TY  - JOUR
AU  - Radovanović, Dragana
AU  - Dikić, Jelena
AU  - Štulović, Marija
AU  - Anđić, Zoran
AU  - Kamberović, Željko
AU  - Jevtić, Sanja
PY  - 2023
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/6300
AB  - Low-cost and easily available natural zeolite is a promising adsorbent for metal ions removal in wastewater treatment. The possibility of using zeolitic tuff from Serbia in the form of Na-enriched natural zeolite (Na-Z) for the adsorption of Pb2+, Zn2+, Cu2+, and Ni2+ ions from wastewater was investigated in the presented paper. The research included Na-Z characterization and determination of adsorption kinetics in individual ion adsorption tests using Weber-Morris intraparticle diffusion model, non-linear pseudo-first-order (PFO), pseudo-second-order (PSO) and mixed-order (MO) kinetic models. The results indicate that the adsorption processes of metal ions on Na-Z are complex processes dominated by multiple rate-limiting mechanisms and best defined by the MO model. The mechanisms of ion diffusion and adsorption to active sites are equally represented in the Pb2+ adsorption process. The mechanism of ion adsorption on the active sites is the rate-limiting step in the Zn2+ adsorption process, while in the case of the Cu2+ and Ni2+ adsorption ion diffusion is the rate-limiting kinetic mechanism. Within the MO model, the PFO rate (external/internal diffusion) and the PSO rate (adsorption on active sites) were calculated and results were applied to a multicomponent wastewater sample in order to determine and explain the adsorption efficiency in wastewater treatment. The results show that the rate of adsorption of individual metal ions and the efficiency of ion removal from a multicomponent wastewater sample are influenced by several factors including the radius of the hydrated ion and the free energy of hydration. The achieved removal of metal ions by Na-Z is Pb2+ (89%) > Cu2+ (72%) > Zn2+ (61%) > Ni2+ (58%) and defines Na-enriched natural zeolite as an effective adsorbent in wastewater treatment.
PB  - Association of Metallurgical Engineers of Serbia AMES
T2  - Metallurgical and Materials Engineering
T1  - Sorption of Pb2+, Zn2+, Cu2+ and Ni2+ Ions on Na-enriched Natural Zeolite for Wastewater Treatment Process: A Kinetic Approach
VL  - 29
IS  - 3
SP  - 20
EP  - 35
DO  - 10.56801/MME1007
ER  - 

@article{
author = "Radovanović, Dragana and Dikić, Jelena and Štulović, Marija and Anđić, Zoran and Kamberović, Željko and Jevtić, Sanja",
year = "2023",
abstract = "Low-cost and easily available natural zeolite is a promising adsorbent for metal ions removal in wastewater treatment. The possibility of using zeolitic tuff from Serbia in the form of Na-enriched natural zeolite (Na-Z) for the adsorption of Pb2+, Zn2+, Cu2+, and Ni2+ ions from wastewater was investigated in the presented paper. The research included Na-Z characterization and determination of adsorption kinetics in individual ion adsorption tests using Weber-Morris intraparticle diffusion model, non-linear pseudo-first-order (PFO), pseudo-second-order (PSO) and mixed-order (MO) kinetic models. The results indicate that the adsorption processes of metal ions on Na-Z are complex processes dominated by multiple rate-limiting mechanisms and best defined by the MO model. The mechanisms of ion diffusion and adsorption to active sites are equally represented in the Pb2+ adsorption process. The mechanism of ion adsorption on the active sites is the rate-limiting step in the Zn2+ adsorption process, while in the case of the Cu2+ and Ni2+ adsorption ion diffusion is the rate-limiting kinetic mechanism. Within the MO model, the PFO rate (external/internal diffusion) and the PSO rate (adsorption on active sites) were calculated and results were applied to a multicomponent wastewater sample in order to determine and explain the adsorption efficiency in wastewater treatment. The results show that the rate of adsorption of individual metal ions and the efficiency of ion removal from a multicomponent wastewater sample are influenced by several factors including the radius of the hydrated ion and the free energy of hydration. The achieved removal of metal ions by Na-Z is Pb2+ (89%) > Cu2+ (72%) > Zn2+ (61%) > Ni2+ (58%) and defines Na-enriched natural zeolite as an effective adsorbent in wastewater treatment.",
publisher = "Association of Metallurgical Engineers of Serbia AMES",
journal = "Metallurgical and Materials Engineering",
title = "Sorption of Pb2+, Zn2+, Cu2+ and Ni2+ Ions on Na-enriched Natural Zeolite for Wastewater Treatment Process: A Kinetic Approach",
volume = "29",
number = "3",
pages = "20-35",
doi = "10.56801/MME1007"
}

Radovanović, D., Dikić, J., Štulović, M., Anđić, Z., Kamberović, Ž.,& Jevtić, S.. (2023). Sorption of Pb2+, Zn2+, Cu2+ and Ni2+ Ions on Na-enriched Natural Zeolite for Wastewater Treatment Process: A Kinetic Approach. in Metallurgical and Materials Engineering
Association of Metallurgical Engineers of Serbia AMES., 29(3), 20-35.
https://doi.org/10.56801/MME1007

Radovanović D, Dikić J, Štulović M, Anđić Z, Kamberović Ž, Jevtić S. Sorption of Pb2+, Zn2+, Cu2+ and Ni2+ Ions on Na-enriched Natural Zeolite for Wastewater Treatment Process: A Kinetic Approach. in Metallurgical and Materials Engineering. 2023;29(3):20-35.
doi:10.56801/MME1007 .

Radovanović, Dragana, Dikić, Jelena, Štulović, Marija, Anđić, Zoran, Kamberović, Željko, Jevtić, Sanja, "Sorption of Pb2+, Zn2+, Cu2+ and Ni2+ Ions on Na-enriched Natural Zeolite for Wastewater Treatment Process: A Kinetic Approach" in Metallurgical and Materials Engineering, 29, no. 3 (2023):20-35,
https://doi.org/10.56801/MME1007 . .

TY  - CONF
AU  - Đokić, Jovana
AU  - Štulović, Marija
AU  - Korać, Marija
AU  - Anđić, Zoran
AU  - Kamberović, Željko
PY  - 2023
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/6305
AB  - More than 90 % of lead produced in Europe comes from secondary lead flows, of
which 85 % is attributed to waste lead-acid batteries (LAB). The main technological
approach for LAB processing implies pyrometallurgy by which 100–400 kg of waste slag
(WS) is generated per 1 ton of produced metallic lead. Due to recycling process parameters,
generated WS has great potential for releasing toxic elements contributing to environmental
pollution [1]. Namely, the most common flux in the recycling process is sodium-based
(Na2CO3) when alkali lead waste slag (ALWS) is generated, characterized as hazardous due
to its physical-chemical characteristics: high leachability, hygroscopic and pulverized
nature and, ultimately, instability [2,3]. Therefore, ALWS treatment prior to disposal should
be considered an integral part of waste LAB treatment systems. Immobilization of toxic
elements contained in slag is crucial and can be achieved by stabilization/solidification
processes (S/S) as one of the most widely used technologies in the treatment of heavy metal containing wastes for final disposal or utilization.
In this research, ALWS generated in the waste LAB recycling is used to determine
the S/S process efficiency as a function of the added binder amount (cement, in the range of
5 – 10 %), pre-treatment (the removal of water-soluble compounds), and activator addition
(MgO). The liquid to solid (L/S) ratio was 1/4 in all S/S experiments. The basic parameters
for the effectiveness assessments were compressive strength (UCS) and pollutants leaching
(Method 1311 Toxicity characteristic leaching procedure, TCLP).
The conclusion is that, contrary to the pre-treatment process, the addition of MgO has
an overall positive effect on the S/S process of ALSW, ensuring both mechanical and
chemical stability. This ALWS solidificate, obtained through the S/S process by using MgO
as an activator, is safe for disposal, according to environmental regulations.
PB  - Belgrade : Serbian Chemical Society
C3  - 9th Symposium Chemistry and Environmental Protection EnviroChem2023 with International Participation, Book of Abstracts, Kladovo, June 4-7, 2023
T1  - Stabilization/solidification process of alkali lead waste slag: influence of pre-treatment and addition of selected additives
SP  - 177
EP  - 178
UR  - https://hdl.handle.net/21.15107/rcub_cherry_6305
ER  - 

@conference{
author = "Đokić, Jovana and Štulović, Marija and Korać, Marija and Anđić, Zoran and Kamberović, Željko",
year = "2023",
abstract = "More than 90 % of lead produced in Europe comes from secondary lead flows, of
which 85 % is attributed to waste lead-acid batteries (LAB). The main technological
approach for LAB processing implies pyrometallurgy by which 100–400 kg of waste slag
(WS) is generated per 1 ton of produced metallic lead. Due to recycling process parameters,
generated WS has great potential for releasing toxic elements contributing to environmental
pollution [1]. Namely, the most common flux in the recycling process is sodium-based
(Na2CO3) when alkali lead waste slag (ALWS) is generated, characterized as hazardous due
to its physical-chemical characteristics: high leachability, hygroscopic and pulverized
nature and, ultimately, instability [2,3]. Therefore, ALWS treatment prior to disposal should
be considered an integral part of waste LAB treatment systems. Immobilization of toxic
elements contained in slag is crucial and can be achieved by stabilization/solidification
processes (S/S) as one of the most widely used technologies in the treatment of heavy metal containing wastes for final disposal or utilization.
In this research, ALWS generated in the waste LAB recycling is used to determine
the S/S process efficiency as a function of the added binder amount (cement, in the range of
5 – 10 %), pre-treatment (the removal of water-soluble compounds), and activator addition
(MgO). The liquid to solid (L/S) ratio was 1/4 in all S/S experiments. The basic parameters
for the effectiveness assessments were compressive strength (UCS) and pollutants leaching
(Method 1311 Toxicity characteristic leaching procedure, TCLP).
The conclusion is that, contrary to the pre-treatment process, the addition of MgO has
an overall positive effect on the S/S process of ALSW, ensuring both mechanical and
chemical stability. This ALWS solidificate, obtained through the S/S process by using MgO
as an activator, is safe for disposal, according to environmental regulations.",
publisher = "Belgrade : Serbian Chemical Society",
journal = "9th Symposium Chemistry and Environmental Protection EnviroChem2023 with International Participation, Book of Abstracts, Kladovo, June 4-7, 2023",
title = "Stabilization/solidification process of alkali lead waste slag: influence of pre-treatment and addition of selected additives",
pages = "177-178",
url = "https://hdl.handle.net/21.15107/rcub_cherry_6305"
}

Đokić, J., Štulović, M., Korać, M., Anđić, Z.,& Kamberović, Ž.. (2023). Stabilization/solidification process of alkali lead waste slag: influence of pre-treatment and addition of selected additives. in 9th Symposium Chemistry and Environmental Protection EnviroChem2023 with International Participation, Book of Abstracts, Kladovo, June 4-7, 2023
Belgrade : Serbian Chemical Society., 177-178.
https://hdl.handle.net/21.15107/rcub_cherry_6305

Đokić J, Štulović M, Korać M, Anđić Z, Kamberović Ž. Stabilization/solidification process of alkali lead waste slag: influence of pre-treatment and addition of selected additives. in 9th Symposium Chemistry and Environmental Protection EnviroChem2023 with International Participation, Book of Abstracts, Kladovo, June 4-7, 2023. 2023;:177-178.
https://hdl.handle.net/21.15107/rcub_cherry_6305 .

Đokić, Jovana, Štulović, Marija, Korać, Marija, Anđić, Zoran, Kamberović, Željko, "Stabilization/solidification process of alkali lead waste slag: influence of pre-treatment and addition of selected additives" in 9th Symposium Chemistry and Environmental Protection EnviroChem2023 with International Participation, Book of Abstracts, Kladovo, June 4-7, 2023 (2023):177-178,
https://hdl.handle.net/21.15107/rcub_cherry_6305 .

TY  - JOUR
AU  - Štulović, Marija
AU  - Radovanović, Dragana
AU  - Kamberović, Željko
AU  - Korać, Marija
AU  - Anđić, Zoran
PY  - 2019
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3292
AB  - Reuse of waste is one of the main principles of sustainable development and circular economy. Secondary alkaline lead slag is a hazardous waste generated in the recycling process of lead-acid batteries that may be suitable in construction materials. The environmental impact of the use of lead slag as a partial replacement of fine aggregates in the cement-based stabilization/solidification (S/S) process for the preparation of concrete was studied in this paper. Solidified products containing 10%, 15%, 20%, and 25% slag were laboratory tested by unconfined compressive strength (UCS) analyses and the Toxicity Characteristic Leaching Procedure (TCLP). At the same time, the leachability of toxic elements from solidified products with a high percent of slag was evaluated under environmental conditions for during one year. The results of the UCS and TCLP indicated that utilization of this type of slag in cement-based applications may be justified with its controlled addition. However, the described application of the slag was disputed due to the high release of As under high alkaline environmental conditions. Eh-pH analyses and the geochemical modeling using the software PHREEQC were evaluated, as well as the mechanism of pollutant (Pb, As) immobilization (precipitation, adsorption) as a function of pH conditions.
PB  - MDPI
T2  - International Journal of Environmental Research and Public Health
T1  - Assessment of leaching characteristics of solidified products containing secondary alkaline lead slag
VL  - 16
IS  - 11
DO  - 10.3390/ijerph16112005
ER  - 

@article{
author = "Štulović, Marija and Radovanović, Dragana and Kamberović, Željko and Korać, Marija and Anđić, Zoran",
year = "2019",
abstract = "Reuse of waste is one of the main principles of sustainable development and circular economy. Secondary alkaline lead slag is a hazardous waste generated in the recycling process of lead-acid batteries that may be suitable in construction materials. The environmental impact of the use of lead slag as a partial replacement of fine aggregates in the cement-based stabilization/solidification (S/S) process for the preparation of concrete was studied in this paper. Solidified products containing 10%, 15%, 20%, and 25% slag were laboratory tested by unconfined compressive strength (UCS) analyses and the Toxicity Characteristic Leaching Procedure (TCLP). At the same time, the leachability of toxic elements from solidified products with a high percent of slag was evaluated under environmental conditions for during one year. The results of the UCS and TCLP indicated that utilization of this type of slag in cement-based applications may be justified with its controlled addition. However, the described application of the slag was disputed due to the high release of As under high alkaline environmental conditions. Eh-pH analyses and the geochemical modeling using the software PHREEQC were evaluated, as well as the mechanism of pollutant (Pb, As) immobilization (precipitation, adsorption) as a function of pH conditions.",
publisher = "MDPI",
journal = "International Journal of Environmental Research and Public Health",
title = "Assessment of leaching characteristics of solidified products containing secondary alkaline lead slag",
volume = "16",
number = "11",
doi = "10.3390/ijerph16112005"
}

Štulović, M., Radovanović, D., Kamberović, Ž., Korać, M.,& Anđić, Z.. (2019). Assessment of leaching characteristics of solidified products containing secondary alkaline lead slag. in International Journal of Environmental Research and Public Health
MDPI., 16(11).
https://doi.org/10.3390/ijerph16112005

Štulović M, Radovanović D, Kamberović Ž, Korać M, Anđić Z. Assessment of leaching characteristics of solidified products containing secondary alkaline lead slag. in International Journal of Environmental Research and Public Health. 2019;16(11).
doi:10.3390/ijerph16112005 .

Štulović, Marija, Radovanović, Dragana, Kamberović, Željko, Korać, Marija, Anđić, Zoran, "Assessment of leaching characteristics of solidified products containing secondary alkaline lead slag" in International Journal of Environmental Research and Public Health, 16, no. 11 (2019),
https://doi.org/10.3390/ijerph16112005 . .

TY  - JOUR
AU  - Štulović, Marija
AU  - Radovanović, Dragana
AU  - Kamberović, Željko
AU  - Korać, Marija
AU  - Anđić, Zoran
AU  - Ranitović, Milisav
PY  - 2019
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3695
AB  - Secondary alkaline lead slag (SALS), generated during lead–acid batteries recycling, is a hazardous waste due to its high reactivity, solubility, and migration of toxic elements. After pulverization caused by storage under atmospheric condition for 30 days, the SALS was sieved and coarse fraction (+ 1 mm) was returned to the recycling process. Finer fraction (− 1 mm) was treated by water leaching to remove soluble compounds. SALS compositions prior and after the pre-treatment and effects of liquid-to-solid ratio, stirring rate, and temperature on Na, S, Fe, As, and Pb leaching from SALS were analyzed. The results show that maximal leaching degrees were 95.78%, 75.32%, and 79.89% for Na, S, and As, respectively (20 l kg−1, 600 min−1, 333 K, 120 min). Leachability of Na and S from SALS was controlled by dissolution of Na2SO4 that could be recovered from leaching solution. Isothermal As leaching is described by diffusion mechanism with activation energy of 15.5 kJ mol−1. Insoluble Pb and Fe sulfates, sulfides, and oxides remained in the SALS. Pre-treated SALS, with reduced mass up to 32%, was solidified in cement matrix. The results of toxicity characteristic leaching procedure and unconfined compressive strength confirmed effectiveness of As removal from SALS by water leaching and Pb immobilization in cement matrix containing 20% of SALS.
PB  - Springer Japan
T2  - Journal of Material Cycles and Waste Management
T1  - Leaching of toxic elements from secondary alkaline lead slag and stabilized/solidified products
VL  - 21
IS  - 6
SP  - 1402
EP  - 1413
DO  - 10.1007/s10163-019-00892-8
ER  - 

@article{
author = "Štulović, Marija and Radovanović, Dragana and Kamberović, Željko and Korać, Marija and Anđić, Zoran and Ranitović, Milisav",
year = "2019",
abstract = "Secondary alkaline lead slag (SALS), generated during lead–acid batteries recycling, is a hazardous waste due to its high reactivity, solubility, and migration of toxic elements. After pulverization caused by storage under atmospheric condition for 30 days, the SALS was sieved and coarse fraction (+ 1 mm) was returned to the recycling process. Finer fraction (− 1 mm) was treated by water leaching to remove soluble compounds. SALS compositions prior and after the pre-treatment and effects of liquid-to-solid ratio, stirring rate, and temperature on Na, S, Fe, As, and Pb leaching from SALS were analyzed. The results show that maximal leaching degrees were 95.78%, 75.32%, and 79.89% for Na, S, and As, respectively (20 l kg−1, 600 min−1, 333 K, 120 min). Leachability of Na and S from SALS was controlled by dissolution of Na2SO4 that could be recovered from leaching solution. Isothermal As leaching is described by diffusion mechanism with activation energy of 15.5 kJ mol−1. Insoluble Pb and Fe sulfates, sulfides, and oxides remained in the SALS. Pre-treated SALS, with reduced mass up to 32%, was solidified in cement matrix. The results of toxicity characteristic leaching procedure and unconfined compressive strength confirmed effectiveness of As removal from SALS by water leaching and Pb immobilization in cement matrix containing 20% of SALS.",
publisher = "Springer Japan",
journal = "Journal of Material Cycles and Waste Management",
title = "Leaching of toxic elements from secondary alkaline lead slag and stabilized/solidified products",
volume = "21",
number = "6",
pages = "1402-1413",
doi = "10.1007/s10163-019-00892-8"
}

Štulović, M., Radovanović, D., Kamberović, Ž., Korać, M., Anđić, Z.,& Ranitović, M.. (2019). Leaching of toxic elements from secondary alkaline lead slag and stabilized/solidified products. in Journal of Material Cycles and Waste Management
Springer Japan., 21(6), 1402-1413.
https://doi.org/10.1007/s10163-019-00892-8

Štulović M, Radovanović D, Kamberović Ž, Korać M, Anđić Z, Ranitović M. Leaching of toxic elements from secondary alkaline lead slag and stabilized/solidified products. in Journal of Material Cycles and Waste Management. 2019;21(6):1402-1413.
doi:10.1007/s10163-019-00892-8 .

Štulović, Marija, Radovanović, Dragana, Kamberović, Željko, Korać, Marija, Anđić, Zoran, Ranitović, Milisav, "Leaching of toxic elements from secondary alkaline lead slag and stabilized/solidified products" in Journal of Material Cycles and Waste Management, 21, no. 6 (2019):1402-1413,
https://doi.org/10.1007/s10163-019-00892-8 . .

TY  - JOUR
AU  - Štulović, Marija
AU  - Mihailović, Aleksandar
AU  - Anđić, Zoran
AU  - Korać, Marija
AU  - Kamberović, Željko
PY  - 2014
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5087
AB  - Modification and optimization of the pyrometallurgical process of lead
recovering from the waste lead-acid batteries have been studied in this paper. The aim
of this research is to develop a cleaner production in the field of the secondary lead
metallurgy. Lead smelting process with the addition of flux (sodium(I)-carbonate) and
reducing agents (coke, iron) has been followed. The modified smelting process with the
addition of hazardous waste (activated carbon) as alternative reducing agents has shown
positive results on the quality of the secondary lead, the generated slag and the process
gases. Filtration efficiency of the gases, the return of baghouse dust to the process and
use of oxygen burners have positive effect on the environment protection and energy
efficiency. Optimization of the recycling process has been based on the properties of the
slag. Stabilization of slag is proposed in the furnace with addition of waste dust from
the recycling of cathode ray tube (CRT) monitors. Phosphorus compounds from dust
reduce leachability of toxic elements from the generated slag. Reduction the slag amount and its hazardous character through the elimination of migratory heavy metals
and valorization of useful components have been proposed in the patented innovative
device - cylindrical rotating washer/separator.
PB  - Association of Metallurgical Engineers of Serbia AMES
T2  - Metallurgical & Materials Engineering
T1  - Positive synergistic effect of the hazardous waste use for secondary lead metallurgy, energy efficiency and waste minimization
VL  - 20
IS  - 3
SP  - 171
EP  - 181
UR  - https://hdl.handle.net/21.15107/rcub_cherry_5087
ER  - 

@article{
author = "Štulović, Marija and Mihailović, Aleksandar and Anđić, Zoran and Korać, Marija and Kamberović, Željko",
year = "2014",
abstract = "Modification and optimization of the pyrometallurgical process of lead
recovering from the waste lead-acid batteries have been studied in this paper. The aim
of this research is to develop a cleaner production in the field of the secondary lead
metallurgy. Lead smelting process with the addition of flux (sodium(I)-carbonate) and
reducing agents (coke, iron) has been followed. The modified smelting process with the
addition of hazardous waste (activated carbon) as alternative reducing agents has shown
positive results on the quality of the secondary lead, the generated slag and the process
gases. Filtration efficiency of the gases, the return of baghouse dust to the process and
use of oxygen burners have positive effect on the environment protection and energy
efficiency. Optimization of the recycling process has been based on the properties of the
slag. Stabilization of slag is proposed in the furnace with addition of waste dust from
the recycling of cathode ray tube (CRT) monitors. Phosphorus compounds from dust
reduce leachability of toxic elements from the generated slag. Reduction the slag amount and its hazardous character through the elimination of migratory heavy metals
and valorization of useful components have been proposed in the patented innovative
device - cylindrical rotating washer/separator.",
publisher = "Association of Metallurgical Engineers of Serbia AMES",
journal = "Metallurgical & Materials Engineering",
title = "Positive synergistic effect of the hazardous waste use for secondary lead metallurgy, energy efficiency and waste minimization",
volume = "20",
number = "3",
pages = "171-181",
url = "https://hdl.handle.net/21.15107/rcub_cherry_5087"
}

Štulović, M., Mihailović, A., Anđić, Z., Korać, M.,& Kamberović, Ž.. (2014). Positive synergistic effect of the hazardous waste use for secondary lead metallurgy, energy efficiency and waste minimization. in Metallurgical & Materials Engineering
Association of Metallurgical Engineers of Serbia AMES., 20(3), 171-181.
https://hdl.handle.net/21.15107/rcub_cherry_5087

Štulović M, Mihailović A, Anđić Z, Korać M, Kamberović Ž. Positive synergistic effect of the hazardous waste use for secondary lead metallurgy, energy efficiency and waste minimization. in Metallurgical & Materials Engineering. 2014;20(3):171-181.
https://hdl.handle.net/21.15107/rcub_cherry_5087 .

Štulović, Marija, Mihailović, Aleksandar, Anđić, Zoran, Korać, Marija, Kamberović, Željko, "Positive synergistic effect of the hazardous waste use for secondary lead metallurgy, energy efficiency and waste minimization" in Metallurgical & Materials Engineering, 20, no. 3 (2014):171-181,
https://hdl.handle.net/21.15107/rcub_cherry_5087 .

TY  - JOUR
AU  - Štulović, Marija
AU  - Ivsic-Bajceta, Dragana
AU  - Ristić, Mirjana
AU  - Kamberović, Željko
AU  - Korać, Marija
AU  - Anđić, Zoran
PY  - 2013
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1415
AB  - Sodium lead slag, generated during secondary lead production, is characterized as hazardous waste. The aim of the study was to investigate leaching mechanism and behaviour of lead and arsenic from sodium lead slag previously stabilized/solidified in concrete using additives: MgO, CaO, Ba(OH)(2) and gypsum. The influence of selected additives on pollutant release was also investigated. The results of the NEN 7375 leaching test indicate dissolution of lead and arsenic from the outer layer of specimens, followed by depletion of possible mobile forms. Analysis of leachates from samples with various compositions showed that proper selection of additives may reduce leaching of Pb and As below the specified limits.
PB  - Technical Univ Wroclaw, Wroclaw
T2  - Environment Protection Engineering
T1  - Leaching Properties of Secondary Lead Slag Stabilized/Solidified with Cement and Selected Additives
VL  - 39
IS  - 3
SP  - 149
EP  - 163
DO  - 10.37190/epe130311
ER  - 

@article{
author = "Štulović, Marija and Ivsic-Bajceta, Dragana and Ristić, Mirjana and Kamberović, Željko and Korać, Marija and Anđić, Zoran",
year = "2013",
abstract = "Sodium lead slag, generated during secondary lead production, is characterized as hazardous waste. The aim of the study was to investigate leaching mechanism and behaviour of lead and arsenic from sodium lead slag previously stabilized/solidified in concrete using additives: MgO, CaO, Ba(OH)(2) and gypsum. The influence of selected additives on pollutant release was also investigated. The results of the NEN 7375 leaching test indicate dissolution of lead and arsenic from the outer layer of specimens, followed by depletion of possible mobile forms. Analysis of leachates from samples with various compositions showed that proper selection of additives may reduce leaching of Pb and As below the specified limits.",
publisher = "Technical Univ Wroclaw, Wroclaw",
journal = "Environment Protection Engineering",
title = "Leaching Properties of Secondary Lead Slag Stabilized/Solidified with Cement and Selected Additives",
volume = "39",
number = "3",
pages = "149-163",
doi = "10.37190/epe130311"
}

Štulović, M., Ivsic-Bajceta, D., Ristić, M., Kamberović, Ž., Korać, M.,& Anđić, Z.. (2013). Leaching Properties of Secondary Lead Slag Stabilized/Solidified with Cement and Selected Additives. in Environment Protection Engineering
Technical Univ Wroclaw, Wroclaw., 39(3), 149-163.
https://doi.org/10.37190/epe130311

Štulović M, Ivsic-Bajceta D, Ristić M, Kamberović Ž, Korać M, Anđić Z. Leaching Properties of Secondary Lead Slag Stabilized/Solidified with Cement and Selected Additives. in Environment Protection Engineering. 2013;39(3):149-163.
doi:10.37190/epe130311 .

Štulović, Marija, Ivsic-Bajceta, Dragana, Ristić, Mirjana, Kamberović, Željko, Korać, Marija, Anđić, Zoran, "Leaching Properties of Secondary Lead Slag Stabilized/Solidified with Cement and Selected Additives" in Environment Protection Engineering, 39, no. 3 (2013):149-163,
https://doi.org/10.37190/epe130311 . .

TY  - JOUR
AU  - Kamberović, Željko
AU  - Korać, Marija
AU  - Anđić, Zoran
AU  - Štulović, Marija
AU  - Kovačević, Tihomir
AU  - Vujović, Aleksandar
AU  - Ilić, Ilija
PY  - 2012
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5326
AB  - This paper presents a preliminary design for treatment of mining and metallurgical
wastewaters (MMW) from the basin of antimony “Zajača“, which contains high
concentrations of arsenic and antimony. MMW have been investigated in laboratory,
due to large difference in concentrations of pollutants. Metallurgical wastewaters were
treated using iron (II)-sulfate and lime milk used to adjust the pH value at 7. After
chemical treatment of metallurgical wastewater and its joining with mining wastewater,
residual amount of arsenic in water was below maximum allowed concentrations, while
the concentration of antimony, remained above the maximum allowed value. The final
phase of purification process was performed using ion exchange resin. After treatment
of MMW, they can be used as technical water in the smelting process of secondary raw
lead materials.
PB  - Association of Metallurgical Engineers of Serbia AMES
T2  - Metallurgical and Materials Engineering
T1  - Conteptual design for treatment of mining and metallurgical wastewaters which contains arsenic and antimony
VL  - 18
IS  - 4
SP  - 321
EP  - 331
UR  - https://hdl.handle.net/21.15107/rcub_cherry_5326
ER  - 

@article{
author = "Kamberović, Željko and Korać, Marija and Anđić, Zoran and Štulović, Marija and Kovačević, Tihomir and Vujović, Aleksandar and Ilić, Ilija",
year = "2012",
abstract = "This paper presents a preliminary design for treatment of mining and metallurgical
wastewaters (MMW) from the basin of antimony “Zajača“, which contains high
concentrations of arsenic and antimony. MMW have been investigated in laboratory,
due to large difference in concentrations of pollutants. Metallurgical wastewaters were
treated using iron (II)-sulfate and lime milk used to adjust the pH value at 7. After
chemical treatment of metallurgical wastewater and its joining with mining wastewater,
residual amount of arsenic in water was below maximum allowed concentrations, while
the concentration of antimony, remained above the maximum allowed value. The final
phase of purification process was performed using ion exchange resin. After treatment
of MMW, they can be used as technical water in the smelting process of secondary raw
lead materials.",
publisher = "Association of Metallurgical Engineers of Serbia AMES",
journal = "Metallurgical and Materials Engineering",
title = "Conteptual design for treatment of mining and metallurgical wastewaters which contains arsenic and antimony",
volume = "18",
number = "4",
pages = "321-331",
url = "https://hdl.handle.net/21.15107/rcub_cherry_5326"
}

Kamberović, Ž., Korać, M., Anđić, Z., Štulović, M., Kovačević, T., Vujović, A.,& Ilić, I.. (2012). Conteptual design for treatment of mining and metallurgical wastewaters which contains arsenic and antimony. in Metallurgical and Materials Engineering
Association of Metallurgical Engineers of Serbia AMES., 18(4), 321-331.
https://hdl.handle.net/21.15107/rcub_cherry_5326

Kamberović Ž, Korać M, Anđić Z, Štulović M, Kovačević T, Vujović A, Ilić I. Conteptual design for treatment of mining and metallurgical wastewaters which contains arsenic and antimony. in Metallurgical and Materials Engineering. 2012;18(4):321-331.
https://hdl.handle.net/21.15107/rcub_cherry_5326 .

Kamberović, Željko, Korać, Marija, Anđić, Zoran, Štulović, Marija, Kovačević, Tihomir, Vujović, Aleksandar, Ilić, Ilija, "Conteptual design for treatment of mining and metallurgical wastewaters which contains arsenic and antimony" in Metallurgical and Materials Engineering, 18, no. 4 (2012):321-331,
https://hdl.handle.net/21.15107/rcub_cherry_5326 .

TY  - JOUR
AU  - Kamberović, Željko
AU  - Korać, Marija
AU  - Anđić, Zoran
AU  - Štulović, Marija
AU  - Kovačević, Tihomir
AU  - Vujović, Aleksandar
AU  - Ilić, Ilija
PY  - 2012
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/178
AB  - This paper presents a preliminary design for treatment of mining and metallurgical wastewaters (MMW) from the basin of antimony 'Zajača', which contains high concentrations of arsenic and antimony. MMW have been investigated in laboratory, due to large difference in concentrations of pollutants. Metallurgical wastewaters were treated using iron (II)-sulfate and lime milk used to adjust the pH value at 7. After chemical treatment of metallurgical wastewater and its joining with mining wastewater, residual amount of arsenic in water was below maximum allowed concentrations, while the concentration of antimony, remained above the maximum allowed value. The final phase of purification process was performed using ion exchange resin. After treatment of MMW, they can be used as technical water in the smelting process of secondary raw lead materials.
T2  - Metallurgical and Materials Engineering
T1  - Conceptual design for treatment of mining and metallurgical wastewaters which contains arsenic and antimony
VL  - 18
IS  - 4
SP  - 321
EP  - 331
UR  - https://hdl.handle.net/21.15107/rcub_cherry_178
ER  - 

@article{
author = "Kamberović, Željko and Korać, Marija and Anđić, Zoran and Štulović, Marija and Kovačević, Tihomir and Vujović, Aleksandar and Ilić, Ilija",
year = "2012",
abstract = "This paper presents a preliminary design for treatment of mining and metallurgical wastewaters (MMW) from the basin of antimony 'Zajača', which contains high concentrations of arsenic and antimony. MMW have been investigated in laboratory, due to large difference in concentrations of pollutants. Metallurgical wastewaters were treated using iron (II)-sulfate and lime milk used to adjust the pH value at 7. After chemical treatment of metallurgical wastewater and its joining with mining wastewater, residual amount of arsenic in water was below maximum allowed concentrations, while the concentration of antimony, remained above the maximum allowed value. The final phase of purification process was performed using ion exchange resin. After treatment of MMW, they can be used as technical water in the smelting process of secondary raw lead materials.",
journal = "Metallurgical and Materials Engineering",
title = "Conceptual design for treatment of mining and metallurgical wastewaters which contains arsenic and antimony",
volume = "18",
number = "4",
pages = "321-331",
url = "https://hdl.handle.net/21.15107/rcub_cherry_178"
}

Kamberović, Ž., Korać, M., Anđić, Z., Štulović, M., Kovačević, T., Vujović, A.,& Ilić, I.. (2012). Conceptual design for treatment of mining and metallurgical wastewaters which contains arsenic and antimony. in Metallurgical and Materials Engineering, 18(4), 321-331.
https://hdl.handle.net/21.15107/rcub_cherry_178

Kamberović Ž, Korać M, Anđić Z, Štulović M, Kovačević T, Vujović A, Ilić I. Conceptual design for treatment of mining and metallurgical wastewaters which contains arsenic and antimony. in Metallurgical and Materials Engineering. 2012;18(4):321-331.
https://hdl.handle.net/21.15107/rcub_cherry_178 .

Kamberović, Željko, Korać, Marija, Anđić, Zoran, Štulović, Marija, Kovačević, Tihomir, Vujović, Aleksandar, Ilić, Ilija, "Conceptual design for treatment of mining and metallurgical wastewaters which contains arsenic and antimony" in Metallurgical and Materials Engineering, 18, no. 4 (2012):321-331,
https://hdl.handle.net/21.15107/rcub_cherry_178 .