TY  - JOUR
AU  - Minić, Dragica M.
AU  - Jakovljević, G
AU  - Sladić, Dušan
AU  - Anđelković, Katarina K.
PY  - 2004
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/642
AB  - Thermal behavior of Cu(II), U(VI), Mn(II) and Ni(II) complexes with 2',2"'-(2,6-pyridinediyldiethylidyne)dioxamohydrazide was studied by DSC and TG analysis, in the temperature range of 20-600 degreesC in a stream of nitrogen. Depending on the structure of complexes, thermal degradation occurred mostly in the range of 200-400 degreesC, preceded by a loss of crystal and coordinated solvent if present. Kinetic processes of degradation were studied by analysis of DSC and TG curves recorded at one or more heating rates. Based on activation energies, determined in this way, thermodynamic parameters of activated complexes were also determined for U(VI) and Mn(II) complexes. Mechanisms of,degradation processes were established using the obtained data.
PB  - Trans Tech Publications Ltd, Zurich-Uetikon
T2  - Materials Science Forum
T1  - Investigation of thermal stability and kinetic studies of transition metal complexes with the condensation product of 2,6-diacetylpyridine and semioxamazide
SP  - 567
EP  - 571
DO  - 10.4028/www.scientific.net/MSF.453-454.567
ER  - 

@article{
author = "Minić, Dragica M. and Jakovljević, G and Sladić, Dušan and Anđelković, Katarina K.",
year = "2004",
abstract = "Thermal behavior of Cu(II), U(VI), Mn(II) and Ni(II) complexes with 2',2"'-(2,6-pyridinediyldiethylidyne)dioxamohydrazide was studied by DSC and TG analysis, in the temperature range of 20-600 degreesC in a stream of nitrogen. Depending on the structure of complexes, thermal degradation occurred mostly in the range of 200-400 degreesC, preceded by a loss of crystal and coordinated solvent if present. Kinetic processes of degradation were studied by analysis of DSC and TG curves recorded at one or more heating rates. Based on activation energies, determined in this way, thermodynamic parameters of activated complexes were also determined for U(VI) and Mn(II) complexes. Mechanisms of,degradation processes were established using the obtained data.",
publisher = "Trans Tech Publications Ltd, Zurich-Uetikon",
journal = "Materials Science Forum",
title = "Investigation of thermal stability and kinetic studies of transition metal complexes with the condensation product of 2,6-diacetylpyridine and semioxamazide",
pages = "567-571",
doi = "10.4028/www.scientific.net/MSF.453-454.567"
}

Minić, D. M., Jakovljević, G., Sladić, D.,& Anđelković, K. K.. (2004). Investigation of thermal stability and kinetic studies of transition metal complexes with the condensation product of 2,6-diacetylpyridine and semioxamazide. in Materials Science Forum
Trans Tech Publications Ltd, Zurich-Uetikon., 567-571.
https://doi.org/10.4028/www.scientific.net/MSF.453-454.567

Minić DM, Jakovljević G, Sladić D, Anđelković KK. Investigation of thermal stability and kinetic studies of transition metal complexes with the condensation product of 2,6-diacetylpyridine and semioxamazide. in Materials Science Forum. 2004;:567-571.
doi:10.4028/www.scientific.net/MSF.453-454.567 .

Minić, Dragica M., Jakovljević, G, Sladić, Dušan, Anđelković, Katarina K., "Investigation of thermal stability and kinetic studies of transition metal complexes with the condensation product of 2,6-diacetylpyridine and semioxamazide" in Materials Science Forum (2004):567-571,
https://doi.org/10.4028/www.scientific.net/MSF.453-454.567 . .

TY  - JOUR
AU  - Anđelković, Katarina K.
AU  - Jakovljević, G
AU  - Zlatović, Mario
AU  - Tešić, Živoslav Lj.
AU  - Sladić, Dušan
AU  - Howing, J
AU  - Tellgren, R
PY  - 2004
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/666
AB  - Complexes of Zn(II), Pd(II) and Pt(II) with 2'-[1-(2- pyridinyl)ethyhdene]oxamohydrazide (Hapsox) were synthesized and their structures were determined. All the complexes are of a neutral type with two apsox ligands coordinated to Zn(II) and one apsox ligand coordinated to Pd(II) or Pt(II). In each case. the polydentate was coordinated via pyridine and hydrazone nitrogens and alpha-oxyazine oxygen. forming an octahedral geometry around Zn(II). and a square planar one around Pd(II) and Pt(II). The structure determination was performed by IR. H-1-NMR and C-13-NMR spectroscopy, and for the Zn(II) complex by X-ray structure analysis.
AB  - U ovom radu opisana je sinteza i strukturna karakterizacija kompleksa Zn(II) Pd(II) i Pt(II) sa 2’-[1-(2-piridinil)etiliden]oksamohidrazidom (Hapsox). Sva tri dobijena kompleksa su neutralnog tipa sa dva koordinovana apsox liganda u slučaju kompleksa Zn(II), odnosno jednim apsox ligandom u slučaju Pd(II) i Pt(II) kompleksa. Koordinacija polidentata je u svim kompleksima ostvarena preko piridinskog azota, hidrazonskog azota i α-oksiazinskog kiseonika gradeći oktaedarsku geometriju oko Zn(II), odnosno kvadratno planarnu geometriju oko Pd(II) i Pt(II).Potvrdu za ovakve strukture dobili smo iz IC 1H-NMR i 13C-NMR spektara, dok je za Zn(II) kompleks urađena i rendgenska strukturna analiza.
PB  - Serbian Chemical Soc, Belgrade
T2  - Journal of the Serbian Chemical Society
T1  - Synthesis and characterization of zinc(II), palladium(II) and platinum(II) complex with 2 '-[1-(2-pyridinyl)ethylidene]oxamohydrazide. The crystal structure of bis {2 '-[1-(2-pyridinyl)ethylidene]oxamohydrazido} zinc(II) trihydrate
T1  - Sinteza I karakterizacija kompleksa cinka(II), paladijuma(II) I platine(II) sa 2’-[1-(2-piridinil)etiliden]oksamohidrazidom - kristalna struktura bis {2’-[1-(2-piridinil)etiliden]oksamohidrazido}cink(II) trihidrata
VL  - 69
IS  - 8-9
SP  - 651
EP  - 660
DO  - 10.2298/JSC0409651A
ER  - 

@article{
author = "Anđelković, Katarina K. and Jakovljević, G and Zlatović, Mario and Tešić, Živoslav Lj. and Sladić, Dušan and Howing, J and Tellgren, R",
year = "2004",
abstract = "Complexes of Zn(II), Pd(II) and Pt(II) with 2'-[1-(2- pyridinyl)ethyhdene]oxamohydrazide (Hapsox) were synthesized and their structures were determined. All the complexes are of a neutral type with two apsox ligands coordinated to Zn(II) and one apsox ligand coordinated to Pd(II) or Pt(II). In each case. the polydentate was coordinated via pyridine and hydrazone nitrogens and alpha-oxyazine oxygen. forming an octahedral geometry around Zn(II). and a square planar one around Pd(II) and Pt(II). The structure determination was performed by IR. H-1-NMR and C-13-NMR spectroscopy, and for the Zn(II) complex by X-ray structure analysis., U ovom radu opisana je sinteza i strukturna karakterizacija kompleksa Zn(II) Pd(II) i Pt(II) sa 2’-[1-(2-piridinil)etiliden]oksamohidrazidom (Hapsox). Sva tri dobijena kompleksa su neutralnog tipa sa dva koordinovana apsox liganda u slučaju kompleksa Zn(II), odnosno jednim apsox ligandom u slučaju Pd(II) i Pt(II) kompleksa. Koordinacija polidentata je u svim kompleksima ostvarena preko piridinskog azota, hidrazonskog azota i α-oksiazinskog kiseonika gradeći oktaedarsku geometriju oko Zn(II), odnosno kvadratno planarnu geometriju oko Pd(II) i Pt(II).Potvrdu za ovakve strukture dobili smo iz IC 1H-NMR i 13C-NMR spektara, dok je za Zn(II) kompleks urađena i rendgenska strukturna analiza.",
publisher = "Serbian Chemical Soc, Belgrade",
journal = "Journal of the Serbian Chemical Society",
title = "Synthesis and characterization of zinc(II), palladium(II) and platinum(II) complex with 2 '-[1-(2-pyridinyl)ethylidene]oxamohydrazide. The crystal structure of bis {2 '-[1-(2-pyridinyl)ethylidene]oxamohydrazido} zinc(II) trihydrate, Sinteza I karakterizacija kompleksa cinka(II), paladijuma(II) I platine(II) sa 2’-[1-(2-piridinil)etiliden]oksamohidrazidom - kristalna struktura bis {2’-[1-(2-piridinil)etiliden]oksamohidrazido}cink(II) trihidrata",
volume = "69",
number = "8-9",
pages = "651-660",
doi = "10.2298/JSC0409651A"
}

Anđelković, K. K., Jakovljević, G., Zlatović, M., Tešić, Ž. Lj., Sladić, D., Howing, J.,& Tellgren, R.. (2004). Synthesis and characterization of zinc(II), palladium(II) and platinum(II) complex with 2 '-[1-(2-pyridinyl)ethylidene]oxamohydrazide. The crystal structure of bis {2 '-[1-(2-pyridinyl)ethylidene]oxamohydrazido} zinc(II) trihydrate. in Journal of the Serbian Chemical Society
Serbian Chemical Soc, Belgrade., 69(8-9), 651-660.
https://doi.org/10.2298/JSC0409651A

Anđelković KK, Jakovljević G, Zlatović M, Tešić ŽL, Sladić D, Howing J, Tellgren R. Synthesis and characterization of zinc(II), palladium(II) and platinum(II) complex with 2 '-[1-(2-pyridinyl)ethylidene]oxamohydrazide. The crystal structure of bis {2 '-[1-(2-pyridinyl)ethylidene]oxamohydrazido} zinc(II) trihydrate. in Journal of the Serbian Chemical Society. 2004;69(8-9):651-660.
doi:10.2298/JSC0409651A .

Anđelković, Katarina K., Jakovljević, G, Zlatović, Mario, Tešić, Živoslav Lj., Sladić, Dušan, Howing, J, Tellgren, R, "Synthesis and characterization of zinc(II), palladium(II) and platinum(II) complex with 2 '-[1-(2-pyridinyl)ethylidene]oxamohydrazide. The crystal structure of bis {2 '-[1-(2-pyridinyl)ethylidene]oxamohydrazido} zinc(II) trihydrate" in Journal of the Serbian Chemical Society, 69, no. 8-9 (2004):651-660,
https://doi.org/10.2298/JSC0409651A . .