Kovačević, Vesna V.

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  • Kovačević, Vesna V. (11)

Author's Bibliography

Propranolol Degradation Products after Non-thermal Plasma Treatment using Coaxial DBD Reactor

Savić, Slađana D.; Kovačević, Vesna V.; Sretenović, Goran; Obradović, Bratislav; Roglić, Goran

(University of Ljubljana Press, 2022)

TY  - CONF
AU  - Savić, Slađana D.
AU  - Kovačević, Vesna V.
AU  - Sretenović, Goran
AU  - Obradović, Bratislav
AU  - Roglić, Goran
PY  - 2022
UR  - https://ebooks.uni-lj.si/ZalozbaUL/catalog/book/376
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5789
AB  - Pharmaceuticals represent a considerable threat when they reach the environment. Propranolol (PRP), designed to be a biologically active compound, is a widely used beta-blocker prescribed for heart-related diseases. Due to its frequent use, PRP is detected in numerous aquatic environments and organisms. To completely remove pharmaceuticals such as PRP, advanced oxidation processes (AOPs) are often employed, like ozone, or electrochemical oxidation. Recently, the non-thermal plasma treatment has gained interest for water purification, due to in situ production of reactive oxygen species, such as hydroxyl radicals and superoxide anion radicals. 
The aim of this paper was to investigate plasma treatment for PRP removal from water. To achieve that, the dielectric barrier discharge (DBD) non-thermal reactor was used. This DBD reactor was already tested for degradation of different organic compounds. In this study, PRO solution (100 mg/dm3) was recirculated through the DBD reactor, while plasma was generated using ambient air and argon. The PRP degradation rate was monitored on HPLC-DAD, and the specific energy density (SED) was used to compare plasma effects on PRP degradation. SED was calculated by dividing the power (kept at 35 W and multiplied by the number of cycles of treatment) by the flow rate (held constant at 7.5 dm3/h).
The single most striking observation is that pure argon contributes to faster PRP degradation. Namely, at 75 kJ/dm3, there was less than 5% of PRP left when treated with Ar non-thermal plasma, while only around 35% was achieved at the same point with ambient air. 
As for the degradation products, several compounds were identified (P326, P308, P292, P266, and P134). Interestingly, all compounds were spotted in air-treated PRP solution, but P326 and P308 were not found in samples treated by Ar-generated plasma. 
In summary, both decomposition rate experiments and detected degradation compounds imply that Ar may be a better plasma gas for PRP treatment. A possible explanation is a fact that reactive oxygen species in air plasma are partly consumed to generate reactive nitrogen species, while there is no such phenomenon in Ar-plasma. 
The study confirmed that the non-thermal plasma treatment can be considered promising due to effective and rapid degradation of waterborne organic pollutants, with no catalysts added.
PB  - University of Ljubljana Press
C3  - 22nd European Meeting on Environmental Chemistry, Book of Abstracts, 5 – 8 December 2022, Ljubljana, Slovenia
T1  - Propranolol Degradation Products after Non-thermal Plasma Treatment using Coaxial DBD Reactor
IS  - 22
SP  - 73
EP  - 73
DO  - 10.55295/9789612970352
ER  - 
@conference{
author = "Savić, Slađana D. and Kovačević, Vesna V. and Sretenović, Goran and Obradović, Bratislav and Roglić, Goran",
year = "2022",
abstract = "Pharmaceuticals represent a considerable threat when they reach the environment. Propranolol (PRP), designed to be a biologically active compound, is a widely used beta-blocker prescribed for heart-related diseases. Due to its frequent use, PRP is detected in numerous aquatic environments and organisms. To completely remove pharmaceuticals such as PRP, advanced oxidation processes (AOPs) are often employed, like ozone, or electrochemical oxidation. Recently, the non-thermal plasma treatment has gained interest for water purification, due to in situ production of reactive oxygen species, such as hydroxyl radicals and superoxide anion radicals. 
The aim of this paper was to investigate plasma treatment for PRP removal from water. To achieve that, the dielectric barrier discharge (DBD) non-thermal reactor was used. This DBD reactor was already tested for degradation of different organic compounds. In this study, PRO solution (100 mg/dm3) was recirculated through the DBD reactor, while plasma was generated using ambient air and argon. The PRP degradation rate was monitored on HPLC-DAD, and the specific energy density (SED) was used to compare plasma effects on PRP degradation. SED was calculated by dividing the power (kept at 35 W and multiplied by the number of cycles of treatment) by the flow rate (held constant at 7.5 dm3/h).
The single most striking observation is that pure argon contributes to faster PRP degradation. Namely, at 75 kJ/dm3, there was less than 5% of PRP left when treated with Ar non-thermal plasma, while only around 35% was achieved at the same point with ambient air. 
As for the degradation products, several compounds were identified (P326, P308, P292, P266, and P134). Interestingly, all compounds were spotted in air-treated PRP solution, but P326 and P308 were not found in samples treated by Ar-generated plasma. 
In summary, both decomposition rate experiments and detected degradation compounds imply that Ar may be a better plasma gas for PRP treatment. A possible explanation is a fact that reactive oxygen species in air plasma are partly consumed to generate reactive nitrogen species, while there is no such phenomenon in Ar-plasma. 
The study confirmed that the non-thermal plasma treatment can be considered promising due to effective and rapid degradation of waterborne organic pollutants, with no catalysts added.",
publisher = "University of Ljubljana Press",
journal = "22nd European Meeting on Environmental Chemistry, Book of Abstracts, 5 – 8 December 2022, Ljubljana, Slovenia",
title = "Propranolol Degradation Products after Non-thermal Plasma Treatment using Coaxial DBD Reactor",
number = "22",
pages = "73-73",
doi = "10.55295/9789612970352"
}
Savić, S. D., Kovačević, V. V., Sretenović, G., Obradović, B.,& Roglić, G.. (2022). Propranolol Degradation Products after Non-thermal Plasma Treatment using Coaxial DBD Reactor. in 22nd European Meeting on Environmental Chemistry, Book of Abstracts, 5 – 8 December 2022, Ljubljana, Slovenia
University of Ljubljana Press.(22), 73-73.
https://doi.org/10.55295/9789612970352
Savić SD, Kovačević VV, Sretenović G, Obradović B, Roglić G. Propranolol Degradation Products after Non-thermal Plasma Treatment using Coaxial DBD Reactor. in 22nd European Meeting on Environmental Chemistry, Book of Abstracts, 5 – 8 December 2022, Ljubljana, Slovenia. 2022;(22):73-73.
doi:10.55295/9789612970352 .
Savić, Slađana D., Kovačević, Vesna V., Sretenović, Goran, Obradović, Bratislav, Roglić, Goran, "Propranolol Degradation Products after Non-thermal Plasma Treatment using Coaxial DBD Reactor" in 22nd European Meeting on Environmental Chemistry, Book of Abstracts, 5 – 8 December 2022, Ljubljana, Slovenia, no. 22 (2022):73-73,
https://doi.org/10.55295/9789612970352 . .

The effect of power on the degradation of propranolol by nonthermal plasma reactor

Savić, Slađana D.; Kovačević, Vesna V.; Sretenović, Goran B.; Obradović, Bratislav M.; Roglić, Goran

(Serbian Chemical Society, 2021)

TY  - CONF
AU  - Savić, Slađana D.
AU  - Kovačević, Vesna V.
AU  - Sretenović, Goran B.
AU  - Obradović, Bratislav M.
AU  - Roglić, Goran
PY  - 2021
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5689
AB  - Propranolol (PRO) is a beta-blocker that is readily detected in surface water and hospital wastewater. This pharmaceutical poses a danger for aquatic animals because it is commonly prescribed for heart diseases and anxiety issues. Advanced oxidation processes are commonly tested for the decomposition of pharmaceuticals because they produce various reactive species at room conditions.
A liquid-falling film dielectric barrier discharge (DBD) reactor was used for the treatment of a PRO solution, with no catalysts added. A coaxial construction, accompanied by a peristaltic pump, enables the recirculation of the treated liquid. Ambient air was selected as a feed-gas for nonthermal plasma generation under three levels of power dissipated in plasma. Direct contact of liquid film with plasma in this coaxial reactor enables the efficient transfer of reactive oxygen and nitrogen species generated in plasma to the liquid phase. 
The degradation rate of PRO, pH value, and conductivity were monitored after every cycle of treatment of PRO solution (100 mg/dm3), and in the presence of scavengers (t-butanol and p-benzoquinone). The PRO concentration was monitored by HPLC-DAD, at 213 nm.
As expected, the highest applied power (60 W) contributed to the highest degradation rate (100%). At the same time, in these extreme conditions, pH values dropped from 6 to 2.5 and conductivity increased from 20 µS/cm to almost 1450 µS/cm in the tenth cycle of plasma treatment. Moreover, a high power yielded an excessive decontamination level, but also in the grand production of nitric acid.
On the other hand, lower values of power lead to less successful endpoints, over 85% and less than 60% of degraded PRO when 35 W and 15 W were applied, respectively. Accordingly, under these conditions, the total production of ions was less intensive. The maximum conductivity value was less than 500 µS/cm for PRO treated with plasma generated by 35 W of power, and under 130 µS/cm for 15 W.
To elude the exact role of reactive species, a pair of scavengers were added to a PRO solution. Both t-butanol and p-benzoquinone cut down the degradation efficiency to roughly 50%, which is 35% less than without scavengers. This result indicates an important role of hydroxyl radicals and superoxide anion radicals in air¬-generated nonthermal plasma.
Advanced oxidation using this type of nonthermal plasma reactor enables the production of active species in situ while working in ambient conditions. The effectiveness of plasma treatment was confirmed with the degradation of propranolol, as a model compound for common waterborne pharmaceuticals.
PB  - Serbian Chemical Society
C3  - Book of Abstracts 21st; European Meeting on Environmental Chemistry
T1  - The effect of power on the degradation of propranolol by nonthermal plasma reactor
SP  - 43
EP  - 43
UR  - https://hdl.handle.net/21.15107/rcub_cherry_5689
ER  - 
@conference{
author = "Savić, Slađana D. and Kovačević, Vesna V. and Sretenović, Goran B. and Obradović, Bratislav M. and Roglić, Goran",
year = "2021",
abstract = "Propranolol (PRO) is a beta-blocker that is readily detected in surface water and hospital wastewater. This pharmaceutical poses a danger for aquatic animals because it is commonly prescribed for heart diseases and anxiety issues. Advanced oxidation processes are commonly tested for the decomposition of pharmaceuticals because they produce various reactive species at room conditions.
A liquid-falling film dielectric barrier discharge (DBD) reactor was used for the treatment of a PRO solution, with no catalysts added. A coaxial construction, accompanied by a peristaltic pump, enables the recirculation of the treated liquid. Ambient air was selected as a feed-gas for nonthermal plasma generation under three levels of power dissipated in plasma. Direct contact of liquid film with plasma in this coaxial reactor enables the efficient transfer of reactive oxygen and nitrogen species generated in plasma to the liquid phase. 
The degradation rate of PRO, pH value, and conductivity were monitored after every cycle of treatment of PRO solution (100 mg/dm3), and in the presence of scavengers (t-butanol and p-benzoquinone). The PRO concentration was monitored by HPLC-DAD, at 213 nm.
As expected, the highest applied power (60 W) contributed to the highest degradation rate (100%). At the same time, in these extreme conditions, pH values dropped from 6 to 2.5 and conductivity increased from 20 µS/cm to almost 1450 µS/cm in the tenth cycle of plasma treatment. Moreover, a high power yielded an excessive decontamination level, but also in the grand production of nitric acid.
On the other hand, lower values of power lead to less successful endpoints, over 85% and less than 60% of degraded PRO when 35 W and 15 W were applied, respectively. Accordingly, under these conditions, the total production of ions was less intensive. The maximum conductivity value was less than 500 µS/cm for PRO treated with plasma generated by 35 W of power, and under 130 µS/cm for 15 W.
To elude the exact role of reactive species, a pair of scavengers were added to a PRO solution. Both t-butanol and p-benzoquinone cut down the degradation efficiency to roughly 50%, which is 35% less than without scavengers. This result indicates an important role of hydroxyl radicals and superoxide anion radicals in air¬-generated nonthermal plasma.
Advanced oxidation using this type of nonthermal plasma reactor enables the production of active species in situ while working in ambient conditions. The effectiveness of plasma treatment was confirmed with the degradation of propranolol, as a model compound for common waterborne pharmaceuticals.",
publisher = "Serbian Chemical Society",
journal = "Book of Abstracts 21st; European Meeting on Environmental Chemistry",
title = "The effect of power on the degradation of propranolol by nonthermal plasma reactor",
pages = "43-43",
url = "https://hdl.handle.net/21.15107/rcub_cherry_5689"
}
Savić, S. D., Kovačević, V. V., Sretenović, G. B., Obradović, B. M.,& Roglić, G.. (2021). The effect of power on the degradation of propranolol by nonthermal plasma reactor. in Book of Abstracts 21st; European Meeting on Environmental Chemistry
Serbian Chemical Society., 43-43.
https://hdl.handle.net/21.15107/rcub_cherry_5689
Savić SD, Kovačević VV, Sretenović GB, Obradović BM, Roglić G. The effect of power on the degradation of propranolol by nonthermal plasma reactor. in Book of Abstracts 21st; European Meeting on Environmental Chemistry. 2021;:43-43.
https://hdl.handle.net/21.15107/rcub_cherry_5689 .
Savić, Slađana D., Kovačević, Vesna V., Sretenović, Goran B., Obradović, Bratislav M., Roglić, Goran, "The effect of power on the degradation of propranolol by nonthermal plasma reactor" in Book of Abstracts 21st; European Meeting on Environmental Chemistry (2021):43-43,
https://hdl.handle.net/21.15107/rcub_cherry_5689 .

Plasma assisted degradation of pharmaceutics in water: propranolol hydrochloride as a model compound

Savić, Slađana D.; Kovačević, Vesna V.; Obradović, Bratislav M.; Dojčinović, BIljana P.; Roglić, Goran

(Belgrade : University of Belgrade - Faculty of Chemistry, 2020)

TY  - CONF
AU  - Savić, Slađana D.
AU  - Kovačević, Vesna V.
AU  - Obradović, Bratislav M.
AU  - Dojčinović, BIljana P.
AU  - Roglić, Goran
PY  - 2020
UR  - http://chem.bg.ac.rs/pz/news1.py?q=2506&l=0
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5926
AB  - Propranolol hydrochloride (PRO, Fig. 1), beta-blocker, is poorly degradable in wastewater treatment plants. Because of its wide use, it could pose a threat to aquatic organisms and water users. [1]
The non-thermal plasma reactor (Fig. 2) is tested for degradation of propranolol hydrochloride solution (100 ppm), using different gases under the same electrical conditions (35 W of power dissipated in plasma). 
The concentration of PRO in samples was quantified using HPLC-DAD (213 nm), with acetonitrile and water (70/30 V/V) as eluents. The retention time of PRO was 5.100 min.
The most successful propranolol hydrochloride degradation was achieved using Ar with O2 (80/20 V/V), applying 35 W of power dissipated in plasma, almost 80 % in the 1stcycle of treatment (Fig. 3). The best results with air are slightly over 80 % but in the 10th cycle of plasma reactor treatment.
The presence of N2 in the air decreases the availability of reactive oxygen species, as shown in [2].
This non-thermal plasma is successful at the degradation of organic pollutants in water, such as propranolol hydrochloride, under given conditions.
The level of propranolol hydrochloride degradation can be increased modifying the composition of feed gas, with best results using Ar with O2.
PB  - Belgrade : University of Belgrade - Faculty of Chemistry
C3  - Japan-Serbia Environmental Exchange Symposium, February 21, 2020, Belgrade
T1  - Plasma assisted degradation of pharmaceutics in water: propranolol hydrochloride as a model compound
UR  - https://hdl.handle.net/21.15107/rcub_cherry_5926
ER  - 
@conference{
author = "Savić, Slađana D. and Kovačević, Vesna V. and Obradović, Bratislav M. and Dojčinović, BIljana P. and Roglić, Goran",
year = "2020",
abstract = "Propranolol hydrochloride (PRO, Fig. 1), beta-blocker, is poorly degradable in wastewater treatment plants. Because of its wide use, it could pose a threat to aquatic organisms and water users. [1]
The non-thermal plasma reactor (Fig. 2) is tested for degradation of propranolol hydrochloride solution (100 ppm), using different gases under the same electrical conditions (35 W of power dissipated in plasma). 
The concentration of PRO in samples was quantified using HPLC-DAD (213 nm), with acetonitrile and water (70/30 V/V) as eluents. The retention time of PRO was 5.100 min.
The most successful propranolol hydrochloride degradation was achieved using Ar with O2 (80/20 V/V), applying 35 W of power dissipated in plasma, almost 80 % in the 1stcycle of treatment (Fig. 3). The best results with air are slightly over 80 % but in the 10th cycle of plasma reactor treatment.
The presence of N2 in the air decreases the availability of reactive oxygen species, as shown in [2].
This non-thermal plasma is successful at the degradation of organic pollutants in water, such as propranolol hydrochloride, under given conditions.
The level of propranolol hydrochloride degradation can be increased modifying the composition of feed gas, with best results using Ar with O2.",
publisher = "Belgrade : University of Belgrade - Faculty of Chemistry",
journal = "Japan-Serbia Environmental Exchange Symposium, February 21, 2020, Belgrade",
title = "Plasma assisted degradation of pharmaceutics in water: propranolol hydrochloride as a model compound",
url = "https://hdl.handle.net/21.15107/rcub_cherry_5926"
}
Savić, S. D., Kovačević, V. V., Obradović, B. M., Dojčinović, B. P.,& Roglić, G.. (2020). Plasma assisted degradation of pharmaceutics in water: propranolol hydrochloride as a model compound. in Japan-Serbia Environmental Exchange Symposium, February 21, 2020, Belgrade
Belgrade : University of Belgrade - Faculty of Chemistry..
https://hdl.handle.net/21.15107/rcub_cherry_5926
Savić SD, Kovačević VV, Obradović BM, Dojčinović BP, Roglić G. Plasma assisted degradation of pharmaceutics in water: propranolol hydrochloride as a model compound. in Japan-Serbia Environmental Exchange Symposium, February 21, 2020, Belgrade. 2020;.
https://hdl.handle.net/21.15107/rcub_cherry_5926 .
Savić, Slađana D., Kovačević, Vesna V., Obradović, Bratislav M., Dojčinović, BIljana P., Roglić, Goran, "Plasma assisted degradation of pharmaceutics in water: propranolol hydrochloride as a model compound" in Japan-Serbia Environmental Exchange Symposium, February 21, 2020, Belgrade (2020),
https://hdl.handle.net/21.15107/rcub_cherry_5926 .

Hydrogen Peroxide Production in Water Treated by Non-Thermal Plasma in Different Atmospheres

Savić, Slađana D.; Kovačević, Vesna V.; Obradović, Bratislav; Roglić, Goran

(Belgrade : Serbian Chemical Society, 2019)

TY  - CONF
AU  - Savić, Slađana D.
AU  - Kovačević, Vesna V.
AU  - Obradović, Bratislav
AU  - Roglić, Goran
PY  - 2019
UR  - http://www.kmhem.net/kmhem_fin/wp-content/uploads/2019/01/7th_CYCS_Program_FINAL.pdf
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5923
AB  - Chemical properties of distilled water treated by non-thermal plasma reactor were studied. Hydrogen-peroxide production, pH value and conductivity in distilled water were measured after plasma-treatment in air, argon and argon-oxygen mixture as working gases. Water falling film dielectric barrier discharge (DBD) reactor 1 was used for water treatment. Direct contact of water film with plasma in this reactor enables efficient transfer of reactive species generated in plasma to liquid phase. For optimization of reactive species production frequency and amplitude of the applied voltage were varied. 
Chemical characterization of water treated by DBD generated in different gases shows that hydrogen peroxide production in argon reaches yield of 0.78 g/kWh, while in air it was 0.19 g/kWh. Both measurements were made with 35 W of power dissipated in plasma. Moreover, significant influence of gas atmosphere was observed in measurements of pH value and conductivity which imply that production of ions is about 15 times greater in water treated with plasma generated in air than in argon. Advanced oxidation using this type of non-thermal plasma reactor enables production of active species in situ, while working in ambient conditions.1 Effectiveness of plasma treatment was already confirmed with degradation of some waterborne pharmaceuticals.2 This opens opportunities for new studies of plasma oxidation of pharmaceuticals in aquatic environments.
PB  - Belgrade : Serbian Chemical Society
PB  - Belgrade : Serbian Young Chemists Club
C3  - Seventh Conference of the Young Chemists of Serbia: Book of Abstracts, 2nd November 2019, Belgrade
T1  - Hydrogen Peroxide Production in Water Treated by Non-Thermal Plasma in Different Atmospheres
IS  - 7
SP  - 107
EP  - 107
UR  - https://hdl.handle.net/21.15107/rcub_cherry_5923
ER  - 
@conference{
author = "Savić, Slađana D. and Kovačević, Vesna V. and Obradović, Bratislav and Roglić, Goran",
year = "2019",
abstract = "Chemical properties of distilled water treated by non-thermal plasma reactor were studied. Hydrogen-peroxide production, pH value and conductivity in distilled water were measured after plasma-treatment in air, argon and argon-oxygen mixture as working gases. Water falling film dielectric barrier discharge (DBD) reactor 1 was used for water treatment. Direct contact of water film with plasma in this reactor enables efficient transfer of reactive species generated in plasma to liquid phase. For optimization of reactive species production frequency and amplitude of the applied voltage were varied. 
Chemical characterization of water treated by DBD generated in different gases shows that hydrogen peroxide production in argon reaches yield of 0.78 g/kWh, while in air it was 0.19 g/kWh. Both measurements were made with 35 W of power dissipated in plasma. Moreover, significant influence of gas atmosphere was observed in measurements of pH value and conductivity which imply that production of ions is about 15 times greater in water treated with plasma generated in air than in argon. Advanced oxidation using this type of non-thermal plasma reactor enables production of active species in situ, while working in ambient conditions.1 Effectiveness of plasma treatment was already confirmed with degradation of some waterborne pharmaceuticals.2 This opens opportunities for new studies of plasma oxidation of pharmaceuticals in aquatic environments.",
publisher = "Belgrade : Serbian Chemical Society, Belgrade : Serbian Young Chemists Club",
journal = "Seventh Conference of the Young Chemists of Serbia: Book of Abstracts, 2nd November 2019, Belgrade",
title = "Hydrogen Peroxide Production in Water Treated by Non-Thermal Plasma in Different Atmospheres",
number = "7",
pages = "107-107",
url = "https://hdl.handle.net/21.15107/rcub_cherry_5923"
}
Savić, S. D., Kovačević, V. V., Obradović, B.,& Roglić, G.. (2019). Hydrogen Peroxide Production in Water Treated by Non-Thermal Plasma in Different Atmospheres. in Seventh Conference of the Young Chemists of Serbia: Book of Abstracts, 2nd November 2019, Belgrade
Belgrade : Serbian Chemical Society.(7), 107-107.
https://hdl.handle.net/21.15107/rcub_cherry_5923
Savić SD, Kovačević VV, Obradović B, Roglić G. Hydrogen Peroxide Production in Water Treated by Non-Thermal Plasma in Different Atmospheres. in Seventh Conference of the Young Chemists of Serbia: Book of Abstracts, 2nd November 2019, Belgrade. 2019;(7):107-107.
https://hdl.handle.net/21.15107/rcub_cherry_5923 .
Savić, Slađana D., Kovačević, Vesna V., Obradović, Bratislav, Roglić, Goran, "Hydrogen Peroxide Production in Water Treated by Non-Thermal Plasma in Different Atmospheres" in Seventh Conference of the Young Chemists of Serbia: Book of Abstracts, 2nd November 2019, Belgrade, no. 7 (2019):107-107,
https://hdl.handle.net/21.15107/rcub_cherry_5923 .

Hydrogen Peroxide Production in Water Treated by Non-Thermal Plasma in Different Atmospheres

Savić, Slađana D.; Kovačević, Vesna V.; Obradović, Bratislav; Roglić, Goran

(Belgrade : Serbian Chemical Society, 2019)

TY  - CONF
AU  - Savić, Slađana D.
AU  - Kovačević, Vesna V.
AU  - Obradović, Bratislav
AU  - Roglić, Goran
PY  - 2019
UR  - http://www.kmhem.net/kmhem_fin/wp-content/uploads/2019/01/7th_CYCS_Program_FINAL.pdf
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5924
AB  - Chemical properties of distilled water treated by non-thermal plasma reactor were studied. Hydrogen-peroxide production, pH value and conductivity in distilled water were measured after plasma-treatment in air, argon and argon-oxygen mixture as working gases. Water falling film dielectric barrier discharge (DBD) reactor 1 was used for water treatment. Direct contact of water film with plasma in this reactor enables efficient transfer of reactive species generated in plasma to liquid phase. For optimization of reactive species production frequency and amplitude of the applied voltage were varied. Chemical characterization of water treated by DBD generated in different gases shows that hydrogen peroxide production in argon reaches yield of 0.78 g/kWh, while in air it was 0.19 g/kWh. Both measurements were made with 35 W of power dissipated in plasma. Moreover, significant influence of gas atmosphere was observed in measurements of pH value and conductivity which imply that production of ions is about 15 times greater in water treated with plasma generated in air than in argon. Advanced oxidation using this type of non-thermal plasma reactor enables production of active species in situ, while working in ambient conditions.1 Effectiveness of plasma treatment was already confirmed with degradation of some waterborne pharmaceuticals.2 This opens opportunities for new studies of plasma oxidation of pharmaceuticals in aquatic environments.
PB  - Belgrade : Serbian Chemical Society
PB  - Belgrade : Serbian Young Chemists Club
C3  - Seventh Conference of the Young Chemists of Serbia: Book of Abstracts, 2nd November 2019, Belgrade
T1  - Hydrogen Peroxide Production in Water Treated by Non-Thermal Plasma in Different Atmospheres
UR  - https://hdl.handle.net/21.15107/rcub_cherry_5924
ER  - 
@conference{
author = "Savić, Slađana D. and Kovačević, Vesna V. and Obradović, Bratislav and Roglić, Goran",
year = "2019",
abstract = "Chemical properties of distilled water treated by non-thermal plasma reactor were studied. Hydrogen-peroxide production, pH value and conductivity in distilled water were measured after plasma-treatment in air, argon and argon-oxygen mixture as working gases. Water falling film dielectric barrier discharge (DBD) reactor 1 was used for water treatment. Direct contact of water film with plasma in this reactor enables efficient transfer of reactive species generated in plasma to liquid phase. For optimization of reactive species production frequency and amplitude of the applied voltage were varied. Chemical characterization of water treated by DBD generated in different gases shows that hydrogen peroxide production in argon reaches yield of 0.78 g/kWh, while in air it was 0.19 g/kWh. Both measurements were made with 35 W of power dissipated in plasma. Moreover, significant influence of gas atmosphere was observed in measurements of pH value and conductivity which imply that production of ions is about 15 times greater in water treated with plasma generated in air than in argon. Advanced oxidation using this type of non-thermal plasma reactor enables production of active species in situ, while working in ambient conditions.1 Effectiveness of plasma treatment was already confirmed with degradation of some waterborne pharmaceuticals.2 This opens opportunities for new studies of plasma oxidation of pharmaceuticals in aquatic environments.",
publisher = "Belgrade : Serbian Chemical Society, Belgrade : Serbian Young Chemists Club",
journal = "Seventh Conference of the Young Chemists of Serbia: Book of Abstracts, 2nd November 2019, Belgrade",
title = "Hydrogen Peroxide Production in Water Treated by Non-Thermal Plasma in Different Atmospheres",
url = "https://hdl.handle.net/21.15107/rcub_cherry_5924"
}
Savić, S. D., Kovačević, V. V., Obradović, B.,& Roglić, G.. (2019). Hydrogen Peroxide Production in Water Treated by Non-Thermal Plasma in Different Atmospheres. in Seventh Conference of the Young Chemists of Serbia: Book of Abstracts, 2nd November 2019, Belgrade
Belgrade : Serbian Chemical Society..
https://hdl.handle.net/21.15107/rcub_cherry_5924
Savić SD, Kovačević VV, Obradović B, Roglić G. Hydrogen Peroxide Production in Water Treated by Non-Thermal Plasma in Different Atmospheres. in Seventh Conference of the Young Chemists of Serbia: Book of Abstracts, 2nd November 2019, Belgrade. 2019;.
https://hdl.handle.net/21.15107/rcub_cherry_5924 .
Savić, Slađana D., Kovačević, Vesna V., Obradović, Bratislav, Roglić, Goran, "Hydrogen Peroxide Production in Water Treated by Non-Thermal Plasma in Different Atmospheres" in Seventh Conference of the Young Chemists of Serbia: Book of Abstracts, 2nd November 2019, Belgrade (2019),
https://hdl.handle.net/21.15107/rcub_cherry_5924 .

Degradation of nicotine in water solutions using a water falling film DBD plasma reactor: direct and indirect treatment

Krupež, Jelena; Kovačević, Vesna V.; Jović, Milica; Roglić, Goran; Natić, Maja; Kuraica, Milorad M.; Obradović, Bratislav M.; Dojčinović, Biljana P.

(Iop Publishing Ltd, Bristol, 2018)

TY  - JOUR
AU  - Krupež, Jelena
AU  - Kovačević, Vesna V.
AU  - Jović, Milica
AU  - Roglić, Goran
AU  - Natić, Maja
AU  - Kuraica, Milorad M.
AU  - Obradović, Bratislav M.
AU  - Dojčinović, Biljana P.
PY  - 2018
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/2126
AB  - Nicotine degradation efficiency in water solutions was studied using a water falling film dielectric barrier discharge (DBD) reactor. Two different treatments were applied: direct treatment, the recirculation of the solution through a DBD reactor, and indirect treatment, the bubbling of the gas from the DBD through the porous filter into the solution. In a separate experiment, samples spiked with nicotine in double distilled water (ddH(2)O) and tap water were studied and compared after both treatments. Furthermore, the effects of the homogeneous catalysts, namely, Fe2+ and H2O2, were tested in the direct treatment. Nicotine degradation efficiency was determined using high-performance liquid chromatography. A degradation efficiency of 90% was achieved after the direct treatment catalyzed with Fe2+. In order to analyze the biodegradability, mineralization level, and toxicity of the obtained solutions, after all degradation procedures the values of the following parameters were determined: total organic carbon, chemical oxygen demand, biochemical oxygen demand, and the Artemia salina toxicity test. The results showed that an increase in biodegradability was obtained, after all treatments. A partial nicotine mineralization was achieved and the mortality of the A. salina organism decreased in the treated samples, all of which indicating the effective removal of nicotine and the creation of less toxic solutions. Nicotine degradation products were identified using ultrahigh-performance liquid chromatography coupled with a linear ion trap Orbitrap hybrid mass spectrometer and a simple mechanism for oxidative degradation of nicotine in non-thermal plasma systems is proposed.
PB  - Iop Publishing Ltd, Bristol
T2  - Journal of Physics. D: Applied Physics
T1  - Degradation of nicotine in water solutions using a water falling film DBD plasma reactor: direct and indirect treatment
VL  - 51
IS  - 17
DO  - 10.1088/1361-6463/aab632
ER  - 
@article{
author = "Krupež, Jelena and Kovačević, Vesna V. and Jović, Milica and Roglić, Goran and Natić, Maja and Kuraica, Milorad M. and Obradović, Bratislav M. and Dojčinović, Biljana P.",
year = "2018",
abstract = "Nicotine degradation efficiency in water solutions was studied using a water falling film dielectric barrier discharge (DBD) reactor. Two different treatments were applied: direct treatment, the recirculation of the solution through a DBD reactor, and indirect treatment, the bubbling of the gas from the DBD through the porous filter into the solution. In a separate experiment, samples spiked with nicotine in double distilled water (ddH(2)O) and tap water were studied and compared after both treatments. Furthermore, the effects of the homogeneous catalysts, namely, Fe2+ and H2O2, were tested in the direct treatment. Nicotine degradation efficiency was determined using high-performance liquid chromatography. A degradation efficiency of 90% was achieved after the direct treatment catalyzed with Fe2+. In order to analyze the biodegradability, mineralization level, and toxicity of the obtained solutions, after all degradation procedures the values of the following parameters were determined: total organic carbon, chemical oxygen demand, biochemical oxygen demand, and the Artemia salina toxicity test. The results showed that an increase in biodegradability was obtained, after all treatments. A partial nicotine mineralization was achieved and the mortality of the A. salina organism decreased in the treated samples, all of which indicating the effective removal of nicotine and the creation of less toxic solutions. Nicotine degradation products were identified using ultrahigh-performance liquid chromatography coupled with a linear ion trap Orbitrap hybrid mass spectrometer and a simple mechanism for oxidative degradation of nicotine in non-thermal plasma systems is proposed.",
publisher = "Iop Publishing Ltd, Bristol",
journal = "Journal of Physics. D: Applied Physics",
title = "Degradation of nicotine in water solutions using a water falling film DBD plasma reactor: direct and indirect treatment",
volume = "51",
number = "17",
doi = "10.1088/1361-6463/aab632"
}
Krupež, J., Kovačević, V. V., Jović, M., Roglić, G., Natić, M., Kuraica, M. M., Obradović, B. M.,& Dojčinović, B. P.. (2018). Degradation of nicotine in water solutions using a water falling film DBD plasma reactor: direct and indirect treatment. in Journal of Physics. D: Applied Physics
Iop Publishing Ltd, Bristol., 51(17).
https://doi.org/10.1088/1361-6463/aab632
Krupež J, Kovačević VV, Jović M, Roglić G, Natić M, Kuraica MM, Obradović BM, Dojčinović BP. Degradation of nicotine in water solutions using a water falling film DBD plasma reactor: direct and indirect treatment. in Journal of Physics. D: Applied Physics. 2018;51(17).
doi:10.1088/1361-6463/aab632 .
Krupež, Jelena, Kovačević, Vesna V., Jović, Milica, Roglić, Goran, Natić, Maja, Kuraica, Milorad M., Obradović, Bratislav M., Dojčinović, Biljana P., "Degradation of nicotine in water solutions using a water falling film DBD plasma reactor: direct and indirect treatment" in Journal of Physics. D: Applied Physics, 51, no. 17 (2018),
https://doi.org/10.1088/1361-6463/aab632 . .
19
10
18
16

Measurement of reactive species generated by dielectric barrier discharge in direct contact with water in different atmospheres

Kovačević, Vesna V.; Dojčinović, Biljana P.; Jović, Milica; Roglić, Goran; Obradović, Bratislav M.; Kuraica, Milorad M.

(Iop Publishing Ltd, Bristol, 2017)

TY  - JOUR
AU  - Kovačević, Vesna V.
AU  - Dojčinović, Biljana P.
AU  - Jović, Milica
AU  - Roglić, Goran
AU  - Obradović, Bratislav M.
AU  - Kuraica, Milorad M.
PY  - 2017
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/2440
AB  - The formation of hydroxyl radical and long-living chemical species (H2O2, O-3, NO3- and NO2-) generated in the liquid phase of a water falling film dielectric barrier discharge in dependence on the gas atmosphere (air, nitrogen, oxygen, argon and helium) was studied. The chemical molecular probe dimethyl sulfoxide was employed for quantification of. OH, and the influence of hydroxyl radical scavenging on formation of reactive oxygen and nitrogen species was investigated. In addition to liquid analysis, plasma diagnostics was applied to indicate possible reaction pathways of plasma-liquid interaction. The highest. OH production rate of 1.19 x 10 (5) mol l (1) s (1) was found when water was treated in oxygen, with a yield of 2.75 x 10(-2) molecules of. OH per 100 eV. Formation of hydrogen peroxide in air, nitrogen and argon discharges is determined by recombination reaction of hydroxyl radicals, reaching the highest yield of about 0.7 g kWh(-1) when distilled water was treated in argon discharge. Ozone formation was dominant in oxygen and air discharges. Strong acidification along with formation of reactive nitrogen species was detected in water treated in air and nitrogen discharges.
PB  - Iop Publishing Ltd, Bristol
T2  - Journal of Physics. D: Applied Physics
T1  - Measurement of reactive species generated by dielectric barrier discharge in direct contact with water in different atmospheres
VL  - 50
IS  - 15
DO  - 10.1088/1361-6463/aa5fde
ER  - 
@article{
author = "Kovačević, Vesna V. and Dojčinović, Biljana P. and Jović, Milica and Roglić, Goran and Obradović, Bratislav M. and Kuraica, Milorad M.",
year = "2017",
abstract = "The formation of hydroxyl radical and long-living chemical species (H2O2, O-3, NO3- and NO2-) generated in the liquid phase of a water falling film dielectric barrier discharge in dependence on the gas atmosphere (air, nitrogen, oxygen, argon and helium) was studied. The chemical molecular probe dimethyl sulfoxide was employed for quantification of. OH, and the influence of hydroxyl radical scavenging on formation of reactive oxygen and nitrogen species was investigated. In addition to liquid analysis, plasma diagnostics was applied to indicate possible reaction pathways of plasma-liquid interaction. The highest. OH production rate of 1.19 x 10 (5) mol l (1) s (1) was found when water was treated in oxygen, with a yield of 2.75 x 10(-2) molecules of. OH per 100 eV. Formation of hydrogen peroxide in air, nitrogen and argon discharges is determined by recombination reaction of hydroxyl radicals, reaching the highest yield of about 0.7 g kWh(-1) when distilled water was treated in argon discharge. Ozone formation was dominant in oxygen and air discharges. Strong acidification along with formation of reactive nitrogen species was detected in water treated in air and nitrogen discharges.",
publisher = "Iop Publishing Ltd, Bristol",
journal = "Journal of Physics. D: Applied Physics",
title = "Measurement of reactive species generated by dielectric barrier discharge in direct contact with water in different atmospheres",
volume = "50",
number = "15",
doi = "10.1088/1361-6463/aa5fde"
}
Kovačević, V. V., Dojčinović, B. P., Jović, M., Roglić, G., Obradović, B. M.,& Kuraica, M. M.. (2017). Measurement of reactive species generated by dielectric barrier discharge in direct contact with water in different atmospheres. in Journal of Physics. D: Applied Physics
Iop Publishing Ltd, Bristol., 50(15).
https://doi.org/10.1088/1361-6463/aa5fde
Kovačević VV, Dojčinović BP, Jović M, Roglić G, Obradović BM, Kuraica MM. Measurement of reactive species generated by dielectric barrier discharge in direct contact with water in different atmospheres. in Journal of Physics. D: Applied Physics. 2017;50(15).
doi:10.1088/1361-6463/aa5fde .
Kovačević, Vesna V., Dojčinović, Biljana P., Jović, Milica, Roglić, Goran, Obradović, Bratislav M., Kuraica, Milorad M., "Measurement of reactive species generated by dielectric barrier discharge in direct contact with water in different atmospheres" in Journal of Physics. D: Applied Physics, 50, no. 15 (2017),
https://doi.org/10.1088/1361-6463/aa5fde . .
3
146
88
139
130

Application of Water Falling Film Dbd for Degradation of Nicotine in Water Solutions

Kovačević, Vesna V.; Dojčinović, Biljana P.; Krupež, Jelena; Jović, Mihajlo D.; Natić, Maja; Sretenovic, G. B.; Manojlović, Dragan D.; Obradović, Bratislav M.; Kuraica, Milorad M.

(Masarykova Univ, Brno, 2016)

TY  - CONF
AU  - Kovačević, Vesna V.
AU  - Dojčinović, Biljana P.
AU  - Krupež, Jelena
AU  - Jović, Mihajlo D.
AU  - Natić, Maja
AU  - Sretenovic, G. B.
AU  - Manojlović, Dragan D.
AU  - Obradović, Bratislav M.
AU  - Kuraica, Milorad M.
PY  - 2016
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/2394
AB  - In this paper we present plasma-based degradation of nicotine in water solutions. Water falling film dielectric barrier discharge (DBD) was used as plasma source operating in air at atmospheric pressure. Solutions containing 50 ppm and 300 ppm of nicotine in distilled or tape water were treated directly and indirectly by plasma. Influence of homogeneous catalysts Fe2+ and H2O2 was also tested. Artemia Salina organisms were used for toxicity tests of treated solutions. Degradation efficiency was the highest in direct plasma treatment of nicotine with Fe2+ as a catalyst and in this case the toxicity test showed the lowest mortality.
PB  - Masarykova Univ, Brno
T1  - Application of Water Falling Film Dbd for Degradation of Nicotine in Water Solutions
SP  - 420
EP  - 423
UR  - https://hdl.handle.net/21.15107/rcub_cherry_2394
ER  - 
@conference{
author = "Kovačević, Vesna V. and Dojčinović, Biljana P. and Krupež, Jelena and Jović, Mihajlo D. and Natić, Maja and Sretenovic, G. B. and Manojlović, Dragan D. and Obradović, Bratislav M. and Kuraica, Milorad M.",
year = "2016",
abstract = "In this paper we present plasma-based degradation of nicotine in water solutions. Water falling film dielectric barrier discharge (DBD) was used as plasma source operating in air at atmospheric pressure. Solutions containing 50 ppm and 300 ppm of nicotine in distilled or tape water were treated directly and indirectly by plasma. Influence of homogeneous catalysts Fe2+ and H2O2 was also tested. Artemia Salina organisms were used for toxicity tests of treated solutions. Degradation efficiency was the highest in direct plasma treatment of nicotine with Fe2+ as a catalyst and in this case the toxicity test showed the lowest mortality.",
publisher = "Masarykova Univ, Brno",
title = "Application of Water Falling Film Dbd for Degradation of Nicotine in Water Solutions",
pages = "420-423",
url = "https://hdl.handle.net/21.15107/rcub_cherry_2394"
}
Kovačević, V. V., Dojčinović, B. P., Krupež, J., Jović, M. D., Natić, M., Sretenovic, G. B., Manojlović, D. D., Obradović, B. M.,& Kuraica, M. M.. (2016). Application of Water Falling Film Dbd for Degradation of Nicotine in Water Solutions. 
Masarykova Univ, Brno., 420-423.
https://hdl.handle.net/21.15107/rcub_cherry_2394
Kovačević VV, Dojčinović BP, Krupež J, Jović MD, Natić M, Sretenovic GB, Manojlović DD, Obradović BM, Kuraica MM. Application of Water Falling Film Dbd for Degradation of Nicotine in Water Solutions. 2016;:420-423.
https://hdl.handle.net/21.15107/rcub_cherry_2394 .
Kovačević, Vesna V., Dojčinović, Biljana P., Krupež, Jelena, Jović, Mihajlo D., Natić, Maja, Sretenovic, G. B., Manojlović, Dragan D., Obradović, Bratislav M., Kuraica, Milorad M., "Application of Water Falling Film Dbd for Degradation of Nicotine in Water Solutions" (2016):420-423,
https://hdl.handle.net/21.15107/rcub_cherry_2394 .

Application of non-thermal plasma reactor and Fenton reaction for degradation of ibuprofen

Marković, Marijana; Jović, Milica; Stanković, Dalibor; Kovačević, Vesna V.; Roglić, Goran; Gojgić-Cvijović, Gordana D.; Manojlović, Dragan D.

(Elsevier Science Bv, Amsterdam, 2015)

TY  - JOUR
AU  - Marković, Marijana
AU  - Jović, Milica
AU  - Stanković, Dalibor
AU  - Kovačević, Vesna V.
AU  - Roglić, Goran
AU  - Gojgić-Cvijović, Gordana D.
AU  - Manojlović, Dragan D.
PY  - 2015
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1898
AB  - Pharmaceutical compounds have been detected frequently in surface and ground water. Advanced Oxidation Processes (AOPs) were reported as very efficient for removal of various organic compounds. Nevertheless, due to incomplete degradation, toxic intermediates can induce more severe effects than the parent compound. Therefore, toxicity studies are necessary for the evaluation of possible uses of AOPs. In this study the effectiveness and capacity for environmental application of three different AOPs were estimated. They were applied and evaluated for removal of ibuprofen from water solutions. Therefore, two treatments were performed in a non-thermal plasma reactor with dielectric barrier discharge with and without a homogenous catalyst (Fe2+). The third treatment was the Fenton reaction. The degradation rate of ibuprofen was measured by HPLC-DAD and the main degradation products were identified using LC-MS TOF. Twelve degradation products were identified, and there were differences according to the various treatments applied. Toxicity effects were determined with two bioassays: Vibrio fischeri and Artemia salina. The efficiency of AOPs was demonstrated for all treatments, where after 15 min degradation percentage was over 80% accompanied by opening of the aromatic ring. In the treatment with homogenous catalyst degradation reached 99%. V. fischeri toxicity test has shown greater sensitivity to ibuprofen solution after the Fenton treatment in comparison to A. salina. (C) 2014 Elsevier B.V. All rights reserved.
PB  - Elsevier Science Bv, Amsterdam
T2  - Science of the Total Environment
T1  - Application of non-thermal plasma reactor and Fenton reaction for degradation of ibuprofen
VL  - 505
SP  - 1148
EP  - 1155
DO  - 10.1016/j.scitotenv.2014.11.017
ER  - 
@article{
author = "Marković, Marijana and Jović, Milica and Stanković, Dalibor and Kovačević, Vesna V. and Roglić, Goran and Gojgić-Cvijović, Gordana D. and Manojlović, Dragan D.",
year = "2015",
abstract = "Pharmaceutical compounds have been detected frequently in surface and ground water. Advanced Oxidation Processes (AOPs) were reported as very efficient for removal of various organic compounds. Nevertheless, due to incomplete degradation, toxic intermediates can induce more severe effects than the parent compound. Therefore, toxicity studies are necessary for the evaluation of possible uses of AOPs. In this study the effectiveness and capacity for environmental application of three different AOPs were estimated. They were applied and evaluated for removal of ibuprofen from water solutions. Therefore, two treatments were performed in a non-thermal plasma reactor with dielectric barrier discharge with and without a homogenous catalyst (Fe2+). The third treatment was the Fenton reaction. The degradation rate of ibuprofen was measured by HPLC-DAD and the main degradation products were identified using LC-MS TOF. Twelve degradation products were identified, and there were differences according to the various treatments applied. Toxicity effects were determined with two bioassays: Vibrio fischeri and Artemia salina. The efficiency of AOPs was demonstrated for all treatments, where after 15 min degradation percentage was over 80% accompanied by opening of the aromatic ring. In the treatment with homogenous catalyst degradation reached 99%. V. fischeri toxicity test has shown greater sensitivity to ibuprofen solution after the Fenton treatment in comparison to A. salina. (C) 2014 Elsevier B.V. All rights reserved.",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Science of the Total Environment",
title = "Application of non-thermal plasma reactor and Fenton reaction for degradation of ibuprofen",
volume = "505",
pages = "1148-1155",
doi = "10.1016/j.scitotenv.2014.11.017"
}
Marković, M., Jović, M., Stanković, D., Kovačević, V. V., Roglić, G., Gojgić-Cvijović, G. D.,& Manojlović, D. D.. (2015). Application of non-thermal plasma reactor and Fenton reaction for degradation of ibuprofen. in Science of the Total Environment
Elsevier Science Bv, Amsterdam., 505, 1148-1155.
https://doi.org/10.1016/j.scitotenv.2014.11.017
Marković M, Jović M, Stanković D, Kovačević VV, Roglić G, Gojgić-Cvijović GD, Manojlović DD. Application of non-thermal plasma reactor and Fenton reaction for degradation of ibuprofen. in Science of the Total Environment. 2015;505:1148-1155.
doi:10.1016/j.scitotenv.2014.11.017 .
Marković, Marijana, Jović, Milica, Stanković, Dalibor, Kovačević, Vesna V., Roglić, Goran, Gojgić-Cvijović, Gordana D., Manojlović, Dragan D., "Application of non-thermal plasma reactor and Fenton reaction for degradation of ibuprofen" in Science of the Total Environment, 505 (2015):1148-1155,
https://doi.org/10.1016/j.scitotenv.2014.11.017 . .
1
92
61
89
80

Effect of different catalysts on mesotrione degradation in water falling film DBD reactor

Jović, Milica; Dojčinović, Biljana P.; Kovačević, Vesna V.; Obradović, Bratislav M.; Kuraica, Milorad M.; Gašić, Uroš M.; Roglić, Goran

(Elsevier Science Sa, Lausanne, 2014)

TY  - JOUR
AU  - Jović, Milica
AU  - Dojčinović, Biljana P.
AU  - Kovačević, Vesna V.
AU  - Obradović, Bratislav M.
AU  - Kuraica, Milorad M.
AU  - Gašić, Uroš M.
AU  - Roglić, Goran
PY  - 2014
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1790
AB  - In this study the effect of different homogenous catalysts and their dosage on mesotrione degradation in water falling film dielectric barrier discharge (DBD) reactor was investigated. Four catalytic systems Mn2+ /DBD, Co2+/DBD, Fe2+/DBD and H2O2/DBD were examined. In order to find optimal conditions various concentrations of catalysts and specific energy density (SED) values were tested in each system. Mesotrione degradation efficiency was determined by HPLC-DAD and mineralization efficiency by TOC value. Degradation products were identified by UHPLC-Orbitrap-MS and compared after finding out the optimal concentration for each catalytic system. All studied catalytic systems have proved to be successful in improving mesotrione removal, but the highest improvement in degradation efficiency was obtained with catalytic system 5 ppm Fe2+/DBD (by 50% for SED 124 kJ/L) and 10 mM H2O2/DBD for improving mineralization efficiency (by 45% for SED 310 kJ/L). Nine degradation products were identified in catalytic DBD treatments. Main degradation products were: glutaric acid, 2-nitro-4-methylsulfonylbenzaldehyde and 2-nitro-4-methylsulfonylbenzoic acid. H2O2/DBD gave significantly different degradation products than other catalytic systems. Dominant degradation products in other systems were not identified in system with hydrogen peroxide, which supported the fact that the highest mineralization efficiency was achieved with peroxide catalytic system. Global toxicity of samples after degradation in each system was determined using Artemia sauna and they could be considered as "non toxic". (c) 2014 Elsevier B.V. All rights reserved.
PB  - Elsevier Science Sa, Lausanne
T2  - Chemical Engineering Journal
T1  - Effect of different catalysts on mesotrione degradation in water falling film DBD reactor
VL  - 248
SP  - 63
EP  - 70
DO  - 10.1016/j.cej.2014.03.031
ER  - 
@article{
author = "Jović, Milica and Dojčinović, Biljana P. and Kovačević, Vesna V. and Obradović, Bratislav M. and Kuraica, Milorad M. and Gašić, Uroš M. and Roglić, Goran",
year = "2014",
abstract = "In this study the effect of different homogenous catalysts and their dosage on mesotrione degradation in water falling film dielectric barrier discharge (DBD) reactor was investigated. Four catalytic systems Mn2+ /DBD, Co2+/DBD, Fe2+/DBD and H2O2/DBD were examined. In order to find optimal conditions various concentrations of catalysts and specific energy density (SED) values were tested in each system. Mesotrione degradation efficiency was determined by HPLC-DAD and mineralization efficiency by TOC value. Degradation products were identified by UHPLC-Orbitrap-MS and compared after finding out the optimal concentration for each catalytic system. All studied catalytic systems have proved to be successful in improving mesotrione removal, but the highest improvement in degradation efficiency was obtained with catalytic system 5 ppm Fe2+/DBD (by 50% for SED 124 kJ/L) and 10 mM H2O2/DBD for improving mineralization efficiency (by 45% for SED 310 kJ/L). Nine degradation products were identified in catalytic DBD treatments. Main degradation products were: glutaric acid, 2-nitro-4-methylsulfonylbenzaldehyde and 2-nitro-4-methylsulfonylbenzoic acid. H2O2/DBD gave significantly different degradation products than other catalytic systems. Dominant degradation products in other systems were not identified in system with hydrogen peroxide, which supported the fact that the highest mineralization efficiency was achieved with peroxide catalytic system. Global toxicity of samples after degradation in each system was determined using Artemia sauna and they could be considered as "non toxic". (c) 2014 Elsevier B.V. All rights reserved.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Chemical Engineering Journal",
title = "Effect of different catalysts on mesotrione degradation in water falling film DBD reactor",
volume = "248",
pages = "63-70",
doi = "10.1016/j.cej.2014.03.031"
}
Jović, M., Dojčinović, B. P., Kovačević, V. V., Obradović, B. M., Kuraica, M. M., Gašić, U. M.,& Roglić, G.. (2014). Effect of different catalysts on mesotrione degradation in water falling film DBD reactor. in Chemical Engineering Journal
Elsevier Science Sa, Lausanne., 248, 63-70.
https://doi.org/10.1016/j.cej.2014.03.031
Jović M, Dojčinović BP, Kovačević VV, Obradović BM, Kuraica MM, Gašić UM, Roglić G. Effect of different catalysts on mesotrione degradation in water falling film DBD reactor. in Chemical Engineering Journal. 2014;248:63-70.
doi:10.1016/j.cej.2014.03.031 .
Jović, Milica, Dojčinović, Biljana P., Kovačević, Vesna V., Obradović, Bratislav M., Kuraica, Milorad M., Gašić, Uroš M., Roglić, Goran, "Effect of different catalysts on mesotrione degradation in water falling film DBD reactor" in Chemical Engineering Journal, 248 (2014):63-70,
https://doi.org/10.1016/j.cej.2014.03.031 . .
38
30
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35

Dielectric barrier discharge in water solution treatment

Kovačević, Vesna V.; Dojčinović, Biljana P.; Šupica, D.; Jović, Mihajlo D.; Roglić, Goran; Obradović, Bratislav M.; Kuraica, Milorad M.

(2013)

TY  - CONF
AU  - Kovačević, Vesna V.
AU  - Dojčinović, Biljana P.
AU  - Šupica, D.
AU  - Jović, Mihajlo D.
AU  - Roglić, Goran
AU  - Obradović, Bratislav M.
AU  - Kuraica, Milorad M.
PY  - 2013
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/125
AB  - Application of coaxial dielectric barrier discharge (DBD) reactor for treatment of different water solutions was studied. In this reactor the circulating liquid is a part of discharge electrode configuration. Thus liquid is directly exposed to UV radiation and reactive species like ozone, radicals, ions and electrons. This configuration of DBD also offers to operate the plasma with and without water falling film at one of the electrodes. Thus it can act as a plasma reactor for gas treatment and as a scrubber for soluble compounds in a gas phase, simultaneously. Here we present measurement of hydroxyl radical ("OH) in plasma treated distilled water as well as treatment of phenols, textile dyes, medicaments, herbicides and detergents.
T1  - Dielectric barrier discharge in water solution treatment
SP  - 216
EP  - 219
UR  - https://hdl.handle.net/21.15107/rcub_cherry_125
ER  - 
@conference{
author = "Kovačević, Vesna V. and Dojčinović, Biljana P. and Šupica, D. and Jović, Mihajlo D. and Roglić, Goran and Obradović, Bratislav M. and Kuraica, Milorad M.",
year = "2013",
abstract = "Application of coaxial dielectric barrier discharge (DBD) reactor for treatment of different water solutions was studied. In this reactor the circulating liquid is a part of discharge electrode configuration. Thus liquid is directly exposed to UV radiation and reactive species like ozone, radicals, ions and electrons. This configuration of DBD also offers to operate the plasma with and without water falling film at one of the electrodes. Thus it can act as a plasma reactor for gas treatment and as a scrubber for soluble compounds in a gas phase, simultaneously. Here we present measurement of hydroxyl radical ("OH) in plasma treated distilled water as well as treatment of phenols, textile dyes, medicaments, herbicides and detergents.",
title = "Dielectric barrier discharge in water solution treatment",
pages = "216-219",
url = "https://hdl.handle.net/21.15107/rcub_cherry_125"
}
Kovačević, V. V., Dojčinović, B. P., Šupica, D., Jović, M. D., Roglić, G., Obradović, B. M.,& Kuraica, M. M.. (2013). Dielectric barrier discharge in water solution treatment. , 216-219.
https://hdl.handle.net/21.15107/rcub_cherry_125
Kovačević VV, Dojčinović BP, Šupica D, Jović MD, Roglić G, Obradović BM, Kuraica MM. Dielectric barrier discharge in water solution treatment. 2013;:216-219.
https://hdl.handle.net/21.15107/rcub_cherry_125 .
Kovačević, Vesna V., Dojčinović, Biljana P., Šupica, D., Jović, Mihajlo D., Roglić, Goran, Obradović, Bratislav M., Kuraica, Milorad M., "Dielectric barrier discharge in water solution treatment" (2013):216-219,
https://hdl.handle.net/21.15107/rcub_cherry_125 .