TY  - JOUR
AU  - Argay, C
AU  - Kalman, A
AU  - Parkanyi, L
AU  - Leovac, Vukadin M.
AU  - Brčeski, Ilija
AU  - Radivojsa, PN
PY  - 2000
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/436
AB  - The preparation and physical characterization of two copper(I) complexes Cu(HL)NO3 and [Cu(HL)(2)]NO3 . MeOH formed with a newly synthesized tridentate [S,N,P] HL = 2-(diphenylphosphino)benzaldehyde thiosemicarbazone ligand and the crystal structure analysis of the latter have been carried out. An X-ray study of [Cu(HL)(2)]NO3 . MeOH revealed a copper(I) ion coordinated tetrahedrally to S,N,P,P atoms donated by two HL ligands. One is tridentate [S,N,P], whereas the second HL ligand is monodentate, ligating only its phosphorus atom to the copper. The geometry around the four-coordinate Cu(I) is comparable with Cu{N,S,P,X} tetrahedra (X = N, P, or S) retrieved from the Cambridge Structural Database. In addition, with a restriction to Cu{N,P,X,X} (X = C, N, P) tetrahedra - S is excluded - ca. 60 structures against three or four cases were found to be maintained by Cu(I) ions substantiating the principal role of the phosphorus ligands in the reduction of Cu(II) to Cu(I).
PB  - Taylor & Francis Ltd, Abingdon
T2  - Journal of Coordination Chemistry
T1  - Transition metal complexes with thiosemicarbazide-based ligands. part 37. Synthesis and study of the first thiosemi-carbazide-derived copper(I) complexes: Crystal structure of [2-(diphenylphosphino)benzaldehyde thiosemicarbazonato(-l)] copper(I)nitrate-me
VL  - 51
IS  - 1
SP  - 9
EP  - 19
UR  - https://hdl.handle.net/21.15107/rcub_cherry_436
ER  - 

@article{
author = "Argay, C and Kalman, A and Parkanyi, L and Leovac, Vukadin M. and Brčeski, Ilija and Radivojsa, PN",
year = "2000",
abstract = "The preparation and physical characterization of two copper(I) complexes Cu(HL)NO3 and [Cu(HL)(2)]NO3 . MeOH formed with a newly synthesized tridentate [S,N,P] HL = 2-(diphenylphosphino)benzaldehyde thiosemicarbazone ligand and the crystal structure analysis of the latter have been carried out. An X-ray study of [Cu(HL)(2)]NO3 . MeOH revealed a copper(I) ion coordinated tetrahedrally to S,N,P,P atoms donated by two HL ligands. One is tridentate [S,N,P], whereas the second HL ligand is monodentate, ligating only its phosphorus atom to the copper. The geometry around the four-coordinate Cu(I) is comparable with Cu{N,S,P,X} tetrahedra (X = N, P, or S) retrieved from the Cambridge Structural Database. In addition, with a restriction to Cu{N,P,X,X} (X = C, N, P) tetrahedra - S is excluded - ca. 60 structures against three or four cases were found to be maintained by Cu(I) ions substantiating the principal role of the phosphorus ligands in the reduction of Cu(II) to Cu(I).",
publisher = "Taylor & Francis Ltd, Abingdon",
journal = "Journal of Coordination Chemistry",
title = "Transition metal complexes with thiosemicarbazide-based ligands. part 37. Synthesis and study of the first thiosemi-carbazide-derived copper(I) complexes: Crystal structure of [2-(diphenylphosphino)benzaldehyde thiosemicarbazonato(-l)] copper(I)nitrate-me",
volume = "51",
number = "1",
pages = "9-19",
url = "https://hdl.handle.net/21.15107/rcub_cherry_436"
}

Argay, C., Kalman, A., Parkanyi, L., Leovac, V. M., Brčeski, I.,& Radivojsa, P.. (2000). Transition metal complexes with thiosemicarbazide-based ligands. part 37. Synthesis and study of the first thiosemi-carbazide-derived copper(I) complexes: Crystal structure of [2-(diphenylphosphino)benzaldehyde thiosemicarbazonato(-l)] copper(I)nitrate-me. in Journal of Coordination Chemistry
Taylor & Francis Ltd, Abingdon., 51(1), 9-19.
https://hdl.handle.net/21.15107/rcub_cherry_436

Argay C, Kalman A, Parkanyi L, Leovac VM, Brčeski I, Radivojsa P. Transition metal complexes with thiosemicarbazide-based ligands. part 37. Synthesis and study of the first thiosemi-carbazide-derived copper(I) complexes: Crystal structure of [2-(diphenylphosphino)benzaldehyde thiosemicarbazonato(-l)] copper(I)nitrate-me. in Journal of Coordination Chemistry. 2000;51(1):9-19.
https://hdl.handle.net/21.15107/rcub_cherry_436 .

Argay, C, Kalman, A, Parkanyi, L, Leovac, Vukadin M., Brčeski, Ilija, Radivojsa, PN, "Transition metal complexes with thiosemicarbazide-based ligands. part 37. Synthesis and study of the first thiosemi-carbazide-derived copper(I) complexes: Crystal structure of [2-(diphenylphosphino)benzaldehyde thiosemicarbazonato(-l)] copper(I)nitrate-me" in Journal of Coordination Chemistry, 51, no. 1 (2000):9-19,
https://hdl.handle.net/21.15107/rcub_cherry_436 .