Vuckovic, Gordana

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  • Vuckovic, Gordana (4)
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Author's Bibliography

Crystal structure, thermal behavior, and microbiological activity of a thiosemicarbazide-type ligand and its cobalt complexes

Hollo, Berta; Rodić, Marko; Vojinović-Ješić, Ljiljana S.; Živković-Radovanović, Vukosava; Vuckovic, Gordana; Leovac, Vukadin M.; Szecsenyi, Katalin Meszaros

(Springer, Dordrecht, 2014)

TY  - JOUR
AU  - Hollo, Berta
AU  - Rodić, Marko
AU  - Vojinović-Ješić, Ljiljana S.
AU  - Živković-Radovanović, Vukosava
AU  - Vuckovic, Gordana
AU  - Leovac, Vukadin M.
AU  - Szecsenyi, Katalin Meszaros
PY  - 2014
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1767
AB  - The synthesis of a potentially bioactive mixed-valence Co-III/Co-II complex with 2-acetylpyridine S-methylisothiosemicarbazone (HL) ligand is described. The crystal and molecular structure of the formed [(CoL2)-L-III][(CoCl3)-Cl-II py]center dot Me2CO (I) compound (py stands for pyridine) is determined by single-crystal X-ray crystallography. It's thermal decomposition along with the decomposition of the ligand and six structurally related complexes with formulas [CoL2]NO3 center dot MeOH (1), [CoL2]Br center dot MeOH (2), [CoL2]HSO4 center dot MeOH (3), [CoL2](2)[Co-II(NCS)(4)] (4), [Co(HL)(L)]I-2 center dot 2MeOH (5), and [Co(HL)(L)][(CoCl4)-Cl-II]center dot MeOH (6) was determined by simultaneous TG/DSC measurements. The decomposition pattern is evaluated using TG/DTA-MS data. The results were related to the solvent/moisture content and the decomposition mechanism of the compounds. The antimicrobial activity of the ligand and of all the complexes was tested in vitro for selected gram-negative and gram-positive bacteria and fungi. The activity of the ligand against all tested bacteria is comparable with those obtained for standard antibiotics, while it is less active against fungi. Surprisingly, the activity of the complexes is very low. The low antimicrobial activity of the complexes may be in connection with their high thermodynamic and kinetic inertness in solution. The results are also supported by the relatively high thermal stability of the complexes.
PB  - Springer, Dordrecht
T2  - Journal of Thermal Analysis and Calorimetry
T1  - Crystal structure, thermal behavior, and microbiological activity of a thiosemicarbazide-type ligand and its cobalt complexes
VL  - 116
IS  - 2
SP  - 655
EP  - 662
DO  - 10.1007/s10973-013-3489-1
ER  - 
@article{
author = "Hollo, Berta and Rodić, Marko and Vojinović-Ješić, Ljiljana S. and Živković-Radovanović, Vukosava and Vuckovic, Gordana and Leovac, Vukadin M. and Szecsenyi, Katalin Meszaros",
year = "2014",
abstract = "The synthesis of a potentially bioactive mixed-valence Co-III/Co-II complex with 2-acetylpyridine S-methylisothiosemicarbazone (HL) ligand is described. The crystal and molecular structure of the formed [(CoL2)-L-III][(CoCl3)-Cl-II py]center dot Me2CO (I) compound (py stands for pyridine) is determined by single-crystal X-ray crystallography. It's thermal decomposition along with the decomposition of the ligand and six structurally related complexes with formulas [CoL2]NO3 center dot MeOH (1), [CoL2]Br center dot MeOH (2), [CoL2]HSO4 center dot MeOH (3), [CoL2](2)[Co-II(NCS)(4)] (4), [Co(HL)(L)]I-2 center dot 2MeOH (5), and [Co(HL)(L)][(CoCl4)-Cl-II]center dot MeOH (6) was determined by simultaneous TG/DSC measurements. The decomposition pattern is evaluated using TG/DTA-MS data. The results were related to the solvent/moisture content and the decomposition mechanism of the compounds. The antimicrobial activity of the ligand and of all the complexes was tested in vitro for selected gram-negative and gram-positive bacteria and fungi. The activity of the ligand against all tested bacteria is comparable with those obtained for standard antibiotics, while it is less active against fungi. Surprisingly, the activity of the complexes is very low. The low antimicrobial activity of the complexes may be in connection with their high thermodynamic and kinetic inertness in solution. The results are also supported by the relatively high thermal stability of the complexes.",
publisher = "Springer, Dordrecht",
journal = "Journal of Thermal Analysis and Calorimetry",
title = "Crystal structure, thermal behavior, and microbiological activity of a thiosemicarbazide-type ligand and its cobalt complexes",
volume = "116",
number = "2",
pages = "655-662",
doi = "10.1007/s10973-013-3489-1"
}
Hollo, B., Rodić, M., Vojinović-Ješić, L. S., Živković-Radovanović, V., Vuckovic, G., Leovac, V. M.,& Szecsenyi, K. M.. (2014). Crystal structure, thermal behavior, and microbiological activity of a thiosemicarbazide-type ligand and its cobalt complexes. in Journal of Thermal Analysis and Calorimetry
Springer, Dordrecht., 116(2), 655-662.
https://doi.org/10.1007/s10973-013-3489-1
Hollo B, Rodić M, Vojinović-Ješić LS, Živković-Radovanović V, Vuckovic G, Leovac VM, Szecsenyi KM. Crystal structure, thermal behavior, and microbiological activity of a thiosemicarbazide-type ligand and its cobalt complexes. in Journal of Thermal Analysis and Calorimetry. 2014;116(2):655-662.
doi:10.1007/s10973-013-3489-1 .
Hollo, Berta, Rodić, Marko, Vojinović-Ješić, Ljiljana S., Živković-Radovanović, Vukosava, Vuckovic, Gordana, Leovac, Vukadin M., Szecsenyi, Katalin Meszaros, "Crystal structure, thermal behavior, and microbiological activity of a thiosemicarbazide-type ligand and its cobalt complexes" in Journal of Thermal Analysis and Calorimetry, 116, no. 2 (2014):655-662,
https://doi.org/10.1007/s10973-013-3489-1 . .
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New Cu(II) and Co(II) octaazamacrocyclic complexes with 2-amino-3-phenylpropanoic acid

Vuckovic, Gordana; Antonijević-Nikolić, Mirjana; Tanaskovic, Sladana B.; Živković-Radovanović, Vukosava

(Serbian Chemical Soc, Belgrade, 2011)

TY  - JOUR
AU  - Vuckovic, Gordana
AU  - Antonijević-Nikolić, Mirjana
AU  - Tanaskovic, Sladana B.
AU  - Živković-Radovanović, Vukosava
PY  - 2011
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1351
AB  - New cationic Cu(II) and Co(II) complexes with N,N',N '',N'''-tetrakis(2-pyridylmethyl)-1,4,8,11-tetraazacyclotetradecane (tpmc) and the anion of 2-amino-3-phenylpropanoic acid (S-phenylalanine) were prepared. The complexes were analyzed and characterized by elemental analysis, conductometric, polarimetric, magnetic and cyclic voltammetric measurements, as well as by spectroscopic data (UV/Vis, IR). Both complexes are binuclear with the general formula [M(2)(S-Phe)tpmc](ClO(4))(3)center dot nH(2)O; S-PheH = S-phenylalanine, M(II) = Cu, n = 7; Co, n = 0. Based on previously reported data for some familiar complexes and the present results, pentacoordinated geometry was proposed. Both of the central metal ions are coordinated with two pyridyl and two cyclam nitrogens and bridged with -N-(CH(2))(3)-N-portions of the cyclam ring and oxygen atoms of the S-phenylalaninate ion. Antimicrobial screening of the complexes, solvent, starting salts and ligands alone was performed against fungi, mould and some bacteria. In certain cases, enhanced activity of Co(II) complex towards bacteria compared with the relevant free ligands and starting salts was detected.
AB  - Dobijena su dva nova kompleksa Cu(II) i Co(II) sa N,N',N',N'''-tetrakis(2-piridilmetil)-1,4,8,11-ciklotetradekanom (tpmc-om) i anjonom 2-amino-3-fenil-propanske kiseline (S-fenilalanina). Oni su analizirani i okarakterisani: elementalnom analizom, konduktometrijskim, polarimetrijskim, magnetnim i ciklično-voltametrijskim merenjima, kao i spektroskopskim podacima (UV/Vis, IR). Oba kompleksa su dinuklearna opšte formule [M2(S-Phe)tpmc](ClO4)3·nH2O; S-PheH = S-fenilalanin, M(II) = Cu, n = 7; Co, n = 0. Na osnovu ranije dobijenih podataka za srodne komplekse i novih rezultata pretpostavljena je pentakoordinaciona geometrija. Oba centralna metalna jona su koordinovana za po dva piridil i dva ciklamova azota i premošćena -N-(CH2)3-N-fragmentima ciklamovog prstena i kiseonikovim atomima S-fenilalaninato jona. Antimikrobni test kompleksa, rastvarača, polaznih soli i samih liganada je izvršen na gljivice, plesni i bakterije. U izvesnim slučajevima nađena je povećana aktivnost kompleksa Co(II) prema pojedinim bakterijama u odnosu na odgovarajuće slobodne ligande i polazne soli.
PB  - Serbian Chemical Soc, Belgrade
T2  - Journal of the Serbian Chemical Society
T1  - New Cu(II) and Co(II) octaazamacrocyclic complexes with 2-amino-3-phenylpropanoic acid
T1  - Novi Cu(II) i Co(II) oktaazamakrociklični kompleksi sa 2-amino-3-fenil-propanskom kiselinom
VL  - 76
IS  - 5
SP  - 719
EP  - 731
DO  - 10.2298/JSC101201062V
ER  - 
@article{
author = "Vuckovic, Gordana and Antonijević-Nikolić, Mirjana and Tanaskovic, Sladana B. and Živković-Radovanović, Vukosava",
year = "2011",
abstract = "New cationic Cu(II) and Co(II) complexes with N,N',N '',N'''-tetrakis(2-pyridylmethyl)-1,4,8,11-tetraazacyclotetradecane (tpmc) and the anion of 2-amino-3-phenylpropanoic acid (S-phenylalanine) were prepared. The complexes were analyzed and characterized by elemental analysis, conductometric, polarimetric, magnetic and cyclic voltammetric measurements, as well as by spectroscopic data (UV/Vis, IR). Both complexes are binuclear with the general formula [M(2)(S-Phe)tpmc](ClO(4))(3)center dot nH(2)O; S-PheH = S-phenylalanine, M(II) = Cu, n = 7; Co, n = 0. Based on previously reported data for some familiar complexes and the present results, pentacoordinated geometry was proposed. Both of the central metal ions are coordinated with two pyridyl and two cyclam nitrogens and bridged with -N-(CH(2))(3)-N-portions of the cyclam ring and oxygen atoms of the S-phenylalaninate ion. Antimicrobial screening of the complexes, solvent, starting salts and ligands alone was performed against fungi, mould and some bacteria. In certain cases, enhanced activity of Co(II) complex towards bacteria compared with the relevant free ligands and starting salts was detected., Dobijena su dva nova kompleksa Cu(II) i Co(II) sa N,N',N',N'''-tetrakis(2-piridilmetil)-1,4,8,11-ciklotetradekanom (tpmc-om) i anjonom 2-amino-3-fenil-propanske kiseline (S-fenilalanina). Oni su analizirani i okarakterisani: elementalnom analizom, konduktometrijskim, polarimetrijskim, magnetnim i ciklično-voltametrijskim merenjima, kao i spektroskopskim podacima (UV/Vis, IR). Oba kompleksa su dinuklearna opšte formule [M2(S-Phe)tpmc](ClO4)3·nH2O; S-PheH = S-fenilalanin, M(II) = Cu, n = 7; Co, n = 0. Na osnovu ranije dobijenih podataka za srodne komplekse i novih rezultata pretpostavljena je pentakoordinaciona geometrija. Oba centralna metalna jona su koordinovana za po dva piridil i dva ciklamova azota i premošćena -N-(CH2)3-N-fragmentima ciklamovog prstena i kiseonikovim atomima S-fenilalaninato jona. Antimikrobni test kompleksa, rastvarača, polaznih soli i samih liganada je izvršen na gljivice, plesni i bakterije. U izvesnim slučajevima nađena je povećana aktivnost kompleksa Co(II) prema pojedinim bakterijama u odnosu na odgovarajuće slobodne ligande i polazne soli.",
publisher = "Serbian Chemical Soc, Belgrade",
journal = "Journal of the Serbian Chemical Society",
title = "New Cu(II) and Co(II) octaazamacrocyclic complexes with 2-amino-3-phenylpropanoic acid, Novi Cu(II) i Co(II) oktaazamakrociklični kompleksi sa 2-amino-3-fenil-propanskom kiselinom",
volume = "76",
number = "5",
pages = "719-731",
doi = "10.2298/JSC101201062V"
}
Vuckovic, G., Antonijević-Nikolić, M., Tanaskovic, S. B.,& Živković-Radovanović, V.. (2011). New Cu(II) and Co(II) octaazamacrocyclic complexes with 2-amino-3-phenylpropanoic acid. in Journal of the Serbian Chemical Society
Serbian Chemical Soc, Belgrade., 76(5), 719-731.
https://doi.org/10.2298/JSC101201062V
Vuckovic G, Antonijević-Nikolić M, Tanaskovic SB, Živković-Radovanović V. New Cu(II) and Co(II) octaazamacrocyclic complexes with 2-amino-3-phenylpropanoic acid. in Journal of the Serbian Chemical Society. 2011;76(5):719-731.
doi:10.2298/JSC101201062V .
Vuckovic, Gordana, Antonijević-Nikolić, Mirjana, Tanaskovic, Sladana B., Živković-Radovanović, Vukosava, "New Cu(II) and Co(II) octaazamacrocyclic complexes with 2-amino-3-phenylpropanoic acid" in Journal of the Serbian Chemical Society, 76, no. 5 (2011):719-731,
https://doi.org/10.2298/JSC101201062V . .
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A study of novel cobalt(II) octaazamacrocyclic complexes with aminocarboxylates or their derivatives

Vuckovic, Gordana; Tanaskovic, Sladana B.; Antonijević-Nikolić, Mirjana; Živković-Radovanović, Vukosava; Gojgić-Cvijović, Gordana D.

(Serbian Chemical Soc, Belgrade, 2009)

TY  - JOUR
AU  - Vuckovic, Gordana
AU  - Tanaskovic, Sladana B.
AU  - Antonijević-Nikolić, Mirjana
AU  - Živković-Radovanović, Vukosava
AU  - Gojgić-Cvijović, Gordana D.
PY  - 2009
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1003
AB  - Four new air-stable mixed-ligand Co(II) complexes having the general formula [Co(2)(Y)tpmc]Z(3)center dot q(H(2)O/CH(3)CN) (HY = N-methylglycine/N,N-dimethylglycine, Z = BF(4)(-), qH(2)O = 4 or 3; HY = S-norvaline/S-valine Z = ClO(4)(-), qCH(3)CN = 0.5; qH(2)O = 0.5; tpmc = N,N',N '',N'"-tetrakis(2-pyridymethyl)-1,4,8,11-tetraazacyclotetradecane) were prepared. The composition, some physical and chemical properties and their tentative geometries were evaluated based on elemental analysis (C, H, N), conductometric and magnetic measurernents, spectroscopic data (UV/Vis, IR) and cyclic voltammetry. The data were compared with earlier described analogous complexes containing the macrocyclic ligand and aliphatic aminocarboxylates. It is assumed that all complexes are binuclear with an exo coordination mode of the octaazarnacrocyclic pendant ligand in the boat conformation. In addition, two -N-(CH(2))(2)-N- portions of the cyclam ring within the tpmc ligand and Co(II) ions in the high-spin state are most probably bridged via oxygen atoms from the anion of the aminocarboxylate/derivatives, whereas nitrogen atoms rest uncoordinated. In all cases, a combined chelate-bridged coordination is proposed as the most probable. The complexes were electrochemically stable in the potential range -1.0 to 1.0 V. They were also preliminary assayed toward some microorganisms together with the ligands, starting simple salts and solvents as test substances. In some cases, certain antimicrobial activity of the complexes was detected.
AB  - Dobijena su četiri nova mešovito-ligandna kompleksa Co(II), stabilna na vazduhu, opšte formule [Co2(Y)tpmc]Z3×q(H2O/CH3CN) (HY = N-metilglicin/N,N-dimetilglicin, Z=-4BF , qH2O=4 ili 3); HY = S-norvalin/S-valin, Z=-ClO4, qCH3CN=0,5; qH2O=0,5; tpmc= N,N',N'',N'''-tetrakis(2-piridilmetil)-1,4,8,11-tetraazaciklotetradekan). Sastav, neka fizička i hemijska svojstva i njihove približne geometrije su izvedene na osnovu elementalne analize (C, H, N), konduktometrijskih i magnetnih merenja, spektroskopskih podataka (UV/Vis, IR) odnosno ciklične voltametrije. Podaci su upoređeni sa ranije opisanim analogim kompleksima koji sadrže makrociklični ligand i alifatične aminokarboksilate. Pretpostavljeno je da su svi kompleksi dinuklearni sa egzo koordinacijom pendantnog oktaazamakrocikla u konformaciji lađe. Pored dva -N-(CH2)2-N- dela ciklamovog prstena unutar tpmc-a, joni visoko-spinskog Co(II) su najverovatnije premošćeni angažovanjem kiseonikovih atoma sa anjona aminokarboksilata/derivata, dok atomi azota ostaju nekoordinovani. Za sve komplekse predložen je kombinovani helatno-mostovni način vezivanja. Kompleksi su bili elektrohemijski stabilni u opsegu potencijala -1,0 do 1,0 V. Oni su preliminarno testirani na mikroorganizme zajedno sa ligandima, polaznim prostim solima i rastvaračima kao test supstancama. U nekim slučajevima je nađena izvesna antimikrobna aktivnost kompleksa.
PB  - Serbian Chemical Soc, Belgrade
T2  - Journal of the Serbian Chemical Society
T1  - A study of novel cobalt(II) octaazamacrocyclic complexes with aminocarboxylates or their derivatives
T1  - Proučavanje novih kompleksa kobalta(II) sa oktaazamakrociklom i aminokarboksilatima ili njihovim derivatima
VL  - 74
IS  - 6
SP  - 629
EP  - 640
DO  - 10.2298/JSC0906629V
ER  - 
@article{
author = "Vuckovic, Gordana and Tanaskovic, Sladana B. and Antonijević-Nikolić, Mirjana and Živković-Radovanović, Vukosava and Gojgić-Cvijović, Gordana D.",
year = "2009",
abstract = "Four new air-stable mixed-ligand Co(II) complexes having the general formula [Co(2)(Y)tpmc]Z(3)center dot q(H(2)O/CH(3)CN) (HY = N-methylglycine/N,N-dimethylglycine, Z = BF(4)(-), qH(2)O = 4 or 3; HY = S-norvaline/S-valine Z = ClO(4)(-), qCH(3)CN = 0.5; qH(2)O = 0.5; tpmc = N,N',N '',N'"-tetrakis(2-pyridymethyl)-1,4,8,11-tetraazacyclotetradecane) were prepared. The composition, some physical and chemical properties and their tentative geometries were evaluated based on elemental analysis (C, H, N), conductometric and magnetic measurernents, spectroscopic data (UV/Vis, IR) and cyclic voltammetry. The data were compared with earlier described analogous complexes containing the macrocyclic ligand and aliphatic aminocarboxylates. It is assumed that all complexes are binuclear with an exo coordination mode of the octaazarnacrocyclic pendant ligand in the boat conformation. In addition, two -N-(CH(2))(2)-N- portions of the cyclam ring within the tpmc ligand and Co(II) ions in the high-spin state are most probably bridged via oxygen atoms from the anion of the aminocarboxylate/derivatives, whereas nitrogen atoms rest uncoordinated. In all cases, a combined chelate-bridged coordination is proposed as the most probable. The complexes were electrochemically stable in the potential range -1.0 to 1.0 V. They were also preliminary assayed toward some microorganisms together with the ligands, starting simple salts and solvents as test substances. In some cases, certain antimicrobial activity of the complexes was detected., Dobijena su četiri nova mešovito-ligandna kompleksa Co(II), stabilna na vazduhu, opšte formule [Co2(Y)tpmc]Z3×q(H2O/CH3CN) (HY = N-metilglicin/N,N-dimetilglicin, Z=-4BF , qH2O=4 ili 3); HY = S-norvalin/S-valin, Z=-ClO4, qCH3CN=0,5; qH2O=0,5; tpmc= N,N',N'',N'''-tetrakis(2-piridilmetil)-1,4,8,11-tetraazaciklotetradekan). Sastav, neka fizička i hemijska svojstva i njihove približne geometrije su izvedene na osnovu elementalne analize (C, H, N), konduktometrijskih i magnetnih merenja, spektroskopskih podataka (UV/Vis, IR) odnosno ciklične voltametrije. Podaci su upoređeni sa ranije opisanim analogim kompleksima koji sadrže makrociklični ligand i alifatične aminokarboksilate. Pretpostavljeno je da su svi kompleksi dinuklearni sa egzo koordinacijom pendantnog oktaazamakrocikla u konformaciji lađe. Pored dva -N-(CH2)2-N- dela ciklamovog prstena unutar tpmc-a, joni visoko-spinskog Co(II) su najverovatnije premošćeni angažovanjem kiseonikovih atoma sa anjona aminokarboksilata/derivata, dok atomi azota ostaju nekoordinovani. Za sve komplekse predložen je kombinovani helatno-mostovni način vezivanja. Kompleksi su bili elektrohemijski stabilni u opsegu potencijala -1,0 do 1,0 V. Oni su preliminarno testirani na mikroorganizme zajedno sa ligandima, polaznim prostim solima i rastvaračima kao test supstancama. U nekim slučajevima je nađena izvesna antimikrobna aktivnost kompleksa.",
publisher = "Serbian Chemical Soc, Belgrade",
journal = "Journal of the Serbian Chemical Society",
title = "A study of novel cobalt(II) octaazamacrocyclic complexes with aminocarboxylates or their derivatives, Proučavanje novih kompleksa kobalta(II) sa oktaazamakrociklom i aminokarboksilatima ili njihovim derivatima",
volume = "74",
number = "6",
pages = "629-640",
doi = "10.2298/JSC0906629V"
}
Vuckovic, G., Tanaskovic, S. B., Antonijević-Nikolić, M., Živković-Radovanović, V.,& Gojgić-Cvijović, G. D.. (2009). A study of novel cobalt(II) octaazamacrocyclic complexes with aminocarboxylates or their derivatives. in Journal of the Serbian Chemical Society
Serbian Chemical Soc, Belgrade., 74(6), 629-640.
https://doi.org/10.2298/JSC0906629V
Vuckovic G, Tanaskovic SB, Antonijević-Nikolić M, Živković-Radovanović V, Gojgić-Cvijović GD. A study of novel cobalt(II) octaazamacrocyclic complexes with aminocarboxylates or their derivatives. in Journal of the Serbian Chemical Society. 2009;74(6):629-640.
doi:10.2298/JSC0906629V .
Vuckovic, Gordana, Tanaskovic, Sladana B., Antonijević-Nikolić, Mirjana, Živković-Radovanović, Vukosava, Gojgić-Cvijović, Gordana D., "A study of novel cobalt(II) octaazamacrocyclic complexes with aminocarboxylates or their derivatives" in Journal of the Serbian Chemical Society, 74, no. 6 (2009):629-640,
https://doi.org/10.2298/JSC0906629V . .
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Use of different salt solutions in salting-out TLC of Co(III) complexes on silica gel

Živković-Radovanović, Vukosava; Vuckovic, Gordana

(Vieweg, Wiesbaden, 2008)

TY  - JOUR
AU  - Živković-Radovanović, Vukosava
AU  - Vuckovic, Gordana
PY  - 2008
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/911
AB  - Saturated aqueous solutions of 28 different salts have been studied as a potential mobile phases for salting-out thin-layer chromatography, on silica gel, of a series of four mixed bis-aminocarboxylato cobalt(III) complexes. In addition, by linear regression analysis of chromatographic data obtained for fifteen mixed aminocarboxylato Co(III) complexes (four series) with solutions of ammonium chloride, three alkali metal chlorides, and four alkaline earth metal chlorides, four linear dependences previously established on different adsorbents with (NH4)(2)SO4 solutions were confirmed. The qualities of the separations achieved with the salts were compared and Li+, Mg2+, and Ca2+ chlorides are proposed as the most suitable.
PB  - Vieweg, Wiesbaden
T2  - Chromatographia
T1  - Use of different salt solutions in salting-out TLC of Co(III) complexes on silica gel
VL  - 67
IS  - 3-4
SP  - 259
EP  - 267
DO  - 10.1365/s10337-007-0489-y
ER  - 
@article{
author = "Živković-Radovanović, Vukosava and Vuckovic, Gordana",
year = "2008",
abstract = "Saturated aqueous solutions of 28 different salts have been studied as a potential mobile phases for salting-out thin-layer chromatography, on silica gel, of a series of four mixed bis-aminocarboxylato cobalt(III) complexes. In addition, by linear regression analysis of chromatographic data obtained for fifteen mixed aminocarboxylato Co(III) complexes (four series) with solutions of ammonium chloride, three alkali metal chlorides, and four alkaline earth metal chlorides, four linear dependences previously established on different adsorbents with (NH4)(2)SO4 solutions were confirmed. The qualities of the separations achieved with the salts were compared and Li+, Mg2+, and Ca2+ chlorides are proposed as the most suitable.",
publisher = "Vieweg, Wiesbaden",
journal = "Chromatographia",
title = "Use of different salt solutions in salting-out TLC of Co(III) complexes on silica gel",
volume = "67",
number = "3-4",
pages = "259-267",
doi = "10.1365/s10337-007-0489-y"
}
Živković-Radovanović, V.,& Vuckovic, G.. (2008). Use of different salt solutions in salting-out TLC of Co(III) complexes on silica gel. in Chromatographia
Vieweg, Wiesbaden., 67(3-4), 259-267.
https://doi.org/10.1365/s10337-007-0489-y
Živković-Radovanović V, Vuckovic G. Use of different salt solutions in salting-out TLC of Co(III) complexes on silica gel. in Chromatographia. 2008;67(3-4):259-267.
doi:10.1365/s10337-007-0489-y .
Živković-Radovanović, Vukosava, Vuckovic, Gordana, "Use of different salt solutions in salting-out TLC of Co(III) complexes on silica gel" in Chromatographia, 67, no. 3-4 (2008):259-267,
https://doi.org/10.1365/s10337-007-0489-y . .
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