TY  - JOUR
AU  - Mitrović, Aleksandra D.
AU  - Wild, Stefan
AU  - Lloret, Vicent
AU  - Fickert, Michael
AU  - Assebban, Mhamed
AU  - Márkus, Bence Gábor
AU  - Simon, Ferenc
AU  - Hauke, Frank
AU  - Abellán, Gonzalo
AU  - Hirsch, Andreas
PY  - 2021
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/4501
AB  - Two-dimensional (2D) black phosphorus (BP) represents one of the most appealing 2D materials due to its electronic, optical, and chemical properties. Many strategies have been pursued to face its environmental instability, covalent functionalization being one of the most promising. However, the extremely low functionalization degrees and the limitations in proving the nature of the covalent functionalization still represent challenges in many of these sheet architectures reported to date. Here we shine light on the structural evolution of 2D-BP upon the addition of electrophilic diazonium salts. We demonstrated the absence of covalent functionalization in both the neutral and the reductive routes, observing in the latter case an unexpected interface conversion of BP to red phosphorus (RP), as characterized by Raman, 31P-MAS NMR, and X-ray photoelectron spectroscopies (XPS). Furthermore, thermogravimetric analysis coupled to gas chromatography and mass spectrometry (TG-GC-MS), as well as electron paramagnetic resonance (EPR) gave insights into the potential underlying radical mechanism, suggesting a Sandmeyer-like reaction.
PB  - Wiley-VCH Verlag
T2  - European Chemical Societies
T1  - Interface Amorphization of Two-Dimensional Black Phosphorus upon Treatment with Diazonium Salts
VL  - 27
SP  - 3361
EP  - 3366
DO  - 10.1002/chem.202003584
ER  - 

@article{
author = "Mitrović, Aleksandra D. and Wild, Stefan and Lloret, Vicent and Fickert, Michael and Assebban, Mhamed and Márkus, Bence Gábor and Simon, Ferenc and Hauke, Frank and Abellán, Gonzalo and Hirsch, Andreas",
year = "2021",
abstract = "Two-dimensional (2D) black phosphorus (BP) represents one of the most appealing 2D materials due to its electronic, optical, and chemical properties. Many strategies have been pursued to face its environmental instability, covalent functionalization being one of the most promising. However, the extremely low functionalization degrees and the limitations in proving the nature of the covalent functionalization still represent challenges in many of these sheet architectures reported to date. Here we shine light on the structural evolution of 2D-BP upon the addition of electrophilic diazonium salts. We demonstrated the absence of covalent functionalization in both the neutral and the reductive routes, observing in the latter case an unexpected interface conversion of BP to red phosphorus (RP), as characterized by Raman, 31P-MAS NMR, and X-ray photoelectron spectroscopies (XPS). Furthermore, thermogravimetric analysis coupled to gas chromatography and mass spectrometry (TG-GC-MS), as well as electron paramagnetic resonance (EPR) gave insights into the potential underlying radical mechanism, suggesting a Sandmeyer-like reaction.",
publisher = "Wiley-VCH Verlag",
journal = "European Chemical Societies",
title = "Interface Amorphization of Two-Dimensional Black Phosphorus upon Treatment with Diazonium Salts",
volume = "27",
pages = "3361-3366",
doi = "10.1002/chem.202003584"
}

Mitrović, A. D., Wild, S., Lloret, V., Fickert, M., Assebban, M., Márkus, B. G., Simon, F., Hauke, F., Abellán, G.,& Hirsch, A.. (2021). Interface Amorphization of Two-Dimensional Black Phosphorus upon Treatment with Diazonium Salts. in European Chemical Societies
Wiley-VCH Verlag., 27, 3361-3366.
https://doi.org/10.1002/chem.202003584

Mitrović AD, Wild S, Lloret V, Fickert M, Assebban M, Márkus BG, Simon F, Hauke F, Abellán G, Hirsch A. Interface Amorphization of Two-Dimensional Black Phosphorus upon Treatment with Diazonium Salts. in European Chemical Societies. 2021;27:3361-3366.
doi:10.1002/chem.202003584 .

Mitrović, Aleksandra D., Wild, Stefan, Lloret, Vicent, Fickert, Michael, Assebban, Mhamed, Márkus, Bence Gábor, Simon, Ferenc, Hauke, Frank, Abellán, Gonzalo, Hirsch, Andreas, "Interface Amorphization of Two-Dimensional Black Phosphorus upon Treatment with Diazonium Salts" in European Chemical Societies, 27 (2021):3361-3366,
https://doi.org/10.1002/chem.202003584 . .

TY  - DATA
AU  - Mitrović, Aleksandra D.
AU  - Wild, Stefan
AU  - Lloret, Vicent
AU  - Fickert, Michael
AU  - Assebban, Mhamed
AU  - Márkus, Bence Gábor
AU  - Simon, Ferenc
AU  - Hauke, Frank
AU  - Abellán, Gonzalo
AU  - Hirsch, Andreas
PY  - 2021
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/4501
PB  - Wiley-VCH Verlag
T2  - European Chemical Societies
T1  - Supplementary data for the article: Mitrović, A.; Wild, S.; Lloret, V.; Fickert, M.; Assebban, M.; Márkus, B. G.; Simon, F.; Hauke, F.; Abellán, G.; Hirsch, A. Interface Amorphization of Two-Dimensional Black Phosphorus upon Treatment with Diazonium Salts. Chemistry – A European Journal 2021, 27 (10), 3361–3366. https://doi.org/10.1002/chem.202003584.
UR  - https://hdl.handle.net/21.15107/rcub_cherry_4502
ER  - 

@misc{
author = "Mitrović, Aleksandra D. and Wild, Stefan and Lloret, Vicent and Fickert, Michael and Assebban, Mhamed and Márkus, Bence Gábor and Simon, Ferenc and Hauke, Frank and Abellán, Gonzalo and Hirsch, Andreas",
year = "2021",
publisher = "Wiley-VCH Verlag",
journal = "European Chemical Societies",
title = "Supplementary data for the article: Mitrović, A.; Wild, S.; Lloret, V.; Fickert, M.; Assebban, M.; Márkus, B. G.; Simon, F.; Hauke, F.; Abellán, G.; Hirsch, A. Interface Amorphization of Two-Dimensional Black Phosphorus upon Treatment with Diazonium Salts. Chemistry – A European Journal 2021, 27 (10), 3361–3366. https://doi.org/10.1002/chem.202003584.",
url = "https://hdl.handle.net/21.15107/rcub_cherry_4502"
}

Mitrović, A. D., Wild, S., Lloret, V., Fickert, M., Assebban, M., Márkus, B. G., Simon, F., Hauke, F., Abellán, G.,& Hirsch, A.. (2021). Supplementary data for the article: Mitrović, A.; Wild, S.; Lloret, V.; Fickert, M.; Assebban, M.; Márkus, B. G.; Simon, F.; Hauke, F.; Abellán, G.; Hirsch, A. Interface Amorphization of Two-Dimensional Black Phosphorus upon Treatment with Diazonium Salts. Chemistry – A European Journal 2021, 27 (10), 3361–3366. https://doi.org/10.1002/chem.202003584.. in European Chemical Societies
Wiley-VCH Verlag..
https://hdl.handle.net/21.15107/rcub_cherry_4502

Mitrović AD, Wild S, Lloret V, Fickert M, Assebban M, Márkus BG, Simon F, Hauke F, Abellán G, Hirsch A. Supplementary data for the article: Mitrović, A.; Wild, S.; Lloret, V.; Fickert, M.; Assebban, M.; Márkus, B. G.; Simon, F.; Hauke, F.; Abellán, G.; Hirsch, A. Interface Amorphization of Two-Dimensional Black Phosphorus upon Treatment with Diazonium Salts. Chemistry – A European Journal 2021, 27 (10), 3361–3366. https://doi.org/10.1002/chem.202003584.. in European Chemical Societies. 2021;.
https://hdl.handle.net/21.15107/rcub_cherry_4502 .

Mitrović, Aleksandra D., Wild, Stefan, Lloret, Vicent, Fickert, Michael, Assebban, Mhamed, Márkus, Bence Gábor, Simon, Ferenc, Hauke, Frank, Abellán, Gonzalo, Hirsch, Andreas, "Supplementary data for the article: Mitrović, A.; Wild, S.; Lloret, V.; Fickert, M.; Assebban, M.; Márkus, B. G.; Simon, F.; Hauke, F.; Abellán, G.; Hirsch, A. Interface Amorphization of Two-Dimensional Black Phosphorus upon Treatment with Diazonium Salts. Chemistry – A European Journal 2021, 27 (10), 3361–3366. https://doi.org/10.1002/chem.202003584." in European Chemical Societies (2021),
https://hdl.handle.net/21.15107/rcub_cherry_4502 .

TY  - JOUR
AU  - Mitrović, Aleksandra D.
AU  - Wild, Stefan
AU  - Lloret, Vicent
AU  - Fickert, Michael
AU  - Assebban, Mhamed
AU  - Márkus, Bence G.
AU  - Simon, Ferenc
AU  - Hauke, Frank
AU  - Abellan, Gonzalo
AU  - Hirsch, Andreas
PY  - 2020
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5350
AB  - Two‐dimensional (2D) black phosphorus (BP) represents one of the most appealing 2D materials due to its electronic, optical, and chemical properties. Many strategies have been pursued to face its environmental instability, covalent functionalization being one of the most promising. However, the extremely low functionalization degrees and the limitations in proving the nature of the covalent functionalization still represent challenges in many of these sheet architectures reported to date. Here we shine light on the structural evolution of 2D‐BP upon the addition of electrophilic diazonium salts. We demonstrated the absence of covalent functionalization in both the neutral and the reductive routes, observing in the latter case an unexpected interface conversion of BP to red phosphorus (RP), as characterized by Raman, 31P‐MAS NMR, and X‐ray photoelectron spectroscopies (XPS). Furthermore, thermogravimetric analysis coupled to gas chromatography and mass spectrometry (TG‐GC‐MS), as well as electron paramagnetic resonance (EPR) gave insights into the potential underlying radical mechanism, suggesting a Sandmeyer‐like reaction.
PB  - Wiley
T2  - Chemistry - A European Journal
T1  - Interface Amorphization of Two‐Dimensional Black Phosphorus upon Treatment with Diazonium Salts
VL  - 27
DO  - 10.1002/chem.202003584
ER  - 

@article{
author = "Mitrović, Aleksandra D. and Wild, Stefan and Lloret, Vicent and Fickert, Michael and Assebban, Mhamed and Márkus, Bence G. and Simon, Ferenc and Hauke, Frank and Abellan, Gonzalo and Hirsch, Andreas",
year = "2020",
abstract = "Two‐dimensional (2D) black phosphorus (BP) represents one of the most appealing 2D materials due to its electronic, optical, and chemical properties. Many strategies have been pursued to face its environmental instability, covalent functionalization being one of the most promising. However, the extremely low functionalization degrees and the limitations in proving the nature of the covalent functionalization still represent challenges in many of these sheet architectures reported to date. Here we shine light on the structural evolution of 2D‐BP upon the addition of electrophilic diazonium salts. We demonstrated the absence of covalent functionalization in both the neutral and the reductive routes, observing in the latter case an unexpected interface conversion of BP to red phosphorus (RP), as characterized by Raman, 31P‐MAS NMR, and X‐ray photoelectron spectroscopies (XPS). Furthermore, thermogravimetric analysis coupled to gas chromatography and mass spectrometry (TG‐GC‐MS), as well as electron paramagnetic resonance (EPR) gave insights into the potential underlying radical mechanism, suggesting a Sandmeyer‐like reaction.",
publisher = "Wiley",
journal = "Chemistry - A European Journal",
title = "Interface Amorphization of Two‐Dimensional Black Phosphorus upon Treatment with Diazonium Salts",
volume = "27",
doi = "10.1002/chem.202003584"
}

Mitrović, A. D., Wild, S., Lloret, V., Fickert, M., Assebban, M., Márkus, B. G., Simon, F., Hauke, F., Abellan, G.,& Hirsch, A.. (2020). Interface Amorphization of Two‐Dimensional Black Phosphorus upon Treatment with Diazonium Salts. in Chemistry - A European Journal
Wiley., 27.
https://doi.org/10.1002/chem.202003584

Mitrović AD, Wild S, Lloret V, Fickert M, Assebban M, Márkus BG, Simon F, Hauke F, Abellan G, Hirsch A. Interface Amorphization of Two‐Dimensional Black Phosphorus upon Treatment with Diazonium Salts. in Chemistry - A European Journal. 2020;27.
doi:10.1002/chem.202003584 .

Mitrović, Aleksandra D., Wild, Stefan, Lloret, Vicent, Fickert, Michael, Assebban, Mhamed, Márkus, Bence G., Simon, Ferenc, Hauke, Frank, Abellan, Gonzalo, Hirsch, Andreas, "Interface Amorphization of Two‐Dimensional Black Phosphorus upon Treatment with Diazonium Salts" in Chemistry - A European Journal, 27 (2020),
https://doi.org/10.1002/chem.202003584 . .

TY  - JOUR
AU  - Wild, Stefan
AU  - Fickert, Michael
AU  - Mitrović, Aleksandra D.
AU  - Lloret, Vicent
AU  - Neiss, Christian
AU  - Vidal‐Moya, Jose Alejandro
AU  - Rivero‐Crespo, Miguel Angel
AU  - Leyva‐Pérez, Antonio
AU  - Werbach, Katharina
AU  - Peterlik, Herwig
AU  - Grabau, Mathias
AU  - Wittkämper, Haiko
AU  - Papp, Christian
AU  - Steinrück, Hans-Peter
AU  - Pichler, Thomas
AU  - Görling, Andreas
AU  - Hauke, Frank
AU  - Abellán, Gonzalo
AU  - Hirsch, Andreas
PY  - 2019
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3936
AB  - The chemical bulk reductive covalent functionalization of thin‐layer black phosphorus (BP) using BP intercalation compounds has been developed. Through effective reductive activation, covalent functionalization of the charged BP by reaction with organic alkyl halides is achieved. Functionalization was extensively demonstrated by means of several spectroscopic techniques and DFT calculations; the products showed higher functionalization degrees than those obtained by neutral routes
PB  - Wiley
T2  - Angewandte Chemie International Edition
T1  - Lattice Opening upon Bulk Reductive Covalent Functionalization of Black Phosphorus
VL  - 58
IS  - 17
SP  - 5763
EP  - 5768
DO  - 10.1002/anie.201811181
ER  - 

@article{
author = "Wild, Stefan and Fickert, Michael and Mitrović, Aleksandra D. and Lloret, Vicent and Neiss, Christian and Vidal‐Moya, Jose Alejandro and Rivero‐Crespo, Miguel Angel and Leyva‐Pérez, Antonio and Werbach, Katharina and Peterlik, Herwig and Grabau, Mathias and Wittkämper, Haiko and Papp, Christian and Steinrück, Hans-Peter and Pichler, Thomas and Görling, Andreas and Hauke, Frank and Abellán, Gonzalo and Hirsch, Andreas",
year = "2019",
abstract = "The chemical bulk reductive covalent functionalization of thin‐layer black phosphorus (BP) using BP intercalation compounds has been developed. Through effective reductive activation, covalent functionalization of the charged BP by reaction with organic alkyl halides is achieved. Functionalization was extensively demonstrated by means of several spectroscopic techniques and DFT calculations; the products showed higher functionalization degrees than those obtained by neutral routes",
publisher = "Wiley",
journal = "Angewandte Chemie International Edition",
title = "Lattice Opening upon Bulk Reductive Covalent Functionalization of Black Phosphorus",
volume = "58",
number = "17",
pages = "5763-5768",
doi = "10.1002/anie.201811181"
}

Wild, S., Fickert, M., Mitrović, A. D., Lloret, V., Neiss, C., Vidal‐Moya, J. A., Rivero‐Crespo, M. A., Leyva‐Pérez, A., Werbach, K., Peterlik, H., Grabau, M., Wittkämper, H., Papp, C., Steinrück, H., Pichler, T., Görling, A., Hauke, F., Abellán, G.,& Hirsch, A.. (2019). Lattice Opening upon Bulk Reductive Covalent Functionalization of Black Phosphorus. in Angewandte Chemie International Edition
Wiley., 58(17), 5763-5768.
https://doi.org/10.1002/anie.201811181

Wild S, Fickert M, Mitrović AD, Lloret V, Neiss C, Vidal‐Moya JA, Rivero‐Crespo MA, Leyva‐Pérez A, Werbach K, Peterlik H, Grabau M, Wittkämper H, Papp C, Steinrück H, Pichler T, Görling A, Hauke F, Abellán G, Hirsch A. Lattice Opening upon Bulk Reductive Covalent Functionalization of Black Phosphorus. in Angewandte Chemie International Edition. 2019;58(17):5763-5768.
doi:10.1002/anie.201811181 .

Wild, Stefan, Fickert, Michael, Mitrović, Aleksandra D., Lloret, Vicent, Neiss, Christian, Vidal‐Moya, Jose Alejandro, Rivero‐Crespo, Miguel Angel, Leyva‐Pérez, Antonio, Werbach, Katharina, Peterlik, Herwig, Grabau, Mathias, Wittkämper, Haiko, Papp, Christian, Steinrück, Hans-Peter, Pichler, Thomas, Görling, Andreas, Hauke, Frank, Abellán, Gonzalo, Hirsch, Andreas, "Lattice Opening upon Bulk Reductive Covalent Functionalization of Black Phosphorus" in Angewandte Chemie International Edition, 58, no. 17 (2019):5763-5768,
https://doi.org/10.1002/anie.201811181 . .