TY  - JOUR
AU  - Cinderella, Andrew P.
AU  - Vulović, Bojan
AU  - Watson, Donald A.
PY  - 2017
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/2475
AB  - We report the first example of a silyl-Negishi reaction between secondary zinc organometallics and silicon electrophiles. This palladium-catalyzed process provides direct access to alkyl silanes. The delicate balance of steric and electronic parameters of the employed DrewPhos ligand is paramount to suppressing isomerization and promoting efficient and selective cross-coupling.
PB  - Amer Chemical Soc, Washington
T2  - Journal of the American Chemical Society
T1  - Palladium-Catalyzed Cross-Coupling of Silyl Electrophiles with Alkylzinc Halides: A Silyl-Negishi Reaction
VL  - 139
IS  - 23
SP  - 7741
EP  - 7744
DO  - 10.1021/jacs.7b04364
ER  - 

@article{
author = "Cinderella, Andrew P. and Vulović, Bojan and Watson, Donald A.",
year = "2017",
abstract = "We report the first example of a silyl-Negishi reaction between secondary zinc organometallics and silicon electrophiles. This palladium-catalyzed process provides direct access to alkyl silanes. The delicate balance of steric and electronic parameters of the employed DrewPhos ligand is paramount to suppressing isomerization and promoting efficient and selective cross-coupling.",
publisher = "Amer Chemical Soc, Washington",
journal = "Journal of the American Chemical Society",
title = "Palladium-Catalyzed Cross-Coupling of Silyl Electrophiles with Alkylzinc Halides: A Silyl-Negishi Reaction",
volume = "139",
number = "23",
pages = "7741-7744",
doi = "10.1021/jacs.7b04364"
}

Cinderella, A. P., Vulović, B.,& Watson, D. A.. (2017). Palladium-Catalyzed Cross-Coupling of Silyl Electrophiles with Alkylzinc Halides: A Silyl-Negishi Reaction. in Journal of the American Chemical Society
Amer Chemical Soc, Washington., 139(23), 7741-7744.
https://doi.org/10.1021/jacs.7b04364

Cinderella AP, Vulović B, Watson DA. Palladium-Catalyzed Cross-Coupling of Silyl Electrophiles with Alkylzinc Halides: A Silyl-Negishi Reaction. in Journal of the American Chemical Society. 2017;139(23):7741-7744.
doi:10.1021/jacs.7b04364 .

Cinderella, Andrew P., Vulović, Bojan, Watson, Donald A., "Palladium-Catalyzed Cross-Coupling of Silyl Electrophiles with Alkylzinc Halides: A Silyl-Negishi Reaction" in Journal of the American Chemical Society, 139, no. 23 (2017):7741-7744,
https://doi.org/10.1021/jacs.7b04364 . .

TY  - DATA
AU  - Cinderella, Andrew P.
AU  - Vulović, Bojan
AU  - Watson, Donald A.
PY  - 2017
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3099
PB  - Amer Chemical Soc, Washington
T2  - Journal of the American Chemical Society
T1  - Supplementary data for article:           Cinderella, A. P.; Vulovic, B.; Watson, D. A. Palladium-Catalyzed Cross-Coupling of Silyl Electrophiles with Alkylzinc Halides: A Silyl-Negishi Reaction. Journal of the American Chemical Society 2017, 139 (23), 7741–7744. https://doi.org/10.1021/jacs.7b04364
UR  - https://hdl.handle.net/21.15107/rcub_cherry_3099
ER  - 

@misc{
author = "Cinderella, Andrew P. and Vulović, Bojan and Watson, Donald A.",
year = "2017",
publisher = "Amer Chemical Soc, Washington",
journal = "Journal of the American Chemical Society",
title = "Supplementary data for article:           Cinderella, A. P.; Vulovic, B.; Watson, D. A. Palladium-Catalyzed Cross-Coupling of Silyl Electrophiles with Alkylzinc Halides: A Silyl-Negishi Reaction. Journal of the American Chemical Society 2017, 139 (23), 7741–7744. https://doi.org/10.1021/jacs.7b04364",
url = "https://hdl.handle.net/21.15107/rcub_cherry_3099"
}

Cinderella, A. P., Vulović, B.,& Watson, D. A.. (2017). Supplementary data for article:           Cinderella, A. P.; Vulovic, B.; Watson, D. A. Palladium-Catalyzed Cross-Coupling of Silyl Electrophiles with Alkylzinc Halides: A Silyl-Negishi Reaction. Journal of the American Chemical Society 2017, 139 (23), 7741–7744. https://doi.org/10.1021/jacs.7b04364. in Journal of the American Chemical Society
Amer Chemical Soc, Washington..
https://hdl.handle.net/21.15107/rcub_cherry_3099

Cinderella AP, Vulović B, Watson DA. Supplementary data for article:           Cinderella, A. P.; Vulovic, B.; Watson, D. A. Palladium-Catalyzed Cross-Coupling of Silyl Electrophiles with Alkylzinc Halides: A Silyl-Negishi Reaction. Journal of the American Chemical Society 2017, 139 (23), 7741–7744. https://doi.org/10.1021/jacs.7b04364. in Journal of the American Chemical Society. 2017;.
https://hdl.handle.net/21.15107/rcub_cherry_3099 .

Cinderella, Andrew P., Vulović, Bojan, Watson, Donald A., "Supplementary data for article:           Cinderella, A. P.; Vulovic, B.; Watson, D. A. Palladium-Catalyzed Cross-Coupling of Silyl Electrophiles with Alkylzinc Halides: A Silyl-Negishi Reaction. Journal of the American Chemical Society 2017, 139 (23), 7741–7744. https://doi.org/10.1021/jacs.7b04364" in Journal of the American Chemical Society (2017),
https://hdl.handle.net/21.15107/rcub_cherry_3099 .

TY  - JOUR
AU  - Vulović, Bojan
AU  - Cinderella, Andrew P.
AU  - Watson, Donald A.
PY  - 2017
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3923
AB  - Using a palladium catalyst supported by DrewPhos, the alkylation of monochlorosilanes with primary and secondary alkylmagnesium halides is now possible. Arylation with sterically demanding aromatic magnesium halides is also enabled. This transformation overcomes the high bond strength of the Si–Cl bond (113 kcal/mol) and is a rare example of a transition-metal catalyzed process involving its activation. Because of the availability of both chlorosilanes and organomagnesium halide reagents, this method allows for the preparation of a wide range of alkyl and aryl silanes.
PB  - American Chemical Society
T2  - ACS Catalysis
T1  - Palladium-Catalyzed Cross-Coupling of Monochlorosilanes and Grignard Reagents
VL  - 7
IS  - 12
SP  - 8113
EP  - 8117
DO  - 10.1021/acscatal.7b03465
ER  - 

@article{
author = "Vulović, Bojan and Cinderella, Andrew P. and Watson, Donald A.",
year = "2017",
abstract = "Using a palladium catalyst supported by DrewPhos, the alkylation of monochlorosilanes with primary and secondary alkylmagnesium halides is now possible. Arylation with sterically demanding aromatic magnesium halides is also enabled. This transformation overcomes the high bond strength of the Si–Cl bond (113 kcal/mol) and is a rare example of a transition-metal catalyzed process involving its activation. Because of the availability of both chlorosilanes and organomagnesium halide reagents, this method allows for the preparation of a wide range of alkyl and aryl silanes.",
publisher = "American Chemical Society",
journal = "ACS Catalysis",
title = "Palladium-Catalyzed Cross-Coupling of Monochlorosilanes and Grignard Reagents",
volume = "7",
number = "12",
pages = "8113-8117",
doi = "10.1021/acscatal.7b03465"
}

Vulović, B., Cinderella, A. P.,& Watson, D. A.. (2017). Palladium-Catalyzed Cross-Coupling of Monochlorosilanes and Grignard Reagents. in ACS Catalysis
American Chemical Society., 7(12), 8113-8117.
https://doi.org/10.1021/acscatal.7b03465

Vulović B, Cinderella AP, Watson DA. Palladium-Catalyzed Cross-Coupling of Monochlorosilanes and Grignard Reagents. in ACS Catalysis. 2017;7(12):8113-8117.
doi:10.1021/acscatal.7b03465 .

Vulović, Bojan, Cinderella, Andrew P., Watson, Donald A., "Palladium-Catalyzed Cross-Coupling of Monochlorosilanes and Grignard Reagents" in ACS Catalysis, 7, no. 12 (2017):8113-8117,
https://doi.org/10.1021/acscatal.7b03465 . .

TY  - DATA
AU  - Vulović, Bojan
AU  - Cinderella, Andrew P.
AU  - Watson, Donald A.
PY  - 2017
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3924
PB  - American Chemical Society
T2  - ACS Catalysis
T1  - Supplementary data for the article: Vulović, B.; Cinderella, A. P.; Watson, D. A. Palladium-Catalyzed Cross-Coupling of Monochlorosilanes and Grignard Reagents. ACS Catalysis 2017, 7 (12), 8113–8117. https://doi.org/10.1021/acscatal.7b03465
UR  - https://hdl.handle.net/21.15107/rcub_cherry_3924
ER  - 

@misc{
author = "Vulović, Bojan and Cinderella, Andrew P. and Watson, Donald A.",
year = "2017",
publisher = "American Chemical Society",
journal = "ACS Catalysis",
title = "Supplementary data for the article: Vulović, B.; Cinderella, A. P.; Watson, D. A. Palladium-Catalyzed Cross-Coupling of Monochlorosilanes and Grignard Reagents. ACS Catalysis 2017, 7 (12), 8113–8117. https://doi.org/10.1021/acscatal.7b03465",
url = "https://hdl.handle.net/21.15107/rcub_cherry_3924"
}

Vulović, B., Cinderella, A. P.,& Watson, D. A.. (2017). Supplementary data for the article: Vulović, B.; Cinderella, A. P.; Watson, D. A. Palladium-Catalyzed Cross-Coupling of Monochlorosilanes and Grignard Reagents. ACS Catalysis 2017, 7 (12), 8113–8117. https://doi.org/10.1021/acscatal.7b03465. in ACS Catalysis
American Chemical Society..
https://hdl.handle.net/21.15107/rcub_cherry_3924

Vulović B, Cinderella AP, Watson DA. Supplementary data for the article: Vulović, B.; Cinderella, A. P.; Watson, D. A. Palladium-Catalyzed Cross-Coupling of Monochlorosilanes and Grignard Reagents. ACS Catalysis 2017, 7 (12), 8113–8117. https://doi.org/10.1021/acscatal.7b03465. in ACS Catalysis. 2017;.
https://hdl.handle.net/21.15107/rcub_cherry_3924 .

Vulović, Bojan, Cinderella, Andrew P., Watson, Donald A., "Supplementary data for the article: Vulović, B.; Cinderella, A. P.; Watson, D. A. Palladium-Catalyzed Cross-Coupling of Monochlorosilanes and Grignard Reagents. ACS Catalysis 2017, 7 (12), 8113–8117. https://doi.org/10.1021/acscatal.7b03465" in ACS Catalysis (2017),
https://hdl.handle.net/21.15107/rcub_cherry_3924 .

TY  - JOUR
AU  - Vulović, Bojan
AU  - Cinderella, Andrew P.
AU  - Watson, Donald A.
PY  - 2017
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3925
AB  - Using a palladium catalyst supported by DrewPhos, the alkylation of monochlorosilanes with primary and secondary alkylmagnesium halides is now possible. Arylation with sterically demanding aromatic magnesium halides is also enabled. This transformation overcomes the high bond strength of the Si–Cl bond (113 kcal/mol) and is a rare example of a transition-metal catalyzed process involving its activation. Because of the availability of both chlorosilanes and organomagnesium halide reagents, this method allows for the preparation of a wide range of alkyl and aryl silanes.
PB  - American Chemical Society
T2  - ACS Catalysis
T1  - Palladium-Catalyzed Cross-Coupling of Monochlorosilanes and Grignard Reagents
VL  - 7
IS  - 12
SP  - 8113
EP  - 8117
DO  - 10.1021/acscatal.7b03465
ER  - 

@article{
author = "Vulović, Bojan and Cinderella, Andrew P. and Watson, Donald A.",
year = "2017",
abstract = "Using a palladium catalyst supported by DrewPhos, the alkylation of monochlorosilanes with primary and secondary alkylmagnesium halides is now possible. Arylation with sterically demanding aromatic magnesium halides is also enabled. This transformation overcomes the high bond strength of the Si–Cl bond (113 kcal/mol) and is a rare example of a transition-metal catalyzed process involving its activation. Because of the availability of both chlorosilanes and organomagnesium halide reagents, this method allows for the preparation of a wide range of alkyl and aryl silanes.",
publisher = "American Chemical Society",
journal = "ACS Catalysis",
title = "Palladium-Catalyzed Cross-Coupling of Monochlorosilanes and Grignard Reagents",
volume = "7",
number = "12",
pages = "8113-8117",
doi = "10.1021/acscatal.7b03465"
}

Vulović, B., Cinderella, A. P.,& Watson, D. A.. (2017). Palladium-Catalyzed Cross-Coupling of Monochlorosilanes and Grignard Reagents. in ACS Catalysis
American Chemical Society., 7(12), 8113-8117.
https://doi.org/10.1021/acscatal.7b03465

Vulović B, Cinderella AP, Watson DA. Palladium-Catalyzed Cross-Coupling of Monochlorosilanes and Grignard Reagents. in ACS Catalysis. 2017;7(12):8113-8117.
doi:10.1021/acscatal.7b03465 .

Vulović, Bojan, Cinderella, Andrew P., Watson, Donald A., "Palladium-Catalyzed Cross-Coupling of Monochlorosilanes and Grignard Reagents" in ACS Catalysis, 7, no. 12 (2017):8113-8117,
https://doi.org/10.1021/acscatal.7b03465 . .