TY  - CONF
AU  - Kasalica, Kristina
AU  - Jimenez, Begona
AU  - Yamamoto, Atsushi
AU  - Inui, Hideyuki
AU  - Lješević, Marija
AU  - Radić, Nenad
AU  - Gojgić-Cvijović, Gordana D.
AU  - Slavković Beškoski, Latinka
AU  - Radulović, Jelena
AU  - Nakano, Takeshi
AU  - Beškoski, Vladimir
PY  - 2023
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/6405
AB  - Danas se u životnoj sredini mogu pronaći brojna hemijska jedinjenja koja je stvorio
čovek u svojim laboratorijama. Ideja vodilja sredinom dvadesetog veka je bila kreirati
jedinjenja kvalitetnih osobina koja će dugo imati upotrebnu vrednost a samim tim i dugo
trajati. Neka od tih jedinjenja su danas prepoznata i kao „večne hemikalije”. Per- i
polifluorovana jedinjenja (PFAS) su grupa sintetičkih hemijskih jedinjenja koja poseduju C-
F, najjaču kovalentnu vezu. Zbog hemijske strukture koja im omogućava stabilnost na
povišenim temperaturama, otpornost na niske pH vrednosti kao i visoku površinsku
aktivnost, ova jedinjenja su u vidu različitih formulacija već nekoliko decenija našla široku
primenu u brojnim potrošačkim proizvodima. Međutim, PFAS su poslednje dve decenije
otkriveni u vodi, zemljištu, sedimentu, vazduhu, hrani i uzorcima biote na svim
kontinentima, što prepoznato kao rizik za životnu sredinu i zdravlje ljudi. Zbog ovoga su
u poslednjoj deceniji intenzivno testirane postojeće tehnologije za sanaciju i remedijaciju
poput adsorpcije, filtracije, termalne destrukcije, oksidacije/redukcije kao i pranje zemljišta.
Ipak, opisani su i brojni nedostaci ovih tehnologija.
PB  - Belgrade : Serbian Chemical Society
C3  - 9th Symposium Chemistry and Environmental Protection EnviroChem2023, Book of Abstract, 4-7 June 2023, Kladovo, Serbia
T1  - Per- and Polyfluorinated Substances, 'forever chemicals' (or maybe not)
SP  - 41
EP  - 42
UR  - https://hdl.handle.net/21.15107/rcub_cherry_6405
ER  - 

@conference{
author = "Kasalica, Kristina and Jimenez, Begona and Yamamoto, Atsushi and Inui, Hideyuki and Lješević, Marija and Radić, Nenad and Gojgić-Cvijović, Gordana D. and Slavković Beškoski, Latinka and Radulović, Jelena and Nakano, Takeshi and Beškoski, Vladimir",
year = "2023",
abstract = "Danas se u životnoj sredini mogu pronaći brojna hemijska jedinjenja koja je stvorio
čovek u svojim laboratorijama. Ideja vodilja sredinom dvadesetog veka je bila kreirati
jedinjenja kvalitetnih osobina koja će dugo imati upotrebnu vrednost a samim tim i dugo
trajati. Neka od tih jedinjenja su danas prepoznata i kao „večne hemikalije”. Per- i
polifluorovana jedinjenja (PFAS) su grupa sintetičkih hemijskih jedinjenja koja poseduju C-
F, najjaču kovalentnu vezu. Zbog hemijske strukture koja im omogućava stabilnost na
povišenim temperaturama, otpornost na niske pH vrednosti kao i visoku površinsku
aktivnost, ova jedinjenja su u vidu različitih formulacija već nekoliko decenija našla široku
primenu u brojnim potrošačkim proizvodima. Međutim, PFAS su poslednje dve decenije
otkriveni u vodi, zemljištu, sedimentu, vazduhu, hrani i uzorcima biote na svim
kontinentima, što prepoznato kao rizik za životnu sredinu i zdravlje ljudi. Zbog ovoga su
u poslednjoj deceniji intenzivno testirane postojeće tehnologije za sanaciju i remedijaciju
poput adsorpcije, filtracije, termalne destrukcije, oksidacije/redukcije kao i pranje zemljišta.
Ipak, opisani su i brojni nedostaci ovih tehnologija.",
publisher = "Belgrade : Serbian Chemical Society",
journal = "9th Symposium Chemistry and Environmental Protection EnviroChem2023, Book of Abstract, 4-7 June 2023, Kladovo, Serbia",
title = "Per- and Polyfluorinated Substances, 'forever chemicals' (or maybe not)",
pages = "41-42",
url = "https://hdl.handle.net/21.15107/rcub_cherry_6405"
}

Kasalica, K., Jimenez, B., Yamamoto, A., Inui, H., Lješević, M., Radić, N., Gojgić-Cvijović, G. D., Slavković Beškoski, L., Radulović, J., Nakano, T.,& Beškoski, V.. (2023). Per- and Polyfluorinated Substances, 'forever chemicals' (or maybe not). in 9th Symposium Chemistry and Environmental Protection EnviroChem2023, Book of Abstract, 4-7 June 2023, Kladovo, Serbia
Belgrade : Serbian Chemical Society., 41-42.
https://hdl.handle.net/21.15107/rcub_cherry_6405

Kasalica K, Jimenez B, Yamamoto A, Inui H, Lješević M, Radić N, Gojgić-Cvijović GD, Slavković Beškoski L, Radulović J, Nakano T, Beškoski V. Per- and Polyfluorinated Substances, 'forever chemicals' (or maybe not). in 9th Symposium Chemistry and Environmental Protection EnviroChem2023, Book of Abstract, 4-7 June 2023, Kladovo, Serbia. 2023;:41-42.
https://hdl.handle.net/21.15107/rcub_cherry_6405 .

Kasalica, Kristina, Jimenez, Begona, Yamamoto, Atsushi, Inui, Hideyuki, Lješević, Marija, Radić, Nenad, Gojgić-Cvijović, Gordana D., Slavković Beškoski, Latinka, Radulović, Jelena, Nakano, Takeshi, Beškoski, Vladimir, "Per- and Polyfluorinated Substances, 'forever chemicals' (or maybe not)" in 9th Symposium Chemistry and Environmental Protection EnviroChem2023, Book of Abstract, 4-7 June 2023, Kladovo, Serbia (2023):41-42,
https://hdl.handle.net/21.15107/rcub_cherry_6405 .

TY  - CONF
AU  - Kasalica, Kristina
AU  - Jiménez, Begoña
AU  - Yamamoto, Atsushi
AU  - Inui, Hideyuki
AU  - Lješević, Marija
AU  - Radić, Nenad
AU  - Gojgić-Cvijović, Gordana D.
AU  - Slavković-Beškoski, Latinka
AU  - Radulović, Jelena
AU  - Nakano, Takeshi
AU  - Beškoski, Vladimir
PY  - 2023
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/6410
AB  - Per- and polyfluoroalkyl substances (PFAS) are a group of synthetic chemicals with extremely strong C-F bonds. Due to their thermal stability, acid resistance, and high surface activity, they have been widely used for several decades in various consumer products. PFAS has been detected in water, soil, sediment, air, food, and biota samples on all continents and due to this are recognized as environmental and human health risk (Carlson et al. 2022). In the last decade, several available technologies were tested for the remediation of PFAS-polluted environments, such as adsorption, filtration, thermal destruction, oxidation/reduction, and soil washing, but several disadvantages were reported (Bolan et al., 2021). We hypothesize that by using advanced oxidation techniques followed by microbial treatment decrease in the concentration of PFOA as a PFAS model compound will occur. In the beginning, we tested separately abiotic and biotic degradation of PFOA. Target LC-MS/MS was used for quantitative analysis of PFOA decrease, and for detecting degradation products, nontargeted LC-MS/MS analysis was used.  In the photocatalysis study, we used selected Ti and Al-based photocatalysts. The experiments were conducted at 20 °C in an open cylindrical polypropylene reactor, and a simulated solar radiation lamp (Solimed BH Quarzlampen) was used as a light source. Microbial communities were isolated from the locations in Serbia, Japan, and Italy known for their pollution with PFAS, and enrichment was conducted on the media supplemented with ppm values of PFOA (Beskoski et al., 2018). Microbial communities were used as inoculum in the PFOA biodegradation study.
C3  - 18th International Conference on Chemistry and the Environment (ICCE 2023), Book of Abstracts, 11-15 June 2023, Venice, Italy
T1  - PFAS, from here to Eternity - or maybe not
SP  - 183
EP  - 183
UR  - https://hdl.handle.net/21.15107/rcub_cherry_6410
ER  - 

@conference{
author = "Kasalica, Kristina and Jiménez, Begoña and Yamamoto, Atsushi and Inui, Hideyuki and Lješević, Marija and Radić, Nenad and Gojgić-Cvijović, Gordana D. and Slavković-Beškoski, Latinka and Radulović, Jelena and Nakano, Takeshi and Beškoski, Vladimir",
year = "2023",
abstract = "Per- and polyfluoroalkyl substances (PFAS) are a group of synthetic chemicals with extremely strong C-F bonds. Due to their thermal stability, acid resistance, and high surface activity, they have been widely used for several decades in various consumer products. PFAS has been detected in water, soil, sediment, air, food, and biota samples on all continents and due to this are recognized as environmental and human health risk (Carlson et al. 2022). In the last decade, several available technologies were tested for the remediation of PFAS-polluted environments, such as adsorption, filtration, thermal destruction, oxidation/reduction, and soil washing, but several disadvantages were reported (Bolan et al., 2021). We hypothesize that by using advanced oxidation techniques followed by microbial treatment decrease in the concentration of PFOA as a PFAS model compound will occur. In the beginning, we tested separately abiotic and biotic degradation of PFOA. Target LC-MS/MS was used for quantitative analysis of PFOA decrease, and for detecting degradation products, nontargeted LC-MS/MS analysis was used.  In the photocatalysis study, we used selected Ti and Al-based photocatalysts. The experiments were conducted at 20 °C in an open cylindrical polypropylene reactor, and a simulated solar radiation lamp (Solimed BH Quarzlampen) was used as a light source. Microbial communities were isolated from the locations in Serbia, Japan, and Italy known for their pollution with PFAS, and enrichment was conducted on the media supplemented with ppm values of PFOA (Beskoski et al., 2018). Microbial communities were used as inoculum in the PFOA biodegradation study.",
journal = "18th International Conference on Chemistry and the Environment (ICCE 2023), Book of Abstracts, 11-15 June 2023, Venice, Italy",
title = "PFAS, from here to Eternity - or maybe not",
pages = "183-183",
url = "https://hdl.handle.net/21.15107/rcub_cherry_6410"
}

Kasalica, K., Jiménez, B., Yamamoto, A., Inui, H., Lješević, M., Radić, N., Gojgić-Cvijović, G. D., Slavković-Beškoski, L., Radulović, J., Nakano, T.,& Beškoski, V.. (2023). PFAS, from here to Eternity - or maybe not. in 18th International Conference on Chemistry and the Environment (ICCE 2023), Book of Abstracts, 11-15 June 2023, Venice, Italy, 183-183.
https://hdl.handle.net/21.15107/rcub_cherry_6410

Kasalica K, Jiménez B, Yamamoto A, Inui H, Lješević M, Radić N, Gojgić-Cvijović GD, Slavković-Beškoski L, Radulović J, Nakano T, Beškoski V. PFAS, from here to Eternity - or maybe not. in 18th International Conference on Chemistry and the Environment (ICCE 2023), Book of Abstracts, 11-15 June 2023, Venice, Italy. 2023;:183-183.
https://hdl.handle.net/21.15107/rcub_cherry_6410 .

Kasalica, Kristina, Jiménez, Begoña, Yamamoto, Atsushi, Inui, Hideyuki, Lješević, Marija, Radić, Nenad, Gojgić-Cvijović, Gordana D., Slavković-Beškoski, Latinka, Radulović, Jelena, Nakano, Takeshi, Beškoski, Vladimir, "PFAS, from here to Eternity - or maybe not" in 18th International Conference on Chemistry and the Environment (ICCE 2023), Book of Abstracts, 11-15 June 2023, Venice, Italy (2023):183-183,
https://hdl.handle.net/21.15107/rcub_cherry_6410 .

TY  - JOUR
AU  - Joksimović, Kristina
AU  - Kodranov, Igor D.
AU  - Randjelović, Danijela
AU  - Slavković-Beškoski, Latinka
AU  - Radulović, Jelena
AU  - Lješević, Marija
AU  - Manojlović, Dragan D.
AU  - Beškoski, Vladimir
PY  - 2022
UR  - https://www.sciencedirect.com/science/article/pii/S1567539422000391
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5045
AB  - The problem of wastewater has long been ubiquitous and has great consequences for the environment and its inhabitants. Microbial fuel cells (MFCs) have enormous potential for the treatment of wastewaters polluted with azo dyes. The amount of energy that can be produced from a single-chamber MFC is sufficient to perform decolorization and degradation of such dyes, which are widely used in the textile industry. This study on the azo dye, reactive black 5 (RB5), provides an alternative method through three parallel-connected MFCs to obtain electricity that directly serves for the dye’s electrochemical degradation. We examined degradation followed by decolorization of RB5 using Fe and Pt electrodes, together with H2O2, to achieve the electro-Fenton process. The amount of voltage produced (295 mV), the current density (276 mA m−3) and the power density (50 mW m−3) were sufficient to degrade 25 mg L-1 RB5 dye with 0.5 mM H2O2 in just 2 h. The dye degradation mechanism was investigated using UV–VIS, FT-IR and HPLC-MS/MS. The ecotoxicity of the degradation products was assessed using a bacterial model, Aliivibrio fischeri. These tests showed that there was successful degradation of the dye to products whose toxicity is less than that of RB5.
T2  - Bioelectrochemistry
T1  - Microbial fuel cells as an electrical energy source for degradation followed by decolorization of Reactive Black 5 azo dye
VL  - 145
SP  - 108088
DO  - 10.1016/j.bioelechem.2022.108088
ER  - 

@article{
author = "Joksimović, Kristina and Kodranov, Igor D. and Randjelović, Danijela and Slavković-Beškoski, Latinka and Radulović, Jelena and Lješević, Marija and Manojlović, Dragan D. and Beškoski, Vladimir",
year = "2022",
abstract = "The problem of wastewater has long been ubiquitous and has great consequences for the environment and its inhabitants. Microbial fuel cells (MFCs) have enormous potential for the treatment of wastewaters polluted with azo dyes. The amount of energy that can be produced from a single-chamber MFC is sufficient to perform decolorization and degradation of such dyes, which are widely used in the textile industry. This study on the azo dye, reactive black 5 (RB5), provides an alternative method through three parallel-connected MFCs to obtain electricity that directly serves for the dye’s electrochemical degradation. We examined degradation followed by decolorization of RB5 using Fe and Pt electrodes, together with H2O2, to achieve the electro-Fenton process. The amount of voltage produced (295 mV), the current density (276 mA m−3) and the power density (50 mW m−3) were sufficient to degrade 25 mg L-1 RB5 dye with 0.5 mM H2O2 in just 2 h. The dye degradation mechanism was investigated using UV–VIS, FT-IR and HPLC-MS/MS. The ecotoxicity of the degradation products was assessed using a bacterial model, Aliivibrio fischeri. These tests showed that there was successful degradation of the dye to products whose toxicity is less than that of RB5.",
journal = "Bioelectrochemistry",
title = "Microbial fuel cells as an electrical energy source for degradation followed by decolorization of Reactive Black 5 azo dye",
volume = "145",
pages = "108088",
doi = "10.1016/j.bioelechem.2022.108088"
}

Joksimović, K., Kodranov, I. D., Randjelović, D., Slavković-Beškoski, L., Radulović, J., Lješević, M., Manojlović, D. D.,& Beškoski, V.. (2022). Microbial fuel cells as an electrical energy source for degradation followed by decolorization of Reactive Black 5 azo dye. in Bioelectrochemistry, 145, 108088.
https://doi.org/10.1016/j.bioelechem.2022.108088

Joksimović K, Kodranov ID, Randjelović D, Slavković-Beškoski L, Radulović J, Lješević M, Manojlović DD, Beškoski V. Microbial fuel cells as an electrical energy source for degradation followed by decolorization of Reactive Black 5 azo dye. in Bioelectrochemistry. 2022;145:108088.
doi:10.1016/j.bioelechem.2022.108088 .

Joksimović, Kristina, Kodranov, Igor D., Randjelović, Danijela, Slavković-Beškoski, Latinka, Radulović, Jelena, Lješević, Marija, Manojlović, Dragan D., Beškoski, Vladimir, "Microbial fuel cells as an electrical energy source for degradation followed by decolorization of Reactive Black 5 azo dye" in Bioelectrochemistry, 145 (2022):108088,
https://doi.org/10.1016/j.bioelechem.2022.108088 . .