Milenković, Milica R.

Link to this page

Authority KeyName Variants
orcid::0000-0003-2053-3704
  • Milenković, Milica R. (70)
  • MIlenković, Milica R. (2)
  • Milenković, Milica (1)
Projects
Interactions of natural products, their derivatives and coordination compounds with proteins and nucleic acids Slovenian Research Agency [P-0175]
SFedU [213.01-07-2014/03PChVG] Pharmacodynamic and pharmacogenomic research of new drugs in the treatment of solid tumors
Slovenian Research Agency [P1-0175] Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200168 (University of Belgrade, Faculty of Chemistry)
Slovenian Research Agency (ARRS) [P-0175] COST Action [CM1305]
ICREA Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200026 (University of Belgrade, Institute of Chemistry, Technology and Metallurgy - IChTM)
DIUE of the Generalitat de Catalunya (XRQTC) FEDER fund (European Fund for Regional Development) [UNGI08-4E-003]
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200053 (University of Belgrade, Institute for Multidisciplinary Research) MICINN (Ministry of Science and Innovation, Spain)
Ministerio de Ciencia e Innovacion (MICINN) [CTQ2011-25086/BQU] Slovenian Research Agency (P-0175 and P2-0348)
COST Action COST Action CA15106 (C-H Activation in Organic Synthesis – CHAOS)
COST Action CM1305 Explicit Control Over Spin-states in Technology and Biochemistry (ECOSTBio) DIUE of the Generalitat de Catalunya [20145GR1202]
EN-FIST Centre of Excellence Rational design and synthesis of biologically active and coordination compounds and functional materials, relevant for (bio)nanotechnology
Biological response modifiers in physiological and pathological conditions Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200162 (University of Belgrade, Faculty of Physics)
Slovenian Research Agency (P-0175) Slovenian Research Agency (P1-0112)
Slovenian Research Agency (P1-0175) Southern Federal University
Special Account for Research Grants of the National and Kapodistrian University of Athens (Research Program 70/3/14872) COST Action [CM1305, COST-STSM-CM1305-37566]

Author's Bibliography

Coordination of hydralazine with Cu2+ at acidic pH promotes its oxidative degradation at neutral pH

Korać Jačić, Jelena; Bajuk-Bogdanović, Danica; Savić, Slađana D.; Božić Cvijan, Bojana; Spasojević, Milica; MIlenković, Milica R.

(Elsevier, 2023)

TY  - JOUR
AU  - Korać Jačić, Jelena
AU  - Bajuk-Bogdanović, Danica
AU  - Savić, Slađana D.
AU  - Božić Cvijan, Bojana
AU  - Spasojević, Milica
AU  - MIlenković, Milica R.
PY  - 2023
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5881
AB  - Hydralazine (HL), a frequently prescribed oral antihypertensive drug, shows redox interactions with transition metals such as copper that are not fully understood. Copper may be present at high concentrations in the digestive tract and can affect oral drugs. An important parameter for such interactions is pH, which changes from acidic in the gastric juice to neutral pH in intestines. In this study, we examined interactions of HL with Cu2+ ions in conditions that mimic pH shift in the digestive tract using UV–Vis, Raman and EPR spectroscopy, cyclic voltammetry and oximetry. In the acidic solution, Cu2+ formed a stable mononuclear complex with two bidentate coordinated HL molecules. On the other hand, at neutral pH, Cu2+ initiated oxidation and degradation of HL. The degradation was more rapid in the HL-Cu2+ system that was initially prepared at acidic pH and then shifted to neutral pH. The formation of the complex at acidic pH increases the availability of Cu2+ for redox reactions after the shift to neutral pH at which Cu2+ is poorly soluble. These results imply that the change of pH along the digestive tract may promote HL degradation by allowing the formation of the complex at gastric pH which makes Cu2+ available for subsequent oxidation of HL at neutral pH.
PB  - Elsevier
T2  - Journal of Inorganic Biochemistry
T1  - Coordination of hydralazine with Cu2+ at acidic pH promotes its oxidative degradation at neutral pH
VL  - 243
SP  - 112181
DO  - 10.1016/j.jinorgbio.2023.112181
ER  - 
@article{
author = "Korać Jačić, Jelena and Bajuk-Bogdanović, Danica and Savić, Slađana D. and Božić Cvijan, Bojana and Spasojević, Milica and MIlenković, Milica R.",
year = "2023",
abstract = "Hydralazine (HL), a frequently prescribed oral antihypertensive drug, shows redox interactions with transition metals such as copper that are not fully understood. Copper may be present at high concentrations in the digestive tract and can affect oral drugs. An important parameter for such interactions is pH, which changes from acidic in the gastric juice to neutral pH in intestines. In this study, we examined interactions of HL with Cu2+ ions in conditions that mimic pH shift in the digestive tract using UV–Vis, Raman and EPR spectroscopy, cyclic voltammetry and oximetry. In the acidic solution, Cu2+ formed a stable mononuclear complex with two bidentate coordinated HL molecules. On the other hand, at neutral pH, Cu2+ initiated oxidation and degradation of HL. The degradation was more rapid in the HL-Cu2+ system that was initially prepared at acidic pH and then shifted to neutral pH. The formation of the complex at acidic pH increases the availability of Cu2+ for redox reactions after the shift to neutral pH at which Cu2+ is poorly soluble. These results imply that the change of pH along the digestive tract may promote HL degradation by allowing the formation of the complex at gastric pH which makes Cu2+ available for subsequent oxidation of HL at neutral pH.",
publisher = "Elsevier",
journal = "Journal of Inorganic Biochemistry",
title = "Coordination of hydralazine with Cu2+ at acidic pH promotes its oxidative degradation at neutral pH",
volume = "243",
pages = "112181",
doi = "10.1016/j.jinorgbio.2023.112181"
}
Korać Jačić, J., Bajuk-Bogdanović, D., Savić, S. D., Božić Cvijan, B., Spasojević, M.,& MIlenković, M. R.. (2023). Coordination of hydralazine with Cu2+ at acidic pH promotes its oxidative degradation at neutral pH. in Journal of Inorganic Biochemistry
Elsevier., 243, 112181.
https://doi.org/10.1016/j.jinorgbio.2023.112181
Korać Jačić J, Bajuk-Bogdanović D, Savić SD, Božić Cvijan B, Spasojević M, MIlenković MR. Coordination of hydralazine with Cu2+ at acidic pH promotes its oxidative degradation at neutral pH. in Journal of Inorganic Biochemistry. 2023;243:112181.
doi:10.1016/j.jinorgbio.2023.112181 .
Korać Jačić, Jelena, Bajuk-Bogdanović, Danica, Savić, Slađana D., Božić Cvijan, Bojana, Spasojević, Milica, MIlenković, Milica R., "Coordination of hydralazine with Cu2+ at acidic pH promotes its oxidative degradation at neutral pH" in Journal of Inorganic Biochemistry, 243 (2023):112181,
https://doi.org/10.1016/j.jinorgbio.2023.112181 . .

Coordination of hydralazine with Cu2+ at acidic pH promotes its oxidative degradation at neutral pH

Korać Jačić, Jelena; Bajuk-Bogdanović, Danica; Savić, Slađana D.; Božić Cvijan, Bojana; Spasojević, Milica; MIlenković, Milica R.

(Elsevier, 2023)

TY  - JOUR
AU  - Korać Jačić, Jelena
AU  - Bajuk-Bogdanović, Danica
AU  - Savić, Slađana D.
AU  - Božić Cvijan, Bojana
AU  - Spasojević, Milica
AU  - MIlenković, Milica R.
PY  - 2023
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5882
AB  - Hydralazine (HL), a frequently prescribed oral antihypertensive drug, shows redox interactions with transition metals such as copper that are not fully understood. Copper may be present at high concentrations in the digestive tract and can affect oral drugs. An important parameter for such interactions is pH, which changes from acidic in the gastric juice to neutral pH in intestines. In this study, we examined interactions of HL with Cu2+ ions in conditions that mimic pH shift in the digestive tract using UV–Vis, Raman and EPR spectroscopy, cyclic voltammetry and oximetry. In the acidic solution, Cu2+ formed a stable mononuclear complex with two bidentate coordinated HL molecules. On the other hand, at neutral pH, Cu2+ initiated oxidation and degradation of HL. The degradation was more rapid in the HL-Cu2+ system that was initially prepared at acidic pH and then shifted to neutral pH. The formation of the complex at acidic pH increases the availability of Cu2+ for redox reactions after the shift to neutral pH at which Cu2+ is poorly soluble. These results imply that the change of pH along the digestive tract may promote HL degradation by allowing the formation of the complex at gastric pH which makes Cu2+ available for subsequent oxidation of HL at neutral pH.
PB  - Elsevier
T2  - Journal of Inorganic Biochemistry
T1  - Coordination of hydralazine with Cu2+ at acidic pH promotes its oxidative degradation at neutral pH
VL  - 243
SP  - 112181
DO  - 10.1016/j.jinorgbio.2023.112181
ER  - 
@article{
author = "Korać Jačić, Jelena and Bajuk-Bogdanović, Danica and Savić, Slađana D. and Božić Cvijan, Bojana and Spasojević, Milica and MIlenković, Milica R.",
year = "2023",
abstract = "Hydralazine (HL), a frequently prescribed oral antihypertensive drug, shows redox interactions with transition metals such as copper that are not fully understood. Copper may be present at high concentrations in the digestive tract and can affect oral drugs. An important parameter for such interactions is pH, which changes from acidic in the gastric juice to neutral pH in intestines. In this study, we examined interactions of HL with Cu2+ ions in conditions that mimic pH shift in the digestive tract using UV–Vis, Raman and EPR spectroscopy, cyclic voltammetry and oximetry. In the acidic solution, Cu2+ formed a stable mononuclear complex with two bidentate coordinated HL molecules. On the other hand, at neutral pH, Cu2+ initiated oxidation and degradation of HL. The degradation was more rapid in the HL-Cu2+ system that was initially prepared at acidic pH and then shifted to neutral pH. The formation of the complex at acidic pH increases the availability of Cu2+ for redox reactions after the shift to neutral pH at which Cu2+ is poorly soluble. These results imply that the change of pH along the digestive tract may promote HL degradation by allowing the formation of the complex at gastric pH which makes Cu2+ available for subsequent oxidation of HL at neutral pH.",
publisher = "Elsevier",
journal = "Journal of Inorganic Biochemistry",
title = "Coordination of hydralazine with Cu2+ at acidic pH promotes its oxidative degradation at neutral pH",
volume = "243",
pages = "112181",
doi = "10.1016/j.jinorgbio.2023.112181"
}
Korać Jačić, J., Bajuk-Bogdanović, D., Savić, S. D., Božić Cvijan, B., Spasojević, M.,& MIlenković, M. R.. (2023). Coordination of hydralazine with Cu2+ at acidic pH promotes its oxidative degradation at neutral pH. in Journal of Inorganic Biochemistry
Elsevier., 243, 112181.
https://doi.org/10.1016/j.jinorgbio.2023.112181
Korać Jačić J, Bajuk-Bogdanović D, Savić SD, Božić Cvijan B, Spasojević M, MIlenković MR. Coordination of hydralazine with Cu2+ at acidic pH promotes its oxidative degradation at neutral pH. in Journal of Inorganic Biochemistry. 2023;243:112181.
doi:10.1016/j.jinorgbio.2023.112181 .
Korać Jačić, Jelena, Bajuk-Bogdanović, Danica, Savić, Slađana D., Božić Cvijan, Bojana, Spasojević, Milica, MIlenković, Milica R., "Coordination of hydralazine with Cu2+ at acidic pH promotes its oxidative degradation at neutral pH" in Journal of Inorganic Biochemistry, 243 (2023):112181,
https://doi.org/10.1016/j.jinorgbio.2023.112181 . .

Silver distribution and binding mode as key determinants of the antimicrobial performance of iron oxide/silver nanocomposites

Šuljagić, Marija; Milenković, Milica R.; Uskoković, Vuk; Mirković, Miljana; Vrbica, Boško; Pavlović, Vladimir D.; Živković-Radovanović, Vukosava; Stanković, Dalibor; Anđelković, Ljubica

(Elsevier, 2022)

TY  - JOUR
AU  - Šuljagić, Marija
AU  - Milenković, Milica R.
AU  - Uskoković, Vuk
AU  - Mirković, Miljana
AU  - Vrbica, Boško
AU  - Pavlović, Vladimir D.
AU  - Živković-Radovanović, Vukosava
AU  - Stanković, Dalibor
AU  - Anđelković, Ljubica
PY  - 2022
UR  - https://www.sciencedirect.com/journal/materials-today-communications
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5521
AB  - The emerging threat of bacterial resistance to antibiotics prompts the urgent search for biomaterials for the treatment of infectious disease. Here we report on the synthesis and characterization of a multiphasic nanocomposite comprising magnetic iron oxide and silver nanoparticles. The method of synthesis involved the combustion of a metalorganic complex and reduction of the silver ions that were exchanged and/or adsorbed on the surface of iron oxide. Different physical and chemical treatments coupled to the reduction process, including ultrasound and Lugol's iodine solution, respectively, homogenized the distribution of the silver nanoparticles on the iron oxide phase. Remarkably, using ascorbic acid as a reductant enhanced the magnetic properties of the material as a result of the reduction of the magnetic matrix alongside the silver cations. The treatment with ultrasound detached large amounts of silver from the iron oxide phase and resulted in the lowest amount of silver incorporated in the nanocomposite. Despite that, this treatment led to the highest antibacterial activity against both Gram-positive and Gram-negative strains, indicating that the homogeneity of the distribution of silver on the iron oxide matrix is a more important determinant of the antibacterial performance than the amount of silver incorporated in the material. At the same time, the treatment with Lugol's iodine equally increased the distribution homogeneity, but induced excessive ion exchange and crystal lattice substitutions, thereby adversely affecting the antibacterial performance. This has indicated that the mode of binding silver to iron oxide can compensate for the positive effects of homogeneous distribution with respect to the antibacterial performance.
PB  - Elsevier
T2  - Materials Today Communications
T1  - Silver distribution and binding mode as key determinants of the antimicrobial performance of iron oxide/silver nanocomposites
VL  - 32
SP  - 104157
DO  - 10.1016/j.mtcomm.2022.104157
ER  - 
@article{
author = "Šuljagić, Marija and Milenković, Milica R. and Uskoković, Vuk and Mirković, Miljana and Vrbica, Boško and Pavlović, Vladimir D. and Živković-Radovanović, Vukosava and Stanković, Dalibor and Anđelković, Ljubica",
year = "2022",
abstract = "The emerging threat of bacterial resistance to antibiotics prompts the urgent search for biomaterials for the treatment of infectious disease. Here we report on the synthesis and characterization of a multiphasic nanocomposite comprising magnetic iron oxide and silver nanoparticles. The method of synthesis involved the combustion of a metalorganic complex and reduction of the silver ions that were exchanged and/or adsorbed on the surface of iron oxide. Different physical and chemical treatments coupled to the reduction process, including ultrasound and Lugol's iodine solution, respectively, homogenized the distribution of the silver nanoparticles on the iron oxide phase. Remarkably, using ascorbic acid as a reductant enhanced the magnetic properties of the material as a result of the reduction of the magnetic matrix alongside the silver cations. The treatment with ultrasound detached large amounts of silver from the iron oxide phase and resulted in the lowest amount of silver incorporated in the nanocomposite. Despite that, this treatment led to the highest antibacterial activity against both Gram-positive and Gram-negative strains, indicating that the homogeneity of the distribution of silver on the iron oxide matrix is a more important determinant of the antibacterial performance than the amount of silver incorporated in the material. At the same time, the treatment with Lugol's iodine equally increased the distribution homogeneity, but induced excessive ion exchange and crystal lattice substitutions, thereby adversely affecting the antibacterial performance. This has indicated that the mode of binding silver to iron oxide can compensate for the positive effects of homogeneous distribution with respect to the antibacterial performance.",
publisher = "Elsevier",
journal = "Materials Today Communications",
title = "Silver distribution and binding mode as key determinants of the antimicrobial performance of iron oxide/silver nanocomposites",
volume = "32",
pages = "104157",
doi = "10.1016/j.mtcomm.2022.104157"
}
Šuljagić, M., Milenković, M. R., Uskoković, V., Mirković, M., Vrbica, B., Pavlović, V. D., Živković-Radovanović, V., Stanković, D.,& Anđelković, L.. (2022). Silver distribution and binding mode as key determinants of the antimicrobial performance of iron oxide/silver nanocomposites. in Materials Today Communications
Elsevier., 32, 104157.
https://doi.org/10.1016/j.mtcomm.2022.104157
Šuljagić M, Milenković MR, Uskoković V, Mirković M, Vrbica B, Pavlović VD, Živković-Radovanović V, Stanković D, Anđelković L. Silver distribution and binding mode as key determinants of the antimicrobial performance of iron oxide/silver nanocomposites. in Materials Today Communications. 2022;32:104157.
doi:10.1016/j.mtcomm.2022.104157 .
Šuljagić, Marija, Milenković, Milica R., Uskoković, Vuk, Mirković, Miljana, Vrbica, Boško, Pavlović, Vladimir D., Živković-Radovanović, Vukosava, Stanković, Dalibor, Anđelković, Ljubica, "Silver distribution and binding mode as key determinants of the antimicrobial performance of iron oxide/silver nanocomposites" in Materials Today Communications, 32 (2022):104157,
https://doi.org/10.1016/j.mtcomm.2022.104157 . .
2
1
1

The impact of ferric iron and pH on photo-degradation of tetracycline in water

Korać Jačić, Jelena; Milenković, Milica R.; Bajuk-Bogdanović, Danica; Stanković, Dalibor; Dimitrijević, Milena; Spasojević, Ivan

(Elsevier, 2022)

TY  - JOUR
AU  - Korać Jačić, Jelena
AU  - Milenković, Milica R.
AU  - Bajuk-Bogdanović, Danica
AU  - Stanković, Dalibor
AU  - Dimitrijević, Milena
AU  - Spasojević, Ivan
PY  - 2022
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5511
AB  - There is a significant interest in understanding coordination and photo-chemistry of tetracycline antibiotics, primarily in relation to the development of advanced oxidation processes for degradation of these pollutants in water processing. Herein we analyzed the pH-dependence of interactions of tetracycline with ferric iron and photosensitivity of tetracycline to UV-A and UV-B, using a set of methods – UV–vis, Raman and electron paramagnetic resonance spectroscopy, MS spectrometry, HPLC, and cyclic voltammetry. Tetracycline and Fe3+ mainly bind through amide and OH groups in tricarbonylamide moiety to form a stable complex with 1:1 stoichiometry at pH ≤ 5. The interaction is reversible and tetracycline is released from the complex with pH increase. Tetracycline in the complex is stabilized and less susceptible than free tetracycline to oxidation by hydroxyl radical that is produced by UV-induced photolysis of Fe3+–OH- complexes. Redox properties of tetracycline were altered with increasing pH and it showed increased susceptibility to UV-induced degradation. In close, the system composed of tetracycline and ferric iron shows coordination and photo-redox chemistry that is dependent of pH in relation to the solubility of Fe3+ species and protonation of tetracycline. The development and optimization of advanced oxidation processes should take into account that iron may bind and stabilize pollutants and that the redox landscape of water changes drastically with pH.
PB  - Elsevier
T2  - Journal of Photochemistry & Photobiology, A: Chemistry
T1  - The impact of ferric iron and pH on photo-degradation of tetracycline in water
VL  - 433
SP  - 114155
DO  - 10.1016/j.jphotochem.2022.114155
ER  - 
@article{
author = "Korać Jačić, Jelena and Milenković, Milica R. and Bajuk-Bogdanović, Danica and Stanković, Dalibor and Dimitrijević, Milena and Spasojević, Ivan",
year = "2022",
abstract = "There is a significant interest in understanding coordination and photo-chemistry of tetracycline antibiotics, primarily in relation to the development of advanced oxidation processes for degradation of these pollutants in water processing. Herein we analyzed the pH-dependence of interactions of tetracycline with ferric iron and photosensitivity of tetracycline to UV-A and UV-B, using a set of methods – UV–vis, Raman and electron paramagnetic resonance spectroscopy, MS spectrometry, HPLC, and cyclic voltammetry. Tetracycline and Fe3+ mainly bind through amide and OH groups in tricarbonylamide moiety to form a stable complex with 1:1 stoichiometry at pH ≤ 5. The interaction is reversible and tetracycline is released from the complex with pH increase. Tetracycline in the complex is stabilized and less susceptible than free tetracycline to oxidation by hydroxyl radical that is produced by UV-induced photolysis of Fe3+–OH- complexes. Redox properties of tetracycline were altered with increasing pH and it showed increased susceptibility to UV-induced degradation. In close, the system composed of tetracycline and ferric iron shows coordination and photo-redox chemistry that is dependent of pH in relation to the solubility of Fe3+ species and protonation of tetracycline. The development and optimization of advanced oxidation processes should take into account that iron may bind and stabilize pollutants and that the redox landscape of water changes drastically with pH.",
publisher = "Elsevier",
journal = "Journal of Photochemistry & Photobiology, A: Chemistry",
title = "The impact of ferric iron and pH on photo-degradation of tetracycline in water",
volume = "433",
pages = "114155",
doi = "10.1016/j.jphotochem.2022.114155"
}
Korać Jačić, J., Milenković, M. R., Bajuk-Bogdanović, D., Stanković, D., Dimitrijević, M.,& Spasojević, I.. (2022). The impact of ferric iron and pH on photo-degradation of tetracycline in water. in Journal of Photochemistry & Photobiology, A: Chemistry
Elsevier., 433, 114155.
https://doi.org/10.1016/j.jphotochem.2022.114155
Korać Jačić J, Milenković MR, Bajuk-Bogdanović D, Stanković D, Dimitrijević M, Spasojević I. The impact of ferric iron and pH on photo-degradation of tetracycline in water. in Journal of Photochemistry & Photobiology, A: Chemistry. 2022;433:114155.
doi:10.1016/j.jphotochem.2022.114155 .
Korać Jačić, Jelena, Milenković, Milica R., Bajuk-Bogdanović, Danica, Stanković, Dalibor, Dimitrijević, Milena, Spasojević, Ivan, "The impact of ferric iron and pH on photo-degradation of tetracycline in water" in Journal of Photochemistry & Photobiology, A: Chemistry, 433 (2022):114155,
https://doi.org/10.1016/j.jphotochem.2022.114155 . .
10
10
8

Supplementary information for the article: Korać Jačić, J.; Milenković, M. R.; Bajuk-Bogdanović, D.; Stanković, D.; Dimitrijević, M.; Spasojević, I. The Impact of Ferric Iron and PH on Photo-Degradation of Tetracycline in Water. Journal of Photochemistry and Photobiology A: Chemistry 2022, 433, 114155. https://doi.org/10.1016/j.jphotochem.2022.114155.

Korać Jačić, Jelena; Milenković, Milica R.; Bajuk-Bogdanović, Danica; Stanković, Dalibor; Dimitrijević, Milena; Spasojević, Ivan

(Elsevier, 2022)

TY  - DATA
AU  - Korać Jačić, Jelena
AU  - Milenković, Milica R.
AU  - Bajuk-Bogdanović, Danica
AU  - Stanković, Dalibor
AU  - Dimitrijević, Milena
AU  - Spasojević, Ivan
PY  - 2022
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5511
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5512
AB  - There is a significant interest in understanding coordination and photo-chemistry of tetracycline antibiotics, primarily in relation to the development of advanced oxidation processes for degradation of these pollutants in water processing. Herein we analyzed the pH-dependence of interactions of tetracycline with ferric iron and photosensitivity of tetracycline to UV-A and UV-B, using a set of methods – UV–vis, Raman and electron paramagnetic resonance spectroscopy, MS spectrometry, HPLC, and cyclic voltammetry. Tetracycline and Fe3+ mainly bind through amide and OH groups in tricarbonylamide moiety to form a stable complex with 1:1 stoichiometry at pH ≤ 5. The interaction is reversible and tetracycline is released from the complex with pH increase. Tetracycline in the complex is stabilized and less susceptible than free tetracycline to oxidation by hydroxyl radical that is produced by UV-induced photolysis of Fe3+–OH- complexes. Redox properties of tetracycline were altered with increasing pH and it showed increased susceptibility to UV-induced degradation. In close, the system composed of tetracycline and ferric iron shows coordination and photo-redox chemistry that is dependent of pH in relation to the solubility of Fe3+ species and protonation of tetracycline. The development and optimization of advanced oxidation processes should take into account that iron may bind and stabilize pollutants and that the redox landscape of water changes drastically with pH.
PB  - Elsevier
T2  - Journal of Photochemistry & Photobiology, A: Chemistry
T1  - Supplementary information for the article: Korać Jačić, J.; Milenković, M. R.; Bajuk-Bogdanović, D.; Stanković, D.; Dimitrijević, M.; Spasojević, I. The Impact of Ferric Iron and PH on Photo-Degradation of Tetracycline in Water. Journal of Photochemistry and Photobiology A: Chemistry 2022, 433, 114155. https://doi.org/10.1016/j.jphotochem.2022.114155.
VL  - 433
SP  - 114155
UR  - https://hdl.handle.net/21.15107/rcub_cherry_5512
ER  - 
@misc{
author = "Korać Jačić, Jelena and Milenković, Milica R. and Bajuk-Bogdanović, Danica and Stanković, Dalibor and Dimitrijević, Milena and Spasojević, Ivan",
year = "2022",
abstract = "There is a significant interest in understanding coordination and photo-chemistry of tetracycline antibiotics, primarily in relation to the development of advanced oxidation processes for degradation of these pollutants in water processing. Herein we analyzed the pH-dependence of interactions of tetracycline with ferric iron and photosensitivity of tetracycline to UV-A and UV-B, using a set of methods – UV–vis, Raman and electron paramagnetic resonance spectroscopy, MS spectrometry, HPLC, and cyclic voltammetry. Tetracycline and Fe3+ mainly bind through amide and OH groups in tricarbonylamide moiety to form a stable complex with 1:1 stoichiometry at pH ≤ 5. The interaction is reversible and tetracycline is released from the complex with pH increase. Tetracycline in the complex is stabilized and less susceptible than free tetracycline to oxidation by hydroxyl radical that is produced by UV-induced photolysis of Fe3+–OH- complexes. Redox properties of tetracycline were altered with increasing pH and it showed increased susceptibility to UV-induced degradation. In close, the system composed of tetracycline and ferric iron shows coordination and photo-redox chemistry that is dependent of pH in relation to the solubility of Fe3+ species and protonation of tetracycline. The development and optimization of advanced oxidation processes should take into account that iron may bind and stabilize pollutants and that the redox landscape of water changes drastically with pH.",
publisher = "Elsevier",
journal = "Journal of Photochemistry & Photobiology, A: Chemistry",
title = "Supplementary information for the article: Korać Jačić, J.; Milenković, M. R.; Bajuk-Bogdanović, D.; Stanković, D.; Dimitrijević, M.; Spasojević, I. The Impact of Ferric Iron and PH on Photo-Degradation of Tetracycline in Water. Journal of Photochemistry and Photobiology A: Chemistry 2022, 433, 114155. https://doi.org/10.1016/j.jphotochem.2022.114155.",
volume = "433",
pages = "114155",
url = "https://hdl.handle.net/21.15107/rcub_cherry_5512"
}
Korać Jačić, J., Milenković, M. R., Bajuk-Bogdanović, D., Stanković, D., Dimitrijević, M.,& Spasojević, I.. (2022). Supplementary information for the article: Korać Jačić, J.; Milenković, M. R.; Bajuk-Bogdanović, D.; Stanković, D.; Dimitrijević, M.; Spasojević, I. The Impact of Ferric Iron and PH on Photo-Degradation of Tetracycline in Water. Journal of Photochemistry and Photobiology A: Chemistry 2022, 433, 114155. https://doi.org/10.1016/j.jphotochem.2022.114155.. in Journal of Photochemistry & Photobiology, A: Chemistry
Elsevier., 433, 114155.
https://hdl.handle.net/21.15107/rcub_cherry_5512
Korać Jačić J, Milenković MR, Bajuk-Bogdanović D, Stanković D, Dimitrijević M, Spasojević I. Supplementary information for the article: Korać Jačić, J.; Milenković, M. R.; Bajuk-Bogdanović, D.; Stanković, D.; Dimitrijević, M.; Spasojević, I. The Impact of Ferric Iron and PH on Photo-Degradation of Tetracycline in Water. Journal of Photochemistry and Photobiology A: Chemistry 2022, 433, 114155. https://doi.org/10.1016/j.jphotochem.2022.114155.. in Journal of Photochemistry & Photobiology, A: Chemistry. 2022;433:114155.
https://hdl.handle.net/21.15107/rcub_cherry_5512 .
Korać Jačić, Jelena, Milenković, Milica R., Bajuk-Bogdanović, Danica, Stanković, Dalibor, Dimitrijević, Milena, Spasojević, Ivan, "Supplementary information for the article: Korać Jačić, J.; Milenković, M. R.; Bajuk-Bogdanović, D.; Stanković, D.; Dimitrijević, M.; Spasojević, I. The Impact of Ferric Iron and PH on Photo-Degradation of Tetracycline in Water. Journal of Photochemistry and Photobiology A: Chemistry 2022, 433, 114155. https://doi.org/10.1016/j.jphotochem.2022.114155." in Journal of Photochemistry & Photobiology, A: Chemistry, 433 (2022):114155,
https://hdl.handle.net/21.15107/rcub_cherry_5512 .

The influence of the starch coating on the magnetic properties of nanosized cobalt ferrites obtained by different synthetic methods

Šuljagić, Marija; Vulić, Predrag J.; Jeremić, Dejan; Pavlović, Vladimir B.; Filipović, Suzana; Kilanski, Lukasz; Lewinska, Sabina; Slawska-Waniewska, Anna; Milenković, Milica R.; Nikolić, Aleksandar S.; Anđelković, Ljubica

(Elsevier, 2021)

TY  - JOUR
AU  - Šuljagić, Marija
AU  - Vulić, Predrag J.
AU  - Jeremić, Dejan
AU  - Pavlović, Vladimir B.
AU  - Filipović, Suzana
AU  - Kilanski, Lukasz
AU  - Lewinska, Sabina
AU  - Slawska-Waniewska, Anna
AU  - Milenković, Milica R.
AU  - Nikolić, Aleksandar S.
AU  - Anđelković, Ljubica
PY  - 2021
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/4271
AB  - To investigate the magnetic behavior of starch-coated cobalt ferrites, well-established synthetic methods, i.e., coprecipitation, mechanochemical, ultrasonically assisted coprecipitation, microemulsion, and microwave-assisted hydrothermal syntheses were chosen for their preparation. The obtained materials had pure single-phase spinel structures. Scanning and transmission electron microscopy analyses revealed that the morphology of the samples is not uniform, and particle aggregation is a dominant process. Fourier transform infrared spectra and thermogravimetric analysis confirmed the presence of starch in all–coated samples. The unusually higher saturation magnetization of starch-coated samples than their as-prepared analogs, obtained by coprecipitation, ultrasonically assisted coprecipitation, and microwave-assisted hydrothermal methods, might be explained by the Ostwald ripening mechanism induced by the coating process. A decrease in magnetization was noticed for the starch-functionalized nanomaterials synthesized by mechanochemical and microemulsion methods, in comparison to their as-prepared analogs, i.e., the size distribution of such nanoparticles is narrow, and the average diameter of the grains is near critical for the Ostwald ripening process.
PB  - Elsevier
T2  - Materials Research Bulletin
T1  - The influence of the starch coating on the magnetic properties of nanosized cobalt ferrites obtained by different synthetic methods
VL  - 134
SP  - 111117
DO  - 10.1016/j.materresbull.2020.111117
ER  - 
@article{
author = "Šuljagić, Marija and Vulić, Predrag J. and Jeremić, Dejan and Pavlović, Vladimir B. and Filipović, Suzana and Kilanski, Lukasz and Lewinska, Sabina and Slawska-Waniewska, Anna and Milenković, Milica R. and Nikolić, Aleksandar S. and Anđelković, Ljubica",
year = "2021",
abstract = "To investigate the magnetic behavior of starch-coated cobalt ferrites, well-established synthetic methods, i.e., coprecipitation, mechanochemical, ultrasonically assisted coprecipitation, microemulsion, and microwave-assisted hydrothermal syntheses were chosen for their preparation. The obtained materials had pure single-phase spinel structures. Scanning and transmission electron microscopy analyses revealed that the morphology of the samples is not uniform, and particle aggregation is a dominant process. Fourier transform infrared spectra and thermogravimetric analysis confirmed the presence of starch in all–coated samples. The unusually higher saturation magnetization of starch-coated samples than their as-prepared analogs, obtained by coprecipitation, ultrasonically assisted coprecipitation, and microwave-assisted hydrothermal methods, might be explained by the Ostwald ripening mechanism induced by the coating process. A decrease in magnetization was noticed for the starch-functionalized nanomaterials synthesized by mechanochemical and microemulsion methods, in comparison to their as-prepared analogs, i.e., the size distribution of such nanoparticles is narrow, and the average diameter of the grains is near critical for the Ostwald ripening process.",
publisher = "Elsevier",
journal = "Materials Research Bulletin",
title = "The influence of the starch coating on the magnetic properties of nanosized cobalt ferrites obtained by different synthetic methods",
volume = "134",
pages = "111117",
doi = "10.1016/j.materresbull.2020.111117"
}
Šuljagić, M., Vulić, P. J., Jeremić, D., Pavlović, V. B., Filipović, S., Kilanski, L., Lewinska, S., Slawska-Waniewska, A., Milenković, M. R., Nikolić, A. S.,& Anđelković, L.. (2021). The influence of the starch coating on the magnetic properties of nanosized cobalt ferrites obtained by different synthetic methods. in Materials Research Bulletin
Elsevier., 134, 111117.
https://doi.org/10.1016/j.materresbull.2020.111117
Šuljagić M, Vulić PJ, Jeremić D, Pavlović VB, Filipović S, Kilanski L, Lewinska S, Slawska-Waniewska A, Milenković MR, Nikolić AS, Anđelković L. The influence of the starch coating on the magnetic properties of nanosized cobalt ferrites obtained by different synthetic methods. in Materials Research Bulletin. 2021;134:111117.
doi:10.1016/j.materresbull.2020.111117 .
Šuljagić, Marija, Vulić, Predrag J., Jeremić, Dejan, Pavlović, Vladimir B., Filipović, Suzana, Kilanski, Lukasz, Lewinska, Sabina, Slawska-Waniewska, Anna, Milenković, Milica R., Nikolić, Aleksandar S., Anđelković, Ljubica, "The influence of the starch coating on the magnetic properties of nanosized cobalt ferrites obtained by different synthetic methods" in Materials Research Bulletin, 134 (2021):111117,
https://doi.org/10.1016/j.materresbull.2020.111117 . .
19
5
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14

Light-Transmitting Measurements through Starch-Coated Cobalt Ferrite Ferrofluids Exposed to an External Magnetic Field

Šuljagić, Marija; Anđelković, Ljubica; Iskrenović, Predrag; Nikolić, Aleksandar S.; Milenković, Milica R.

(Springer Nature, 2021)

TY  - JOUR
AU  - Šuljagić, Marija
AU  - Anđelković, Ljubica
AU  - Iskrenović, Predrag
AU  - Nikolić, Aleksandar S.
AU  - Milenković, Milica R.
PY  - 2021
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/4423
AB  - The light-transmitting measurements at the 655 nm wavelength have been performed through starch-coated cobalt ferrite ferrofluids synthesized by well-established synthetic methods, i.e., coprecipitation, mechanochemical, ultrasonically assisted coprecipitation, microemulsion, and microwave-assisted hydrothermal syntheses, exposed to an external magnetic field of 200–400 mT. The investigated samples can be divided into the two groups. The first is where the samples showed higher rate of agglomeration and sedimentation effects. The group of samples synthesized by microemulsion, microwave-assisted hydrothermal method, and mechanochemical method showed less pronounced rate of chain formation. Such measurements present good method for the preliminary selection of possible magnetic resonance imaging (MRI) contrast agents between differently synthesized ferrite suspensions.
PB  - Springer Nature
T2  - JETP Letters
T1  - Light-Transmitting Measurements through Starch-Coated Cobalt Ferrite Ferrofluids Exposed to an External Magnetic Field
VL  - 113
IS  - 4
SP  - 238
EP  - 241
DO  - 10.1134/S0021364021040056
ER  - 
@article{
author = "Šuljagić, Marija and Anđelković, Ljubica and Iskrenović, Predrag and Nikolić, Aleksandar S. and Milenković, Milica R.",
year = "2021",
abstract = "The light-transmitting measurements at the 655 nm wavelength have been performed through starch-coated cobalt ferrite ferrofluids synthesized by well-established synthetic methods, i.e., coprecipitation, mechanochemical, ultrasonically assisted coprecipitation, microemulsion, and microwave-assisted hydrothermal syntheses, exposed to an external magnetic field of 200–400 mT. The investigated samples can be divided into the two groups. The first is where the samples showed higher rate of agglomeration and sedimentation effects. The group of samples synthesized by microemulsion, microwave-assisted hydrothermal method, and mechanochemical method showed less pronounced rate of chain formation. Such measurements present good method for the preliminary selection of possible magnetic resonance imaging (MRI) contrast agents between differently synthesized ferrite suspensions.",
publisher = "Springer Nature",
journal = "JETP Letters",
title = "Light-Transmitting Measurements through Starch-Coated Cobalt Ferrite Ferrofluids Exposed to an External Magnetic Field",
volume = "113",
number = "4",
pages = "238-241",
doi = "10.1134/S0021364021040056"
}
Šuljagić, M., Anđelković, L., Iskrenović, P., Nikolić, A. S.,& Milenković, M. R.. (2021). Light-Transmitting Measurements through Starch-Coated Cobalt Ferrite Ferrofluids Exposed to an External Magnetic Field. in JETP Letters
Springer Nature., 113(4), 238-241.
https://doi.org/10.1134/S0021364021040056
Šuljagić M, Anđelković L, Iskrenović P, Nikolić AS, Milenković MR. Light-Transmitting Measurements through Starch-Coated Cobalt Ferrite Ferrofluids Exposed to an External Magnetic Field. in JETP Letters. 2021;113(4):238-241.
doi:10.1134/S0021364021040056 .
Šuljagić, Marija, Anđelković, Ljubica, Iskrenović, Predrag, Nikolić, Aleksandar S., Milenković, Milica R., "Light-Transmitting Measurements through Starch-Coated Cobalt Ferrite Ferrofluids Exposed to an External Magnetic Field" in JETP Letters, 113, no. 4 (2021):238-241,
https://doi.org/10.1134/S0021364021040056 . .
1
1
1
1

Synthesis and Antimicrobial Activity of (3-Formyl-4-hydroxybenzyl)triphenylphosphonium Chloride Acylhydrazones

Milenković, Milica R.; Živković-Radovanović, Vukosava; Anđelković, Ljubica

(Springer, 2020)

TY  - JOUR
AU  - Milenković, Milica R.
AU  - Živković-Radovanović, Vukosava
AU  - Anđelković, Ljubica
PY  - 2020
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/4259
AB  - In this study, four novel quaternary phosphonium acylhydrazones, derivatives of (3-formyl-4-hydroxybenzyl)triphenylphosphonium chloride, have been synthesized and their structures elucidated from IR and NMR spectra, and elemental analysis. All synthesized compounds have been tested for their antimicrobial activity, and acylhydrazones have demonstrated selective activity against Gram-positive bacteria strains.
PB  - Springer
T2  - Russian Journal of General Chemistry
T1  - Synthesis and Antimicrobial Activity of (3-Formyl-4-hydroxybenzyl)triphenylphosphonium Chloride Acylhydrazones
VL  - 90
IS  - 9
SP  - 1716
EP  - 1720
DO  - 10.1134/S1070363220090194
ER  - 
@article{
author = "Milenković, Milica R. and Živković-Radovanović, Vukosava and Anđelković, Ljubica",
year = "2020",
abstract = "In this study, four novel quaternary phosphonium acylhydrazones, derivatives of (3-formyl-4-hydroxybenzyl)triphenylphosphonium chloride, have been synthesized and their structures elucidated from IR and NMR spectra, and elemental analysis. All synthesized compounds have been tested for their antimicrobial activity, and acylhydrazones have demonstrated selective activity against Gram-positive bacteria strains.",
publisher = "Springer",
journal = "Russian Journal of General Chemistry",
title = "Synthesis and Antimicrobial Activity of (3-Formyl-4-hydroxybenzyl)triphenylphosphonium Chloride Acylhydrazones",
volume = "90",
number = "9",
pages = "1716-1720",
doi = "10.1134/S1070363220090194"
}
Milenković, M. R., Živković-Radovanović, V.,& Anđelković, L.. (2020). Synthesis and Antimicrobial Activity of (3-Formyl-4-hydroxybenzyl)triphenylphosphonium Chloride Acylhydrazones. in Russian Journal of General Chemistry
Springer., 90(9), 1716-1720.
https://doi.org/10.1134/S1070363220090194
Milenković MR, Živković-Radovanović V, Anđelković L. Synthesis and Antimicrobial Activity of (3-Formyl-4-hydroxybenzyl)triphenylphosphonium Chloride Acylhydrazones. in Russian Journal of General Chemistry. 2020;90(9):1716-1720.
doi:10.1134/S1070363220090194 .
Milenković, Milica R., Živković-Radovanović, Vukosava, Anđelković, Ljubica, "Synthesis and Antimicrobial Activity of (3-Formyl-4-hydroxybenzyl)triphenylphosphonium Chloride Acylhydrazones" in Russian Journal of General Chemistry, 90, no. 9 (2020):1716-1720,
https://doi.org/10.1134/S1070363220090194 . .
2
2

One-pot combustion synthesis of nickel oxide and hematite: From simple coordination compounds to high purity metal oxide nanoparticles

Jeremić, Dejan; Anđelković, Ljubica; Milenković, Milica R.; Šuljagić, Marija; Šumar-Ristović, Maja; Ostojić, Sanja B.; Nikolić, Aleksandar S.; Vulić, Predrag J.; Brčeski, Ilija; Pavlović, Vladimir B.

(2020)

TY  - JOUR
AU  - Jeremić, Dejan
AU  - Anđelković, Ljubica
AU  - Milenković, Milica R.
AU  - Šuljagić, Marija
AU  - Šumar-Ristović, Maja
AU  - Ostojić, Sanja B.
AU  - Nikolić, Aleksandar S.
AU  - Vulić, Predrag J.
AU  - Brčeski, Ilija
AU  - Pavlović, Vladimir B.
PY  - 2020
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/4306
AB  - This work is the first report of a very simple and fast one-pot synthesis of nickel oxide (NiO) and hematite (α-Fe2O3) nanoparticles by thermal decomposition of transition metal aqua complexes with camphor sulfonate anions. Obtained nanopowders were characterized by X-ray powder diffraction, Fourier transform IR analysis, scanning electron microscopy, and Energy-dispersive X-ray spectroscopy. X-ray powder diffraction confirmed the formation of high purity NiO and α-Fe2O3 crystal phases. In the case of α-Fe2O3, about five times larger average crystallite size was obtained. Fourier transform IR spectra of synthesized materials showed characteristic peaks for NiO and α-Fe2O3 nanostructures. To visualize the morphology and the chemical composition of the final products Scanning electron microscopy and Energy-dispersive X-ray spectroscopy were performed. The thermogravimetric analysis was done for a better understanding of the general thermal behavior of precursor compounds. This easy-to-perform and fast preparation method opens a broad range of obtained materials’ usage, particularly due to its economic viability
T2  - Science of Sintering
T1  - One-pot combustion synthesis of nickel oxide and hematite: From simple coordination compounds to high purity metal oxide nanoparticles
VL  - 52
IS  - 4
SP  - 481
EP  - 490
DO  - 10.2298/SOS2004481J
ER  - 
@article{
author = "Jeremić, Dejan and Anđelković, Ljubica and Milenković, Milica R. and Šuljagić, Marija and Šumar-Ristović, Maja and Ostojić, Sanja B. and Nikolić, Aleksandar S. and Vulić, Predrag J. and Brčeski, Ilija and Pavlović, Vladimir B.",
year = "2020",
abstract = "This work is the first report of a very simple and fast one-pot synthesis of nickel oxide (NiO) and hematite (α-Fe2O3) nanoparticles by thermal decomposition of transition metal aqua complexes with camphor sulfonate anions. Obtained nanopowders were characterized by X-ray powder diffraction, Fourier transform IR analysis, scanning electron microscopy, and Energy-dispersive X-ray spectroscopy. X-ray powder diffraction confirmed the formation of high purity NiO and α-Fe2O3 crystal phases. In the case of α-Fe2O3, about five times larger average crystallite size was obtained. Fourier transform IR spectra of synthesized materials showed characteristic peaks for NiO and α-Fe2O3 nanostructures. To visualize the morphology and the chemical composition of the final products Scanning electron microscopy and Energy-dispersive X-ray spectroscopy were performed. The thermogravimetric analysis was done for a better understanding of the general thermal behavior of precursor compounds. This easy-to-perform and fast preparation method opens a broad range of obtained materials’ usage, particularly due to its economic viability",
journal = "Science of Sintering",
title = "One-pot combustion synthesis of nickel oxide and hematite: From simple coordination compounds to high purity metal oxide nanoparticles",
volume = "52",
number = "4",
pages = "481-490",
doi = "10.2298/SOS2004481J"
}
Jeremić, D., Anđelković, L., Milenković, M. R., Šuljagić, M., Šumar-Ristović, M., Ostojić, S. B., Nikolić, A. S., Vulić, P. J., Brčeski, I.,& Pavlović, V. B.. (2020). One-pot combustion synthesis of nickel oxide and hematite: From simple coordination compounds to high purity metal oxide nanoparticles. in Science of Sintering, 52(4), 481-490.
https://doi.org/10.2298/SOS2004481J
Jeremić D, Anđelković L, Milenković MR, Šuljagić M, Šumar-Ristović M, Ostojić SB, Nikolić AS, Vulić PJ, Brčeski I, Pavlović VB. One-pot combustion synthesis of nickel oxide and hematite: From simple coordination compounds to high purity metal oxide nanoparticles. in Science of Sintering. 2020;52(4):481-490.
doi:10.2298/SOS2004481J .
Jeremić, Dejan, Anđelković, Ljubica, Milenković, Milica R., Šuljagić, Marija, Šumar-Ristović, Maja, Ostojić, Sanja B., Nikolić, Aleksandar S., Vulić, Predrag J., Brčeski, Ilija, Pavlović, Vladimir B., "One-pot combustion synthesis of nickel oxide and hematite: From simple coordination compounds to high purity metal oxide nanoparticles" in Science of Sintering, 52, no. 4 (2020):481-490,
https://doi.org/10.2298/SOS2004481J . .
8
3
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8

Synthesis, structure, spectroscopic studies and magnetic properties of Cu2N2O4-, Cu2N2O2(S2)-, Cu2N2S4-chromophores based on aminomethylene derivatives of pyrazole-5-one(thione)

Uraev, Ali I.; Nefedov, Sergey E.; Lyssenko, Konstantin A.; Vlasenko, Valery G.; Ikorskii, Vladimir N.; Garnovskii, Dmitrii A.; Makarova, Nadezhda I.; Levchenkov, Sergey I.; Shcherbakov, Igor N.; Milenković, Milica R.; Borodkin, Gennadii S.

(Elsevier, 2020)

TY  - JOUR
AU  - Uraev, Ali I.
AU  - Nefedov, Sergey E.
AU  - Lyssenko, Konstantin A.
AU  - Vlasenko, Valery G.
AU  - Ikorskii, Vladimir N.
AU  - Garnovskii, Dmitrii A.
AU  - Makarova, Nadezhda I.
AU  - Levchenkov, Sergey I.
AU  - Shcherbakov, Igor N.
AU  - Milenković, Milica R.
AU  - Borodkin, Gennadii S.
PY  - 2020
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/4221
AB  - The aminomethylene derivatives of pyrazole-5-one (6) and pyrazole-5-thione (7) were synthesized in the reaction of 2-aminophenol (4) with corresponding 1-phenyl-3-methyl-5-X-pyrazole-4-carbaldehyde (1, X = hydroxy) or (2, X = sulfanyl). Reaction of 2-aminobenzenethiol (5) with 1-R-3-methyl-5-sulfanyl-pyrazole-4-carbaldehydes (2, R = phenyl and 3, R = isopropyl) results in the formation of disulfide compounds 8 and 9. The structures of compounds 6–9 were determined by IR and NMR spectroscopy and elemental analysis. The reaction of each ligand 6–9 with copper(II) acetate monohydrate in ethanol resulted in dinuclear metal-chelates with Cu2N2O4, Cu2N2O2S2, Cu2N2S4 chromophores. All complexes were characterized with C, H, N elemental analysis, FT-IR, ESR and X-ray absorption spectroscopy. The structures of the complexes 11 and 13 were determined by X-ray single-crystal diffraction. The variable-temperature magnetic susceptibility measurements in the 2–300 K temperature range were performed and the influence of the type of bridging atoms on the magnetic and spectral properties was discussed. The nature of magnetic and spectral properties of the copper chelates was analyzed using DFT quantum-chemical calculations within broken-symmetry and time dependent (TD DFT) approximations, correspondingly.
PB  - Elsevier
T2  - Polyhedron
T1  - Synthesis, structure, spectroscopic studies and magnetic properties of Cu2N2O4-, Cu2N2O2(S2)-, Cu2N2S4-chromophores based on aminomethylene derivatives of pyrazole-5-one(thione)
VL  - 188
SP  - 114623
DO  - 10.1016/j.poly.2020.114623
ER  - 
@article{
author = "Uraev, Ali I. and Nefedov, Sergey E. and Lyssenko, Konstantin A. and Vlasenko, Valery G. and Ikorskii, Vladimir N. and Garnovskii, Dmitrii A. and Makarova, Nadezhda I. and Levchenkov, Sergey I. and Shcherbakov, Igor N. and Milenković, Milica R. and Borodkin, Gennadii S.",
year = "2020",
abstract = "The aminomethylene derivatives of pyrazole-5-one (6) and pyrazole-5-thione (7) were synthesized in the reaction of 2-aminophenol (4) with corresponding 1-phenyl-3-methyl-5-X-pyrazole-4-carbaldehyde (1, X = hydroxy) or (2, X = sulfanyl). Reaction of 2-aminobenzenethiol (5) with 1-R-3-methyl-5-sulfanyl-pyrazole-4-carbaldehydes (2, R = phenyl and 3, R = isopropyl) results in the formation of disulfide compounds 8 and 9. The structures of compounds 6–9 were determined by IR and NMR spectroscopy and elemental analysis. The reaction of each ligand 6–9 with copper(II) acetate monohydrate in ethanol resulted in dinuclear metal-chelates with Cu2N2O4, Cu2N2O2S2, Cu2N2S4 chromophores. All complexes were characterized with C, H, N elemental analysis, FT-IR, ESR and X-ray absorption spectroscopy. The structures of the complexes 11 and 13 were determined by X-ray single-crystal diffraction. The variable-temperature magnetic susceptibility measurements in the 2–300 K temperature range were performed and the influence of the type of bridging atoms on the magnetic and spectral properties was discussed. The nature of magnetic and spectral properties of the copper chelates was analyzed using DFT quantum-chemical calculations within broken-symmetry and time dependent (TD DFT) approximations, correspondingly.",
publisher = "Elsevier",
journal = "Polyhedron",
title = "Synthesis, structure, spectroscopic studies and magnetic properties of Cu2N2O4-, Cu2N2O2(S2)-, Cu2N2S4-chromophores based on aminomethylene derivatives of pyrazole-5-one(thione)",
volume = "188",
pages = "114623",
doi = "10.1016/j.poly.2020.114623"
}
Uraev, A. I., Nefedov, S. E., Lyssenko, K. A., Vlasenko, V. G., Ikorskii, V. N., Garnovskii, D. A., Makarova, N. I., Levchenkov, S. I., Shcherbakov, I. N., Milenković, M. R.,& Borodkin, G. S.. (2020). Synthesis, structure, spectroscopic studies and magnetic properties of Cu2N2O4-, Cu2N2O2(S2)-, Cu2N2S4-chromophores based on aminomethylene derivatives of pyrazole-5-one(thione). in Polyhedron
Elsevier., 188, 114623.
https://doi.org/10.1016/j.poly.2020.114623
Uraev AI, Nefedov SE, Lyssenko KA, Vlasenko VG, Ikorskii VN, Garnovskii DA, Makarova NI, Levchenkov SI, Shcherbakov IN, Milenković MR, Borodkin GS. Synthesis, structure, spectroscopic studies and magnetic properties of Cu2N2O4-, Cu2N2O2(S2)-, Cu2N2S4-chromophores based on aminomethylene derivatives of pyrazole-5-one(thione). in Polyhedron. 2020;188:114623.
doi:10.1016/j.poly.2020.114623 .
Uraev, Ali I., Nefedov, Sergey E., Lyssenko, Konstantin A., Vlasenko, Valery G., Ikorskii, Vladimir N., Garnovskii, Dmitrii A., Makarova, Nadezhda I., Levchenkov, Sergey I., Shcherbakov, Igor N., Milenković, Milica R., Borodkin, Gennadii S., "Synthesis, structure, spectroscopic studies and magnetic properties of Cu2N2O4-, Cu2N2O2(S2)-, Cu2N2S4-chromophores based on aminomethylene derivatives of pyrazole-5-one(thione)" in Polyhedron, 188 (2020):114623,
https://doi.org/10.1016/j.poly.2020.114623 . .
1
3
1
3
2

Supplementary data for the article: Uraev, A. I.; Nefedov, S. E.; Lyssenko, K. A.; Vlasenko, V. G.; Ikorskii, V. N.; Garnovskii, D. A.; Makarova, N. I.; Levchenkov, S. I.; Shcherbakov, I. N.; Milenković, M. R.; Borodkin, G. S. Synthesis, Structure, Spectroscopic Studies and Magnetic Properties of Cu2N2O4-, Cu2N2O2(S2)-, Cu2N2S4-Chromophores Based on Aminomethylene Derivatives of Pyrazole-5-One(Thione). Polyhedron 2020, 188, 114623. https://doi.org/10.1016/j.poly.2020.114623

Uraev, Ali I.; Nefedov, Sergey E.; Lyssenko, Konstantin A.; Vlasenko, Valery G.; Ikorskii, Vladimir N.; Garnovskii, Dmitrii A.; Makarova, Nadezhda I.; Levchenkov, Sergey I.; Shcherbakov, Igor N.; Milenković, Milica R.; Borodkin, Gennadii S.

(Elsevier, 2020)

TY  - DATA
AU  - Uraev, Ali I.
AU  - Nefedov, Sergey E.
AU  - Lyssenko, Konstantin A.
AU  - Vlasenko, Valery G.
AU  - Ikorskii, Vladimir N.
AU  - Garnovskii, Dmitrii A.
AU  - Makarova, Nadezhda I.
AU  - Levchenkov, Sergey I.
AU  - Shcherbakov, Igor N.
AU  - Milenković, Milica R.
AU  - Borodkin, Gennadii S.
PY  - 2020
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/4236
PB  - Elsevier
T2  - Polyhedron
T1  - Supplementary data for the article: Uraev, A. I.; Nefedov, S. E.; Lyssenko, K. A.; Vlasenko, V. G.; Ikorskii, V. N.; Garnovskii, D. A.; Makarova, N. I.; Levchenkov, S. I.; Shcherbakov, I. N.; Milenković, M. R.; Borodkin, G. S. Synthesis, Structure, Spectroscopic Studies and Magnetic Properties of Cu2N2O4-, Cu2N2O2(S2)-, Cu2N2S4-Chromophores Based on Aminomethylene Derivatives of Pyrazole-5-One(Thione). Polyhedron 2020, 188, 114623. https://doi.org/10.1016/j.poly.2020.114623
UR  - https://hdl.handle.net/21.15107/rcub_cherry_4236
ER  - 
@misc{
author = "Uraev, Ali I. and Nefedov, Sergey E. and Lyssenko, Konstantin A. and Vlasenko, Valery G. and Ikorskii, Vladimir N. and Garnovskii, Dmitrii A. and Makarova, Nadezhda I. and Levchenkov, Sergey I. and Shcherbakov, Igor N. and Milenković, Milica R. and Borodkin, Gennadii S.",
year = "2020",
publisher = "Elsevier",
journal = "Polyhedron",
title = "Supplementary data for the article: Uraev, A. I.; Nefedov, S. E.; Lyssenko, K. A.; Vlasenko, V. G.; Ikorskii, V. N.; Garnovskii, D. A.; Makarova, N. I.; Levchenkov, S. I.; Shcherbakov, I. N.; Milenković, M. R.; Borodkin, G. S. Synthesis, Structure, Spectroscopic Studies and Magnetic Properties of Cu2N2O4-, Cu2N2O2(S2)-, Cu2N2S4-Chromophores Based on Aminomethylene Derivatives of Pyrazole-5-One(Thione). Polyhedron 2020, 188, 114623. https://doi.org/10.1016/j.poly.2020.114623",
url = "https://hdl.handle.net/21.15107/rcub_cherry_4236"
}
Uraev, A. I., Nefedov, S. E., Lyssenko, K. A., Vlasenko, V. G., Ikorskii, V. N., Garnovskii, D. A., Makarova, N. I., Levchenkov, S. I., Shcherbakov, I. N., Milenković, M. R.,& Borodkin, G. S.. (2020). Supplementary data for the article: Uraev, A. I.; Nefedov, S. E.; Lyssenko, K. A.; Vlasenko, V. G.; Ikorskii, V. N.; Garnovskii, D. A.; Makarova, N. I.; Levchenkov, S. I.; Shcherbakov, I. N.; Milenković, M. R.; Borodkin, G. S. Synthesis, Structure, Spectroscopic Studies and Magnetic Properties of Cu2N2O4-, Cu2N2O2(S2)-, Cu2N2S4-Chromophores Based on Aminomethylene Derivatives of Pyrazole-5-One(Thione). Polyhedron 2020, 188, 114623. https://doi.org/10.1016/j.poly.2020.114623. in Polyhedron
Elsevier..
https://hdl.handle.net/21.15107/rcub_cherry_4236
Uraev AI, Nefedov SE, Lyssenko KA, Vlasenko VG, Ikorskii VN, Garnovskii DA, Makarova NI, Levchenkov SI, Shcherbakov IN, Milenković MR, Borodkin GS. Supplementary data for the article: Uraev, A. I.; Nefedov, S. E.; Lyssenko, K. A.; Vlasenko, V. G.; Ikorskii, V. N.; Garnovskii, D. A.; Makarova, N. I.; Levchenkov, S. I.; Shcherbakov, I. N.; Milenković, M. R.; Borodkin, G. S. Synthesis, Structure, Spectroscopic Studies and Magnetic Properties of Cu2N2O4-, Cu2N2O2(S2)-, Cu2N2S4-Chromophores Based on Aminomethylene Derivatives of Pyrazole-5-One(Thione). Polyhedron 2020, 188, 114623. https://doi.org/10.1016/j.poly.2020.114623. in Polyhedron. 2020;.
https://hdl.handle.net/21.15107/rcub_cherry_4236 .
Uraev, Ali I., Nefedov, Sergey E., Lyssenko, Konstantin A., Vlasenko, Valery G., Ikorskii, Vladimir N., Garnovskii, Dmitrii A., Makarova, Nadezhda I., Levchenkov, Sergey I., Shcherbakov, Igor N., Milenković, Milica R., Borodkin, Gennadii S., "Supplementary data for the article: Uraev, A. I.; Nefedov, S. E.; Lyssenko, K. A.; Vlasenko, V. G.; Ikorskii, V. N.; Garnovskii, D. A.; Makarova, N. I.; Levchenkov, S. I.; Shcherbakov, I. N.; Milenković, M. R.; Borodkin, G. S. Synthesis, Structure, Spectroscopic Studies and Magnetic Properties of Cu2N2O4-, Cu2N2O2(S2)-, Cu2N2S4-Chromophores Based on Aminomethylene Derivatives of Pyrazole-5-One(Thione). Polyhedron 2020, 188, 114623. https://doi.org/10.1016/j.poly.2020.114623" in Polyhedron (2020),
https://hdl.handle.net/21.15107/rcub_cherry_4236 .

Mechanisms of detoxification of high copper concentrations by the microalga Chlorella sorokiniana

Vojvodić, Snežana; Stanić, Marina; Zechmann, Bernd; Dučić, Tanja; Žižić, Milan; Dimitrijević, Milena; Danilović Luković, Jelena; Milenković, Milica R.; Pittman, Jon K.; Spasojević, Ivan

(Portland Press, 2020)

TY  - JOUR
AU  - Vojvodić, Snežana
AU  - Stanić, Marina
AU  - Zechmann, Bernd
AU  - Dučić, Tanja
AU  - Žižić, Milan
AU  - Dimitrijević, Milena
AU  - Danilović Luković, Jelena
AU  - Milenković, Milica R.
AU  - Pittman, Jon K.
AU  - Spasojević, Ivan
PY  - 2020
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/4263
AB  - Microalgae have evolved mechanisms to respond to changes in copper ion availability, which are very important for normal cellular function, to tolerate metal pollution of aquatic ecosystems, and for modulation of copper bioavailability and toxicity to other organisms. Knowledge and application of these mechanisms will benefit the use of microalgae in wastewater processing and biomass production, and the use of copper compounds in the suppression of harmful algal blooms. Here, using electron microscopy, synchrotron radiation-based Fourier transform infrared spectroscopy, electron paramagnetic resonance spectroscopy, and X-ray absorption fine structure spectroscopy, we show that the microalga Chlorella sorokiniana responds promptly to Cu2+ at high non-toxic concentration, by mucilage release, alterations in the architecture of the outer cell wall layer and lipid structures, and polyphosphate accumulation within mucilage matrix. The main route of copper detoxification is by Cu2+ coordination to polyphosphates in penta-coordinated geometry. The sequestrated Cu2+ was accessible and could be released by extracellular chelating agents. Finally, the reduction in Cu2+ to Cu1+ appears also to take place. These findings reveal the biochemical basis of the capacity of microalgae to adapt to high external copper concentrations and to serve as both, sinks and pools of environmental copper.
PB  - Portland Press
T2  - The Biochemical Journal
T1  - Mechanisms of detoxification of high copper concentrations by the microalga Chlorella sorokiniana
VL  - 477
IS  - 19
SP  - 3729
EP  - 3741
DO  - 10.1042/BCJ20200600
ER  - 
@article{
author = "Vojvodić, Snežana and Stanić, Marina and Zechmann, Bernd and Dučić, Tanja and Žižić, Milan and Dimitrijević, Milena and Danilović Luković, Jelena and Milenković, Milica R. and Pittman, Jon K. and Spasojević, Ivan",
year = "2020",
abstract = "Microalgae have evolved mechanisms to respond to changes in copper ion availability, which are very important for normal cellular function, to tolerate metal pollution of aquatic ecosystems, and for modulation of copper bioavailability and toxicity to other organisms. Knowledge and application of these mechanisms will benefit the use of microalgae in wastewater processing and biomass production, and the use of copper compounds in the suppression of harmful algal blooms. Here, using electron microscopy, synchrotron radiation-based Fourier transform infrared spectroscopy, electron paramagnetic resonance spectroscopy, and X-ray absorption fine structure spectroscopy, we show that the microalga Chlorella sorokiniana responds promptly to Cu2+ at high non-toxic concentration, by mucilage release, alterations in the architecture of the outer cell wall layer and lipid structures, and polyphosphate accumulation within mucilage matrix. The main route of copper detoxification is by Cu2+ coordination to polyphosphates in penta-coordinated geometry. The sequestrated Cu2+ was accessible and could be released by extracellular chelating agents. Finally, the reduction in Cu2+ to Cu1+ appears also to take place. These findings reveal the biochemical basis of the capacity of microalgae to adapt to high external copper concentrations and to serve as both, sinks and pools of environmental copper.",
publisher = "Portland Press",
journal = "The Biochemical Journal",
title = "Mechanisms of detoxification of high copper concentrations by the microalga Chlorella sorokiniana",
volume = "477",
number = "19",
pages = "3729-3741",
doi = "10.1042/BCJ20200600"
}
Vojvodić, S., Stanić, M., Zechmann, B., Dučić, T., Žižić, M., Dimitrijević, M., Danilović Luković, J., Milenković, M. R., Pittman, J. K.,& Spasojević, I.. (2020). Mechanisms of detoxification of high copper concentrations by the microalga Chlorella sorokiniana. in The Biochemical Journal
Portland Press., 477(19), 3729-3741.
https://doi.org/10.1042/BCJ20200600
Vojvodić S, Stanić M, Zechmann B, Dučić T, Žižić M, Dimitrijević M, Danilović Luković J, Milenković MR, Pittman JK, Spasojević I. Mechanisms of detoxification of high copper concentrations by the microalga Chlorella sorokiniana. in The Biochemical Journal. 2020;477(19):3729-3741.
doi:10.1042/BCJ20200600 .
Vojvodić, Snežana, Stanić, Marina, Zechmann, Bernd, Dučić, Tanja, Žižić, Milan, Dimitrijević, Milena, Danilović Luković, Jelena, Milenković, Milica R., Pittman, Jon K., Spasojević, Ivan, "Mechanisms of detoxification of high copper concentrations by the microalga Chlorella sorokiniana" in The Biochemical Journal, 477, no. 19 (2020):3729-3741,
https://doi.org/10.1042/BCJ20200600 . .
3
9
4
8
6

Combined Experimental and Theoretical Investigation of the Origin of Magnetic Anisotropy in Pentagonal Bipyramidal Isothiocyanato Co(II), Ni(II), and Fe(III) Complexes with Quaternary-Ammonium-Functionalized 2,6-Diacetylpyridine Bisacylhydrazone

Darmanović, Darinka; Shcherbakov, Igor N.; Duboc, Carole; Spasojević, Vojislav; Hanžel, Darko; Anđelković, Katarina K.; Radanović, Dušanka D.; Turel, Iztok; Milenković, Milica R.; Gruden, Maja; Čobeljić, Božidar; Zlatar, Matija

(American Chemical Society (ACS), 2019)

TY  - JOUR
AU  - Darmanović, Darinka
AU  - Shcherbakov, Igor N.
AU  - Duboc, Carole
AU  - Spasojević, Vojislav
AU  - Hanžel, Darko
AU  - Anđelković, Katarina K.
AU  - Radanović, Dušanka D.
AU  - Turel, Iztok
AU  - Milenković, Milica R.
AU  - Gruden, Maja
AU  - Čobeljić, Božidar
AU  - Zlatar, Matija
PY  - 2019
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3855
AB  - Magnetic anisotropy in pentagonal bipyramidal complexes of Co(II) (1 and 2), Fe(III) (3 and 4), and Ni(II) (5) with a 2,2′-[2,6-pyridinediylbis(ethylidyne-1-hydrazinyl-2-ylidene)]bis[N,N,N-trimethyl-2-oxoethanaminium] equatorial ligand and isothiocyanato axial ligands has been investigated by magnetic susceptibility measurements, powder X-band electron paramagnetic resonance (EPR) spectroscopy, Mössbauer spectroscopy, ab initio, and ligand-field density functional theory (LFDFT) calculations. The studied complexes display three distinct types of magnetic anisotropy. Co(II) complexes (1 and 2) show an easy plane anisotropy with large and positive D values and negligible rhombicity. The Ni(II) complex (5) has uniaxial magnetic anisotropy with a negative D value. Fe(III) complexes (3 and 4) have small zero-field splitting (ZFS) parameters. Theoretical modeling is used to rationalize the magnetic anisotropy in these systems and to identify the most important excited states that are responsible for the zero-field splitting. These excitations are a consequence of the electronic structure of the central metal ion in ideal pentagonal bipyramidal coordination.
PB  - American Chemical Society (ACS)
T2  - The Journal of Physical Chemistry C
T1  - Combined Experimental and Theoretical Investigation of the Origin of Magnetic Anisotropy in Pentagonal Bipyramidal Isothiocyanato Co(II), Ni(II), and Fe(III) Complexes with Quaternary-Ammonium-Functionalized 2,6-Diacetylpyridine Bisacylhydrazone
VL  - 123
IS  - 51
SP  - 31142
EP  - 31155
DO  - 10.1021/acs.jpcc.9b08066
ER  - 
@article{
author = "Darmanović, Darinka and Shcherbakov, Igor N. and Duboc, Carole and Spasojević, Vojislav and Hanžel, Darko and Anđelković, Katarina K. and Radanović, Dušanka D. and Turel, Iztok and Milenković, Milica R. and Gruden, Maja and Čobeljić, Božidar and Zlatar, Matija",
year = "2019",
abstract = "Magnetic anisotropy in pentagonal bipyramidal complexes of Co(II) (1 and 2), Fe(III) (3 and 4), and Ni(II) (5) with a 2,2′-[2,6-pyridinediylbis(ethylidyne-1-hydrazinyl-2-ylidene)]bis[N,N,N-trimethyl-2-oxoethanaminium] equatorial ligand and isothiocyanato axial ligands has been investigated by magnetic susceptibility measurements, powder X-band electron paramagnetic resonance (EPR) spectroscopy, Mössbauer spectroscopy, ab initio, and ligand-field density functional theory (LFDFT) calculations. The studied complexes display three distinct types of magnetic anisotropy. Co(II) complexes (1 and 2) show an easy plane anisotropy with large and positive D values and negligible rhombicity. The Ni(II) complex (5) has uniaxial magnetic anisotropy with a negative D value. Fe(III) complexes (3 and 4) have small zero-field splitting (ZFS) parameters. Theoretical modeling is used to rationalize the magnetic anisotropy in these systems and to identify the most important excited states that are responsible for the zero-field splitting. These excitations are a consequence of the electronic structure of the central metal ion in ideal pentagonal bipyramidal coordination.",
publisher = "American Chemical Society (ACS)",
journal = "The Journal of Physical Chemistry C",
title = "Combined Experimental and Theoretical Investigation of the Origin of Magnetic Anisotropy in Pentagonal Bipyramidal Isothiocyanato Co(II), Ni(II), and Fe(III) Complexes with Quaternary-Ammonium-Functionalized 2,6-Diacetylpyridine Bisacylhydrazone",
volume = "123",
number = "51",
pages = "31142-31155",
doi = "10.1021/acs.jpcc.9b08066"
}
Darmanović, D., Shcherbakov, I. N., Duboc, C., Spasojević, V., Hanžel, D., Anđelković, K. K., Radanović, D. D., Turel, I., Milenković, M. R., Gruden, M., Čobeljić, B.,& Zlatar, M.. (2019). Combined Experimental and Theoretical Investigation of the Origin of Magnetic Anisotropy in Pentagonal Bipyramidal Isothiocyanato Co(II), Ni(II), and Fe(III) Complexes with Quaternary-Ammonium-Functionalized 2,6-Diacetylpyridine Bisacylhydrazone. in The Journal of Physical Chemistry C
American Chemical Society (ACS)., 123(51), 31142-31155.
https://doi.org/10.1021/acs.jpcc.9b08066
Darmanović D, Shcherbakov IN, Duboc C, Spasojević V, Hanžel D, Anđelković KK, Radanović DD, Turel I, Milenković MR, Gruden M, Čobeljić B, Zlatar M. Combined Experimental and Theoretical Investigation of the Origin of Magnetic Anisotropy in Pentagonal Bipyramidal Isothiocyanato Co(II), Ni(II), and Fe(III) Complexes with Quaternary-Ammonium-Functionalized 2,6-Diacetylpyridine Bisacylhydrazone. in The Journal of Physical Chemistry C. 2019;123(51):31142-31155.
doi:10.1021/acs.jpcc.9b08066 .
Darmanović, Darinka, Shcherbakov, Igor N., Duboc, Carole, Spasojević, Vojislav, Hanžel, Darko, Anđelković, Katarina K., Radanović, Dušanka D., Turel, Iztok, Milenković, Milica R., Gruden, Maja, Čobeljić, Božidar, Zlatar, Matija, "Combined Experimental and Theoretical Investigation of the Origin of Magnetic Anisotropy in Pentagonal Bipyramidal Isothiocyanato Co(II), Ni(II), and Fe(III) Complexes with Quaternary-Ammonium-Functionalized 2,6-Diacetylpyridine Bisacylhydrazone" in The Journal of Physical Chemistry C, 123, no. 51 (2019):31142-31155,
https://doi.org/10.1021/acs.jpcc.9b08066 . .
1
14
6
14
13

Combined Experimental and Theoretical Investigation of the Origin of Magnetic Anisotropy in Pentagonal Bipyramidal Isothiocyanato Co(II), Ni(II), and Fe(III) Complexes with Quaternary-Ammonium-Functionalized 2,6-Diacetylpyridine Bisacylhydrazone

Darmanović, Darinka; Shcherbakov, Igor N.; Duboc, Carole; Spasojević, Vojislav; Hanžel, Darko; Anđelković, Katarina K.; Radanović, Dušanka D.; Turel, Iztok; Milenković, Milica R.; Gruden, Maja; Čobeljić, Božidar; Zlatar, Matija

(American Chemical Society (ACS), 2019)

TY  - JOUR
AU  - Darmanović, Darinka
AU  - Shcherbakov, Igor N.
AU  - Duboc, Carole
AU  - Spasojević, Vojislav
AU  - Hanžel, Darko
AU  - Anđelković, Katarina K.
AU  - Radanović, Dušanka D.
AU  - Turel, Iztok
AU  - Milenković, Milica R.
AU  - Gruden, Maja
AU  - Čobeljić, Božidar
AU  - Zlatar, Matija
PY  - 2019
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3856
AB  - Magnetic anisotropy in pentagonal bipyramidal complexes of Co(II) (1 and 2), Fe(III) (3 and 4), and Ni(II) (5) with a 2,2′-[2,6-pyridinediylbis(ethylidyne-1-hydrazinyl-2-ylidene)]bis[N,N,N-trimethyl-2-oxoethanaminium] equatorial ligand and isothiocyanato axial ligands has been investigated by magnetic susceptibility measurements, powder X-band electron paramagnetic resonance (EPR) spectroscopy, Mössbauer spectroscopy, ab initio, and ligand-field density functional theory (LFDFT) calculations. The studied complexes display three distinct types of magnetic anisotropy. Co(II) complexes (1 and 2) show an easy plane anisotropy with large and positive D values and negligible rhombicity. The Ni(II) complex (5) has uniaxial magnetic anisotropy with a negative D value. Fe(III) complexes (3 and 4) have small zero-field splitting (ZFS) parameters. Theoretical modeling is used to rationalize the magnetic anisotropy in these systems and to identify the most important excited states that are responsible for the zero-field splitting. These excitations are a consequence of the electronic structure of the central metal ion in ideal pentagonal bipyramidal coordination.
PB  - American Chemical Society (ACS)
T2  - The Journal of Physical Chemistry C
T1  - Combined Experimental and Theoretical Investigation of the Origin of Magnetic Anisotropy in Pentagonal Bipyramidal Isothiocyanato Co(II), Ni(II), and Fe(III) Complexes with Quaternary-Ammonium-Functionalized 2,6-Diacetylpyridine Bisacylhydrazone
VL  - 123
IS  - 51
SP  - 31142
EP  - 31155
DO  - 10.1021/acs.jpcc.9b08066
ER  - 
@article{
author = "Darmanović, Darinka and Shcherbakov, Igor N. and Duboc, Carole and Spasojević, Vojislav and Hanžel, Darko and Anđelković, Katarina K. and Radanović, Dušanka D. and Turel, Iztok and Milenković, Milica R. and Gruden, Maja and Čobeljić, Božidar and Zlatar, Matija",
year = "2019",
abstract = "Magnetic anisotropy in pentagonal bipyramidal complexes of Co(II) (1 and 2), Fe(III) (3 and 4), and Ni(II) (5) with a 2,2′-[2,6-pyridinediylbis(ethylidyne-1-hydrazinyl-2-ylidene)]bis[N,N,N-trimethyl-2-oxoethanaminium] equatorial ligand and isothiocyanato axial ligands has been investigated by magnetic susceptibility measurements, powder X-band electron paramagnetic resonance (EPR) spectroscopy, Mössbauer spectroscopy, ab initio, and ligand-field density functional theory (LFDFT) calculations. The studied complexes display three distinct types of magnetic anisotropy. Co(II) complexes (1 and 2) show an easy plane anisotropy with large and positive D values and negligible rhombicity. The Ni(II) complex (5) has uniaxial magnetic anisotropy with a negative D value. Fe(III) complexes (3 and 4) have small zero-field splitting (ZFS) parameters. Theoretical modeling is used to rationalize the magnetic anisotropy in these systems and to identify the most important excited states that are responsible for the zero-field splitting. These excitations are a consequence of the electronic structure of the central metal ion in ideal pentagonal bipyramidal coordination.",
publisher = "American Chemical Society (ACS)",
journal = "The Journal of Physical Chemistry C",
title = "Combined Experimental and Theoretical Investigation of the Origin of Magnetic Anisotropy in Pentagonal Bipyramidal Isothiocyanato Co(II), Ni(II), and Fe(III) Complexes with Quaternary-Ammonium-Functionalized 2,6-Diacetylpyridine Bisacylhydrazone",
volume = "123",
number = "51",
pages = "31142-31155",
doi = "10.1021/acs.jpcc.9b08066"
}
Darmanović, D., Shcherbakov, I. N., Duboc, C., Spasojević, V., Hanžel, D., Anđelković, K. K., Radanović, D. D., Turel, I., Milenković, M. R., Gruden, M., Čobeljić, B.,& Zlatar, M.. (2019). Combined Experimental and Theoretical Investigation of the Origin of Magnetic Anisotropy in Pentagonal Bipyramidal Isothiocyanato Co(II), Ni(II), and Fe(III) Complexes with Quaternary-Ammonium-Functionalized 2,6-Diacetylpyridine Bisacylhydrazone. in The Journal of Physical Chemistry C
American Chemical Society (ACS)., 123(51), 31142-31155.
https://doi.org/10.1021/acs.jpcc.9b08066
Darmanović D, Shcherbakov IN, Duboc C, Spasojević V, Hanžel D, Anđelković KK, Radanović DD, Turel I, Milenković MR, Gruden M, Čobeljić B, Zlatar M. Combined Experimental and Theoretical Investigation of the Origin of Magnetic Anisotropy in Pentagonal Bipyramidal Isothiocyanato Co(II), Ni(II), and Fe(III) Complexes with Quaternary-Ammonium-Functionalized 2,6-Diacetylpyridine Bisacylhydrazone. in The Journal of Physical Chemistry C. 2019;123(51):31142-31155.
doi:10.1021/acs.jpcc.9b08066 .
Darmanović, Darinka, Shcherbakov, Igor N., Duboc, Carole, Spasojević, Vojislav, Hanžel, Darko, Anđelković, Katarina K., Radanović, Dušanka D., Turel, Iztok, Milenković, Milica R., Gruden, Maja, Čobeljić, Božidar, Zlatar, Matija, "Combined Experimental and Theoretical Investigation of the Origin of Magnetic Anisotropy in Pentagonal Bipyramidal Isothiocyanato Co(II), Ni(II), and Fe(III) Complexes with Quaternary-Ammonium-Functionalized 2,6-Diacetylpyridine Bisacylhydrazone" in The Journal of Physical Chemistry C, 123, no. 51 (2019):31142-31155,
https://doi.org/10.1021/acs.jpcc.9b08066 . .
1
14
6
14
13

Supplementary data for the article: Darmanović, D.; Shcherbakov, I. N.; Duboc, C.; Spasojević, V.; Hanžel, D.; Anđelković, K.; Radanović, D.; Turel, I.; Milenković, M.; Gruden, M.; et al. Combined Experimental and Theoretical Investigation of the Origin of Magnetic Anisotropy in Pentagonal Bipyramidal Isothiocyanato Co(II), Ni(II), and Fe(III) Complexes with Quaternary-Ammonium-Functionalized 2,6-Diacetylpyridine Bisacylhydrazone. Journal of Physical Chemistry C 2019, 123 (51), 31142–31155. https://doi.org/10.1021/acs.jpcc.9b08066

Darmanović, Darinka; Shcherbakov, Igor N.; Duboc, Carole; Spasojević, Vojislav; Hanžel, Darko; Anđelković, Katarina K.; Radanović, Dušanka D.; Turel, Iztok; Milenković, Milica R.; Gruden, Maja; Čobeljić, Božidar; Zlatar, Matija

(American Chemical Society (ACS), 2019)

TY  - DATA
AU  - Darmanović, Darinka
AU  - Shcherbakov, Igor N.
AU  - Duboc, Carole
AU  - Spasojević, Vojislav
AU  - Hanžel, Darko
AU  - Anđelković, Katarina K.
AU  - Radanović, Dušanka D.
AU  - Turel, Iztok
AU  - Milenković, Milica R.
AU  - Gruden, Maja
AU  - Čobeljić, Božidar
AU  - Zlatar, Matija
PY  - 2019
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3857
PB  - American Chemical Society (ACS)
T2  - The Journal of Physical Chemistry C
T1  - Supplementary data for the article: Darmanović, D.; Shcherbakov, I. N.; Duboc, C.; Spasojević, V.; Hanžel, D.; Anđelković, K.; Radanović, D.; Turel, I.; Milenković, M.; Gruden, M.; et al. Combined Experimental and Theoretical Investigation of the Origin of Magnetic Anisotropy in Pentagonal Bipyramidal Isothiocyanato Co(II), Ni(II), and Fe(III) Complexes with Quaternary-Ammonium-Functionalized 2,6-Diacetylpyridine Bisacylhydrazone. Journal of Physical Chemistry C 2019, 123 (51), 31142–31155. https://doi.org/10.1021/acs.jpcc.9b08066
UR  - https://hdl.handle.net/21.15107/rcub_cherry_3857
ER  - 
@misc{
author = "Darmanović, Darinka and Shcherbakov, Igor N. and Duboc, Carole and Spasojević, Vojislav and Hanžel, Darko and Anđelković, Katarina K. and Radanović, Dušanka D. and Turel, Iztok and Milenković, Milica R. and Gruden, Maja and Čobeljić, Božidar and Zlatar, Matija",
year = "2019",
publisher = "American Chemical Society (ACS)",
journal = "The Journal of Physical Chemistry C",
title = "Supplementary data for the article: Darmanović, D.; Shcherbakov, I. N.; Duboc, C.; Spasojević, V.; Hanžel, D.; Anđelković, K.; Radanović, D.; Turel, I.; Milenković, M.; Gruden, M.; et al. Combined Experimental and Theoretical Investigation of the Origin of Magnetic Anisotropy in Pentagonal Bipyramidal Isothiocyanato Co(II), Ni(II), and Fe(III) Complexes with Quaternary-Ammonium-Functionalized 2,6-Diacetylpyridine Bisacylhydrazone. Journal of Physical Chemistry C 2019, 123 (51), 31142–31155. https://doi.org/10.1021/acs.jpcc.9b08066",
url = "https://hdl.handle.net/21.15107/rcub_cherry_3857"
}
Darmanović, D., Shcherbakov, I. N., Duboc, C., Spasojević, V., Hanžel, D., Anđelković, K. K., Radanović, D. D., Turel, I., Milenković, M. R., Gruden, M., Čobeljić, B.,& Zlatar, M.. (2019). Supplementary data for the article: Darmanović, D.; Shcherbakov, I. N.; Duboc, C.; Spasojević, V.; Hanžel, D.; Anđelković, K.; Radanović, D.; Turel, I.; Milenković, M.; Gruden, M.; et al. Combined Experimental and Theoretical Investigation of the Origin of Magnetic Anisotropy in Pentagonal Bipyramidal Isothiocyanato Co(II), Ni(II), and Fe(III) Complexes with Quaternary-Ammonium-Functionalized 2,6-Diacetylpyridine Bisacylhydrazone. Journal of Physical Chemistry C 2019, 123 (51), 31142–31155. https://doi.org/10.1021/acs.jpcc.9b08066. in The Journal of Physical Chemistry C
American Chemical Society (ACS)..
https://hdl.handle.net/21.15107/rcub_cherry_3857
Darmanović D, Shcherbakov IN, Duboc C, Spasojević V, Hanžel D, Anđelković KK, Radanović DD, Turel I, Milenković MR, Gruden M, Čobeljić B, Zlatar M. Supplementary data for the article: Darmanović, D.; Shcherbakov, I. N.; Duboc, C.; Spasojević, V.; Hanžel, D.; Anđelković, K.; Radanović, D.; Turel, I.; Milenković, M.; Gruden, M.; et al. Combined Experimental and Theoretical Investigation of the Origin of Magnetic Anisotropy in Pentagonal Bipyramidal Isothiocyanato Co(II), Ni(II), and Fe(III) Complexes with Quaternary-Ammonium-Functionalized 2,6-Diacetylpyridine Bisacylhydrazone. Journal of Physical Chemistry C 2019, 123 (51), 31142–31155. https://doi.org/10.1021/acs.jpcc.9b08066. in The Journal of Physical Chemistry C. 2019;.
https://hdl.handle.net/21.15107/rcub_cherry_3857 .
Darmanović, Darinka, Shcherbakov, Igor N., Duboc, Carole, Spasojević, Vojislav, Hanžel, Darko, Anđelković, Katarina K., Radanović, Dušanka D., Turel, Iztok, Milenković, Milica R., Gruden, Maja, Čobeljić, Božidar, Zlatar, Matija, "Supplementary data for the article: Darmanović, D.; Shcherbakov, I. N.; Duboc, C.; Spasojević, V.; Hanžel, D.; Anđelković, K.; Radanović, D.; Turel, I.; Milenković, M.; Gruden, M.; et al. Combined Experimental and Theoretical Investigation of the Origin of Magnetic Anisotropy in Pentagonal Bipyramidal Isothiocyanato Co(II), Ni(II), and Fe(III) Complexes with Quaternary-Ammonium-Functionalized 2,6-Diacetylpyridine Bisacylhydrazone. Journal of Physical Chemistry C 2019, 123 (51), 31142–31155. https://doi.org/10.1021/acs.jpcc.9b08066" in The Journal of Physical Chemistry C (2019),
https://hdl.handle.net/21.15107/rcub_cherry_3857 .

Mechanochemically synthesized cobalt-ferrite and starch-coated cobalt-ferrite nanoparticles as efficient adsorbents for hexavalent chromium removal

Šuljagić, Marija; Jeremić, Dejan; Milenković, Milica R.; Nikolić, Aleksandar S.; Anđelković, Ljubica

(Belgrade : Institute of Technical Sciences of SASA, 2019)

TY  - CONF
AU  - Šuljagić, Marija
AU  - Jeremić, Dejan
AU  - Milenković, Milica R.
AU  - Nikolić, Aleksandar S.
AU  - Anđelković, Ljubica
PY  - 2019
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3786
AB  - Cobalt-ferrite (CoFe2O4) and starch-coated CoFe2O4 nanoparticles were prepared by the
mechanochemical method and carefully chosen as adsorbents for Cr(VI) removal from
wastewater. The kinetic study, adsorption isotherms and influence of pH, contact time and
interfering ions were investigated to have deeper insight into adsorbent quality. UV/Vis
spectroscopy confirmed that the dominant adsorption mechanism is the electrostatic
attraction at lower pH values. The study showed there was no significant change in
adsorption efficiency for starch-coated nanoparticles. However, starch as a natural and
biocompatible compound can enhance nanoparticles water dispersibility. The advantage of
such materials is that saturation time does not exceed 20 minutes. Therefore, the as-prepared
and starch-coated CoFe2O4 presents very efficient material for application in the field of
water remediation.
PB  - Belgrade : Institute of Technical Sciences of SASA
C3  - Program and the Book of abstracts / Eighteenth Young Researchers' Conference Materials Sciences and Engineering, December 4-6, 2019, Belgrade, Serbia
T1  - Mechanochemically synthesized cobalt-ferrite and starch-coated cobalt-ferrite nanoparticles as efficient adsorbents for hexavalent chromium removal
SP  - 70
EP  - 70
UR  - https://hdl.handle.net/21.15107/rcub_cherry_3786
ER  - 
@conference{
author = "Šuljagić, Marija and Jeremić, Dejan and Milenković, Milica R. and Nikolić, Aleksandar S. and Anđelković, Ljubica",
year = "2019",
abstract = "Cobalt-ferrite (CoFe2O4) and starch-coated CoFe2O4 nanoparticles were prepared by the
mechanochemical method and carefully chosen as adsorbents for Cr(VI) removal from
wastewater. The kinetic study, adsorption isotherms and influence of pH, contact time and
interfering ions were investigated to have deeper insight into adsorbent quality. UV/Vis
spectroscopy confirmed that the dominant adsorption mechanism is the electrostatic
attraction at lower pH values. The study showed there was no significant change in
adsorption efficiency for starch-coated nanoparticles. However, starch as a natural and
biocompatible compound can enhance nanoparticles water dispersibility. The advantage of
such materials is that saturation time does not exceed 20 minutes. Therefore, the as-prepared
and starch-coated CoFe2O4 presents very efficient material for application in the field of
water remediation.",
publisher = "Belgrade : Institute of Technical Sciences of SASA",
journal = "Program and the Book of abstracts / Eighteenth Young Researchers' Conference Materials Sciences and Engineering, December 4-6, 2019, Belgrade, Serbia",
title = "Mechanochemically synthesized cobalt-ferrite and starch-coated cobalt-ferrite nanoparticles as efficient adsorbents for hexavalent chromium removal",
pages = "70-70",
url = "https://hdl.handle.net/21.15107/rcub_cherry_3786"
}
Šuljagić, M., Jeremić, D., Milenković, M. R., Nikolić, A. S.,& Anđelković, L.. (2019). Mechanochemically synthesized cobalt-ferrite and starch-coated cobalt-ferrite nanoparticles as efficient adsorbents for hexavalent chromium removal. in Program and the Book of abstracts / Eighteenth Young Researchers' Conference Materials Sciences and Engineering, December 4-6, 2019, Belgrade, Serbia
Belgrade : Institute of Technical Sciences of SASA., 70-70.
https://hdl.handle.net/21.15107/rcub_cherry_3786
Šuljagić M, Jeremić D, Milenković MR, Nikolić AS, Anđelković L. Mechanochemically synthesized cobalt-ferrite and starch-coated cobalt-ferrite nanoparticles as efficient adsorbents for hexavalent chromium removal. in Program and the Book of abstracts / Eighteenth Young Researchers' Conference Materials Sciences and Engineering, December 4-6, 2019, Belgrade, Serbia. 2019;:70-70.
https://hdl.handle.net/21.15107/rcub_cherry_3786 .
Šuljagić, Marija, Jeremić, Dejan, Milenković, Milica R., Nikolić, Aleksandar S., Anđelković, Ljubica, "Mechanochemically synthesized cobalt-ferrite and starch-coated cobalt-ferrite nanoparticles as efficient adsorbents for hexavalent chromium removal" in Program and the Book of abstracts / Eighteenth Young Researchers' Conference Materials Sciences and Engineering, December 4-6, 2019, Belgrade, Serbia (2019):70-70,
https://hdl.handle.net/21.15107/rcub_cherry_3786 .

Supplementary data for article: Milenković, M. R.; Papastavrou, A. T.; Radanović, D. D.; Pevec, A.; Jagličić, Z.; Zlatar, M.; Gruden, M.; Vougioukalakis, G. C.; Turel, I.; Anđelković, K. K.; et al. Highly-Efficient N-Arylation of Imidazole Catalyzed by Cu(II) Complexes with Quaternary Ammonium-Functionalized 2-Acetylpyridine Acylhydrazone. Polyhedron 2019, 165, 22–30. https://doi.org/10.1016/j.poly.2019.03.001

Milenković, Milica R.; Papastavrou, Agyro T.; Radanović, Dušanka D.; Pevec, Andrej; Jagličić, Zvonko; Zlatar, Matija; Gruden-Pavlović, Maja; Vougioukalakis, Georgios C.; Turel, Iztok; Anđelković, Katarina K.; Čobeljić, Božidar

(Elsevier, 2019)

TY  - DATA
AU  - Milenković, Milica R.
AU  - Papastavrou, Agyro T.
AU  - Radanović, Dušanka D.
AU  - Pevec, Andrej
AU  - Jagličić, Zvonko
AU  - Zlatar, Matija
AU  - Gruden-Pavlović, Maja
AU  - Vougioukalakis, Georgios C.
AU  - Turel, Iztok
AU  - Anđelković, Katarina K.
AU  - Čobeljić, Božidar
PY  - 2019
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3006
PB  - Elsevier
T2  - Polyhedron
T1  - Supplementary data for article: Milenković, M. R.; Papastavrou, A. T.; Radanović, D. D.; Pevec, A.; Jagličić, Z.; Zlatar, M.; Gruden, M.; Vougioukalakis, G. C.; Turel, I.; Anđelković, K. K.; et al. Highly-Efficient N-Arylation of Imidazole Catalyzed by Cu(II) Complexes with Quaternary Ammonium-Functionalized 2-Acetylpyridine Acylhydrazone. Polyhedron 2019, 165, 22–30. https://doi.org/10.1016/j.poly.2019.03.001
UR  - https://hdl.handle.net/21.15107/rcub_cherry_3006
ER  - 
@misc{
author = "Milenković, Milica R. and Papastavrou, Agyro T. and Radanović, Dušanka D. and Pevec, Andrej and Jagličić, Zvonko and Zlatar, Matija and Gruden-Pavlović, Maja and Vougioukalakis, Georgios C. and Turel, Iztok and Anđelković, Katarina K. and Čobeljić, Božidar",
year = "2019",
publisher = "Elsevier",
journal = "Polyhedron",
title = "Supplementary data for article: Milenković, M. R.; Papastavrou, A. T.; Radanović, D. D.; Pevec, A.; Jagličić, Z.; Zlatar, M.; Gruden, M.; Vougioukalakis, G. C.; Turel, I.; Anđelković, K. K.; et al. Highly-Efficient N-Arylation of Imidazole Catalyzed by Cu(II) Complexes with Quaternary Ammonium-Functionalized 2-Acetylpyridine Acylhydrazone. Polyhedron 2019, 165, 22–30. https://doi.org/10.1016/j.poly.2019.03.001",
url = "https://hdl.handle.net/21.15107/rcub_cherry_3006"
}
Milenković, M. R., Papastavrou, A. T., Radanović, D. D., Pevec, A., Jagličić, Z., Zlatar, M., Gruden-Pavlović, M., Vougioukalakis, G. C., Turel, I., Anđelković, K. K.,& Čobeljić, B.. (2019). Supplementary data for article: Milenković, M. R.; Papastavrou, A. T.; Radanović, D. D.; Pevec, A.; Jagličić, Z.; Zlatar, M.; Gruden, M.; Vougioukalakis, G. C.; Turel, I.; Anđelković, K. K.; et al. Highly-Efficient N-Arylation of Imidazole Catalyzed by Cu(II) Complexes with Quaternary Ammonium-Functionalized 2-Acetylpyridine Acylhydrazone. Polyhedron 2019, 165, 22–30. https://doi.org/10.1016/j.poly.2019.03.001. in Polyhedron
Elsevier..
https://hdl.handle.net/21.15107/rcub_cherry_3006
Milenković MR, Papastavrou AT, Radanović DD, Pevec A, Jagličić Z, Zlatar M, Gruden-Pavlović M, Vougioukalakis GC, Turel I, Anđelković KK, Čobeljić B. Supplementary data for article: Milenković, M. R.; Papastavrou, A. T.; Radanović, D. D.; Pevec, A.; Jagličić, Z.; Zlatar, M.; Gruden, M.; Vougioukalakis, G. C.; Turel, I.; Anđelković, K. K.; et al. Highly-Efficient N-Arylation of Imidazole Catalyzed by Cu(II) Complexes with Quaternary Ammonium-Functionalized 2-Acetylpyridine Acylhydrazone. Polyhedron 2019, 165, 22–30. https://doi.org/10.1016/j.poly.2019.03.001. in Polyhedron. 2019;.
https://hdl.handle.net/21.15107/rcub_cherry_3006 .
Milenković, Milica R., Papastavrou, Agyro T., Radanović, Dušanka D., Pevec, Andrej, Jagličić, Zvonko, Zlatar, Matija, Gruden-Pavlović, Maja, Vougioukalakis, Georgios C., Turel, Iztok, Anđelković, Katarina K., Čobeljić, Božidar, "Supplementary data for article: Milenković, M. R.; Papastavrou, A. T.; Radanović, D. D.; Pevec, A.; Jagličić, Z.; Zlatar, M.; Gruden, M.; Vougioukalakis, G. C.; Turel, I.; Anđelković, K. K.; et al. Highly-Efficient N-Arylation of Imidazole Catalyzed by Cu(II) Complexes with Quaternary Ammonium-Functionalized 2-Acetylpyridine Acylhydrazone. Polyhedron 2019, 165, 22–30. https://doi.org/10.1016/j.poly.2019.03.001" in Polyhedron (2019),
https://hdl.handle.net/21.15107/rcub_cherry_3006 .

Highly-efficient N-arylation of imidazole catalyzed by Cu(II) complexes with quaternary ammonium-functionalized 2-acetylpyridine acylhydrazone

Milenković, Milica R.; Papastavrou, Agyro T.; Radanović, Dušanka D.; Pevec, Andrej; Jagličić, Zvonko; Zlatar, Matija; Gruden-Pavlović, Maja; Vougioukalakis, Georgios C.; Turel, Iztok; Anđelković, Katarina K.; Čobeljić, Božidar

(Elsevier, 2019)

TY  - JOUR
AU  - Milenković, Milica R.
AU  - Papastavrou, Agyro T.
AU  - Radanović, Dušanka D.
AU  - Pevec, Andrej
AU  - Jagličić, Zvonko
AU  - Zlatar, Matija
AU  - Gruden-Pavlović, Maja
AU  - Vougioukalakis, Georgios C.
AU  - Turel, Iztok
AU  - Anđelković, Katarina K.
AU  - Čobeljić, Božidar
PY  - 2019
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/2865
AB  - The reaction of (E)-N,N,N-trimethyl-2-oxo-2-(2-(1-(pyridin-2-yl)ethylidene)hydrazinyl)ethan-1-aminium-chloride (HLCl) with copper(II) perchlorate led to mononuclear [CuLCl]ClO 4 complex (1). The same reaction with excess of sodium azide gives dinuclear azido double end-on bridged Cu(II) complex [Cu 2 L 2 (μ- 1,1 -N 3 ) 2 ](ClO 4 ) 2 (2). In both complexes hydrazone ligand is NNO coordinated in monodeprotonated formally neutral zwitter-ionic form. Complexes were characterized by elemental analysis, IR spectroscopy and single-crystal X-ray crystallography. Variable‐temperature magnetic susceptibility measurements for dinuclear Cu(II) complex showed intra-dimer ferromagnetic coupling between Cu(II) ions (J = 7.4 cm −1 ). DFT-BS calculations provided explanation for magnetic properties of dinuclear Cu(II) complex. Both complexes were shown to highly efficiently catalyze the N-arylation of imidazole and benzimidazole with electron-poor or electron-rich aryl iodides, under user-friendly and sustainable conditions.
PB  - Elsevier
T2  - Polyhedron
T1  - Highly-efficient N-arylation of imidazole catalyzed by Cu(II) complexes with quaternary ammonium-functionalized 2-acetylpyridine acylhydrazone
VL  - 165
SP  - 22
EP  - 30
DO  - 10.1016/j.poly.2019.03.001
ER  - 
@article{
author = "Milenković, Milica R. and Papastavrou, Agyro T. and Radanović, Dušanka D. and Pevec, Andrej and Jagličić, Zvonko and Zlatar, Matija and Gruden-Pavlović, Maja and Vougioukalakis, Georgios C. and Turel, Iztok and Anđelković, Katarina K. and Čobeljić, Božidar",
year = "2019",
abstract = "The reaction of (E)-N,N,N-trimethyl-2-oxo-2-(2-(1-(pyridin-2-yl)ethylidene)hydrazinyl)ethan-1-aminium-chloride (HLCl) with copper(II) perchlorate led to mononuclear [CuLCl]ClO 4 complex (1). The same reaction with excess of sodium azide gives dinuclear azido double end-on bridged Cu(II) complex [Cu 2 L 2 (μ- 1,1 -N 3 ) 2 ](ClO 4 ) 2 (2). In both complexes hydrazone ligand is NNO coordinated in monodeprotonated formally neutral zwitter-ionic form. Complexes were characterized by elemental analysis, IR spectroscopy and single-crystal X-ray crystallography. Variable‐temperature magnetic susceptibility measurements for dinuclear Cu(II) complex showed intra-dimer ferromagnetic coupling between Cu(II) ions (J = 7.4 cm −1 ). DFT-BS calculations provided explanation for magnetic properties of dinuclear Cu(II) complex. Both complexes were shown to highly efficiently catalyze the N-arylation of imidazole and benzimidazole with electron-poor or electron-rich aryl iodides, under user-friendly and sustainable conditions.",
publisher = "Elsevier",
journal = "Polyhedron",
title = "Highly-efficient N-arylation of imidazole catalyzed by Cu(II) complexes with quaternary ammonium-functionalized 2-acetylpyridine acylhydrazone",
volume = "165",
pages = "22-30",
doi = "10.1016/j.poly.2019.03.001"
}
Milenković, M. R., Papastavrou, A. T., Radanović, D. D., Pevec, A., Jagličić, Z., Zlatar, M., Gruden-Pavlović, M., Vougioukalakis, G. C., Turel, I., Anđelković, K. K.,& Čobeljić, B.. (2019). Highly-efficient N-arylation of imidazole catalyzed by Cu(II) complexes with quaternary ammonium-functionalized 2-acetylpyridine acylhydrazone. in Polyhedron
Elsevier., 165, 22-30.
https://doi.org/10.1016/j.poly.2019.03.001
Milenković MR, Papastavrou AT, Radanović DD, Pevec A, Jagličić Z, Zlatar M, Gruden-Pavlović M, Vougioukalakis GC, Turel I, Anđelković KK, Čobeljić B. Highly-efficient N-arylation of imidazole catalyzed by Cu(II) complexes with quaternary ammonium-functionalized 2-acetylpyridine acylhydrazone. in Polyhedron. 2019;165:22-30.
doi:10.1016/j.poly.2019.03.001 .
Milenković, Milica R., Papastavrou, Agyro T., Radanović, Dušanka D., Pevec, Andrej, Jagličić, Zvonko, Zlatar, Matija, Gruden-Pavlović, Maja, Vougioukalakis, Georgios C., Turel, Iztok, Anđelković, Katarina K., Čobeljić, Božidar, "Highly-efficient N-arylation of imidazole catalyzed by Cu(II) complexes with quaternary ammonium-functionalized 2-acetylpyridine acylhydrazone" in Polyhedron, 165 (2019):22-30,
https://doi.org/10.1016/j.poly.2019.03.001 . .
1
16
13
17
15

Highly-efficient N-arylation of imidazole catalyzed by Cu(II) complexes with quaternary ammonium-functionalized 2-acetylpyridine acylhydrazone

Milenković, Milica R.; Papastavrou, Agyro T.; Radanović, Dušanka D.; Pevec, Andrej; Jagličić, Zvonko; Zlatar, Matija; Gruden-Pavlović, Maja; Vougioukalakis, Georgios C.; Turel, Iztok; Anđelković, Katarina K.; Čobeljić, Božidar

(Elsevier, 2019)

TY  - JOUR
AU  - Milenković, Milica R.
AU  - Papastavrou, Agyro T.
AU  - Radanović, Dušanka D.
AU  - Pevec, Andrej
AU  - Jagličić, Zvonko
AU  - Zlatar, Matija
AU  - Gruden-Pavlović, Maja
AU  - Vougioukalakis, Georgios C.
AU  - Turel, Iztok
AU  - Anđelković, Katarina K.
AU  - Čobeljić, Božidar
PY  - 2019
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/2858
AB  - The reaction of (E)-N,N,N-trimethyl-2-oxo-2-(2-(1-(pyridin-2-yl)ethylidene)hydrazinyl)ethan-1-aminium-chloride (HLCl) with copper(II) perchlorate led to mononuclear [CuLCl]ClO 4 complex (1). The same reaction with excess of sodium azide gives dinuclear azido double end-on bridged Cu(II) complex [Cu 2 L 2 (μ- 1,1 -N 3 ) 2 ](ClO 4 ) 2 (2). In both complexes hydrazone ligand is NNO coordinated in monodeprotonated formally neutral zwitter-ionic form. Complexes were characterized by elemental analysis, IR spectroscopy and single-crystal X-ray crystallography. Variable‐temperature magnetic susceptibility measurements for dinuclear Cu(II) complex showed intra-dimer ferromagnetic coupling between Cu(II) ions (J = 7.4 cm −1 ). DFT-BS calculations provided explanation for magnetic properties of dinuclear Cu(II) complex. Both complexes were shown to highly efficiently catalyze the N-arylation of imidazole and benzimidazole with electron-poor or electron-rich aryl iodides, under user-friendly and sustainable conditions.
PB  - Elsevier
T2  - Polyhedron
T1  - Highly-efficient N-arylation of imidazole catalyzed by Cu(II) complexes with quaternary ammonium-functionalized 2-acetylpyridine acylhydrazone
VL  - 165
SP  - 22
EP  - 30
DO  - 10.1016/j.poly.2019.03.001
ER  - 
@article{
author = "Milenković, Milica R. and Papastavrou, Agyro T. and Radanović, Dušanka D. and Pevec, Andrej and Jagličić, Zvonko and Zlatar, Matija and Gruden-Pavlović, Maja and Vougioukalakis, Georgios C. and Turel, Iztok and Anđelković, Katarina K. and Čobeljić, Božidar",
year = "2019",
abstract = "The reaction of (E)-N,N,N-trimethyl-2-oxo-2-(2-(1-(pyridin-2-yl)ethylidene)hydrazinyl)ethan-1-aminium-chloride (HLCl) with copper(II) perchlorate led to mononuclear [CuLCl]ClO 4 complex (1). The same reaction with excess of sodium azide gives dinuclear azido double end-on bridged Cu(II) complex [Cu 2 L 2 (μ- 1,1 -N 3 ) 2 ](ClO 4 ) 2 (2). In both complexes hydrazone ligand is NNO coordinated in monodeprotonated formally neutral zwitter-ionic form. Complexes were characterized by elemental analysis, IR spectroscopy and single-crystal X-ray crystallography. Variable‐temperature magnetic susceptibility measurements for dinuclear Cu(II) complex showed intra-dimer ferromagnetic coupling between Cu(II) ions (J = 7.4 cm −1 ). DFT-BS calculations provided explanation for magnetic properties of dinuclear Cu(II) complex. Both complexes were shown to highly efficiently catalyze the N-arylation of imidazole and benzimidazole with electron-poor or electron-rich aryl iodides, under user-friendly and sustainable conditions.",
publisher = "Elsevier",
journal = "Polyhedron",
title = "Highly-efficient N-arylation of imidazole catalyzed by Cu(II) complexes with quaternary ammonium-functionalized 2-acetylpyridine acylhydrazone",
volume = "165",
pages = "22-30",
doi = "10.1016/j.poly.2019.03.001"
}
Milenković, M. R., Papastavrou, A. T., Radanović, D. D., Pevec, A., Jagličić, Z., Zlatar, M., Gruden-Pavlović, M., Vougioukalakis, G. C., Turel, I., Anđelković, K. K.,& Čobeljić, B.. (2019). Highly-efficient N-arylation of imidazole catalyzed by Cu(II) complexes with quaternary ammonium-functionalized 2-acetylpyridine acylhydrazone. in Polyhedron
Elsevier., 165, 22-30.
https://doi.org/10.1016/j.poly.2019.03.001
Milenković MR, Papastavrou AT, Radanović DD, Pevec A, Jagličić Z, Zlatar M, Gruden-Pavlović M, Vougioukalakis GC, Turel I, Anđelković KK, Čobeljić B. Highly-efficient N-arylation of imidazole catalyzed by Cu(II) complexes with quaternary ammonium-functionalized 2-acetylpyridine acylhydrazone. in Polyhedron. 2019;165:22-30.
doi:10.1016/j.poly.2019.03.001 .
Milenković, Milica R., Papastavrou, Agyro T., Radanović, Dušanka D., Pevec, Andrej, Jagličić, Zvonko, Zlatar, Matija, Gruden-Pavlović, Maja, Vougioukalakis, Georgios C., Turel, Iztok, Anđelković, Katarina K., Čobeljić, Božidar, "Highly-efficient N-arylation of imidazole catalyzed by Cu(II) complexes with quaternary ammonium-functionalized 2-acetylpyridine acylhydrazone" in Polyhedron, 165 (2019):22-30,
https://doi.org/10.1016/j.poly.2019.03.001 . .
1
16
13
17
15

Crystal structures and DFT calculations of mixed chloride-azide zinc(II) and chloride-isocyanate cadmium(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent

Anđelković, Katarina K.; Pevec, Andrej; Grubišić, Sonja; Turel, Iztok; Čobeljić, Božidar; Milenković, Milica R.; Keskic, Tanja; Radanović, Dušanka D.

(Elsevier Science Bv, Amsterdam, 2018)

TY  - JOUR
AU  - Anđelković, Katarina K.
AU  - Pevec, Andrej
AU  - Grubišić, Sonja
AU  - Turel, Iztok
AU  - Čobeljić, Božidar
AU  - Milenković, Milica R.
AU  - Keskic, Tanja
AU  - Radanović, Dušanka D.
PY  - 2018
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3188
AB  - The mixed chloride-azide [ZnL(N-3)(1.65)Cl-0.35] (1) and chloride-isocyanate [CdL(NCO)(1.64)Cl-0.36] (2) complexes with the condensation product of 2-quinolinecarboxaldehyde and trimethylammonium aceto-hydrazide chloride (Girard's T reagent) (HLCl) have been prepared and characterized by X-ray crystallography. In complexes 1 and 2, Znl and Cd1 ions, respectively, are five-coordinated in a distorted square based pyramidal geometry with NNO set of donor atoms of deprotonated hydrazone ligand and two monodentate ligands N-3(-) and/or N-3(-) and Cl- in the case of I and OCN- and/or OCN- and Cl- in the case of 2. The structural parameters of 1 and 2 have been discussed in relation to those of previously reported M(II) complexes with the same hydrazone ligand. Density functional theory calculations have been employed to study the interaction between the Zn2+ and Cd2+ ions and ligands. High affinity of ligands towards the Zn2+ and Cd2+ ions are predicted for both complexes. (C) 2018 Elsevier B.V. All rights reserved.
PB  - Elsevier Science Bv, Amsterdam
T2  - Journal of Molecular Structure
T1  - Crystal structures and DFT calculations of mixed chloride-azide zinc(II) and chloride-isocyanate cadmium(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent
VL  - 1162
SP  - 63
EP  - 70
DO  - 10.1016/j.molstruc.2018.02.074
ER  - 
@article{
author = "Anđelković, Katarina K. and Pevec, Andrej and Grubišić, Sonja and Turel, Iztok and Čobeljić, Božidar and Milenković, Milica R. and Keskic, Tanja and Radanović, Dušanka D.",
year = "2018",
abstract = "The mixed chloride-azide [ZnL(N-3)(1.65)Cl-0.35] (1) and chloride-isocyanate [CdL(NCO)(1.64)Cl-0.36] (2) complexes with the condensation product of 2-quinolinecarboxaldehyde and trimethylammonium aceto-hydrazide chloride (Girard's T reagent) (HLCl) have been prepared and characterized by X-ray crystallography. In complexes 1 and 2, Znl and Cd1 ions, respectively, are five-coordinated in a distorted square based pyramidal geometry with NNO set of donor atoms of deprotonated hydrazone ligand and two monodentate ligands N-3(-) and/or N-3(-) and Cl- in the case of I and OCN- and/or OCN- and Cl- in the case of 2. The structural parameters of 1 and 2 have been discussed in relation to those of previously reported M(II) complexes with the same hydrazone ligand. Density functional theory calculations have been employed to study the interaction between the Zn2+ and Cd2+ ions and ligands. High affinity of ligands towards the Zn2+ and Cd2+ ions are predicted for both complexes. (C) 2018 Elsevier B.V. All rights reserved.",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Journal of Molecular Structure",
title = "Crystal structures and DFT calculations of mixed chloride-azide zinc(II) and chloride-isocyanate cadmium(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent",
volume = "1162",
pages = "63-70",
doi = "10.1016/j.molstruc.2018.02.074"
}
Anđelković, K. K., Pevec, A., Grubišić, S., Turel, I., Čobeljić, B., Milenković, M. R., Keskic, T.,& Radanović, D. D.. (2018). Crystal structures and DFT calculations of mixed chloride-azide zinc(II) and chloride-isocyanate cadmium(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent. in Journal of Molecular Structure
Elsevier Science Bv, Amsterdam., 1162, 63-70.
https://doi.org/10.1016/j.molstruc.2018.02.074
Anđelković KK, Pevec A, Grubišić S, Turel I, Čobeljić B, Milenković MR, Keskic T, Radanović DD. Crystal structures and DFT calculations of mixed chloride-azide zinc(II) and chloride-isocyanate cadmium(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent. in Journal of Molecular Structure. 2018;1162:63-70.
doi:10.1016/j.molstruc.2018.02.074 .
Anđelković, Katarina K., Pevec, Andrej, Grubišić, Sonja, Turel, Iztok, Čobeljić, Božidar, Milenković, Milica R., Keskic, Tanja, Radanović, Dušanka D., "Crystal structures and DFT calculations of mixed chloride-azide zinc(II) and chloride-isocyanate cadmium(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent" in Journal of Molecular Structure, 1162 (2018):63-70,
https://doi.org/10.1016/j.molstruc.2018.02.074 . .
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4
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7

Crystal structures, magnetic properties and DFT study of cobalt(II) azido complexes with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent

Romanović, Mima; Milenković, Milica R.; Pevec, Andrej; Turel, Iztok; Spasojević, Vojislav; Grubišić, Sonja; Radanović, Dušanka D.; Anđelković, Katarina K.; Čobeljić, Božidar

(Pergamon-Elsevier Science Ltd, Oxford, 2018)

TY  - JOUR
AU  - Romanović, Mima
AU  - Milenković, Milica R.
AU  - Pevec, Andrej
AU  - Turel, Iztok
AU  - Spasojević, Vojislav
AU  - Grubišić, Sonja
AU  - Radanović, Dušanka D.
AU  - Anđelković, Katarina K.
AU  - Čobeljić, Božidar
PY  - 2018
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3193
AB  - A tridentate NNO condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent (HLC1) in the presence of azide ions coordinates with cobalt(II) giving mononuclear azido Co(II) complex [CoHL (N-3)(3)](1) as a main product and dinuclear end-on azido bridged Co(II) complex [Co2L2(mu-(1,1)-N-3)(2)(N-3)(2)] (2) in traces. Crystal structures of both complexes were determined. Variable temperature magnetic susceptibility measurement studies of complex I showed that Co(II) cation is in the low-spin state with t(2g)(6)e(g)(1) (S = 1/2) configuration. DFT-BS calculations for complex 2 anticipated ferromagnetic type interaction between paramagnetic centers (J = 53 cm(-1)). (C) 2017 Elsevier Ltd. All rights reserved.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - Polyhedron
T1  - Crystal structures, magnetic properties and DFT study of cobalt(II) azido complexes with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent
VL  - 139
SP  - 142
EP  - 147
DO  - 10.1016/j.poly.2017.10.018
ER  - 
@article{
author = "Romanović, Mima and Milenković, Milica R. and Pevec, Andrej and Turel, Iztok and Spasojević, Vojislav and Grubišić, Sonja and Radanović, Dušanka D. and Anđelković, Katarina K. and Čobeljić, Božidar",
year = "2018",
abstract = "A tridentate NNO condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent (HLC1) in the presence of azide ions coordinates with cobalt(II) giving mononuclear azido Co(II) complex [CoHL (N-3)(3)](1) as a main product and dinuclear end-on azido bridged Co(II) complex [Co2L2(mu-(1,1)-N-3)(2)(N-3)(2)] (2) in traces. Crystal structures of both complexes were determined. Variable temperature magnetic susceptibility measurement studies of complex I showed that Co(II) cation is in the low-spin state with t(2g)(6)e(g)(1) (S = 1/2) configuration. DFT-BS calculations for complex 2 anticipated ferromagnetic type interaction between paramagnetic centers (J = 53 cm(-1)). (C) 2017 Elsevier Ltd. All rights reserved.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Polyhedron",
title = "Crystal structures, magnetic properties and DFT study of cobalt(II) azido complexes with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent",
volume = "139",
pages = "142-147",
doi = "10.1016/j.poly.2017.10.018"
}
Romanović, M., Milenković, M. R., Pevec, A., Turel, I., Spasojević, V., Grubišić, S., Radanović, D. D., Anđelković, K. K.,& Čobeljić, B.. (2018). Crystal structures, magnetic properties and DFT study of cobalt(II) azido complexes with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent. in Polyhedron
Pergamon-Elsevier Science Ltd, Oxford., 139, 142-147.
https://doi.org/10.1016/j.poly.2017.10.018
Romanović M, Milenković MR, Pevec A, Turel I, Spasojević V, Grubišić S, Radanović DD, Anđelković KK, Čobeljić B. Crystal structures, magnetic properties and DFT study of cobalt(II) azido complexes with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent. in Polyhedron. 2018;139:142-147.
doi:10.1016/j.poly.2017.10.018 .
Romanović, Mima, Milenković, Milica R., Pevec, Andrej, Turel, Iztok, Spasojević, Vojislav, Grubišić, Sonja, Radanović, Dušanka D., Anđelković, Katarina K., Čobeljić, Božidar, "Crystal structures, magnetic properties and DFT study of cobalt(II) azido complexes with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent" in Polyhedron, 139 (2018):142-147,
https://doi.org/10.1016/j.poly.2017.10.018 . .
1
13
7
13
12

Supplementary material for the article: Romanović, M. Č.; Milenković, M. R.; Pevec, A.; Turel, I.; Spasojević, V.; Grubišić, S.; Radanović, D.; Anđelković, K.; Čobeljić, B. Crystal Structures, Magnetic Properties and DFT Study of Cobalt(II) Azido Complexes with the Condensation Product of 2 Quinolinecarboxaldehyde and Girard’s T Reagent. Polyhedron 2018, 139, 142–147. https://doi.org/10.1016/j.poly.2017.10.018

Romanović, Mima; Milenković, Milica R.; Pevec, Andrej; Turel, Iztok; Spasojević, Vojislav; Grubišić, Sonja; Radanović, Dušanka D.; Anđelković, Katarina K.; Čobeljić, Božidar

(Pergamon-Elsevier Science Ltd, Oxford, 2018)

TY  - DATA
AU  - Romanović, Mima
AU  - Milenković, Milica R.
AU  - Pevec, Andrej
AU  - Turel, Iztok
AU  - Spasojević, Vojislav
AU  - Grubišić, Sonja
AU  - Radanović, Dušanka D.
AU  - Anđelković, Katarina K.
AU  - Čobeljić, Božidar
PY  - 2018
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3194
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - Polyhedron
T1  - Supplementary material for the article: Romanović, M. Č.; Milenković, M. R.; Pevec, A.; Turel, I.; Spasojević, V.; Grubišić, S.;  Radanović, D.; Anđelković, K.; Čobeljić, B. Crystal Structures, Magnetic Properties and DFT  Study of Cobalt(II) Azido Complexes with the Condensation Product of 2 Quinolinecarboxaldehyde and Girard’s T Reagent. Polyhedron 2018, 139, 142–147.  https://doi.org/10.1016/j.poly.2017.10.018
UR  - https://hdl.handle.net/21.15107/rcub_cherry_3194
ER  - 
@misc{
author = "Romanović, Mima and Milenković, Milica R. and Pevec, Andrej and Turel, Iztok and Spasojević, Vojislav and Grubišić, Sonja and Radanović, Dušanka D. and Anđelković, Katarina K. and Čobeljić, Božidar",
year = "2018",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Polyhedron",
title = "Supplementary material for the article: Romanović, M. Č.; Milenković, M. R.; Pevec, A.; Turel, I.; Spasojević, V.; Grubišić, S.;  Radanović, D.; Anđelković, K.; Čobeljić, B. Crystal Structures, Magnetic Properties and DFT  Study of Cobalt(II) Azido Complexes with the Condensation Product of 2 Quinolinecarboxaldehyde and Girard’s T Reagent. Polyhedron 2018, 139, 142–147.  https://doi.org/10.1016/j.poly.2017.10.018",
url = "https://hdl.handle.net/21.15107/rcub_cherry_3194"
}
Romanović, M., Milenković, M. R., Pevec, A., Turel, I., Spasojević, V., Grubišić, S., Radanović, D. D., Anđelković, K. K.,& Čobeljić, B.. (2018). Supplementary material for the article: Romanović, M. Č.; Milenković, M. R.; Pevec, A.; Turel, I.; Spasojević, V.; Grubišić, S.;  Radanović, D.; Anđelković, K.; Čobeljić, B. Crystal Structures, Magnetic Properties and DFT  Study of Cobalt(II) Azido Complexes with the Condensation Product of 2 Quinolinecarboxaldehyde and Girard’s T Reagent. Polyhedron 2018, 139, 142–147.  https://doi.org/10.1016/j.poly.2017.10.018. in Polyhedron
Pergamon-Elsevier Science Ltd, Oxford..
https://hdl.handle.net/21.15107/rcub_cherry_3194
Romanović M, Milenković MR, Pevec A, Turel I, Spasojević V, Grubišić S, Radanović DD, Anđelković KK, Čobeljić B. Supplementary material for the article: Romanović, M. Č.; Milenković, M. R.; Pevec, A.; Turel, I.; Spasojević, V.; Grubišić, S.;  Radanović, D.; Anđelković, K.; Čobeljić, B. Crystal Structures, Magnetic Properties and DFT  Study of Cobalt(II) Azido Complexes with the Condensation Product of 2 Quinolinecarboxaldehyde and Girard’s T Reagent. Polyhedron 2018, 139, 142–147.  https://doi.org/10.1016/j.poly.2017.10.018. in Polyhedron. 2018;.
https://hdl.handle.net/21.15107/rcub_cherry_3194 .
Romanović, Mima, Milenković, Milica R., Pevec, Andrej, Turel, Iztok, Spasojević, Vojislav, Grubišić, Sonja, Radanović, Dušanka D., Anđelković, Katarina K., Čobeljić, Božidar, "Supplementary material for the article: Romanović, M. Č.; Milenković, M. R.; Pevec, A.; Turel, I.; Spasojević, V.; Grubišić, S.;  Radanović, D.; Anđelković, K.; Čobeljić, B. Crystal Structures, Magnetic Properties and DFT  Study of Cobalt(II) Azido Complexes with the Condensation Product of 2 Quinolinecarboxaldehyde and Girard’s T Reagent. Polyhedron 2018, 139, 142–147.  https://doi.org/10.1016/j.poly.2017.10.018" in Polyhedron (2018),
https://hdl.handle.net/21.15107/rcub_cherry_3194 .

Supplementary data for the article: Čobeljić, B.; Pevec, A.; Stepanović, S.; Milenković, M. R.; Turel, I.; Gruden, M.; Radanović, D.; Anđelković, K. Structural Diversity of Isothiocyanato Cd(II) and Zn(II) Girard’s T Hydrazone Complexes in Solution and Solid State: Effect of H-Bonding on Coordination Number and Supramolecular Assembly of Cd(II) Complex in Solid State. Structural Chemistry 2018, 29 (6), 1797–1806. https://doi.org/10.1007/s11224-018-1155-8

Čobeljić, Božidar; Pevec, Andrej; Stepanović, Stepan; Milenković, Milica R.; Turel, Iztok; Gruden-Pavlović, Maja; Radanović, Dušanka D.; Anđelković, Katarina K.

(2018)

TY  - DATA
AU  - Čobeljić, Božidar
AU  - Pevec, Andrej
AU  - Stepanović, Stepan
AU  - Milenković, Milica R.
AU  - Turel, Iztok
AU  - Gruden-Pavlović, Maja
AU  - Radanović, Dušanka D.
AU  - Anđelković, Katarina K.
PY  - 2018
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3305
T2  - Structural Chemistry
T1  - Supplementary data for the article: Čobeljić, B.; Pevec, A.; Stepanović, S.; Milenković, M. R.; Turel, I.; Gruden, M.; Radanović, D.; Anđelković, K. Structural Diversity of Isothiocyanato Cd(II) and Zn(II) Girard’s T Hydrazone Complexes in Solution and Solid State: Effect of H-Bonding on Coordination Number and Supramolecular Assembly of Cd(II) Complex in Solid State. Structural Chemistry 2018, 29 (6), 1797–1806. https://doi.org/10.1007/s11224-018-1155-8
UR  - https://hdl.handle.net/21.15107/rcub_cherry_3305
ER  - 
@misc{
author = "Čobeljić, Božidar and Pevec, Andrej and Stepanović, Stepan and Milenković, Milica R. and Turel, Iztok and Gruden-Pavlović, Maja and Radanović, Dušanka D. and Anđelković, Katarina K.",
year = "2018",
journal = "Structural Chemistry",
title = "Supplementary data for the article: Čobeljić, B.; Pevec, A.; Stepanović, S.; Milenković, M. R.; Turel, I.; Gruden, M.; Radanović, D.; Anđelković, K. Structural Diversity of Isothiocyanato Cd(II) and Zn(II) Girard’s T Hydrazone Complexes in Solution and Solid State: Effect of H-Bonding on Coordination Number and Supramolecular Assembly of Cd(II) Complex in Solid State. Structural Chemistry 2018, 29 (6), 1797–1806. https://doi.org/10.1007/s11224-018-1155-8",
url = "https://hdl.handle.net/21.15107/rcub_cherry_3305"
}
Čobeljić, B., Pevec, A., Stepanović, S., Milenković, M. R., Turel, I., Gruden-Pavlović, M., Radanović, D. D.,& Anđelković, K. K.. (2018). Supplementary data for the article: Čobeljić, B.; Pevec, A.; Stepanović, S.; Milenković, M. R.; Turel, I.; Gruden, M.; Radanović, D.; Anđelković, K. Structural Diversity of Isothiocyanato Cd(II) and Zn(II) Girard’s T Hydrazone Complexes in Solution and Solid State: Effect of H-Bonding on Coordination Number and Supramolecular Assembly of Cd(II) Complex in Solid State. Structural Chemistry 2018, 29 (6), 1797–1806. https://doi.org/10.1007/s11224-018-1155-8. in Structural Chemistry.
https://hdl.handle.net/21.15107/rcub_cherry_3305
Čobeljić B, Pevec A, Stepanović S, Milenković MR, Turel I, Gruden-Pavlović M, Radanović DD, Anđelković KK. Supplementary data for the article: Čobeljić, B.; Pevec, A.; Stepanović, S.; Milenković, M. R.; Turel, I.; Gruden, M.; Radanović, D.; Anđelković, K. Structural Diversity of Isothiocyanato Cd(II) and Zn(II) Girard’s T Hydrazone Complexes in Solution and Solid State: Effect of H-Bonding on Coordination Number and Supramolecular Assembly of Cd(II) Complex in Solid State. Structural Chemistry 2018, 29 (6), 1797–1806. https://doi.org/10.1007/s11224-018-1155-8. in Structural Chemistry. 2018;.
https://hdl.handle.net/21.15107/rcub_cherry_3305 .
Čobeljić, Božidar, Pevec, Andrej, Stepanović, Stepan, Milenković, Milica R., Turel, Iztok, Gruden-Pavlović, Maja, Radanović, Dušanka D., Anđelković, Katarina K., "Supplementary data for the article: Čobeljić, B.; Pevec, A.; Stepanović, S.; Milenković, M. R.; Turel, I.; Gruden, M.; Radanović, D.; Anđelković, K. Structural Diversity of Isothiocyanato Cd(II) and Zn(II) Girard’s T Hydrazone Complexes in Solution and Solid State: Effect of H-Bonding on Coordination Number and Supramolecular Assembly of Cd(II) Complex in Solid State. Structural Chemistry 2018, 29 (6), 1797–1806. https://doi.org/10.1007/s11224-018-1155-8" in Structural Chemistry (2018),
https://hdl.handle.net/21.15107/rcub_cherry_3305 .

Supplementary data for the article: Čobeljić, B.; Pevec, A.; Jagličić, Z.; Milenković, M. R.; Turel, I.; Radanović, D.; Milenković, M.; Anđelković, K. Synthesis, Characterization and Antimicrobial Activity of the Isothiocyanato Fe(III) Girard’s T Hydrazone Complex. Journal of the Serbian Chemical Society 2018, 83 (12), 1327–1337. https://doi.org/10.2298/JSC180828079C

Čobeljić, Božidar; Pevec, Andrej; Jagličić, Zvonko; Milenković, Milica R.; Turel, Iztok; Radanović, Dušanka D.; Milenković, Marina; Anđelković, Katarina K.

(2018)

TY  - DATA
AU  - Čobeljić, Božidar
AU  - Pevec, Andrej
AU  - Jagličić, Zvonko
AU  - Milenković, Milica R.
AU  - Turel, Iztok
AU  - Radanović, Dušanka D.
AU  - Milenković, Marina
AU  - Anđelković, Katarina K.
PY  - 2018
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3307
T2  - Journal of the Serbian Chemical Society
T1  - Supplementary data for the article: Čobeljić, B.; Pevec, A.; Jagličić, Z.; Milenković, M. R.; Turel, I.; Radanović, D.; Milenković, M.; Anđelković, K. Synthesis, Characterization and Antimicrobial Activity of the Isothiocyanato Fe(III) Girard’s T Hydrazone Complex. Journal of the Serbian Chemical Society 2018, 83 (12), 1327–1337. https://doi.org/10.2298/JSC180828079C
UR  - https://hdl.handle.net/21.15107/rcub_cherry_3307
ER  - 
@misc{
author = "Čobeljić, Božidar and Pevec, Andrej and Jagličić, Zvonko and Milenković, Milica R. and Turel, Iztok and Radanović, Dušanka D. and Milenković, Marina and Anđelković, Katarina K.",
year = "2018",
journal = "Journal of the Serbian Chemical Society",
title = "Supplementary data for the article: Čobeljić, B.; Pevec, A.; Jagličić, Z.; Milenković, M. R.; Turel, I.; Radanović, D.; Milenković, M.; Anđelković, K. Synthesis, Characterization and Antimicrobial Activity of the Isothiocyanato Fe(III) Girard’s T Hydrazone Complex. Journal of the Serbian Chemical Society 2018, 83 (12), 1327–1337. https://doi.org/10.2298/JSC180828079C",
url = "https://hdl.handle.net/21.15107/rcub_cherry_3307"
}
Čobeljić, B., Pevec, A., Jagličić, Z., Milenković, M. R., Turel, I., Radanović, D. D., Milenković, M.,& Anđelković, K. K.. (2018). Supplementary data for the article: Čobeljić, B.; Pevec, A.; Jagličić, Z.; Milenković, M. R.; Turel, I.; Radanović, D.; Milenković, M.; Anđelković, K. Synthesis, Characterization and Antimicrobial Activity of the Isothiocyanato Fe(III) Girard’s T Hydrazone Complex. Journal of the Serbian Chemical Society 2018, 83 (12), 1327–1337. https://doi.org/10.2298/JSC180828079C. in Journal of the Serbian Chemical Society.
https://hdl.handle.net/21.15107/rcub_cherry_3307
Čobeljić B, Pevec A, Jagličić Z, Milenković MR, Turel I, Radanović DD, Milenković M, Anđelković KK. Supplementary data for the article: Čobeljić, B.; Pevec, A.; Jagličić, Z.; Milenković, M. R.; Turel, I.; Radanović, D.; Milenković, M.; Anđelković, K. Synthesis, Characterization and Antimicrobial Activity of the Isothiocyanato Fe(III) Girard’s T Hydrazone Complex. Journal of the Serbian Chemical Society 2018, 83 (12), 1327–1337. https://doi.org/10.2298/JSC180828079C. in Journal of the Serbian Chemical Society. 2018;.
https://hdl.handle.net/21.15107/rcub_cherry_3307 .
Čobeljić, Božidar, Pevec, Andrej, Jagličić, Zvonko, Milenković, Milica R., Turel, Iztok, Radanović, Dušanka D., Milenković, Marina, Anđelković, Katarina K., "Supplementary data for the article: Čobeljić, B.; Pevec, A.; Jagličić, Z.; Milenković, M. R.; Turel, I.; Radanović, D.; Milenković, M.; Anđelković, K. Synthesis, Characterization and Antimicrobial Activity of the Isothiocyanato Fe(III) Girard’s T Hydrazone Complex. Journal of the Serbian Chemical Society 2018, 83 (12), 1327–1337. https://doi.org/10.2298/JSC180828079C" in Journal of the Serbian Chemical Society (2018),
https://hdl.handle.net/21.15107/rcub_cherry_3307 .

Molecular Structures and Spin-States of Pseudohalide Metal Complexes with Hydrazones of Girard's T Reagent

Milenković, Milica R.; Čobeljić, Božidar; Anđelković, Katarina K.; Turel, Iztok

(Wiley, 2018)

TY  - JOUR
AU  - Milenković, Milica R.
AU  - Čobeljić, Božidar
AU  - Anđelković, Katarina K.
AU  - Turel, Iztok
PY  - 2018
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/2890
AB  - Pseudohalide metal complexes with hydrazones of the Girard T reagent are reviewed with respect to their synthesis, characterization, structures (both in solution and in the solid state), and magnetic properties. It is hoped that this microreview might serve as a concise guide to the chemistry of pseudohalide metal complexes with hydrazones of the Girard T reagent.
PB  - Wiley
T2  - European Journal of Inorganic Chemistry
T1  - Molecular Structures and Spin-States of Pseudohalide Metal Complexes with Hydrazones of Girard's T Reagent
IS  - 7
SP  - 838
EP  - 846
DO  - 10.1002/ejic.201701387
ER  - 
@article{
author = "Milenković, Milica R. and Čobeljić, Božidar and Anđelković, Katarina K. and Turel, Iztok",
year = "2018",
abstract = "Pseudohalide metal complexes with hydrazones of the Girard T reagent are reviewed with respect to their synthesis, characterization, structures (both in solution and in the solid state), and magnetic properties. It is hoped that this microreview might serve as a concise guide to the chemistry of pseudohalide metal complexes with hydrazones of the Girard T reagent.",
publisher = "Wiley",
journal = "European Journal of Inorganic Chemistry",
title = "Molecular Structures and Spin-States of Pseudohalide Metal Complexes with Hydrazones of Girard's T Reagent",
number = "7",
pages = "838-846",
doi = "10.1002/ejic.201701387"
}
Milenković, M. R., Čobeljić, B., Anđelković, K. K.,& Turel, I.. (2018). Molecular Structures and Spin-States of Pseudohalide Metal Complexes with Hydrazones of Girard's T Reagent. in European Journal of Inorganic Chemistry
Wiley.(7), 838-846.
https://doi.org/10.1002/ejic.201701387
Milenković MR, Čobeljić B, Anđelković KK, Turel I. Molecular Structures and Spin-States of Pseudohalide Metal Complexes with Hydrazones of Girard's T Reagent. in European Journal of Inorganic Chemistry. 2018;(7):838-846.
doi:10.1002/ejic.201701387 .
Milenković, Milica R., Čobeljić, Božidar, Anđelković, Katarina K., Turel, Iztok, "Molecular Structures and Spin-States of Pseudohalide Metal Complexes with Hydrazones of Girard's T Reagent" in European Journal of Inorganic Chemistry, no. 7 (2018):838-846,
https://doi.org/10.1002/ejic.201701387 . .
2
7
7
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7