TY  - JOUR
AU  - Bouffier, Laurent
AU  - Manojlović, Dragan D.
AU  - Kuhn, Alexander
AU  - Šojić, Nešo
PY  - 2019
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3046
AB  - Bipolar electrochemistry (BPE) contrasts very much with conventional electrochemistry because it is based on the control of the solution potential instead of the working electrode potential. In a typical setup, a piece of conducting materials is immersed in an electrolyte and submitted to an electric field. Such conditions split the interfacial nature of the materials into cathodic and anodic domains where electrochemical reactions can readily take place. BPE has many potential applications, and the present contribution aims to focus on recent analytical applications that involve electrogenerated chemiluminescence (ECL) detection. ECL is a special case of luminescence where the excited state of the luminophore is populated after a sequence of reaction that is triggered by an initial electron transfer step occurring at the electrode surface. The coupling between BPE and ECL is a powerful approach because it provides a unique opportunity to combine the intrinsic advantages of both techniques. BPE enables the spatial separation of sensing and reporting poles, whereas ECL provides a simple and sensitive visual readout. This opinion article will describe the experimental possibilities and the most recent applications of BPE/ECL coupling for the detection of biorelevant molecular targets.
T2  - Current Opinion in Electrochemistry
T1  - Advances in bipolar electrochemiluminescence for the detection of biorelevant molecular targets
VL  - 16
SP  - 28
EP  - 34
DO  - 10.1016/j.coelec.2019.04.004
ER  - 

@article{
author = "Bouffier, Laurent and Manojlović, Dragan D. and Kuhn, Alexander and Šojić, Nešo",
year = "2019",
abstract = "Bipolar electrochemistry (BPE) contrasts very much with conventional electrochemistry because it is based on the control of the solution potential instead of the working electrode potential. In a typical setup, a piece of conducting materials is immersed in an electrolyte and submitted to an electric field. Such conditions split the interfacial nature of the materials into cathodic and anodic domains where electrochemical reactions can readily take place. BPE has many potential applications, and the present contribution aims to focus on recent analytical applications that involve electrogenerated chemiluminescence (ECL) detection. ECL is a special case of luminescence where the excited state of the luminophore is populated after a sequence of reaction that is triggered by an initial electron transfer step occurring at the electrode surface. The coupling between BPE and ECL is a powerful approach because it provides a unique opportunity to combine the intrinsic advantages of both techniques. BPE enables the spatial separation of sensing and reporting poles, whereas ECL provides a simple and sensitive visual readout. This opinion article will describe the experimental possibilities and the most recent applications of BPE/ECL coupling for the detection of biorelevant molecular targets.",
journal = "Current Opinion in Electrochemistry",
title = "Advances in bipolar electrochemiluminescence for the detection of biorelevant molecular targets",
volume = "16",
pages = "28-34",
doi = "10.1016/j.coelec.2019.04.004"
}

Bouffier, L., Manojlović, D. D., Kuhn, A.,& Šojić, N.. (2019). Advances in bipolar electrochemiluminescence for the detection of biorelevant molecular targets. in Current Opinion in Electrochemistry, 16, 28-34.
https://doi.org/10.1016/j.coelec.2019.04.004

Bouffier L, Manojlović DD, Kuhn A, Šojić N. Advances in bipolar electrochemiluminescence for the detection of biorelevant molecular targets. in Current Opinion in Electrochemistry. 2019;16:28-34.
doi:10.1016/j.coelec.2019.04.004 .

Bouffier, Laurent, Manojlović, Dragan D., Kuhn, Alexander, Šojić, Nešo, "Advances in bipolar electrochemiluminescence for the detection of biorelevant molecular targets" in Current Opinion in Electrochemistry, 16 (2019):28-34,
https://doi.org/10.1016/j.coelec.2019.04.004 . .

TY  - JOUR
AU  - Bouffier, Laurent
AU  - Manojlović, Dragan D.
AU  - Kuhn, Alexander
AU  - Šojić, Nešo
PY  - 2019
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3044
AB  - Bipolar electrochemistry (BPE) contrasts very much with conventional electrochemistry because it is based on the control of the solution potential instead of the working electrode potential. In a typical setup, a piece of conducting materials is immersed in an electrolyte and submitted to an electric field. Such conditions split the interfacial nature of the materials into cathodic and anodic domains where electrochemical reactions can readily take place. BPE has many potential applications, and the present contribution aims to focus on recent analytical applications that involve electrogenerated chemiluminescence (ECL) detection. ECL is a special case of luminescence where the excited state of the luminophore is populated after a sequence of reaction that is triggered by an initial electron transfer step occurring at the electrode surface. The coupling between BPE and ECL is a powerful approach because it provides a unique opportunity to combine the intrinsic advantages of both techniques. BPE enables the spatial separation of sensing and reporting poles, whereas ECL provides a simple and sensitive visual readout. This opinion article will describe the experimental possibilities and the most recent applications of BPE/ECL coupling for the detection of biorelevant molecular targets.
T2  - Current Opinion in Electrochemistry
T1  - Advances in bipolar electrochemiluminescence for the detection of biorelevant molecular targets
VL  - 16
SP  - 28
EP  - 34
DO  - 10.1016/j.coelec.2019.04.004
ER  - 

@article{
author = "Bouffier, Laurent and Manojlović, Dragan D. and Kuhn, Alexander and Šojić, Nešo",
year = "2019",
abstract = "Bipolar electrochemistry (BPE) contrasts very much with conventional electrochemistry because it is based on the control of the solution potential instead of the working electrode potential. In a typical setup, a piece of conducting materials is immersed in an electrolyte and submitted to an electric field. Such conditions split the interfacial nature of the materials into cathodic and anodic domains where electrochemical reactions can readily take place. BPE has many potential applications, and the present contribution aims to focus on recent analytical applications that involve electrogenerated chemiluminescence (ECL) detection. ECL is a special case of luminescence where the excited state of the luminophore is populated after a sequence of reaction that is triggered by an initial electron transfer step occurring at the electrode surface. The coupling between BPE and ECL is a powerful approach because it provides a unique opportunity to combine the intrinsic advantages of both techniques. BPE enables the spatial separation of sensing and reporting poles, whereas ECL provides a simple and sensitive visual readout. This opinion article will describe the experimental possibilities and the most recent applications of BPE/ECL coupling for the detection of biorelevant molecular targets.",
journal = "Current Opinion in Electrochemistry",
title = "Advances in bipolar electrochemiluminescence for the detection of biorelevant molecular targets",
volume = "16",
pages = "28-34",
doi = "10.1016/j.coelec.2019.04.004"
}

Bouffier, L., Manojlović, D. D., Kuhn, A.,& Šojić, N.. (2019). Advances in bipolar electrochemiluminescence for the detection of biorelevant molecular targets. in Current Opinion in Electrochemistry, 16, 28-34.
https://doi.org/10.1016/j.coelec.2019.04.004

Bouffier L, Manojlović DD, Kuhn A, Šojić N. Advances in bipolar electrochemiluminescence for the detection of biorelevant molecular targets. in Current Opinion in Electrochemistry. 2019;16:28-34.
doi:10.1016/j.coelec.2019.04.004 .

Bouffier, Laurent, Manojlović, Dragan D., Kuhn, Alexander, Šojić, Nešo, "Advances in bipolar electrochemiluminescence for the detection of biorelevant molecular targets" in Current Opinion in Electrochemistry, 16 (2019):28-34,
https://doi.org/10.1016/j.coelec.2019.04.004 . .

TY  - JOUR
AU  - Sentić, Milica
AU  - Arbault, Stephane
AU  - Bouffier, Laurent
AU  - Manojlović, Dragan D.
AU  - Kuhn, Alexander
AU  - Šojić, Nešo
PY  - 2015
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1737
AB  - Among luminescence techniques, electrogenerated chemiluminescence (ECL) provides a unique level of manipulation of the luminescent process by controlling the electrochemical trigger. Despite its attractiveness, ECL is by essence a 2D process where light emission is strictly confined to the electrode surface. To overcome this intrinsic limitation, we added a new spatial dimension to the ECL process by generating 3D ECL at the level of millions of micro-emitters dispersed in solution. Each single object is addressed remotely by bipolar electrochemistry and they generate collectively the luminescence in the bulk. Therefore, the entire volume of the solution produces light. To illustrate the generality of this concept, we extended it to a suspension of multi-walled carbon nanotubes where each one acts as an individual ECL nano-emitter. This approach enables a change of paradigm by switching from a surface-limited process to 3D electrogenerated light emission.
PB  - Royal Soc Chemistry, Cambridge
T2  - Chemical Science
T1  - 3D electrogenerated chemiluminescence: from surface-confined reactions to bulk emission
VL  - 6
IS  - 8
SP  - 4433
EP  - 4437
DO  - 10.1039/c5sc01530h
ER  - 

@article{
author = "Sentić, Milica and Arbault, Stephane and Bouffier, Laurent and Manojlović, Dragan D. and Kuhn, Alexander and Šojić, Nešo",
year = "2015",
abstract = "Among luminescence techniques, electrogenerated chemiluminescence (ECL) provides a unique level of manipulation of the luminescent process by controlling the electrochemical trigger. Despite its attractiveness, ECL is by essence a 2D process where light emission is strictly confined to the electrode surface. To overcome this intrinsic limitation, we added a new spatial dimension to the ECL process by generating 3D ECL at the level of millions of micro-emitters dispersed in solution. Each single object is addressed remotely by bipolar electrochemistry and they generate collectively the luminescence in the bulk. Therefore, the entire volume of the solution produces light. To illustrate the generality of this concept, we extended it to a suspension of multi-walled carbon nanotubes where each one acts as an individual ECL nano-emitter. This approach enables a change of paradigm by switching from a surface-limited process to 3D electrogenerated light emission.",
publisher = "Royal Soc Chemistry, Cambridge",
journal = "Chemical Science",
title = "3D electrogenerated chemiluminescence: from surface-confined reactions to bulk emission",
volume = "6",
number = "8",
pages = "4433-4437",
doi = "10.1039/c5sc01530h"
}

Sentić, M., Arbault, S., Bouffier, L., Manojlović, D. D., Kuhn, A.,& Šojić, N.. (2015). 3D electrogenerated chemiluminescence: from surface-confined reactions to bulk emission. in Chemical Science
Royal Soc Chemistry, Cambridge., 6(8), 4433-4437.
https://doi.org/10.1039/c5sc01530h

Sentić M, Arbault S, Bouffier L, Manojlović DD, Kuhn A, Šojić N. 3D electrogenerated chemiluminescence: from surface-confined reactions to bulk emission. in Chemical Science. 2015;6(8):4433-4437.
doi:10.1039/c5sc01530h .

Sentić, Milica, Arbault, Stephane, Bouffier, Laurent, Manojlović, Dragan D., Kuhn, Alexander, Šojić, Nešo, "3D electrogenerated chemiluminescence: from surface-confined reactions to bulk emission" in Chemical Science, 6, no. 8 (2015):4433-4437,
https://doi.org/10.1039/c5sc01530h . .

TY  - JOUR
AU  - Sentić, Milica
AU  - Arbault, Stephane
AU  - Goudeau, Bertrand
AU  - Manojlović, Dragan D.
AU  - Kuhn, Alexander
AU  - Bouffier, Laurent
AU  - Šojić, Nešo
PY  - 2014
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1834
AB  - An electrochemiluminescent (ECL) swimmer driven by bipolar electrochemistry is reported for enzymatic glucose sensing. The chemomechanical motion is induced by localized hydrogen bubble generation. The concomitant oxidation of the luminophore and of the enzymatically-produced NADH leads to ECL emission with a direct glucose-dependent light intensity. We demonstrate herein the local sensing and reporting of glucose in a concentration gradient explored by the ECL swimmer. Such a dynamic sensing approach combines in a synergetic way the wireless propulsion with the enzymatic selectivity using ECL as a readout method at the level of moving objects.
PB  - Royal Soc Chemistry, Cambridge
T2  - Chemical Communications
T1  - Electrochemiluminescent swimmers for dynamic enzymatic sensing
VL  - 50
IS  - 71
SP  - 10202
EP  - 10205
DO  - 10.1039/c4cc04105d
ER  - 

@article{
author = "Sentić, Milica and Arbault, Stephane and Goudeau, Bertrand and Manojlović, Dragan D. and Kuhn, Alexander and Bouffier, Laurent and Šojić, Nešo",
year = "2014",
abstract = "An electrochemiluminescent (ECL) swimmer driven by bipolar electrochemistry is reported for enzymatic glucose sensing. The chemomechanical motion is induced by localized hydrogen bubble generation. The concomitant oxidation of the luminophore and of the enzymatically-produced NADH leads to ECL emission with a direct glucose-dependent light intensity. We demonstrate herein the local sensing and reporting of glucose in a concentration gradient explored by the ECL swimmer. Such a dynamic sensing approach combines in a synergetic way the wireless propulsion with the enzymatic selectivity using ECL as a readout method at the level of moving objects.",
publisher = "Royal Soc Chemistry, Cambridge",
journal = "Chemical Communications",
title = "Electrochemiluminescent swimmers for dynamic enzymatic sensing",
volume = "50",
number = "71",
pages = "10202-10205",
doi = "10.1039/c4cc04105d"
}

Sentić, M., Arbault, S., Goudeau, B., Manojlović, D. D., Kuhn, A., Bouffier, L.,& Šojić, N.. (2014). Electrochemiluminescent swimmers for dynamic enzymatic sensing. in Chemical Communications
Royal Soc Chemistry, Cambridge., 50(71), 10202-10205.
https://doi.org/10.1039/c4cc04105d

Sentić M, Arbault S, Goudeau B, Manojlović DD, Kuhn A, Bouffier L, Šojić N. Electrochemiluminescent swimmers for dynamic enzymatic sensing. in Chemical Communications. 2014;50(71):10202-10205.
doi:10.1039/c4cc04105d .

Sentić, Milica, Arbault, Stephane, Goudeau, Bertrand, Manojlović, Dragan D., Kuhn, Alexander, Bouffier, Laurent, Šojić, Nešo, "Electrochemiluminescent swimmers for dynamic enzymatic sensing" in Chemical Communications, 50, no. 71 (2014):10202-10205,
https://doi.org/10.1039/c4cc04105d . .

TY  - JOUR
AU  - Bouffier, Laurent
AU  - Zigah, Dodzi
AU  - Adam, Catherine
AU  - Sentić, Milica
AU  - Fattah, Zahra
AU  - Manojlović, Dragan D.
AU  - Kuhn, Alexander
AU  - Šojić, Nešo
PY  - 2014
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1802
PB  - Wiley-V C H Verlag Gmbh, Weinheim
T2  - CHEMELECTROCHEM
T1  - Lighting Up Redox Propulsion with Luminol Electrogenerated Chemiluminescence
VL  - 1
IS  - 1
SP  - 95
EP  - 98
DO  - 10.1002/celc.201300042
ER  - 

@article{
author = "Bouffier, Laurent and Zigah, Dodzi and Adam, Catherine and Sentić, Milica and Fattah, Zahra and Manojlović, Dragan D. and Kuhn, Alexander and Šojić, Nešo",
year = "2014",
publisher = "Wiley-V C H Verlag Gmbh, Weinheim",
journal = "CHEMELECTROCHEM",
title = "Lighting Up Redox Propulsion with Luminol Electrogenerated Chemiluminescence",
volume = "1",
number = "1",
pages = "95-98",
doi = "10.1002/celc.201300042"
}

Bouffier, L., Zigah, D., Adam, C., Sentić, M., Fattah, Z., Manojlović, D. D., Kuhn, A.,& Šojić, N.. (2014). Lighting Up Redox Propulsion with Luminol Electrogenerated Chemiluminescence. in CHEMELECTROCHEM
Wiley-V C H Verlag Gmbh, Weinheim., 1(1), 95-98.
https://doi.org/10.1002/celc.201300042

Bouffier L, Zigah D, Adam C, Sentić M, Fattah Z, Manojlović DD, Kuhn A, Šojić N. Lighting Up Redox Propulsion with Luminol Electrogenerated Chemiluminescence. in CHEMELECTROCHEM. 2014;1(1):95-98.
doi:10.1002/celc.201300042 .

Bouffier, Laurent, Zigah, Dodzi, Adam, Catherine, Sentić, Milica, Fattah, Zahra, Manojlović, Dragan D., Kuhn, Alexander, Šojić, Nešo, "Lighting Up Redox Propulsion with Luminol Electrogenerated Chemiluminescence" in CHEMELECTROCHEM, 1, no. 1 (2014):95-98,
https://doi.org/10.1002/celc.201300042 . .