TY  - JOUR
AU  - Draskovic, Bojana M.
AU  - Bogdanović, Goran A.
AU  - Leovac, Vukadin M.
AU  - Brčeski, Ilija
AU  - Poleti, Dejan
PY  - 2006
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/785
AB  - The title compound, [Ni(C28H30N3O2PS)], crystallizes with two independent molecules in the asymmetric unit. The Ni-II atoms are in significantly deformed square-planar environments formed by an ONNP donor set from a thiosemicarbazide-based tetradentate ligand. The Ni-II atom and the ONN donor atoms are nearly coplanar, while the P atom deviates from their mean planes by 0.278 (4) and 0.202 (4) angstrom for the two independent molecules. The P-containing chelate rings are remarkably non-planar, adopting a boat conformation, which is unusual for chelate rings in transition metal complexes with thiosemicarbazide-based tetradentate ligands. The orientation of the ethoxy group bonded to this chelate ring is caused by an intramolecular C-H center dot center dot center dot pi interaction with the opposing phenyl ring. There are no hydrogen bonds; instead, numerous intermolecular C-H center dot center dot center dot pi interactions dominate in the crystal packing.
PB  - Int Union Crystallography, Chester
T2  - ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY
T1  - Transition metal complexes with thiosemicarbazide-based ligands. LIII. [4-(2-diphenylphosphino-alpha-ethoxybenzyl-kappa P)-S-methyl-1-(4-oxidopent-3-en-4-ylidene-kappa O)-thiosemicarbazido-kappa(2) N-1, N-4]nickel (II)
VL  - 62
IS  - 7
DO  - 10.1107/S0108270106018932
ER  - 

@article{
author = "Draskovic, Bojana M. and Bogdanović, Goran A. and Leovac, Vukadin M. and Brčeski, Ilija and Poleti, Dejan",
year = "2006",
abstract = "The title compound, [Ni(C28H30N3O2PS)], crystallizes with two independent molecules in the asymmetric unit. The Ni-II atoms are in significantly deformed square-planar environments formed by an ONNP donor set from a thiosemicarbazide-based tetradentate ligand. The Ni-II atom and the ONN donor atoms are nearly coplanar, while the P atom deviates from their mean planes by 0.278 (4) and 0.202 (4) angstrom for the two independent molecules. The P-containing chelate rings are remarkably non-planar, adopting a boat conformation, which is unusual for chelate rings in transition metal complexes with thiosemicarbazide-based tetradentate ligands. The orientation of the ethoxy group bonded to this chelate ring is caused by an intramolecular C-H center dot center dot center dot pi interaction with the opposing phenyl ring. There are no hydrogen bonds; instead, numerous intermolecular C-H center dot center dot center dot pi interactions dominate in the crystal packing.",
publisher = "Int Union Crystallography, Chester",
journal = "ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY",
title = "Transition metal complexes with thiosemicarbazide-based ligands. LIII. [4-(2-diphenylphosphino-alpha-ethoxybenzyl-kappa P)-S-methyl-1-(4-oxidopent-3-en-4-ylidene-kappa O)-thiosemicarbazido-kappa(2) N-1, N-4]nickel (II)",
volume = "62",
number = "7",
doi = "10.1107/S0108270106018932"
}

Draskovic, B. M., Bogdanović, G. A., Leovac, V. M., Brčeski, I.,& Poleti, D.. (2006). Transition metal complexes with thiosemicarbazide-based ligands. LIII. [4-(2-diphenylphosphino-alpha-ethoxybenzyl-kappa P)-S-methyl-1-(4-oxidopent-3-en-4-ylidene-kappa O)-thiosemicarbazido-kappa(2) N-1, N-4]nickel (II). in ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY
Int Union Crystallography, Chester., 62(7).
https://doi.org/10.1107/S0108270106018932

Draskovic BM, Bogdanović GA, Leovac VM, Brčeski I, Poleti D. Transition metal complexes with thiosemicarbazide-based ligands. LIII. [4-(2-diphenylphosphino-alpha-ethoxybenzyl-kappa P)-S-methyl-1-(4-oxidopent-3-en-4-ylidene-kappa O)-thiosemicarbazido-kappa(2) N-1, N-4]nickel (II). in ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY. 2006;62(7).
doi:10.1107/S0108270106018932 .

Draskovic, Bojana M., Bogdanović, Goran A., Leovac, Vukadin M., Brčeski, Ilija, Poleti, Dejan, "Transition metal complexes with thiosemicarbazide-based ligands. LIII. [4-(2-diphenylphosphino-alpha-ethoxybenzyl-kappa P)-S-methyl-1-(4-oxidopent-3-en-4-ylidene-kappa O)-thiosemicarbazido-kappa(2) N-1, N-4]nickel (II)" in ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 62, no. 7 (2006),
https://doi.org/10.1107/S0108270106018932 . .