",
abstract = "Reakcija Suzuki-Miyaura kuplovanja je po prvi put predstavljena 1979.godine. Pre toga je Richard F. Heck uočio transmetalovanje boronske kiseline sa stehiometrijskom količinom paladijumskog katalizatora, dok je Ei-ichi Negishi primetio ukršteno kuplovanje između alkinil-borana i aril-halogenida i objavio u svom čuvenom radu u kom je proizvoljno ispitivao sklonost različitih organometala ka reakciji ukrštenog kuplovanja. Međutim, Heck-ovo zapažanje ima samo istorijski značaj, jer je jedna od najvećih prednosti ukrštenih kuplovanja upravo to što se radi o katalitičkom procesu, čime se postiže ekonomičnost procesa i olakšava eksperimentalini rad. Negishi svoje otkriće nije mogao da primeni na drugim supstratima, na kojima je Suzuki kasnije uspeo da izvrši transformaciju i predstavi temelje široke primenljivosti Suzuki-Miyaura reakcije, koji su proširivani daljim razvojem. Razlog za Negishi-jev neuspeh, Akira Suzuki uspeo je da pronađe i tako uđe u istoriju. Da bi se odigrala reakcija, neophodno je dodati bazu, što je osnovna razlika Suzuki-Miyaura reakcije u odnosu na ostale reakcije ukrštenog kuplovanja.",
title = "Sinteza i upotreba katalizatora na magnetnom nosaču u reakciji Suzuki-Miyaura ukrštenog kuplovanja",
pages = "4-26",
url = "https://hdl.handle.net/21.15107/rcub_cherry_4071"
}
Kokić, B.. (2020). Sinteza i upotreba katalizatora na magnetnom nosaču u reakciji Suzuki-Miyaura ukrštenog kuplovanja. , 4-26.
https://hdl.handle.net/21.15107/rcub_cherry_4071
Kokić B. Sinteza i upotreba katalizatora na magnetnom nosaču u reakciji Suzuki-Miyaura ukrštenog kuplovanja. 2020;:4-26.
https://hdl.handle.net/21.15107/rcub_cherry_4071 .
Kokić, Branislav, "Sinteza i upotreba katalizatora na magnetnom nosaču u reakciji Suzuki-Miyaura ukrštenog kuplovanja" (2020):4-26,
https://hdl.handle.net/21.15107/rcub_cherry_4071 .