TY  - DATA
AU  - Dorko, Zsanett
AU  - Szakolczai, Anett
AU  - Verbić, Tatjana
AU  - Horvai, George
PY  - 2015
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3342
PB  - Wiley-V C H Verlag Gmbh, Weinheim
T2  - Journal of Separation Science
T1  - Supplementary data for article: Dorkó, Z.; Szakolczai, A.; Verbic, T.; Horvai, G. Binding Capacity of Molecularly Imprinted Polymers and Their Nonimprinted Analogs. Journal of Separation Science 2015, 38 (24), 4240–4247. https://doi.org/10.1002/jssc.201500874
UR  - https://hdl.handle.net/21.15107/rcub_cherry_3342
ER  - 

@misc{
author = "Dorko, Zsanett and Szakolczai, Anett and Verbić, Tatjana and Horvai, George",
year = "2015",
publisher = "Wiley-V C H Verlag Gmbh, Weinheim",
journal = "Journal of Separation Science",
title = "Supplementary data for article: Dorkó, Z.; Szakolczai, A.; Verbic, T.; Horvai, G. Binding Capacity of Molecularly Imprinted Polymers and Their Nonimprinted Analogs. Journal of Separation Science 2015, 38 (24), 4240–4247. https://doi.org/10.1002/jssc.201500874",
url = "https://hdl.handle.net/21.15107/rcub_cherry_3342"
}

Dorko, Z., Szakolczai, A., Verbić, T.,& Horvai, G.. (2015). Supplementary data for article: Dorkó, Z.; Szakolczai, A.; Verbic, T.; Horvai, G. Binding Capacity of Molecularly Imprinted Polymers and Their Nonimprinted Analogs. Journal of Separation Science 2015, 38 (24), 4240–4247. https://doi.org/10.1002/jssc.201500874. in Journal of Separation Science
Wiley-V C H Verlag Gmbh, Weinheim..
https://hdl.handle.net/21.15107/rcub_cherry_3342

Dorko Z, Szakolczai A, Verbić T, Horvai G. Supplementary data for article: Dorkó, Z.; Szakolczai, A.; Verbic, T.; Horvai, G. Binding Capacity of Molecularly Imprinted Polymers and Their Nonimprinted Analogs. Journal of Separation Science 2015, 38 (24), 4240–4247. https://doi.org/10.1002/jssc.201500874. in Journal of Separation Science. 2015;.
https://hdl.handle.net/21.15107/rcub_cherry_3342 .

Dorko, Zsanett, Szakolczai, Anett, Verbić, Tatjana, Horvai, George, "Supplementary data for article: Dorkó, Z.; Szakolczai, A.; Verbic, T.; Horvai, G. Binding Capacity of Molecularly Imprinted Polymers and Their Nonimprinted Analogs. Journal of Separation Science 2015, 38 (24), 4240–4247. https://doi.org/10.1002/jssc.201500874" in Journal of Separation Science (2015),
https://hdl.handle.net/21.15107/rcub_cherry_3342 .

TY  - JOUR
AU  - Dorko, Zsanett
AU  - Szakolczai, Anett
AU  - Verbić, Tatjana
AU  - Horvai, George
PY  - 2015
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/2021
AB  - Molecularly imprinted polymers bind their target compounds at binding sites. The binding sites are typically based on some type of functional group, such as carboxyl group. The total amount of such functional groups and their distribution into available and unavailable groups is not well known. The total binding capacity is usually indirectly determined from adsorption isotherms, which are measured much below the theoretical binding capacity. This work shows that in a variety of differently prepared, methacrylic acid based molecularly imprinted and nonimprinted polymers, all carboxylic groups used for the polymer synthesis are retained in the polymer, 80-90% of them can be accessed by strong bases and essentially the same amount can be used for adsorption of weak bases. This high level of adsorption can only be achieved, however, if the adsorbed weak base is strong enough, if the polymer is sufficiently elastic and if the solvent does not compete too strongly for the binding sites. These results may explain why the maximum binding capacities obtained from isotherm measurements are usually not equal to the total amount of available binding sites. This study confirms the usefulness of nonimprinted polymers at high loadings.
PB  - Wiley-V C H Verlag Gmbh, Weinheim
T2  - Journal of Separation Science
T1  - Binding capacity of molecularly imprinted polymers and their nonimprinted analogs
VL  - 38
IS  - 24
SP  - 4240
EP  - 4247
DO  - 10.1002/jssc.201500874
ER  - 

@article{
author = "Dorko, Zsanett and Szakolczai, Anett and Verbić, Tatjana and Horvai, George",
year = "2015",
abstract = "Molecularly imprinted polymers bind their target compounds at binding sites. The binding sites are typically based on some type of functional group, such as carboxyl group. The total amount of such functional groups and their distribution into available and unavailable groups is not well known. The total binding capacity is usually indirectly determined from adsorption isotherms, which are measured much below the theoretical binding capacity. This work shows that in a variety of differently prepared, methacrylic acid based molecularly imprinted and nonimprinted polymers, all carboxylic groups used for the polymer synthesis are retained in the polymer, 80-90% of them can be accessed by strong bases and essentially the same amount can be used for adsorption of weak bases. This high level of adsorption can only be achieved, however, if the adsorbed weak base is strong enough, if the polymer is sufficiently elastic and if the solvent does not compete too strongly for the binding sites. These results may explain why the maximum binding capacities obtained from isotherm measurements are usually not equal to the total amount of available binding sites. This study confirms the usefulness of nonimprinted polymers at high loadings.",
publisher = "Wiley-V C H Verlag Gmbh, Weinheim",
journal = "Journal of Separation Science",
title = "Binding capacity of molecularly imprinted polymers and their nonimprinted analogs",
volume = "38",
number = "24",
pages = "4240-4247",
doi = "10.1002/jssc.201500874"
}

Dorko, Z., Szakolczai, A., Verbić, T.,& Horvai, G.. (2015). Binding capacity of molecularly imprinted polymers and their nonimprinted analogs. in Journal of Separation Science
Wiley-V C H Verlag Gmbh, Weinheim., 38(24), 4240-4247.
https://doi.org/10.1002/jssc.201500874

Dorko Z, Szakolczai A, Verbić T, Horvai G. Binding capacity of molecularly imprinted polymers and their nonimprinted analogs. in Journal of Separation Science. 2015;38(24):4240-4247.
doi:10.1002/jssc.201500874 .

Dorko, Zsanett, Szakolczai, Anett, Verbić, Tatjana, Horvai, George, "Binding capacity of molecularly imprinted polymers and their nonimprinted analogs" in Journal of Separation Science, 38, no. 24 (2015):4240-4247,
https://doi.org/10.1002/jssc.201500874 . .