Jović, Milica

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  • Jović, Milica (12)

Author's Bibliography

Degradation of nicotine in water solutions using a water falling film DBD plasma reactor: direct and indirect treatment

Krupež, Jelena; Kovačević, Vesna V.; Jović, Milica; Roglić, Goran; Natić, Maja; Kuraica, Milorad M.; Obradović, Bratislav M.; Dojčinović, Biljana P.

(Iop Publishing Ltd, Bristol, 2018)

TY  - JOUR
AU  - Krupež, Jelena
AU  - Kovačević, Vesna V.
AU  - Jović, Milica
AU  - Roglić, Goran
AU  - Natić, Maja
AU  - Kuraica, Milorad M.
AU  - Obradović, Bratislav M.
AU  - Dojčinović, Biljana P.
PY  - 2018
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/2126
AB  - Nicotine degradation efficiency in water solutions was studied using a water falling film dielectric barrier discharge (DBD) reactor. Two different treatments were applied: direct treatment, the recirculation of the solution through a DBD reactor, and indirect treatment, the bubbling of the gas from the DBD through the porous filter into the solution. In a separate experiment, samples spiked with nicotine in double distilled water (ddH(2)O) and tap water were studied and compared after both treatments. Furthermore, the effects of the homogeneous catalysts, namely, Fe2+ and H2O2, were tested in the direct treatment. Nicotine degradation efficiency was determined using high-performance liquid chromatography. A degradation efficiency of 90% was achieved after the direct treatment catalyzed with Fe2+. In order to analyze the biodegradability, mineralization level, and toxicity of the obtained solutions, after all degradation procedures the values of the following parameters were determined: total organic carbon, chemical oxygen demand, biochemical oxygen demand, and the Artemia salina toxicity test. The results showed that an increase in biodegradability was obtained, after all treatments. A partial nicotine mineralization was achieved and the mortality of the A. salina organism decreased in the treated samples, all of which indicating the effective removal of nicotine and the creation of less toxic solutions. Nicotine degradation products were identified using ultrahigh-performance liquid chromatography coupled with a linear ion trap Orbitrap hybrid mass spectrometer and a simple mechanism for oxidative degradation of nicotine in non-thermal plasma systems is proposed.
PB  - Iop Publishing Ltd, Bristol
T2  - Journal of Physics. D: Applied Physics
T1  - Degradation of nicotine in water solutions using a water falling film DBD plasma reactor: direct and indirect treatment
VL  - 51
IS  - 17
DO  - 10.1088/1361-6463/aab632
ER  - 
@article{
author = "Krupež, Jelena and Kovačević, Vesna V. and Jović, Milica and Roglić, Goran and Natić, Maja and Kuraica, Milorad M. and Obradović, Bratislav M. and Dojčinović, Biljana P.",
year = "2018",
abstract = "Nicotine degradation efficiency in water solutions was studied using a water falling film dielectric barrier discharge (DBD) reactor. Two different treatments were applied: direct treatment, the recirculation of the solution through a DBD reactor, and indirect treatment, the bubbling of the gas from the DBD through the porous filter into the solution. In a separate experiment, samples spiked with nicotine in double distilled water (ddH(2)O) and tap water were studied and compared after both treatments. Furthermore, the effects of the homogeneous catalysts, namely, Fe2+ and H2O2, were tested in the direct treatment. Nicotine degradation efficiency was determined using high-performance liquid chromatography. A degradation efficiency of 90% was achieved after the direct treatment catalyzed with Fe2+. In order to analyze the biodegradability, mineralization level, and toxicity of the obtained solutions, after all degradation procedures the values of the following parameters were determined: total organic carbon, chemical oxygen demand, biochemical oxygen demand, and the Artemia salina toxicity test. The results showed that an increase in biodegradability was obtained, after all treatments. A partial nicotine mineralization was achieved and the mortality of the A. salina organism decreased in the treated samples, all of which indicating the effective removal of nicotine and the creation of less toxic solutions. Nicotine degradation products were identified using ultrahigh-performance liquid chromatography coupled with a linear ion trap Orbitrap hybrid mass spectrometer and a simple mechanism for oxidative degradation of nicotine in non-thermal plasma systems is proposed.",
publisher = "Iop Publishing Ltd, Bristol",
journal = "Journal of Physics. D: Applied Physics",
title = "Degradation of nicotine in water solutions using a water falling film DBD plasma reactor: direct and indirect treatment",
volume = "51",
number = "17",
doi = "10.1088/1361-6463/aab632"
}
Krupež, J., Kovačević, V. V., Jović, M., Roglić, G., Natić, M., Kuraica, M. M., Obradović, B. M.,& Dojčinović, B. P.. (2018). Degradation of nicotine in water solutions using a water falling film DBD plasma reactor: direct and indirect treatment. in Journal of Physics. D: Applied Physics
Iop Publishing Ltd, Bristol., 51(17).
https://doi.org/10.1088/1361-6463/aab632
Krupež J, Kovačević VV, Jović M, Roglić G, Natić M, Kuraica MM, Obradović BM, Dojčinović BP. Degradation of nicotine in water solutions using a water falling film DBD plasma reactor: direct and indirect treatment. in Journal of Physics. D: Applied Physics. 2018;51(17).
doi:10.1088/1361-6463/aab632 .
Krupež, Jelena, Kovačević, Vesna V., Jović, Milica, Roglić, Goran, Natić, Maja, Kuraica, Milorad M., Obradović, Bratislav M., Dojčinović, Biljana P., "Degradation of nicotine in water solutions using a water falling film DBD plasma reactor: direct and indirect treatment" in Journal of Physics. D: Applied Physics, 51, no. 17 (2018),
https://doi.org/10.1088/1361-6463/aab632 . .
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Measurement of reactive species generated by dielectric barrier discharge in direct contact with water in different atmospheres

Kovačević, Vesna V.; Dojčinović, Biljana P.; Jović, Milica; Roglić, Goran; Obradović, Bratislav M.; Kuraica, Milorad M.

(Iop Publishing Ltd, Bristol, 2017)

TY  - JOUR
AU  - Kovačević, Vesna V.
AU  - Dojčinović, Biljana P.
AU  - Jović, Milica
AU  - Roglić, Goran
AU  - Obradović, Bratislav M.
AU  - Kuraica, Milorad M.
PY  - 2017
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/2440
AB  - The formation of hydroxyl radical and long-living chemical species (H2O2, O-3, NO3- and NO2-) generated in the liquid phase of a water falling film dielectric barrier discharge in dependence on the gas atmosphere (air, nitrogen, oxygen, argon and helium) was studied. The chemical molecular probe dimethyl sulfoxide was employed for quantification of. OH, and the influence of hydroxyl radical scavenging on formation of reactive oxygen and nitrogen species was investigated. In addition to liquid analysis, plasma diagnostics was applied to indicate possible reaction pathways of plasma-liquid interaction. The highest. OH production rate of 1.19 x 10 (5) mol l (1) s (1) was found when water was treated in oxygen, with a yield of 2.75 x 10(-2) molecules of. OH per 100 eV. Formation of hydrogen peroxide in air, nitrogen and argon discharges is determined by recombination reaction of hydroxyl radicals, reaching the highest yield of about 0.7 g kWh(-1) when distilled water was treated in argon discharge. Ozone formation was dominant in oxygen and air discharges. Strong acidification along with formation of reactive nitrogen species was detected in water treated in air and nitrogen discharges.
PB  - Iop Publishing Ltd, Bristol
T2  - Journal of Physics. D: Applied Physics
T1  - Measurement of reactive species generated by dielectric barrier discharge in direct contact with water in different atmospheres
VL  - 50
IS  - 15
DO  - 10.1088/1361-6463/aa5fde
ER  - 
@article{
author = "Kovačević, Vesna V. and Dojčinović, Biljana P. and Jović, Milica and Roglić, Goran and Obradović, Bratislav M. and Kuraica, Milorad M.",
year = "2017",
abstract = "The formation of hydroxyl radical and long-living chemical species (H2O2, O-3, NO3- and NO2-) generated in the liquid phase of a water falling film dielectric barrier discharge in dependence on the gas atmosphere (air, nitrogen, oxygen, argon and helium) was studied. The chemical molecular probe dimethyl sulfoxide was employed for quantification of. OH, and the influence of hydroxyl radical scavenging on formation of reactive oxygen and nitrogen species was investigated. In addition to liquid analysis, plasma diagnostics was applied to indicate possible reaction pathways of plasma-liquid interaction. The highest. OH production rate of 1.19 x 10 (5) mol l (1) s (1) was found when water was treated in oxygen, with a yield of 2.75 x 10(-2) molecules of. OH per 100 eV. Formation of hydrogen peroxide in air, nitrogen and argon discharges is determined by recombination reaction of hydroxyl radicals, reaching the highest yield of about 0.7 g kWh(-1) when distilled water was treated in argon discharge. Ozone formation was dominant in oxygen and air discharges. Strong acidification along with formation of reactive nitrogen species was detected in water treated in air and nitrogen discharges.",
publisher = "Iop Publishing Ltd, Bristol",
journal = "Journal of Physics. D: Applied Physics",
title = "Measurement of reactive species generated by dielectric barrier discharge in direct contact with water in different atmospheres",
volume = "50",
number = "15",
doi = "10.1088/1361-6463/aa5fde"
}
Kovačević, V. V., Dojčinović, B. P., Jović, M., Roglić, G., Obradović, B. M.,& Kuraica, M. M.. (2017). Measurement of reactive species generated by dielectric barrier discharge in direct contact with water in different atmospheres. in Journal of Physics. D: Applied Physics
Iop Publishing Ltd, Bristol., 50(15).
https://doi.org/10.1088/1361-6463/aa5fde
Kovačević VV, Dojčinović BP, Jović M, Roglić G, Obradović BM, Kuraica MM. Measurement of reactive species generated by dielectric barrier discharge in direct contact with water in different atmospheres. in Journal of Physics. D: Applied Physics. 2017;50(15).
doi:10.1088/1361-6463/aa5fde .
Kovačević, Vesna V., Dojčinović, Biljana P., Jović, Milica, Roglić, Goran, Obradović, Bratislav M., Kuraica, Milorad M., "Measurement of reactive species generated by dielectric barrier discharge in direct contact with water in different atmospheres" in Journal of Physics. D: Applied Physics, 50, no. 15 (2017),
https://doi.org/10.1088/1361-6463/aa5fde . .
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Degradation of Triton X-100 in Water Falling Film Dielectric Barrier Discharge Reactor

Aonyas, Munera M.; Nešić, Jelena; Jović, Milica; Marković, Marijana; Dojčinović, Biljana P.; Obradović, Bratislav M.; Roglić, Goran

(Wiley-Blackwell, Hoboken, 2016)

TY  - JOUR
AU  - Aonyas, Munera M.
AU  - Nešić, Jelena
AU  - Jović, Milica
AU  - Marković, Marijana
AU  - Dojčinović, Biljana P.
AU  - Obradović, Bratislav M.
AU  - Roglić, Goran
PY  - 2016
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1920
AB  - The aim of this study was to investigate the degradation of the non-ionic surfactant Triton X-100 (TX-100) by using an advanced oxidation process in a non-thermal plasma reactor based on water falling film dielectric barrier discharge (DBD). The effects of two catalytic plasma systems, Fe2+/DBD and H2O2/DBD, were tested to improve the degradation of TX-100 and the mineralization efficiency in the DBD reactor. Both catalytic systems exhibited significant improvements in degradation efficiency, especially in the beginning of the treatment: the efficiency increased from 23 to 88 and 50%, for 5 mgL(-1) Fe2+/DBD and 10 mmol L-1 H2O2/DBD, respectively. The mineralization efficiency of TX-100 in the non-catalytic DBD treatment was very low (1%), but with addition of catalysts, the mineralization efficiency was drastically improved, with H2O2/DBD at 4-34% (depending on the H2O2 concentration) and Fe2+/DBD at 2-21% (depending on the Fe2+ concentration). Degradation products of TX-100 in non-catalytic and two catalytic systems were identified using UHPLC-Orbitrap-MS. Based on the degradation products that were identified, a simple mechanistic scheme was proposed. MS analysis revealed that degradation of TX-100 in the DBD reactor occurred by shortening the ethoxy chain. In the presence of catalysts, there are additional reactions of cleavage of the alkyl chain followed by formation of polyethoxylated phenol (H2O2/DBD) and addition of OH center dot radicals onto the aromatic ring (Fe2+/DBD). The final degradation products did not cause any significant toxic effects to Vibrio fischeri or Artemia salina.
PB  - Wiley-Blackwell, Hoboken
T2  - CLEAN - Soil Air Water
T1  - Degradation of Triton X-100 in Water Falling Film Dielectric Barrier Discharge Reactor
VL  - 44
IS  - 4
SP  - 422
EP  - 429
DO  - 10.1002/clen.201500501
ER  - 
@article{
author = "Aonyas, Munera M. and Nešić, Jelena and Jović, Milica and Marković, Marijana and Dojčinović, Biljana P. and Obradović, Bratislav M. and Roglić, Goran",
year = "2016",
abstract = "The aim of this study was to investigate the degradation of the non-ionic surfactant Triton X-100 (TX-100) by using an advanced oxidation process in a non-thermal plasma reactor based on water falling film dielectric barrier discharge (DBD). The effects of two catalytic plasma systems, Fe2+/DBD and H2O2/DBD, were tested to improve the degradation of TX-100 and the mineralization efficiency in the DBD reactor. Both catalytic systems exhibited significant improvements in degradation efficiency, especially in the beginning of the treatment: the efficiency increased from 23 to 88 and 50%, for 5 mgL(-1) Fe2+/DBD and 10 mmol L-1 H2O2/DBD, respectively. The mineralization efficiency of TX-100 in the non-catalytic DBD treatment was very low (1%), but with addition of catalysts, the mineralization efficiency was drastically improved, with H2O2/DBD at 4-34% (depending on the H2O2 concentration) and Fe2+/DBD at 2-21% (depending on the Fe2+ concentration). Degradation products of TX-100 in non-catalytic and two catalytic systems were identified using UHPLC-Orbitrap-MS. Based on the degradation products that were identified, a simple mechanistic scheme was proposed. MS analysis revealed that degradation of TX-100 in the DBD reactor occurred by shortening the ethoxy chain. In the presence of catalysts, there are additional reactions of cleavage of the alkyl chain followed by formation of polyethoxylated phenol (H2O2/DBD) and addition of OH center dot radicals onto the aromatic ring (Fe2+/DBD). The final degradation products did not cause any significant toxic effects to Vibrio fischeri or Artemia salina.",
publisher = "Wiley-Blackwell, Hoboken",
journal = "CLEAN - Soil Air Water",
title = "Degradation of Triton X-100 in Water Falling Film Dielectric Barrier Discharge Reactor",
volume = "44",
number = "4",
pages = "422-429",
doi = "10.1002/clen.201500501"
}
Aonyas, M. M., Nešić, J., Jović, M., Marković, M., Dojčinović, B. P., Obradović, B. M.,& Roglić, G.. (2016). Degradation of Triton X-100 in Water Falling Film Dielectric Barrier Discharge Reactor. in CLEAN - Soil Air Water
Wiley-Blackwell, Hoboken., 44(4), 422-429.
https://doi.org/10.1002/clen.201500501
Aonyas MM, Nešić J, Jović M, Marković M, Dojčinović BP, Obradović BM, Roglić G. Degradation of Triton X-100 in Water Falling Film Dielectric Barrier Discharge Reactor. in CLEAN - Soil Air Water. 2016;44(4):422-429.
doi:10.1002/clen.201500501 .
Aonyas, Munera M., Nešić, Jelena, Jović, Milica, Marković, Marijana, Dojčinović, Biljana P., Obradović, Bratislav M., Roglić, Goran, "Degradation of Triton X-100 in Water Falling Film Dielectric Barrier Discharge Reactor" in CLEAN - Soil Air Water, 44, no. 4 (2016):422-429,
https://doi.org/10.1002/clen.201500501 . .
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Microwave-hydrothermal method for the synthesis of composite materials for removal of arsenic from water

Anđelković, Ivan; Jović, Bojan; Jović, Milica; Marković, Marijana; Stanković, Dalibor; Manojlović, Dragan D.; Roglić, Goran

(Springer Heidelberg, Heidelberg, 2016)

TY  - JOUR
AU  - Anđelković, Ivan
AU  - Jović, Bojan
AU  - Jović, Milica
AU  - Marković, Marijana
AU  - Stanković, Dalibor
AU  - Manojlović, Dragan D.
AU  - Roglić, Goran
PY  - 2016
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/2030
AB  - Composite material Zr-doped TiO2, suitable for the removal of arsenic from water, was synthetized with fast and simple microwave-hydrothermal method. Obtained material, Zr-TiO2, had uniform size and composition with zirconium ions incorporated into crystal structure of titanium dioxide. Synthetized composite material had large specific surface area and well-developed micropore and mesopore structure that was responsible for fast adsorption of As(III) and As(V) from water. The influence of pH on the adsorption capacity of arsenic was studied. The kinetics and isotherm experiments were also performed. The treatment of natural water sample containing high concentration of arsenic with composite material Zr-TiO2 was efficient. The concentration of arsenic was reduced to the value recommended by WHO.
PB  - Springer Heidelberg, Heidelberg
T2  - Environmental Science and Pollution Research
T1  - Microwave-hydrothermal method for the synthesis of composite materials for removal of arsenic from water
VL  - 23
IS  - 1
SP  - 469
EP  - 476
DO  - 10.1007/s11356-015-5283-z
ER  - 
@article{
author = "Anđelković, Ivan and Jović, Bojan and Jović, Milica and Marković, Marijana and Stanković, Dalibor and Manojlović, Dragan D. and Roglić, Goran",
year = "2016",
abstract = "Composite material Zr-doped TiO2, suitable for the removal of arsenic from water, was synthetized with fast and simple microwave-hydrothermal method. Obtained material, Zr-TiO2, had uniform size and composition with zirconium ions incorporated into crystal structure of titanium dioxide. Synthetized composite material had large specific surface area and well-developed micropore and mesopore structure that was responsible for fast adsorption of As(III) and As(V) from water. The influence of pH on the adsorption capacity of arsenic was studied. The kinetics and isotherm experiments were also performed. The treatment of natural water sample containing high concentration of arsenic with composite material Zr-TiO2 was efficient. The concentration of arsenic was reduced to the value recommended by WHO.",
publisher = "Springer Heidelberg, Heidelberg",
journal = "Environmental Science and Pollution Research",
title = "Microwave-hydrothermal method for the synthesis of composite materials for removal of arsenic from water",
volume = "23",
number = "1",
pages = "469-476",
doi = "10.1007/s11356-015-5283-z"
}
Anđelković, I., Jović, B., Jović, M., Marković, M., Stanković, D., Manojlović, D. D.,& Roglić, G.. (2016). Microwave-hydrothermal method for the synthesis of composite materials for removal of arsenic from water. in Environmental Science and Pollution Research
Springer Heidelberg, Heidelberg., 23(1), 469-476.
https://doi.org/10.1007/s11356-015-5283-z
Anđelković I, Jović B, Jović M, Marković M, Stanković D, Manojlović DD, Roglić G. Microwave-hydrothermal method for the synthesis of composite materials for removal of arsenic from water. in Environmental Science and Pollution Research. 2016;23(1):469-476.
doi:10.1007/s11356-015-5283-z .
Anđelković, Ivan, Jović, Bojan, Jović, Milica, Marković, Marijana, Stanković, Dalibor, Manojlović, Dragan D., Roglić, Goran, "Microwave-hydrothermal method for the synthesis of composite materials for removal of arsenic from water" in Environmental Science and Pollution Research, 23, no. 1 (2016):469-476,
https://doi.org/10.1007/s11356-015-5283-z . .
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Application of non-thermal plasma reactor and Fenton reaction for degradation of ibuprofen

Marković, Marijana; Jović, Milica; Stanković, Dalibor; Kovačević, Vesna V.; Roglić, Goran; Gojgić-Cvijović, Gordana D.; Manojlović, Dragan D.

(Elsevier Science Bv, Amsterdam, 2015)

TY  - JOUR
AU  - Marković, Marijana
AU  - Jović, Milica
AU  - Stanković, Dalibor
AU  - Kovačević, Vesna V.
AU  - Roglić, Goran
AU  - Gojgić-Cvijović, Gordana D.
AU  - Manojlović, Dragan D.
PY  - 2015
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1898
AB  - Pharmaceutical compounds have been detected frequently in surface and ground water. Advanced Oxidation Processes (AOPs) were reported as very efficient for removal of various organic compounds. Nevertheless, due to incomplete degradation, toxic intermediates can induce more severe effects than the parent compound. Therefore, toxicity studies are necessary for the evaluation of possible uses of AOPs. In this study the effectiveness and capacity for environmental application of three different AOPs were estimated. They were applied and evaluated for removal of ibuprofen from water solutions. Therefore, two treatments were performed in a non-thermal plasma reactor with dielectric barrier discharge with and without a homogenous catalyst (Fe2+). The third treatment was the Fenton reaction. The degradation rate of ibuprofen was measured by HPLC-DAD and the main degradation products were identified using LC-MS TOF. Twelve degradation products were identified, and there were differences according to the various treatments applied. Toxicity effects were determined with two bioassays: Vibrio fischeri and Artemia salina. The efficiency of AOPs was demonstrated for all treatments, where after 15 min degradation percentage was over 80% accompanied by opening of the aromatic ring. In the treatment with homogenous catalyst degradation reached 99%. V. fischeri toxicity test has shown greater sensitivity to ibuprofen solution after the Fenton treatment in comparison to A. salina. (C) 2014 Elsevier B.V. All rights reserved.
PB  - Elsevier Science Bv, Amsterdam
T2  - Science of the Total Environment
T1  - Application of non-thermal plasma reactor and Fenton reaction for degradation of ibuprofen
VL  - 505
SP  - 1148
EP  - 1155
DO  - 10.1016/j.scitotenv.2014.11.017
ER  - 
@article{
author = "Marković, Marijana and Jović, Milica and Stanković, Dalibor and Kovačević, Vesna V. and Roglić, Goran and Gojgić-Cvijović, Gordana D. and Manojlović, Dragan D.",
year = "2015",
abstract = "Pharmaceutical compounds have been detected frequently in surface and ground water. Advanced Oxidation Processes (AOPs) were reported as very efficient for removal of various organic compounds. Nevertheless, due to incomplete degradation, toxic intermediates can induce more severe effects than the parent compound. Therefore, toxicity studies are necessary for the evaluation of possible uses of AOPs. In this study the effectiveness and capacity for environmental application of three different AOPs were estimated. They were applied and evaluated for removal of ibuprofen from water solutions. Therefore, two treatments were performed in a non-thermal plasma reactor with dielectric barrier discharge with and without a homogenous catalyst (Fe2+). The third treatment was the Fenton reaction. The degradation rate of ibuprofen was measured by HPLC-DAD and the main degradation products were identified using LC-MS TOF. Twelve degradation products were identified, and there were differences according to the various treatments applied. Toxicity effects were determined with two bioassays: Vibrio fischeri and Artemia salina. The efficiency of AOPs was demonstrated for all treatments, where after 15 min degradation percentage was over 80% accompanied by opening of the aromatic ring. In the treatment with homogenous catalyst degradation reached 99%. V. fischeri toxicity test has shown greater sensitivity to ibuprofen solution after the Fenton treatment in comparison to A. salina. (C) 2014 Elsevier B.V. All rights reserved.",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Science of the Total Environment",
title = "Application of non-thermal plasma reactor and Fenton reaction for degradation of ibuprofen",
volume = "505",
pages = "1148-1155",
doi = "10.1016/j.scitotenv.2014.11.017"
}
Marković, M., Jović, M., Stanković, D., Kovačević, V. V., Roglić, G., Gojgić-Cvijović, G. D.,& Manojlović, D. D.. (2015). Application of non-thermal plasma reactor and Fenton reaction for degradation of ibuprofen. in Science of the Total Environment
Elsevier Science Bv, Amsterdam., 505, 1148-1155.
https://doi.org/10.1016/j.scitotenv.2014.11.017
Marković M, Jović M, Stanković D, Kovačević VV, Roglić G, Gojgić-Cvijović GD, Manojlović DD. Application of non-thermal plasma reactor and Fenton reaction for degradation of ibuprofen. in Science of the Total Environment. 2015;505:1148-1155.
doi:10.1016/j.scitotenv.2014.11.017 .
Marković, Marijana, Jović, Milica, Stanković, Dalibor, Kovačević, Vesna V., Roglić, Goran, Gojgić-Cvijović, Gordana D., Manojlović, Dragan D., "Application of non-thermal plasma reactor and Fenton reaction for degradation of ibuprofen" in Science of the Total Environment, 505 (2015):1148-1155,
https://doi.org/10.1016/j.scitotenv.2014.11.017 . .
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Electrochemical Degradation of Triketone Herbicides and Identification of Their Main Degradation Products

Jović, Milica; Manojlović, Dragan D.; Stanković, Dalibor; Gašić, Uroš M.; Jeremić, Dejan; Brčeski, Ilija; Roglić, Goran

(Wiley-Blackwell, Hoboken, 2015)

TY  - JOUR
AU  - Jović, Milica
AU  - Manojlović, Dragan D.
AU  - Stanković, Dalibor
AU  - Gašić, Uroš M.
AU  - Jeremić, Dejan
AU  - Brčeski, Ilija
AU  - Roglić, Goran
PY  - 2015
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1744
AB  - The aim of this paper was the development and optimization of an electrochemical method for the degradation of two triketone herbicides, mesotrione, and sulcotrione, in a two-electrode undivided electrochemical cell equipped with commercially available, non-modified, electrode materials. The electrochemical parameters studied included five different electrode systems (Zr/Pt, Pd/Pt, C/Pt, Nb/Pt, and Ti/Pt), current densities (27.66, 55.33, ..., 110.66 mA.cm(-2)) and pH values (3, 7, and 9) in 0.05 M sodium sulfate as supporting electrolyte. The electrical energy consumption and chemical oxygen demand were calculated for optimal conditions. The degradation efficiency was determined by high performance liquid chromatography (HPLC) equipped with a diode array detector, while the degradation products for both pesticides were identified and compared by ultra-high performance liquid chromatography (UHPLC)-mass spectrometry. The results could lead to an accurate estimate of their effect on the environment. A real water sample was used to study the influence of organic matter on pesticide degradation. Based on the results obtained the electrochemical treatment could be used for the successful removal of triketone herbicides from contaminated water.
PB  - Wiley-Blackwell, Hoboken
T2  - CLEAN - Soil Air Water
T1  - Electrochemical Degradation of Triketone Herbicides and Identification of Their Main Degradation Products
VL  - 43
IS  - 7
SP  - 1093
EP  - 1099
DO  - 10.1002/clen.201300951
ER  - 
@article{
author = "Jović, Milica and Manojlović, Dragan D. and Stanković, Dalibor and Gašić, Uroš M. and Jeremić, Dejan and Brčeski, Ilija and Roglić, Goran",
year = "2015",
abstract = "The aim of this paper was the development and optimization of an electrochemical method for the degradation of two triketone herbicides, mesotrione, and sulcotrione, in a two-electrode undivided electrochemical cell equipped with commercially available, non-modified, electrode materials. The electrochemical parameters studied included five different electrode systems (Zr/Pt, Pd/Pt, C/Pt, Nb/Pt, and Ti/Pt), current densities (27.66, 55.33, ..., 110.66 mA.cm(-2)) and pH values (3, 7, and 9) in 0.05 M sodium sulfate as supporting electrolyte. The electrical energy consumption and chemical oxygen demand were calculated for optimal conditions. The degradation efficiency was determined by high performance liquid chromatography (HPLC) equipped with a diode array detector, while the degradation products for both pesticides were identified and compared by ultra-high performance liquid chromatography (UHPLC)-mass spectrometry. The results could lead to an accurate estimate of their effect on the environment. A real water sample was used to study the influence of organic matter on pesticide degradation. Based on the results obtained the electrochemical treatment could be used for the successful removal of triketone herbicides from contaminated water.",
publisher = "Wiley-Blackwell, Hoboken",
journal = "CLEAN - Soil Air Water",
title = "Electrochemical Degradation of Triketone Herbicides and Identification of Their Main Degradation Products",
volume = "43",
number = "7",
pages = "1093-1099",
doi = "10.1002/clen.201300951"
}
Jović, M., Manojlović, D. D., Stanković, D., Gašić, U. M., Jeremić, D., Brčeski, I.,& Roglić, G.. (2015). Electrochemical Degradation of Triketone Herbicides and Identification of Their Main Degradation Products. in CLEAN - Soil Air Water
Wiley-Blackwell, Hoboken., 43(7), 1093-1099.
https://doi.org/10.1002/clen.201300951
Jović M, Manojlović DD, Stanković D, Gašić UM, Jeremić D, Brčeski I, Roglić G. Electrochemical Degradation of Triketone Herbicides and Identification of Their Main Degradation Products. in CLEAN - Soil Air Water. 2015;43(7):1093-1099.
doi:10.1002/clen.201300951 .
Jović, Milica, Manojlović, Dragan D., Stanković, Dalibor, Gašić, Uroš M., Jeremić, Dejan, Brčeski, Ilija, Roglić, Goran, "Electrochemical Degradation of Triketone Herbicides and Identification of Their Main Degradation Products" in CLEAN - Soil Air Water, 43, no. 7 (2015):1093-1099,
https://doi.org/10.1002/clen.201300951 . .
1
3
2
3
3

Microwave-hydrothermal synthesis of TiO2 and zirconium doped TiO2 adsorbents for removal of As(III) and As(V)

Anđelković, Ivan; Stanković, Dalibor; Jović, Milica; Marković, Marijana; Krstic, Jugoslav; Manojlović, Dragan D.; Roglić, Goran

(Elsevier Science Bv, Amsterdam, 2015)

TY  - JOUR
AU  - Anđelković, Ivan
AU  - Stanković, Dalibor
AU  - Jović, Milica
AU  - Marković, Marijana
AU  - Krstic, Jugoslav
AU  - Manojlović, Dragan D.
AU  - Roglić, Goran
PY  - 2015
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1726
AB  - Microwave-hydrothermal method was used for the synthesis of TiO2 and TiO2 doped with zirconium. The method was fast and simple and adsorbents were used for removal of As(III) and As(V) from aqueous solutions. The adsorbents were characterized by BET surface area measurements and powder XRD. Experiments showed that TiO2 doped with 10% of Zr using the microwave-hydrothermal method have greater specific surface area and total pore volume in comparison with TiO2 synthesized using the same method. Better removal with doped adsorbent was obtained for both, As(III) and As(V). Further experiments were carried out with Zr doped TiO2 sorbent in order to examine kinetic of adsorption, influence of pH and effect of common anions present in natural waters. (C) 2014 King Saud University. Production and hosting by Elsevier B.V. All rights reserved.
PB  - Elsevier Science Bv, Amsterdam
T2  - Journal of Saudi Chemical Society
T1  - Microwave-hydrothermal synthesis of TiO2 and zirconium doped TiO2 adsorbents for removal of As(III) and As(V)
VL  - 19
IS  - 4
SP  - 429
EP  - 435
DO  - 10.1016/j.jscs.2014.05.009
ER  - 
@article{
author = "Anđelković, Ivan and Stanković, Dalibor and Jović, Milica and Marković, Marijana and Krstic, Jugoslav and Manojlović, Dragan D. and Roglić, Goran",
year = "2015",
abstract = "Microwave-hydrothermal method was used for the synthesis of TiO2 and TiO2 doped with zirconium. The method was fast and simple and adsorbents were used for removal of As(III) and As(V) from aqueous solutions. The adsorbents were characterized by BET surface area measurements and powder XRD. Experiments showed that TiO2 doped with 10% of Zr using the microwave-hydrothermal method have greater specific surface area and total pore volume in comparison with TiO2 synthesized using the same method. Better removal with doped adsorbent was obtained for both, As(III) and As(V). Further experiments were carried out with Zr doped TiO2 sorbent in order to examine kinetic of adsorption, influence of pH and effect of common anions present in natural waters. (C) 2014 King Saud University. Production and hosting by Elsevier B.V. All rights reserved.",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Journal of Saudi Chemical Society",
title = "Microwave-hydrothermal synthesis of TiO2 and zirconium doped TiO2 adsorbents for removal of As(III) and As(V)",
volume = "19",
number = "4",
pages = "429-435",
doi = "10.1016/j.jscs.2014.05.009"
}
Anđelković, I., Stanković, D., Jović, M., Marković, M., Krstic, J., Manojlović, D. D.,& Roglić, G.. (2015). Microwave-hydrothermal synthesis of TiO2 and zirconium doped TiO2 adsorbents for removal of As(III) and As(V). in Journal of Saudi Chemical Society
Elsevier Science Bv, Amsterdam., 19(4), 429-435.
https://doi.org/10.1016/j.jscs.2014.05.009
Anđelković I, Stanković D, Jović M, Marković M, Krstic J, Manojlović DD, Roglić G. Microwave-hydrothermal synthesis of TiO2 and zirconium doped TiO2 adsorbents for removal of As(III) and As(V). in Journal of Saudi Chemical Society. 2015;19(4):429-435.
doi:10.1016/j.jscs.2014.05.009 .
Anđelković, Ivan, Stanković, Dalibor, Jović, Milica, Marković, Marijana, Krstic, Jugoslav, Manojlović, Dragan D., Roglić, Goran, "Microwave-hydrothermal synthesis of TiO2 and zirconium doped TiO2 adsorbents for removal of As(III) and As(V)" in Journal of Saudi Chemical Society, 19, no. 4 (2015):429-435,
https://doi.org/10.1016/j.jscs.2014.05.009 . .
1
12
7
14
12

Fenton-like oxidation of an azo dye using mesoporous Fe/TiO2 catalysts prepared by a microwave-assisted hydrothermal process

Nešić, Jelena; Manojlović, Dragan D.; Jović, Milica; Dojčinović, Biljana P.; Vulić, Predrag J.; Krstic, Jugoslav; Roglić, Goran

(Serbian Chemical Soc, Belgrade, 2014)

TY  - JOUR
AU  - Nešić, Jelena
AU  - Manojlović, Dragan D.
AU  - Jović, Milica
AU  - Dojčinović, Biljana P.
AU  - Vulić, Predrag J.
AU  - Krstic, Jugoslav
AU  - Roglić, Goran
PY  - 2014
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1835
AB  - Fe-doped TiO2 photocatalysts with different contents of Fe (0.5, 1.6, 3.4 and 6.4 %) were synthesized by a microwave-hydrothermal method and characterized by X-ray diffraction analysis, N-2 physisorption at 77 K and UV-Vis spectrometry. The characterization showed that the Fe ions were highly dispersed in the TiO2 lattice. It was found that all the synthesized catalysts had a mesoporous structure and that Fe-doping increased the BET surface area. The UV-Vis study showed that the absorption spectra were shifted to longer wavelengths (red shift) with increasing dopant concentration. The photocatalytic activity of the samples was evaluated by the decolorization of the textile dye Reactive Blue 52 (RB) in aqueous solutions under sun-like radiation in the presence of H2O2 (a heterogeneous photo-Fenton process). The photocatalyst with 3.4 % Fe was found to be the most efficient in the presence of H2O2. The effect of the initial pH of the dye solution was assessed and dissolution of iron ions was studied as a function of pH value. It was concluded that decolorization was more favorable in acidic pH, and that at pH values  gt 4, the release of Fe ions into the solution was negligible. Photocatalytic degradation of 4-chlorophenol (4-CP) was investigated under the optimal conditions and it was shown that the catalyst was capable of degrading colorless pollutants.
PB  - Serbian Chemical Soc, Belgrade
T2  - Journal of the Serbian Chemical Society
T1  - Fenton-like oxidation of an azo dye using mesoporous Fe/TiO2 catalysts prepared by a microwave-assisted hydrothermal process
VL  - 79
IS  - 8
SP  - 977
EP  - 991
DO  - 10.2298/JSC131001143N
ER  - 
@article{
author = "Nešić, Jelena and Manojlović, Dragan D. and Jović, Milica and Dojčinović, Biljana P. and Vulić, Predrag J. and Krstic, Jugoslav and Roglić, Goran",
year = "2014",
abstract = "Fe-doped TiO2 photocatalysts with different contents of Fe (0.5, 1.6, 3.4 and 6.4 %) were synthesized by a microwave-hydrothermal method and characterized by X-ray diffraction analysis, N-2 physisorption at 77 K and UV-Vis spectrometry. The characterization showed that the Fe ions were highly dispersed in the TiO2 lattice. It was found that all the synthesized catalysts had a mesoporous structure and that Fe-doping increased the BET surface area. The UV-Vis study showed that the absorption spectra were shifted to longer wavelengths (red shift) with increasing dopant concentration. The photocatalytic activity of the samples was evaluated by the decolorization of the textile dye Reactive Blue 52 (RB) in aqueous solutions under sun-like radiation in the presence of H2O2 (a heterogeneous photo-Fenton process). The photocatalyst with 3.4 % Fe was found to be the most efficient in the presence of H2O2. The effect of the initial pH of the dye solution was assessed and dissolution of iron ions was studied as a function of pH value. It was concluded that decolorization was more favorable in acidic pH, and that at pH values  gt 4, the release of Fe ions into the solution was negligible. Photocatalytic degradation of 4-chlorophenol (4-CP) was investigated under the optimal conditions and it was shown that the catalyst was capable of degrading colorless pollutants.",
publisher = "Serbian Chemical Soc, Belgrade",
journal = "Journal of the Serbian Chemical Society",
title = "Fenton-like oxidation of an azo dye using mesoporous Fe/TiO2 catalysts prepared by a microwave-assisted hydrothermal process",
volume = "79",
number = "8",
pages = "977-991",
doi = "10.2298/JSC131001143N"
}
Nešić, J., Manojlović, D. D., Jović, M., Dojčinović, B. P., Vulić, P. J., Krstic, J.,& Roglić, G.. (2014). Fenton-like oxidation of an azo dye using mesoporous Fe/TiO2 catalysts prepared by a microwave-assisted hydrothermal process. in Journal of the Serbian Chemical Society
Serbian Chemical Soc, Belgrade., 79(8), 977-991.
https://doi.org/10.2298/JSC131001143N
Nešić J, Manojlović DD, Jović M, Dojčinović BP, Vulić PJ, Krstic J, Roglić G. Fenton-like oxidation of an azo dye using mesoporous Fe/TiO2 catalysts prepared by a microwave-assisted hydrothermal process. in Journal of the Serbian Chemical Society. 2014;79(8):977-991.
doi:10.2298/JSC131001143N .
Nešić, Jelena, Manojlović, Dragan D., Jović, Milica, Dojčinović, Biljana P., Vulić, Predrag J., Krstic, Jugoslav, Roglić, Goran, "Fenton-like oxidation of an azo dye using mesoporous Fe/TiO2 catalysts prepared by a microwave-assisted hydrothermal process" in Journal of the Serbian Chemical Society, 79, no. 8 (2014):977-991,
https://doi.org/10.2298/JSC131001143N . .
10
10
11
9

Electrochemical Treatment of Reactive Blue 52 Using Zirconium, Palladium and Graphite Electrode

Jović, Milica; Manojlović, Dragan D.; Stanković, Dalibor; Marković, Marijana; Anđelković, Ivan; Papan, Jelena; Roglić, Goran

(Wiley-Blackwell, Hoboken, 2014)

TY  - JOUR
AU  - Jović, Milica
AU  - Manojlović, Dragan D.
AU  - Stanković, Dalibor
AU  - Marković, Marijana
AU  - Anđelković, Ivan
AU  - Papan, Jelena
AU  - Roglić, Goran
PY  - 2014
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1789
AB  - Electrochemical treatment is a new trend for the purification of textile industry wastewater which containing azo dyes. In this paper the electrochemical treatment was used for decolorization of azo dye Reactive Blue 52. The efficiency of decolorization was compared for different electrochemical systems which were all equipped with Fisher platinum electrode as anode and a different cathode (Zr, Pd, C) in sodium sulfate as supporting electrolyte. In order to find optimal conditions the influence of various voltage and pH values of initial dye solution was studied. Decolorization rate was monitored by spectrophotometer while degradation products were identified by high performance liquid chromatography-diode array detector (HPLC-DAD). Results of HPLC analysis confirmed presence of various degradation products in electrochemical systems, which indicated different mechanism of degradation. This was also confirmed by Ek-t curve. In terms of power consumption the most cost effective system was with the graphite cathode (C/Pt).
PB  - Wiley-Blackwell, Hoboken
T2  - CLEAN - Soil Air Water
T1  - Electrochemical Treatment of Reactive Blue 52 Using Zirconium, Palladium and Graphite Electrode
VL  - 42
IS  - 6
SP  - 804
EP  - 808
DO  - 10.1002/clen.201300245
ER  - 
@article{
author = "Jović, Milica and Manojlović, Dragan D. and Stanković, Dalibor and Marković, Marijana and Anđelković, Ivan and Papan, Jelena and Roglić, Goran",
year = "2014",
abstract = "Electrochemical treatment is a new trend for the purification of textile industry wastewater which containing azo dyes. In this paper the electrochemical treatment was used for decolorization of azo dye Reactive Blue 52. The efficiency of decolorization was compared for different electrochemical systems which were all equipped with Fisher platinum electrode as anode and a different cathode (Zr, Pd, C) in sodium sulfate as supporting electrolyte. In order to find optimal conditions the influence of various voltage and pH values of initial dye solution was studied. Decolorization rate was monitored by spectrophotometer while degradation products were identified by high performance liquid chromatography-diode array detector (HPLC-DAD). Results of HPLC analysis confirmed presence of various degradation products in electrochemical systems, which indicated different mechanism of degradation. This was also confirmed by Ek-t curve. In terms of power consumption the most cost effective system was with the graphite cathode (C/Pt).",
publisher = "Wiley-Blackwell, Hoboken",
journal = "CLEAN - Soil Air Water",
title = "Electrochemical Treatment of Reactive Blue 52 Using Zirconium, Palladium and Graphite Electrode",
volume = "42",
number = "6",
pages = "804-808",
doi = "10.1002/clen.201300245"
}
Jović, M., Manojlović, D. D., Stanković, D., Marković, M., Anđelković, I., Papan, J.,& Roglić, G.. (2014). Electrochemical Treatment of Reactive Blue 52 Using Zirconium, Palladium and Graphite Electrode. in CLEAN - Soil Air Water
Wiley-Blackwell, Hoboken., 42(6), 804-808.
https://doi.org/10.1002/clen.201300245
Jović M, Manojlović DD, Stanković D, Marković M, Anđelković I, Papan J, Roglić G. Electrochemical Treatment of Reactive Blue 52 Using Zirconium, Palladium and Graphite Electrode. in CLEAN - Soil Air Water. 2014;42(6):804-808.
doi:10.1002/clen.201300245 .
Jović, Milica, Manojlović, Dragan D., Stanković, Dalibor, Marković, Marijana, Anđelković, Ivan, Papan, Jelena, Roglić, Goran, "Electrochemical Treatment of Reactive Blue 52 Using Zirconium, Palladium and Graphite Electrode" in CLEAN - Soil Air Water, 42, no. 6 (2014):804-808,
https://doi.org/10.1002/clen.201300245 . .
5
4
5
4

Toxicity Screening after Electrochemical Degradation of Reactive Textile Dyes

Marković, Marijana; Jović, Milica; Stanković, Dalibor; Mutić, Jelena; Roglić, Goran; Manojlović, Dragan D.

(Hard, Olsztyn 5, 2014)

TY  - JOUR
AU  - Marković, Marijana
AU  - Jović, Milica
AU  - Stanković, Dalibor
AU  - Mutić, Jelena
AU  - Roglić, Goran
AU  - Manojlović, Dragan D.
PY  - 2014
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1896
AB  - The application of various electrodes for in situ degradation of Reactive Yellow 125 (RY125) and Reactive Green 15 (RG15) dyes, as well as ecotoxicity screening test of their degradation products were studied in this paper. The degradation process was performed in a two-electrode cylindrical cell, with Fisher platinum electrode as anode and Pd, Zr, or C electrodes as cathode; in 0.1 M Na2SO4 as supporting electrolyte. The optimal conditions (voltage and pH value) for degradation were determined in a platinum-palladium (Pt-Pd) model system for 200 mg/L of both reactive dyes. Then the electrolysis with other electrodes was conducted under the same conditions. Decolorization was monitored spectrofotometrically (UV-Vis) and the degradation efficiency was confirmed by HPLC technique with a DAD detector. Differences in degradation efficiency were observed between these three electrochemical systems (Pt-Pd, Pt-Zr, and Pt-C). The Pt-Pd system was the most efficient for the degradation of both reactive dyes. Achieved decolorization percentage for RG15 and RY125 were 98% and 97%, respectively. The ecotoxicity assessment of degradation products was performed using Anemia sauna. Toxicity data were compared by Kruskal-Wallis one-way analysis and pair-wise group comparisons with Mann-Whitney U tests. Statistically significant differences (p lt 0.05) in mortality (%) for Pt-Pd and Pt-Zr systems were determined between treated and untreated dye solutions of RG15. System Pt-C had no detectable significance in treatment of solutions of both dyes.
PB  - Hard, Olsztyn 5
T2  - Polish Journal of Environmental Studies
T1  - Toxicity Screening after Electrochemical Degradation of Reactive Textile Dyes
VL  - 23
IS  - 6
SP  - 2103
EP  - 2109
UR  - https://hdl.handle.net/21.15107/rcub_cherry_1896
ER  - 
@article{
author = "Marković, Marijana and Jović, Milica and Stanković, Dalibor and Mutić, Jelena and Roglić, Goran and Manojlović, Dragan D.",
year = "2014",
abstract = "The application of various electrodes for in situ degradation of Reactive Yellow 125 (RY125) and Reactive Green 15 (RG15) dyes, as well as ecotoxicity screening test of their degradation products were studied in this paper. The degradation process was performed in a two-electrode cylindrical cell, with Fisher platinum electrode as anode and Pd, Zr, or C electrodes as cathode; in 0.1 M Na2SO4 as supporting electrolyte. The optimal conditions (voltage and pH value) for degradation were determined in a platinum-palladium (Pt-Pd) model system for 200 mg/L of both reactive dyes. Then the electrolysis with other electrodes was conducted under the same conditions. Decolorization was monitored spectrofotometrically (UV-Vis) and the degradation efficiency was confirmed by HPLC technique with a DAD detector. Differences in degradation efficiency were observed between these three electrochemical systems (Pt-Pd, Pt-Zr, and Pt-C). The Pt-Pd system was the most efficient for the degradation of both reactive dyes. Achieved decolorization percentage for RG15 and RY125 were 98% and 97%, respectively. The ecotoxicity assessment of degradation products was performed using Anemia sauna. Toxicity data were compared by Kruskal-Wallis one-way analysis and pair-wise group comparisons with Mann-Whitney U tests. Statistically significant differences (p lt 0.05) in mortality (%) for Pt-Pd and Pt-Zr systems were determined between treated and untreated dye solutions of RG15. System Pt-C had no detectable significance in treatment of solutions of both dyes.",
publisher = "Hard, Olsztyn 5",
journal = "Polish Journal of Environmental Studies",
title = "Toxicity Screening after Electrochemical Degradation of Reactive Textile Dyes",
volume = "23",
number = "6",
pages = "2103-2109",
url = "https://hdl.handle.net/21.15107/rcub_cherry_1896"
}
Marković, M., Jović, M., Stanković, D., Mutić, J., Roglić, G.,& Manojlović, D. D.. (2014). Toxicity Screening after Electrochemical Degradation of Reactive Textile Dyes. in Polish Journal of Environmental Studies
Hard, Olsztyn 5., 23(6), 2103-2109.
https://hdl.handle.net/21.15107/rcub_cherry_1896
Marković M, Jović M, Stanković D, Mutić J, Roglić G, Manojlović DD. Toxicity Screening after Electrochemical Degradation of Reactive Textile Dyes. in Polish Journal of Environmental Studies. 2014;23(6):2103-2109.
https://hdl.handle.net/21.15107/rcub_cherry_1896 .
Marković, Marijana, Jović, Milica, Stanković, Dalibor, Mutić, Jelena, Roglić, Goran, Manojlović, Dragan D., "Toxicity Screening after Electrochemical Degradation of Reactive Textile Dyes" in Polish Journal of Environmental Studies, 23, no. 6 (2014):2103-2109,
https://hdl.handle.net/21.15107/rcub_cherry_1896 .
6
9

Degradation of triketone herbicides, mesotrione and sulcotrione, using advanced oxidation processes

Jović, Milica; Manojlović, Dragan D.; Stanković, Dalibor; Dojčinović, Biljana P.; Obradović, Bratislav M.; Gašić, Uroš M.; Roglić, Goran

(Elsevier Science Bv, Amsterdam, 2013)

TY  - JOUR
AU  - Jović, Milica
AU  - Manojlović, Dragan D.
AU  - Stanković, Dalibor
AU  - Dojčinović, Biljana P.
AU  - Obradović, Bratislav M.
AU  - Gašić, Uroš M.
AU  - Roglić, Goran
PY  - 2013
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1400
AB  - Degradation of two triketone herbicides, mesotrione and sulcotrione, was studied using four different advanced oxidation processes (AOPs): ozonization, dielectric barrier discharge (DBD reactor), photocatalysis and Fenton reagent, in order to find differences in mechanism of degradation. Degradation products were identified by high performance liquid chromatography (HPLC-DAD) and UHPLC-Orbitrap-MS analyses. A simple mechanism of degradation for different AOP was proposed. Thirteen products were identified during all degradations for both pesticides. It was assumed that the oxidation mechanisms in the all four technologies were not based only on the production and use of the hydroxyl radical, but they also included other kinds of oxidation mechanisms specific for each technology. Similarity was observed between degradation mechanism of ozonation and DBD. The greatest difference in the products was found in Fenton degradation which included the opening of benzene ring. When degraded with same AOP pesticides gave at the end of treatment the same products. Global toxicity and COD value of samples was determined after all degradations. Real water sample was used to study influence of organic matter on pesticide degradation. These results could lead to accurate estimates of the overall effects of triketone herbicides on environmental ecosystems and also contributed to the development of improved removal processes.
PB  - Elsevier Science Bv, Amsterdam
T2  - Journal of Hazardous Materials
T1  - Degradation of triketone herbicides, mesotrione and sulcotrione, using advanced oxidation processes
VL  - 260
SP  - 1092
EP  - 1099
DO  - 10.1016/j.jhazmat.2013.06.073
ER  - 
@article{
author = "Jović, Milica and Manojlović, Dragan D. and Stanković, Dalibor and Dojčinović, Biljana P. and Obradović, Bratislav M. and Gašić, Uroš M. and Roglić, Goran",
year = "2013",
abstract = "Degradation of two triketone herbicides, mesotrione and sulcotrione, was studied using four different advanced oxidation processes (AOPs): ozonization, dielectric barrier discharge (DBD reactor), photocatalysis and Fenton reagent, in order to find differences in mechanism of degradation. Degradation products were identified by high performance liquid chromatography (HPLC-DAD) and UHPLC-Orbitrap-MS analyses. A simple mechanism of degradation for different AOP was proposed. Thirteen products were identified during all degradations for both pesticides. It was assumed that the oxidation mechanisms in the all four technologies were not based only on the production and use of the hydroxyl radical, but they also included other kinds of oxidation mechanisms specific for each technology. Similarity was observed between degradation mechanism of ozonation and DBD. The greatest difference in the products was found in Fenton degradation which included the opening of benzene ring. When degraded with same AOP pesticides gave at the end of treatment the same products. Global toxicity and COD value of samples was determined after all degradations. Real water sample was used to study influence of organic matter on pesticide degradation. These results could lead to accurate estimates of the overall effects of triketone herbicides on environmental ecosystems and also contributed to the development of improved removal processes.",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Journal of Hazardous Materials",
title = "Degradation of triketone herbicides, mesotrione and sulcotrione, using advanced oxidation processes",
volume = "260",
pages = "1092-1099",
doi = "10.1016/j.jhazmat.2013.06.073"
}
Jović, M., Manojlović, D. D., Stanković, D., Dojčinović, B. P., Obradović, B. M., Gašić, U. M.,& Roglić, G.. (2013). Degradation of triketone herbicides, mesotrione and sulcotrione, using advanced oxidation processes. in Journal of Hazardous Materials
Elsevier Science Bv, Amsterdam., 260, 1092-1099.
https://doi.org/10.1016/j.jhazmat.2013.06.073
Jović M, Manojlović DD, Stanković D, Dojčinović BP, Obradović BM, Gašić UM, Roglić G. Degradation of triketone herbicides, mesotrione and sulcotrione, using advanced oxidation processes. in Journal of Hazardous Materials. 2013;260:1092-1099.
doi:10.1016/j.jhazmat.2013.06.073 .
Jović, Milica, Manojlović, Dragan D., Stanković, Dalibor, Dojčinović, Biljana P., Obradović, Bratislav M., Gašić, Uroš M., Roglić, Goran, "Degradation of triketone herbicides, mesotrione and sulcotrione, using advanced oxidation processes" in Journal of Hazardous Materials, 260 (2013):1092-1099,
https://doi.org/10.1016/j.jhazmat.2013.06.073 . .
68
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64

Study of the Electrochemical Oxidation of Reactive Textile Dyes Using Platinum Electrode

Jović, Milica; Stanković, Dalibor; Manojlović, Dragan D.; Anđelković, Ivan; Milić, Anđelija; Dojčinović, Biljana P.; Roglić, Goran

(Esg, Belgrade, 2013)

TY  - JOUR
AU  - Jović, Milica
AU  - Stanković, Dalibor
AU  - Manojlović, Dragan D.
AU  - Anđelković, Ivan
AU  - Milić, Anđelija
AU  - Dojčinović, Biljana P.
AU  - Roglić, Goran
PY  - 2013
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1615
AB  - Textile industries are widespread in developing countries. Among the various processes in the textile industry, the dyeing process uses large volumes of water for dyeing, fixing and washing. Textile industry wastewater is characterized by intensive color and high chemical oxygen demand (COD) concentrations that discarding of these toxic wastewaters to the environment will cause a major problem. In this study electrochemical oxidation of reactive textile dyes: Reactive Blue 52, Reactive Black 5, Reactive Green 15, and Reactive Yellow 125, using platinum anode was examined. Electrolysis is carried out in electrochemical cell containing membrane which is standard membrane in industry. Membrane separated anodic and cathodic area. Supporting electrolyte was 0.1M sodium sulfate which is also present in real textile effluents. Applied voltage of 6, 12 and 24V, and influence of membrane on electrolysis were examined on model dye (Reactive Blue 52). Highest degradation degree for model dye was achieved at 12V, so electrolysis of other dyes was done on this voltage. COD value of all dyes dropped after 60 minutes of electrolysis below a measurable level ( lt 30mg/L O-2), except Reactive Black 5 whose COD reduction was 57.95% with membrane and 35.28% without membrane applied. Complete decolorization was achieved after 10 to 60 minutes for all dyes. Degradation products of model dye Reactive Blue 52 were monitored with HPLC, and influence of pH on decolorization was also examined on model dye.
PB  - Esg, Belgrade
T2  - International Journal of Electrochemical Science
T1  - Study of the Electrochemical Oxidation of Reactive Textile Dyes Using Platinum Electrode
VL  - 8
IS  - 1
SP  - 168
EP  - 183
UR  - https://hdl.handle.net/21.15107/rcub_cherry_1615
ER  - 
@article{
author = "Jović, Milica and Stanković, Dalibor and Manojlović, Dragan D. and Anđelković, Ivan and Milić, Anđelija and Dojčinović, Biljana P. and Roglić, Goran",
year = "2013",
abstract = "Textile industries are widespread in developing countries. Among the various processes in the textile industry, the dyeing process uses large volumes of water for dyeing, fixing and washing. Textile industry wastewater is characterized by intensive color and high chemical oxygen demand (COD) concentrations that discarding of these toxic wastewaters to the environment will cause a major problem. In this study electrochemical oxidation of reactive textile dyes: Reactive Blue 52, Reactive Black 5, Reactive Green 15, and Reactive Yellow 125, using platinum anode was examined. Electrolysis is carried out in electrochemical cell containing membrane which is standard membrane in industry. Membrane separated anodic and cathodic area. Supporting electrolyte was 0.1M sodium sulfate which is also present in real textile effluents. Applied voltage of 6, 12 and 24V, and influence of membrane on electrolysis were examined on model dye (Reactive Blue 52). Highest degradation degree for model dye was achieved at 12V, so electrolysis of other dyes was done on this voltage. COD value of all dyes dropped after 60 minutes of electrolysis below a measurable level ( lt 30mg/L O-2), except Reactive Black 5 whose COD reduction was 57.95% with membrane and 35.28% without membrane applied. Complete decolorization was achieved after 10 to 60 minutes for all dyes. Degradation products of model dye Reactive Blue 52 were monitored with HPLC, and influence of pH on decolorization was also examined on model dye.",
publisher = "Esg, Belgrade",
journal = "International Journal of Electrochemical Science",
title = "Study of the Electrochemical Oxidation of Reactive Textile Dyes Using Platinum Electrode",
volume = "8",
number = "1",
pages = "168-183",
url = "https://hdl.handle.net/21.15107/rcub_cherry_1615"
}
Jović, M., Stanković, D., Manojlović, D. D., Anđelković, I., Milić, A., Dojčinović, B. P.,& Roglić, G.. (2013). Study of the Electrochemical Oxidation of Reactive Textile Dyes Using Platinum Electrode. in International Journal of Electrochemical Science
Esg, Belgrade., 8(1), 168-183.
https://hdl.handle.net/21.15107/rcub_cherry_1615
Jović M, Stanković D, Manojlović DD, Anđelković I, Milić A, Dojčinović BP, Roglić G. Study of the Electrochemical Oxidation of Reactive Textile Dyes Using Platinum Electrode. in International Journal of Electrochemical Science. 2013;8(1):168-183.
https://hdl.handle.net/21.15107/rcub_cherry_1615 .
Jović, Milica, Stanković, Dalibor, Manojlović, Dragan D., Anđelković, Ivan, Milić, Anđelija, Dojčinović, Biljana P., Roglić, Goran, "Study of the Electrochemical Oxidation of Reactive Textile Dyes Using Platinum Electrode" in International Journal of Electrochemical Science, 8, no. 1 (2013):168-183,
https://hdl.handle.net/21.15107/rcub_cherry_1615 .
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