Brađan, Gabrijela

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2e8f3619-5adf-4ca5-a0c3-ca9dd7e34d2b
  • Brađan, Gabrijela (7)
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Author's Bibliography

Synthesis, characterization and crystal structures of two pentagonal-bipyramidal Fe(III) complexes with dihydrazone of 2,6-diacetylpyridine and Girard's T reagent. Anticancer properties of various metal complexes of the same ligand

Anđelković, Katarina K.; Milenković, Milica R.; Pevec, Andrej; Turel, Iztok; Matić, Ivana Z.; Vujčić, Miroslava; Sladić, Dušan; Radanović, Dušanka D.; Brađan, Gabrijela; Belosević, Svetlana; Čobeljić, Božidar

(Elsevier Science Inc, New York, 2017)

TY  - JOUR
AU  - Anđelković, Katarina K.
AU  - Milenković, Milica R.
AU  - Pevec, Andrej
AU  - Turel, Iztok
AU  - Matić, Ivana Z.
AU  - Vujčić, Miroslava
AU  - Sladić, Dušan
AU  - Radanović, Dušanka D.
AU  - Brađan, Gabrijela
AU  - Belosević, Svetlana
AU  - Čobeljić, Božidar
PY  - 2017
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/2495
AB  - In this work synthesis, characterization and crystal structures of two isothiocyanato Fe(III) complexes with 2,2'[2,6-pyridinediylbis(ethylidyne-1-hydraziny1-2-ylidene)]bis[N,N,N-trimethyl-2-oxoethanaminium] dichloride (H2LCl2) ligand, with composition [FeL(NCS)(2)]SCN center dot 2H(2)O and [FeL(NCS)(2)](2)[Fe(H2O)(NCS)(5)}4H(2)O, has been reported. Both iron(III) complexes possess the same pentagonal-bipyramidal complex cation, while the nature of their anions depends on mole ratio of NH4SCN and FeCl3 center dot 6H(2)O used in reaction. Cytotoxic activity of new Fe(III) complexes, as well as of previously synthesized isothiocyanato Co(II), Ni(II), Mn(II), Zn(II) and Cd(II) complexes with the same ligand, was tested against five human cancer cell lines (HeLa, MDA-MB-453, K562, LS174 and A549) and normal cell line MRC-5. The best activity was observed in the case of Fe(III), Co(II) and Cd(II) complexes. The investigation of potential of these complexes to induce HeLa and K562 cell cycle perturbations was also evaluated. Mechanism of cell death mode was elucidated on the basis of morphological changes of HeLa cells as well as identification of target caspases. It was established that DNA damage could be responsible for the activity of Fe(III) and Co(II) complexes. Synopsis: Pentagonal-bipyramidal Fe(III) complexes with dihydrazone of 2,6-diacetylpyridine and Girard's T reagent have been synthesized and characterized. Cytotoxic activity of Fe(III) complexes and Co(II), Ni(II), Mn (II), Zn(II) and Cd(II) complexes with the same ligand was tested. The best activity was observed in the case of Fe (III), Co(II) and Cd(II) complexes.
PB  - Elsevier Science Inc, New York
T2  - Journal of Inorganic Biochemistry
T1  - Synthesis, characterization and crystal structures of two pentagonal-bipyramidal Fe(III) complexes with dihydrazone of 2,6-diacetylpyridine and Girard's T reagent. Anticancer properties of various metal complexes of the same ligand
VL  - 174
SP  - 137
EP  - 149
DO  - 10.1016/j.jinorgbio.2017.06.011
ER  - 
@article{
author = "Anđelković, Katarina K. and Milenković, Milica R. and Pevec, Andrej and Turel, Iztok and Matić, Ivana Z. and Vujčić, Miroslava and Sladić, Dušan and Radanović, Dušanka D. and Brađan, Gabrijela and Belosević, Svetlana and Čobeljić, Božidar",
year = "2017",
abstract = "In this work synthesis, characterization and crystal structures of two isothiocyanato Fe(III) complexes with 2,2'[2,6-pyridinediylbis(ethylidyne-1-hydraziny1-2-ylidene)]bis[N,N,N-trimethyl-2-oxoethanaminium] dichloride (H2LCl2) ligand, with composition [FeL(NCS)(2)]SCN center dot 2H(2)O and [FeL(NCS)(2)](2)[Fe(H2O)(NCS)(5)}4H(2)O, has been reported. Both iron(III) complexes possess the same pentagonal-bipyramidal complex cation, while the nature of their anions depends on mole ratio of NH4SCN and FeCl3 center dot 6H(2)O used in reaction. Cytotoxic activity of new Fe(III) complexes, as well as of previously synthesized isothiocyanato Co(II), Ni(II), Mn(II), Zn(II) and Cd(II) complexes with the same ligand, was tested against five human cancer cell lines (HeLa, MDA-MB-453, K562, LS174 and A549) and normal cell line MRC-5. The best activity was observed in the case of Fe(III), Co(II) and Cd(II) complexes. The investigation of potential of these complexes to induce HeLa and K562 cell cycle perturbations was also evaluated. Mechanism of cell death mode was elucidated on the basis of morphological changes of HeLa cells as well as identification of target caspases. It was established that DNA damage could be responsible for the activity of Fe(III) and Co(II) complexes. Synopsis: Pentagonal-bipyramidal Fe(III) complexes with dihydrazone of 2,6-diacetylpyridine and Girard's T reagent have been synthesized and characterized. Cytotoxic activity of Fe(III) complexes and Co(II), Ni(II), Mn (II), Zn(II) and Cd(II) complexes with the same ligand was tested. The best activity was observed in the case of Fe (III), Co(II) and Cd(II) complexes.",
publisher = "Elsevier Science Inc, New York",
journal = "Journal of Inorganic Biochemistry",
title = "Synthesis, characterization and crystal structures of two pentagonal-bipyramidal Fe(III) complexes with dihydrazone of 2,6-diacetylpyridine and Girard's T reagent. Anticancer properties of various metal complexes of the same ligand",
volume = "174",
pages = "137-149",
doi = "10.1016/j.jinorgbio.2017.06.011"
}
Anđelković, K. K., Milenković, M. R., Pevec, A., Turel, I., Matić, I. Z., Vujčić, M., Sladić, D., Radanović, D. D., Brađan, G., Belosević, S.,& Čobeljić, B.. (2017). Synthesis, characterization and crystal structures of two pentagonal-bipyramidal Fe(III) complexes with dihydrazone of 2,6-diacetylpyridine and Girard's T reagent. Anticancer properties of various metal complexes of the same ligand. in Journal of Inorganic Biochemistry
Elsevier Science Inc, New York., 174, 137-149.
https://doi.org/10.1016/j.jinorgbio.2017.06.011
Anđelković KK, Milenković MR, Pevec A, Turel I, Matić IZ, Vujčić M, Sladić D, Radanović DD, Brađan G, Belosević S, Čobeljić B. Synthesis, characterization and crystal structures of two pentagonal-bipyramidal Fe(III) complexes with dihydrazone of 2,6-diacetylpyridine and Girard's T reagent. Anticancer properties of various metal complexes of the same ligand. in Journal of Inorganic Biochemistry. 2017;174:137-149.
doi:10.1016/j.jinorgbio.2017.06.011 .
Anđelković, Katarina K., Milenković, Milica R., Pevec, Andrej, Turel, Iztok, Matić, Ivana Z., Vujčić, Miroslava, Sladić, Dušan, Radanović, Dušanka D., Brađan, Gabrijela, Belosević, Svetlana, Čobeljić, Božidar, "Synthesis, characterization and crystal structures of two pentagonal-bipyramidal Fe(III) complexes with dihydrazone of 2,6-diacetylpyridine and Girard's T reagent. Anticancer properties of various metal complexes of the same ligand" in Journal of Inorganic Biochemistry, 174 (2017):137-149,
https://doi.org/10.1016/j.jinorgbio.2017.06.011 . .
18
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Synthesis, characterization, DFT calculations and antimicrobial activity of pentagonal-bipyramidal Zn(II) and Cd(II) complexes with 2,6-diacetylpyridine-bis(trimethylammoniumacetohydrazone)

Brađan, Gabrijela; Pevec, Andrej; Turel, Iztok; Shcherbakov, Igor N.; Milenković, Milica R.; Milenković, Marina; Radanović, Dušanka D.; Čobeljić, Božidar; Anđelković, Katarina K.

(Taylor & Francis Ltd, Abingdon, 2016)

TY  - JOUR
AU  - Brađan, Gabrijela
AU  - Pevec, Andrej
AU  - Turel, Iztok
AU  - Shcherbakov, Igor N.
AU  - Milenković, Milica R.
AU  - Milenković, Marina
AU  - Radanović, Dušanka D.
AU  - Čobeljić, Božidar
AU  - Anđelković, Katarina K.
PY  - 2016
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3646
AB  - Isothiocyanate complexes of Zn(II) and Cd(II) with the condensation product of 2,6-diacetylpyridine and trimethylammoniumacetohydrazide (Girard's T reagent) were synthesized, characterized, and their antimicrobial activities were evaluated. The structures of the complexes were determined by elemental analysis, IR, and NMR spectroscopy. The crystal structure of the Zn(II) complex was also determined. Quantum-chemical calculations of the geometry and total energy of isomers of 2,6-diacetylpyridine-bis(trimethylammoniumacetohydrazone) were performed in vacuum and methanol solution, with the aim to explain conformational behavior and E/Z isomerism of this compound. DFT calculations of the molecular structures and the relative stabilities of linkage isomers of the Cd(II) complex showed that the isomer with N-Cd-N coordination of SCN- is the most stable. Complexes of Zn(II) and Cd(II) exhibited low to moderate activity against the tested microbial strains. [GRAPHICS]
PB  - Taylor & Francis Ltd, Abingdon
T2  - Journal of Coordination Chemistry
T1  - Synthesis, characterization, DFT calculations and antimicrobial activity of pentagonal-bipyramidal Zn(II) and Cd(II) complexes with 2,6-diacetylpyridine-bis(trimethylammoniumacetohydrazone)
VL  - 69
IS  - 18
SP  - 2754
EP  - 2765
DO  - 10.1080/00958972.2016.1212339
ER  - 
@article{
author = "Brađan, Gabrijela and Pevec, Andrej and Turel, Iztok and Shcherbakov, Igor N. and Milenković, Milica R. and Milenković, Marina and Radanović, Dušanka D. and Čobeljić, Božidar and Anđelković, Katarina K.",
year = "2016",
abstract = "Isothiocyanate complexes of Zn(II) and Cd(II) with the condensation product of 2,6-diacetylpyridine and trimethylammoniumacetohydrazide (Girard's T reagent) were synthesized, characterized, and their antimicrobial activities were evaluated. The structures of the complexes were determined by elemental analysis, IR, and NMR spectroscopy. The crystal structure of the Zn(II) complex was also determined. Quantum-chemical calculations of the geometry and total energy of isomers of 2,6-diacetylpyridine-bis(trimethylammoniumacetohydrazone) were performed in vacuum and methanol solution, with the aim to explain conformational behavior and E/Z isomerism of this compound. DFT calculations of the molecular structures and the relative stabilities of linkage isomers of the Cd(II) complex showed that the isomer with N-Cd-N coordination of SCN- is the most stable. Complexes of Zn(II) and Cd(II) exhibited low to moderate activity against the tested microbial strains. [GRAPHICS]",
publisher = "Taylor & Francis Ltd, Abingdon",
journal = "Journal of Coordination Chemistry",
title = "Synthesis, characterization, DFT calculations and antimicrobial activity of pentagonal-bipyramidal Zn(II) and Cd(II) complexes with 2,6-diacetylpyridine-bis(trimethylammoniumacetohydrazone)",
volume = "69",
number = "18",
pages = "2754-2765",
doi = "10.1080/00958972.2016.1212339"
}
Brađan, G., Pevec, A., Turel, I., Shcherbakov, I. N., Milenković, M. R., Milenković, M., Radanović, D. D., Čobeljić, B.,& Anđelković, K. K.. (2016). Synthesis, characterization, DFT calculations and antimicrobial activity of pentagonal-bipyramidal Zn(II) and Cd(II) complexes with 2,6-diacetylpyridine-bis(trimethylammoniumacetohydrazone). in Journal of Coordination Chemistry
Taylor & Francis Ltd, Abingdon., 69(18), 2754-2765.
https://doi.org/10.1080/00958972.2016.1212339
Brađan G, Pevec A, Turel I, Shcherbakov IN, Milenković MR, Milenković M, Radanović DD, Čobeljić B, Anđelković KK. Synthesis, characterization, DFT calculations and antimicrobial activity of pentagonal-bipyramidal Zn(II) and Cd(II) complexes with 2,6-diacetylpyridine-bis(trimethylammoniumacetohydrazone). in Journal of Coordination Chemistry. 2016;69(18):2754-2765.
doi:10.1080/00958972.2016.1212339 .
Brađan, Gabrijela, Pevec, Andrej, Turel, Iztok, Shcherbakov, Igor N., Milenković, Milica R., Milenković, Marina, Radanović, Dušanka D., Čobeljić, Božidar, Anđelković, Katarina K., "Synthesis, characterization, DFT calculations and antimicrobial activity of pentagonal-bipyramidal Zn(II) and Cd(II) complexes with 2,6-diacetylpyridine-bis(trimethylammoniumacetohydrazone)" in Journal of Coordination Chemistry, 69, no. 18 (2016):2754-2765,
https://doi.org/10.1080/00958972.2016.1212339 . .
10
9
9
10

Synthesis, characterization and antimicrobial activity of pentagonal-bipyramidal isothiocyanato Co(II) and Ni(II) complexes with 2,6-diacetylpyridine bis(trimethylammoniumacetohydrazone)

Brađan, Gabrijela; Čobeljić, Božidar; Pevec, Andrej; Turel, Iztok; Milenković, Marina; Radanović, Dušanka D.; Šumar-Ristović, Maja; Adaila, Kawther; Milenković, Milica R.; Anđelković, Katarina K.

(Taylor & Francis Ltd, Abingdon, 2016)

TY  - JOUR
AU  - Brađan, Gabrijela
AU  - Čobeljić, Božidar
AU  - Pevec, Andrej
AU  - Turel, Iztok
AU  - Milenković, Marina
AU  - Radanović, Dušanka D.
AU  - Šumar-Ristović, Maja
AU  - Adaila, Kawther
AU  - Milenković, Milica R.
AU  - Anđelković, Katarina K.
PY  - 2016
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3635
AB  - Pentagonal-bipyramidal isothiocyanato Co(II) and Ni(II) complexes with condensation product of 2,6-diacetylpyridine and trimethylammoniumacetohydrazide (Girard's T reagent) were synthesized and characterized by elemental analyses, IR and UV-vis spectra, molar conductivity, and magnetic susceptibility. Crystal structures of the Co(II) and Ni(II) complexes were also determined. Antimicrobial activities of the ligand and metal complexes were examined. [GRAPHICS] .
PB  - Taylor & Francis Ltd, Abingdon
T2  - Journal of Coordination Chemistry
T1  - Synthesis, characterization and antimicrobial activity of pentagonal-bipyramidal isothiocyanato Co(II) and Ni(II) complexes with 2,6-diacetylpyridine bis(trimethylammoniumacetohydrazone)
UR  - https://hdl.handle.net/21.15107/rcub_cherry_3635
ER  - 
@article{
author = "Brađan, Gabrijela and Čobeljić, Božidar and Pevec, Andrej and Turel, Iztok and Milenković, Marina and Radanović, Dušanka D. and Šumar-Ristović, Maja and Adaila, Kawther and Milenković, Milica R. and Anđelković, Katarina K.",
year = "2016",
abstract = "Pentagonal-bipyramidal isothiocyanato Co(II) and Ni(II) complexes with condensation product of 2,6-diacetylpyridine and trimethylammoniumacetohydrazide (Girard's T reagent) were synthesized and characterized by elemental analyses, IR and UV-vis spectra, molar conductivity, and magnetic susceptibility. Crystal structures of the Co(II) and Ni(II) complexes were also determined. Antimicrobial activities of the ligand and metal complexes were examined. [GRAPHICS] .",
publisher = "Taylor & Francis Ltd, Abingdon",
journal = "Journal of Coordination Chemistry",
title = "Synthesis, characterization and antimicrobial activity of pentagonal-bipyramidal isothiocyanato Co(II) and Ni(II) complexes with 2,6-diacetylpyridine bis(trimethylammoniumacetohydrazone)",
url = "https://hdl.handle.net/21.15107/rcub_cherry_3635"
}
Brađan, G., Čobeljić, B., Pevec, A., Turel, I., Milenković, M., Radanović, D. D., Šumar-Ristović, M., Adaila, K., Milenković, M. R.,& Anđelković, K. K.. (2016). Synthesis, characterization and antimicrobial activity of pentagonal-bipyramidal isothiocyanato Co(II) and Ni(II) complexes with 2,6-diacetylpyridine bis(trimethylammoniumacetohydrazone). in Journal of Coordination Chemistry
Taylor & Francis Ltd, Abingdon..
https://hdl.handle.net/21.15107/rcub_cherry_3635
Brađan G, Čobeljić B, Pevec A, Turel I, Milenković M, Radanović DD, Šumar-Ristović M, Adaila K, Milenković MR, Anđelković KK. Synthesis, characterization and antimicrobial activity of pentagonal-bipyramidal isothiocyanato Co(II) and Ni(II) complexes with 2,6-diacetylpyridine bis(trimethylammoniumacetohydrazone). in Journal of Coordination Chemistry. 2016;.
https://hdl.handle.net/21.15107/rcub_cherry_3635 .
Brađan, Gabrijela, Čobeljić, Božidar, Pevec, Andrej, Turel, Iztok, Milenković, Marina, Radanović, Dušanka D., Šumar-Ristović, Maja, Adaila, Kawther, Milenković, Milica R., Anđelković, Katarina K., "Synthesis, characterization and antimicrobial activity of pentagonal-bipyramidal isothiocyanato Co(II) and Ni(II) complexes with 2,6-diacetylpyridine bis(trimethylammoniumacetohydrazone)" in Journal of Coordination Chemistry (2016),
https://hdl.handle.net/21.15107/rcub_cherry_3635 .

Supplementary data for the article: Brađan, G.; Pevec, A.; Turel, I.; Shcherbakov, I. N.; Milenković, M.; Milenković, M.; Radanović, D.; Čobeljić, B.; Anđelković, K. Synthesis, Characterization, DFT Calculations and Antimicrobial Activity of Pentagonal-Bipyramidal Zn(II) and Cd(II) Complexes with 2,6-Diacetylpyridine-Bis(Trimethylammoniumacetohydrazone). Journal of Coordination Chemistry 2016, 69 (18), 2754–2765. https://doi.org/10.1080/00958972.2016.1212339

Brađan, Gabrijela; Pevec, Andrej; Turel, Iztok; Shcherbakov, Igor N.; Milenković, Milica R.; Milenković, Marina; Radanović, Dušanka D.; Čobeljić, Božidar; Anđelković, Katarina K.

(Taylor & Francis Ltd, Abingdon, 2016)

TY  - DATA
AU  - Brađan, Gabrijela
AU  - Pevec, Andrej
AU  - Turel, Iztok
AU  - Shcherbakov, Igor N.
AU  - Milenković, Milica R.
AU  - Milenković, Marina
AU  - Radanović, Dušanka D.
AU  - Čobeljić, Božidar
AU  - Anđelković, Katarina K.
PY  - 2016
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3647
PB  - Taylor & Francis Ltd, Abingdon
T2  - Journal of Coordination Chemistry
T1  - Supplementary data for the article: Brađan, G.; Pevec, A.; Turel, I.; Shcherbakov, I. N.; Milenković, M.; Milenković, M.; Radanović, D.; Čobeljić, B.; Anđelković, K. Synthesis, Characterization, DFT Calculations and Antimicrobial Activity of Pentagonal-Bipyramidal Zn(II) and Cd(II) Complexes with 2,6-Diacetylpyridine-Bis(Trimethylammoniumacetohydrazone). Journal of Coordination Chemistry 2016, 69 (18), 2754–2765. https://doi.org/10.1080/00958972.2016.1212339
UR  - https://hdl.handle.net/21.15107/rcub_cherry_3647
ER  - 
@misc{
author = "Brađan, Gabrijela and Pevec, Andrej and Turel, Iztok and Shcherbakov, Igor N. and Milenković, Milica R. and Milenković, Marina and Radanović, Dušanka D. and Čobeljić, Božidar and Anđelković, Katarina K.",
year = "2016",
publisher = "Taylor & Francis Ltd, Abingdon",
journal = "Journal of Coordination Chemistry",
title = "Supplementary data for the article: Brađan, G.; Pevec, A.; Turel, I.; Shcherbakov, I. N.; Milenković, M.; Milenković, M.; Radanović, D.; Čobeljić, B.; Anđelković, K. Synthesis, Characterization, DFT Calculations and Antimicrobial Activity of Pentagonal-Bipyramidal Zn(II) and Cd(II) Complexes with 2,6-Diacetylpyridine-Bis(Trimethylammoniumacetohydrazone). Journal of Coordination Chemistry 2016, 69 (18), 2754–2765. https://doi.org/10.1080/00958972.2016.1212339",
url = "https://hdl.handle.net/21.15107/rcub_cherry_3647"
}
Brađan, G., Pevec, A., Turel, I., Shcherbakov, I. N., Milenković, M. R., Milenković, M., Radanović, D. D., Čobeljić, B.,& Anđelković, K. K.. (2016). Supplementary data for the article: Brađan, G.; Pevec, A.; Turel, I.; Shcherbakov, I. N.; Milenković, M.; Milenković, M.; Radanović, D.; Čobeljić, B.; Anđelković, K. Synthesis, Characterization, DFT Calculations and Antimicrobial Activity of Pentagonal-Bipyramidal Zn(II) and Cd(II) Complexes with 2,6-Diacetylpyridine-Bis(Trimethylammoniumacetohydrazone). Journal of Coordination Chemistry 2016, 69 (18), 2754–2765. https://doi.org/10.1080/00958972.2016.1212339. in Journal of Coordination Chemistry
Taylor & Francis Ltd, Abingdon..
https://hdl.handle.net/21.15107/rcub_cherry_3647
Brađan G, Pevec A, Turel I, Shcherbakov IN, Milenković MR, Milenković M, Radanović DD, Čobeljić B, Anđelković KK. Supplementary data for the article: Brađan, G.; Pevec, A.; Turel, I.; Shcherbakov, I. N.; Milenković, M.; Milenković, M.; Radanović, D.; Čobeljić, B.; Anđelković, K. Synthesis, Characterization, DFT Calculations and Antimicrobial Activity of Pentagonal-Bipyramidal Zn(II) and Cd(II) Complexes with 2,6-Diacetylpyridine-Bis(Trimethylammoniumacetohydrazone). Journal of Coordination Chemistry 2016, 69 (18), 2754–2765. https://doi.org/10.1080/00958972.2016.1212339. in Journal of Coordination Chemistry. 2016;.
https://hdl.handle.net/21.15107/rcub_cherry_3647 .
Brađan, Gabrijela, Pevec, Andrej, Turel, Iztok, Shcherbakov, Igor N., Milenković, Milica R., Milenković, Marina, Radanović, Dušanka D., Čobeljić, Božidar, Anđelković, Katarina K., "Supplementary data for the article: Brađan, G.; Pevec, A.; Turel, I.; Shcherbakov, I. N.; Milenković, M.; Milenković, M.; Radanović, D.; Čobeljić, B.; Anđelković, K. Synthesis, Characterization, DFT Calculations and Antimicrobial Activity of Pentagonal-Bipyramidal Zn(II) and Cd(II) Complexes with 2,6-Diacetylpyridine-Bis(Trimethylammoniumacetohydrazone). Journal of Coordination Chemistry 2016, 69 (18), 2754–2765. https://doi.org/10.1080/00958972.2016.1212339" in Journal of Coordination Chemistry (2016),
https://hdl.handle.net/21.15107/rcub_cherry_3647 .

Synthesis, characterization, DFT calculations and antimicrobial activity of pentagonal-bipyramidal Zn(II) and Cd(II) complexes with 2,6-diacetylpyridine-bis(trimethylammoniumacetohydrazone)

Brađan, Gabrijela; Pevec, Andrej; Turel, Iztok; Shcherbakov, Igor N.; Milenković, Milica R.; Milenković, Marina; Radanović, Dušanka D.; Čobeljić, Božidar; Anđelković, Katarina K.

(Taylor & Francis Ltd, Abingdon, 2016)

TY  - JOUR
AU  - Brađan, Gabrijela
AU  - Pevec, Andrej
AU  - Turel, Iztok
AU  - Shcherbakov, Igor N.
AU  - Milenković, Milica R.
AU  - Milenković, Marina
AU  - Radanović, Dušanka D.
AU  - Čobeljić, Božidar
AU  - Anđelković, Katarina K.
PY  - 2016
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/2314
AB  - Isothiocyanate complexes of Zn(II) and Cd(II) with the condensation product of 2,6-diacetylpyridine and trimethylammoniumacetohydrazide (Girard's T reagent) were synthesized, characterized, and their antimicrobial activities were evaluated. The structures of the complexes were determined by elemental analysis, IR, and NMR spectroscopy. The crystal structure of the Zn(II) complex was also determined. Quantum-chemical calculations of the geometry and total energy of isomers of 2,6-diacetylpyridine-bis(trimethylammoniumacetohydrazone) were performed in vacuum and methanol solution, with the aim to explain conformational behavior and E/Z isomerism of this compound. DFT calculations of the molecular structures and the relative stabilities of linkage isomers of the Cd(II) complex showed that the isomer with N-Cd-N coordination of SCN- is the most stable. Complexes of Zn(II) and Cd(II) exhibited low to moderate activity against the tested microbial strains. [GRAPHICS]
PB  - Taylor & Francis Ltd, Abingdon
T2  - Journal of Coordination Chemistry
T1  - Synthesis, characterization, DFT calculations and antimicrobial activity of pentagonal-bipyramidal Zn(II) and Cd(II) complexes with 2,6-diacetylpyridine-bis(trimethylammoniumacetohydrazone)
VL  - 69
IS  - 18
SP  - 2754
EP  - 2765
DO  - 10.1080/00958972.2016.1212339
ER  - 
@article{
author = "Brađan, Gabrijela and Pevec, Andrej and Turel, Iztok and Shcherbakov, Igor N. and Milenković, Milica R. and Milenković, Marina and Radanović, Dušanka D. and Čobeljić, Božidar and Anđelković, Katarina K.",
year = "2016",
abstract = "Isothiocyanate complexes of Zn(II) and Cd(II) with the condensation product of 2,6-diacetylpyridine and trimethylammoniumacetohydrazide (Girard's T reagent) were synthesized, characterized, and their antimicrobial activities were evaluated. The structures of the complexes were determined by elemental analysis, IR, and NMR spectroscopy. The crystal structure of the Zn(II) complex was also determined. Quantum-chemical calculations of the geometry and total energy of isomers of 2,6-diacetylpyridine-bis(trimethylammoniumacetohydrazone) were performed in vacuum and methanol solution, with the aim to explain conformational behavior and E/Z isomerism of this compound. DFT calculations of the molecular structures and the relative stabilities of linkage isomers of the Cd(II) complex showed that the isomer with N-Cd-N coordination of SCN- is the most stable. Complexes of Zn(II) and Cd(II) exhibited low to moderate activity against the tested microbial strains. [GRAPHICS]",
publisher = "Taylor & Francis Ltd, Abingdon",
journal = "Journal of Coordination Chemistry",
title = "Synthesis, characterization, DFT calculations and antimicrobial activity of pentagonal-bipyramidal Zn(II) and Cd(II) complexes with 2,6-diacetylpyridine-bis(trimethylammoniumacetohydrazone)",
volume = "69",
number = "18",
pages = "2754-2765",
doi = "10.1080/00958972.2016.1212339"
}
Brađan, G., Pevec, A., Turel, I., Shcherbakov, I. N., Milenković, M. R., Milenković, M., Radanović, D. D., Čobeljić, B.,& Anđelković, K. K.. (2016). Synthesis, characterization, DFT calculations and antimicrobial activity of pentagonal-bipyramidal Zn(II) and Cd(II) complexes with 2,6-diacetylpyridine-bis(trimethylammoniumacetohydrazone). in Journal of Coordination Chemistry
Taylor & Francis Ltd, Abingdon., 69(18), 2754-2765.
https://doi.org/10.1080/00958972.2016.1212339
Brađan G, Pevec A, Turel I, Shcherbakov IN, Milenković MR, Milenković M, Radanović DD, Čobeljić B, Anđelković KK. Synthesis, characterization, DFT calculations and antimicrobial activity of pentagonal-bipyramidal Zn(II) and Cd(II) complexes with 2,6-diacetylpyridine-bis(trimethylammoniumacetohydrazone). in Journal of Coordination Chemistry. 2016;69(18):2754-2765.
doi:10.1080/00958972.2016.1212339 .
Brađan, Gabrijela, Pevec, Andrej, Turel, Iztok, Shcherbakov, Igor N., Milenković, Milica R., Milenković, Marina, Radanović, Dušanka D., Čobeljić, Božidar, Anđelković, Katarina K., "Synthesis, characterization, DFT calculations and antimicrobial activity of pentagonal-bipyramidal Zn(II) and Cd(II) complexes with 2,6-diacetylpyridine-bis(trimethylammoniumacetohydrazone)" in Journal of Coordination Chemistry, 69, no. 18 (2016):2754-2765,
https://doi.org/10.1080/00958972.2016.1212339 . .
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Synthesis, characterization and antimicrobial activity of pentagonal-bipyramidal isothiocyanato Co(II) and Ni(II) complexes with 2,6-diacetylpyridine bis(trimethylammoniumacetohydrazone)

Brađan, Gabrijela; Čobeljić, Božidar; Pevec, Andrej; Turel, Iztok; Milenković, Marina; Radanović, Dušanka D.; Šumar-Ristović, Maja; Adaila, Kawther; Milenković, Milica R.; Anđelković, Katarina K.

(Taylor & Francis Ltd, Abingdon, 2016)

TY  - JOUR
AU  - Brađan, Gabrijela
AU  - Čobeljić, Božidar
AU  - Pevec, Andrej
AU  - Turel, Iztok
AU  - Milenković, Marina
AU  - Radanović, Dušanka D.
AU  - Šumar-Ristović, Maja
AU  - Adaila, Kawther
AU  - Milenković, Milica R.
AU  - Anđelković, Katarina K.
PY  - 2016
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1907
AB  - Pentagonal-bipyramidal isothiocyanato Co(II) and Ni(II) complexes with condensation product of 2,6-diacetylpyridine and trimethylammoniumacetohydrazide (Girard's T reagent) were synthesized and characterized by elemental analyses, IR and UV-vis spectra, molar conductivity, and magnetic susceptibility. Crystal structures of the Co(II) and Ni(II) complexes were also determined. Antimicrobial activities of the ligand and metal complexes were examined. [GRAPHICS] .
PB  - Taylor & Francis Ltd, Abingdon
T2  - Journal of Coordination Chemistry
T1  - Synthesis, characterization and antimicrobial activity of pentagonal-bipyramidal isothiocyanato Co(II) and Ni(II) complexes with 2,6-diacetylpyridine bis(trimethylammoniumacetohydrazone)
VL  - 69
IS  - 5
SP  - 801
EP  - 811
DO  - 10.1080/00958972.2016.1139702
ER  - 
@article{
author = "Brađan, Gabrijela and Čobeljić, Božidar and Pevec, Andrej and Turel, Iztok and Milenković, Marina and Radanović, Dušanka D. and Šumar-Ristović, Maja and Adaila, Kawther and Milenković, Milica R. and Anđelković, Katarina K.",
year = "2016",
abstract = "Pentagonal-bipyramidal isothiocyanato Co(II) and Ni(II) complexes with condensation product of 2,6-diacetylpyridine and trimethylammoniumacetohydrazide (Girard's T reagent) were synthesized and characterized by elemental analyses, IR and UV-vis spectra, molar conductivity, and magnetic susceptibility. Crystal structures of the Co(II) and Ni(II) complexes were also determined. Antimicrobial activities of the ligand and metal complexes were examined. [GRAPHICS] .",
publisher = "Taylor & Francis Ltd, Abingdon",
journal = "Journal of Coordination Chemistry",
title = "Synthesis, characterization and antimicrobial activity of pentagonal-bipyramidal isothiocyanato Co(II) and Ni(II) complexes with 2,6-diacetylpyridine bis(trimethylammoniumacetohydrazone)",
volume = "69",
number = "5",
pages = "801-811",
doi = "10.1080/00958972.2016.1139702"
}
Brađan, G., Čobeljić, B., Pevec, A., Turel, I., Milenković, M., Radanović, D. D., Šumar-Ristović, M., Adaila, K., Milenković, M. R.,& Anđelković, K. K.. (2016). Synthesis, characterization and antimicrobial activity of pentagonal-bipyramidal isothiocyanato Co(II) and Ni(II) complexes with 2,6-diacetylpyridine bis(trimethylammoniumacetohydrazone). in Journal of Coordination Chemistry
Taylor & Francis Ltd, Abingdon., 69(5), 801-811.
https://doi.org/10.1080/00958972.2016.1139702
Brađan G, Čobeljić B, Pevec A, Turel I, Milenković M, Radanović DD, Šumar-Ristović M, Adaila K, Milenković MR, Anđelković KK. Synthesis, characterization and antimicrobial activity of pentagonal-bipyramidal isothiocyanato Co(II) and Ni(II) complexes with 2,6-diacetylpyridine bis(trimethylammoniumacetohydrazone). in Journal of Coordination Chemistry. 2016;69(5):801-811.
doi:10.1080/00958972.2016.1139702 .
Brađan, Gabrijela, Čobeljić, Božidar, Pevec, Andrej, Turel, Iztok, Milenković, Marina, Radanović, Dušanka D., Šumar-Ristović, Maja, Adaila, Kawther, Milenković, Milica R., Anđelković, Katarina K., "Synthesis, characterization and antimicrobial activity of pentagonal-bipyramidal isothiocyanato Co(II) and Ni(II) complexes with 2,6-diacetylpyridine bis(trimethylammoniumacetohydrazone)" in Journal of Coordination Chemistry, 69, no. 5 (2016):801-811,
https://doi.org/10.1080/00958972.2016.1139702 . .
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Novel methylene bridged ethylenediamine-type ligands: synthesis and spectral characterization

Mihajlović-Lalić, Ljiljana; Savić, Aleksandar; Brađan, Gabrijela; Sabo, Tibor; Grgurić-Šipka, Sanja

(Serbian Chemical Soc, Belgrade, 2014)

TY  - JOUR
AU  - Mihajlović-Lalić, Ljiljana
AU  - Savić, Aleksandar
AU  - Brađan, Gabrijela
AU  - Sabo, Tibor
AU  - Grgurić-Šipka, Sanja
PY  - 2014
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1874
AB  - The synthesis of two new organic compounds, diisobutyl- and diisopentyl (S,S)-alpha(1),alpha(3)-bis(cyclohexylmethyl-1,3-imidazolidinediacetate is reported herein. The one-pot procedure was realized by the addition of the reducing agent and carbonyl compound into a methanolic solution of the parent compounds (isobutyl and isopentyl esters of (S,S)-alpha,alpha '-(1,2-ethanediyldiimino)bis[cyclohexanepropanoic acid] in appropriate stoichiometric ratios. The compounds were fully characterized by infrared, ESI-MS, 1D (H-1 and C-13) and 2D (COSY, HSQC and HMBC) NMR spectroscopy and elemental analysis. The spectral data confirmed the presence of the -CH2- group introduced between the nitrogen atoms of the ethylenediamine moiety, revealing a neutral form of the potential bidentate ligand.
PB  - Serbian Chemical Soc, Belgrade
T2  - Journal of the Serbian Chemical Society
T1  - Novel methylene bridged ethylenediamine-type ligands: synthesis and spectral characterization
VL  - 79
IS  - 10
SP  - 1199
EP  - 1204
DO  - 10.2298/JSC140212042M
ER  - 
@article{
author = "Mihajlović-Lalić, Ljiljana and Savić, Aleksandar and Brađan, Gabrijela and Sabo, Tibor and Grgurić-Šipka, Sanja",
year = "2014",
abstract = "The synthesis of two new organic compounds, diisobutyl- and diisopentyl (S,S)-alpha(1),alpha(3)-bis(cyclohexylmethyl-1,3-imidazolidinediacetate is reported herein. The one-pot procedure was realized by the addition of the reducing agent and carbonyl compound into a methanolic solution of the parent compounds (isobutyl and isopentyl esters of (S,S)-alpha,alpha '-(1,2-ethanediyldiimino)bis[cyclohexanepropanoic acid] in appropriate stoichiometric ratios. The compounds were fully characterized by infrared, ESI-MS, 1D (H-1 and C-13) and 2D (COSY, HSQC and HMBC) NMR spectroscopy and elemental analysis. The spectral data confirmed the presence of the -CH2- group introduced between the nitrogen atoms of the ethylenediamine moiety, revealing a neutral form of the potential bidentate ligand.",
publisher = "Serbian Chemical Soc, Belgrade",
journal = "Journal of the Serbian Chemical Society",
title = "Novel methylene bridged ethylenediamine-type ligands: synthesis and spectral characterization",
volume = "79",
number = "10",
pages = "1199-1204",
doi = "10.2298/JSC140212042M"
}
Mihajlović-Lalić, L., Savić, A., Brađan, G., Sabo, T.,& Grgurić-Šipka, S.. (2014). Novel methylene bridged ethylenediamine-type ligands: synthesis and spectral characterization. in Journal of the Serbian Chemical Society
Serbian Chemical Soc, Belgrade., 79(10), 1199-1204.
https://doi.org/10.2298/JSC140212042M
Mihajlović-Lalić L, Savić A, Brađan G, Sabo T, Grgurić-Šipka S. Novel methylene bridged ethylenediamine-type ligands: synthesis and spectral characterization. in Journal of the Serbian Chemical Society. 2014;79(10):1199-1204.
doi:10.2298/JSC140212042M .
Mihajlović-Lalić, Ljiljana, Savić, Aleksandar, Brađan, Gabrijela, Sabo, Tibor, Grgurić-Šipka, Sanja, "Novel methylene bridged ethylenediamine-type ligands: synthesis and spectral characterization" in Journal of the Serbian Chemical Society, 79, no. 10 (2014):1199-1204,
https://doi.org/10.2298/JSC140212042M . .
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