TY  - JOUR
AU  - Milutinovic, Milena
AU  - Sallard, Sebastien
AU  - Manojlović, Dragan D.
AU  - Mano, Nicolas
AU  - Šojić, Nešo
PY  - 2011
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1203
AB  - In this work, we report a new sensing approach based on electrogenerated chemiluminescence (ECL) in an electrodeposited redox hydrogel using glucose dehydrogenase as a model system. The ECL-hydrogel films were electrodeposited by potential cycling of a PBS solution containing [poly(4-vinylpyridine)Ru(2,2'-bipyridine)(2) Cl-](+/2+). The film was easily prepared in a rapid, reproducible and well-controlled one-step procedure. The deposited hydrogel film is permeable to water-soluble chemicals and biochemicals, like enzyme substrates and coenzymes. Electrochemistry and ECL of NADH were studied at the level of the hydrogel film. Results indicate that ECL emission occurs at a relatively low anodic potential compared to the classical Ru(bipy)(3)(2+) complex. This is an important advantage since the measurements performed with the ECL hydrogel are thus less sensitive to interfering species. An ECL oxidative-reductive mechanism is presented for the ECL-hydrogel. Then we showed that the intensity of the ECL of NADH produced by the enzymatic activity varies with the enzyme substrate concentration. Such sensing approach combines enzymatic selectivity with the ECL advantages at low oxidation potential. (C) 2011 Elsevier B.V. All rights reserved.
PB  - Elsevier Science Sa, Lausanne
T2  - Bioelectrochemistry
T1  - Glucose sensing by electrogenerated chemiluminescence of glucose-dehydrogenase produced NADH on electrodeposited redox hydrogel
VL  - 82
IS  - 1
SP  - 63
EP  - 68
DO  - 10.1016/j.bioelechem.2011.05.005
ER  - 

@article{
author = "Milutinovic, Milena and Sallard, Sebastien and Manojlović, Dragan D. and Mano, Nicolas and Šojić, Nešo",
year = "2011",
abstract = "In this work, we report a new sensing approach based on electrogenerated chemiluminescence (ECL) in an electrodeposited redox hydrogel using glucose dehydrogenase as a model system. The ECL-hydrogel films were electrodeposited by potential cycling of a PBS solution containing [poly(4-vinylpyridine)Ru(2,2'-bipyridine)(2) Cl-](+/2+). The film was easily prepared in a rapid, reproducible and well-controlled one-step procedure. The deposited hydrogel film is permeable to water-soluble chemicals and biochemicals, like enzyme substrates and coenzymes. Electrochemistry and ECL of NADH were studied at the level of the hydrogel film. Results indicate that ECL emission occurs at a relatively low anodic potential compared to the classical Ru(bipy)(3)(2+) complex. This is an important advantage since the measurements performed with the ECL hydrogel are thus less sensitive to interfering species. An ECL oxidative-reductive mechanism is presented for the ECL-hydrogel. Then we showed that the intensity of the ECL of NADH produced by the enzymatic activity varies with the enzyme substrate concentration. Such sensing approach combines enzymatic selectivity with the ECL advantages at low oxidation potential. (C) 2011 Elsevier B.V. All rights reserved.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Bioelectrochemistry",
title = "Glucose sensing by electrogenerated chemiluminescence of glucose-dehydrogenase produced NADH on electrodeposited redox hydrogel",
volume = "82",
number = "1",
pages = "63-68",
doi = "10.1016/j.bioelechem.2011.05.005"
}

Milutinovic, M., Sallard, S., Manojlović, D. D., Mano, N.,& Šojić, N.. (2011). Glucose sensing by electrogenerated chemiluminescence of glucose-dehydrogenase produced NADH on electrodeposited redox hydrogel. in Bioelectrochemistry
Elsevier Science Sa, Lausanne., 82(1), 63-68.
https://doi.org/10.1016/j.bioelechem.2011.05.005

Milutinovic M, Sallard S, Manojlović DD, Mano N, Šojić N. Glucose sensing by electrogenerated chemiluminescence of glucose-dehydrogenase produced NADH on electrodeposited redox hydrogel. in Bioelectrochemistry. 2011;82(1):63-68.
doi:10.1016/j.bioelechem.2011.05.005 .

Milutinovic, Milena, Sallard, Sebastien, Manojlović, Dragan D., Mano, Nicolas, Šojić, Nešo, "Glucose sensing by electrogenerated chemiluminescence of glucose-dehydrogenase produced NADH on electrodeposited redox hydrogel" in Bioelectrochemistry, 82, no. 1 (2011):63-68,
https://doi.org/10.1016/j.bioelechem.2011.05.005 . .

TY  - CONF
AU  - Milutinovic, Milena
AU  - Sallard, Sebastien
AU  - Manojlović, Dragan D.
AU  - Mano, Nicolas
AU  - Šojić, Nešo
PY  - 2010
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1074
PB  - John Wiley & Sons Ltd, Chichester
C3  - Luminescence
T1  - Electrogenerated chemiluminescence in an electrodeposited redox polymer
VL  - 25
IS  - 2
SP  - 85
EP  - 85
UR  - https://hdl.handle.net/21.15107/rcub_cherry_1074
ER  - 

@conference{
author = "Milutinovic, Milena and Sallard, Sebastien and Manojlović, Dragan D. and Mano, Nicolas and Šojić, Nešo",
year = "2010",
publisher = "John Wiley & Sons Ltd, Chichester",
journal = "Luminescence",
title = "Electrogenerated chemiluminescence in an electrodeposited redox polymer",
volume = "25",
number = "2",
pages = "85-85",
url = "https://hdl.handle.net/21.15107/rcub_cherry_1074"
}

Milutinovic, M., Sallard, S., Manojlović, D. D., Mano, N.,& Šojić, N.. (2010). Electrogenerated chemiluminescence in an electrodeposited redox polymer. in Luminescence
John Wiley & Sons Ltd, Chichester., 25(2), 85-85.
https://hdl.handle.net/21.15107/rcub_cherry_1074

Milutinovic M, Sallard S, Manojlović DD, Mano N, Šojić N. Electrogenerated chemiluminescence in an electrodeposited redox polymer. in Luminescence. 2010;25(2):85-85.
https://hdl.handle.net/21.15107/rcub_cherry_1074 .

Milutinovic, Milena, Sallard, Sebastien, Manojlović, Dragan D., Mano, Nicolas, Šojić, Nešo, "Electrogenerated chemiluminescence in an electrodeposited redox polymer" in Luminescence, 25, no. 2 (2010):85-85,
https://hdl.handle.net/21.15107/rcub_cherry_1074 .