TY  - JOUR
AU  - Rodić, Marko
AU  - Miškov-Pajić, Vukoslava
AU  - Leovac, Vukadin M.
AU  - Radanović, Mirjana M.
AU  - Vojinović-Ješić, Ljiljana S.
AU  - Belošević, Svetlana
AU  - Jaćimović, Željko K.
AU  - Živković-Radovanović, Vukosava
PY  - 2020
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/4056
AB  - In the reaction of acetone solutions of CoX2∙nH2O (X = Cl, Br) with methyl pyruvate semi/thiosemicarbazone (Hmps, Hmpt) the first Co(II) complexes with these ligands, i.e., [Co(Hmps)(H2O)X2] (X = Cl (1), Br (2)), [Co(Hmpt)2][CoCl4]∙2H2О (3) and [Co(Hmpt)2]Br2∙Me2CO (4) were obtained. Complexes 1 and 2 represent the first examples of metal complexes of Hmps. All the obtained compounds were characterized by elemental analysis, conductometry, magnetic measurements, and IR spectra, and for complexes 2–4, single crystal X-ray diffraction analysis was also performed. The effective magnetic moments were close to the upper limit (5 μB) for complexes 1 and 2, and close to the lower limit (4.4 μB) for complexes 3 and 4, and as such are characteristic for high-spin Co(II) complexes. Structural analysis showed that both ligands coordinate in a neutral form in a tridentate manner, via the ester oxygen, imine nitrogen and the oxygen atom of the ureido (Hmps), or the sulfur atom of the thioureido group (Hmpt). The central metal atoms are situated in a deformed octahedral coordination environment. Complex 2 has cis-Br configuration, while complexes 3 and 4 have mer-configuration.
PB  - Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - First cobalt complexes with methyl pyruvate semi/thiosemicarbazone - synthesis, physico-chemical and structural characterization
VL  - 85
IS  - 4
SP  - 453
EP  - 466
DO  - 10.2298/JSC191219010R
ER  - 

@article{
author = "Rodić, Marko and Miškov-Pajić, Vukoslava and Leovac, Vukadin M. and Radanović, Mirjana M. and Vojinović-Ješić, Ljiljana S. and Belošević, Svetlana and Jaćimović, Željko K. and Živković-Radovanović, Vukosava",
year = "2020",
abstract = "In the reaction of acetone solutions of CoX2∙nH2O (X = Cl, Br) with methyl pyruvate semi/thiosemicarbazone (Hmps, Hmpt) the first Co(II) complexes with these ligands, i.e., [Co(Hmps)(H2O)X2] (X = Cl (1), Br (2)), [Co(Hmpt)2][CoCl4]∙2H2О (3) and [Co(Hmpt)2]Br2∙Me2CO (4) were obtained. Complexes 1 and 2 represent the first examples of metal complexes of Hmps. All the obtained compounds were characterized by elemental analysis, conductometry, magnetic measurements, and IR spectra, and for complexes 2–4, single crystal X-ray diffraction analysis was also performed. The effective magnetic moments were close to the upper limit (5 μB) for complexes 1 and 2, and close to the lower limit (4.4 μB) for complexes 3 and 4, and as such are characteristic for high-spin Co(II) complexes. Structural analysis showed that both ligands coordinate in a neutral form in a tridentate manner, via the ester oxygen, imine nitrogen and the oxygen atom of the ureido (Hmps), or the sulfur atom of the thioureido group (Hmpt). The central metal atoms are situated in a deformed octahedral coordination environment. Complex 2 has cis-Br configuration, while complexes 3 and 4 have mer-configuration.",
publisher = "Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "First cobalt complexes with methyl pyruvate semi/thiosemicarbazone - synthesis, physico-chemical and structural characterization",
volume = "85",
number = "4",
pages = "453-466",
doi = "10.2298/JSC191219010R"
}

Rodić, M., Miškov-Pajić, V., Leovac, V. M., Radanović, M. M., Vojinović-Ješić, L. S., Belošević, S., Jaćimović, Ž. K.,& Živković-Radovanović, V.. (2020). First cobalt complexes with methyl pyruvate semi/thiosemicarbazone - synthesis, physico-chemical and structural characterization. in Journal of the Serbian Chemical Society
Serbian Chemical Society., 85(4), 453-466.
https://doi.org/10.2298/JSC191219010R

Rodić M, Miškov-Pajić V, Leovac VM, Radanović MM, Vojinović-Ješić LS, Belošević S, Jaćimović ŽK, Živković-Radovanović V. First cobalt complexes with methyl pyruvate semi/thiosemicarbazone - synthesis, physico-chemical and structural characterization. in Journal of the Serbian Chemical Society. 2020;85(4):453-466.
doi:10.2298/JSC191219010R .

Rodić, Marko, Miškov-Pajić, Vukoslava, Leovac, Vukadin M., Radanović, Mirjana M., Vojinović-Ješić, Ljiljana S., Belošević, Svetlana, Jaćimović, Željko K., Živković-Radovanović, Vukosava, "First cobalt complexes with methyl pyruvate semi/thiosemicarbazone - synthesis, physico-chemical and structural characterization" in Journal of the Serbian Chemical Society, 85, no. 4 (2020):453-466,
https://doi.org/10.2298/JSC191219010R . .

TY  - JOUR
AU  - Vojinović-Ješić, Ljiljana S.
AU  - Radanović, Mirjana M.
AU  - Rodić, Marko
AU  - Živković-Radovanović, Vukosava
AU  - Jovanović, Ljiljana S.
AU  - Leovac, Vukadin M.
PY  - 2016
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/2318
AB  - The syntheses, physico-chemical and microbiological properties of the ligand, 2-acetylpyridine-aminoguanidine dihydrogensulfate monohydrate and its five complexes with Cu(II) are described. The compounds were characterized by single crystal X-ray crystallography. Common fragments encountered in some of the structures were compared by r.m.s. overlay calculations as well as half-normal probability plots. In these complexes the chelate ligand is coordinated in its neutral form in a tridentate N-3-coordination mode, via pyridine, azomethine and imino nitrogen atoms of the aminoguanidine fragment. In these complexes the Cu(II) ion is situated in moderately or severely distorted square-pyramidal surroundings. The antimicrobial activity of the ligand and the complexes were examined against 6 selected bacterial and 3 fungal strains. (C) 2016 Elsevier Ltd. All rights reserved.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - Polyhedron
T1  - Syntheses and characterization of 2-acetylpyridine-aminoguanidine and its copper(II) complexes: Crystallographic and antimicrobial study
VL  - 117
SP  - 526
EP  - 534
DO  - 10.1016/j.poly.2016.06.032
ER  - 

@article{
author = "Vojinović-Ješić, Ljiljana S. and Radanović, Mirjana M. and Rodić, Marko and Živković-Radovanović, Vukosava and Jovanović, Ljiljana S. and Leovac, Vukadin M.",
year = "2016",
abstract = "The syntheses, physico-chemical and microbiological properties of the ligand, 2-acetylpyridine-aminoguanidine dihydrogensulfate monohydrate and its five complexes with Cu(II) are described. The compounds were characterized by single crystal X-ray crystallography. Common fragments encountered in some of the structures were compared by r.m.s. overlay calculations as well as half-normal probability plots. In these complexes the chelate ligand is coordinated in its neutral form in a tridentate N-3-coordination mode, via pyridine, azomethine and imino nitrogen atoms of the aminoguanidine fragment. In these complexes the Cu(II) ion is situated in moderately or severely distorted square-pyramidal surroundings. The antimicrobial activity of the ligand and the complexes were examined against 6 selected bacterial and 3 fungal strains. (C) 2016 Elsevier Ltd. All rights reserved.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Polyhedron",
title = "Syntheses and characterization of 2-acetylpyridine-aminoguanidine and its copper(II) complexes: Crystallographic and antimicrobial study",
volume = "117",
pages = "526-534",
doi = "10.1016/j.poly.2016.06.032"
}

Vojinović-Ješić, L. S., Radanović, M. M., Rodić, M., Živković-Radovanović, V., Jovanović, L. S.,& Leovac, V. M.. (2016). Syntheses and characterization of 2-acetylpyridine-aminoguanidine and its copper(II) complexes: Crystallographic and antimicrobial study. in Polyhedron
Pergamon-Elsevier Science Ltd, Oxford., 117, 526-534.
https://doi.org/10.1016/j.poly.2016.06.032

Vojinović-Ješić LS, Radanović MM, Rodić M, Živković-Radovanović V, Jovanović LS, Leovac VM. Syntheses and characterization of 2-acetylpyridine-aminoguanidine and its copper(II) complexes: Crystallographic and antimicrobial study. in Polyhedron. 2016;117:526-534.
doi:10.1016/j.poly.2016.06.032 .

Vojinović-Ješić, Ljiljana S., Radanović, Mirjana M., Rodić, Marko, Živković-Radovanović, Vukosava, Jovanović, Ljiljana S., Leovac, Vukadin M., "Syntheses and characterization of 2-acetylpyridine-aminoguanidine and its copper(II) complexes: Crystallographic and antimicrobial study" in Polyhedron, 117 (2016):526-534,
https://doi.org/10.1016/j.poly.2016.06.032 . .

TY  - JOUR
AU  - Vojinović-Ješić, Ljiljana S.
AU  - Radanović, Mirjana M.
AU  - Rodić, Marko
AU  - Živković-Radovanović, Vukosava
AU  - Jovanović, Ljiljana S.
AU  - Leovac, Vukadin M.
PY  - 2016
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3580
AB  - The syntheses, physico-chemical and microbiological properties of the ligand, 2-acetylpyridine-aminoguanidine dihydrogensulfate monohydrate and its five complexes with Cu(II) are described. The compounds were characterized by single crystal X-ray crystallography. Common fragments encountered in some of the structures were compared by r.m.s. overlay calculations as well as half-normal probability plots. In these complexes the chelate ligand is coordinated in its neutral form in a tridentate N-3-coordination mode, via pyridine, azomethine and imino nitrogen atoms of the aminoguanidine fragment. In these complexes the Cu(II) ion is situated in moderately or severely distorted square-pyramidal surroundings. The antimicrobial activity of the ligand and the complexes were examined against 6 selected bacterial and 3 fungal strains.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - Polyhedron
T1  - Syntheses and characterization of 2-acetylpyridine-aminoguanidine and its copper(II) complexes: Crystallographic and antimicrobial study
VL  - 117
SP  - 526
EP  - 534
DO  - 10.1016/j.poly.2016.06.032
ER  - 

@article{
author = "Vojinović-Ješić, Ljiljana S. and Radanović, Mirjana M. and Rodić, Marko and Živković-Radovanović, Vukosava and Jovanović, Ljiljana S. and Leovac, Vukadin M.",
year = "2016",
abstract = "The syntheses, physico-chemical and microbiological properties of the ligand, 2-acetylpyridine-aminoguanidine dihydrogensulfate monohydrate and its five complexes with Cu(II) are described. The compounds were characterized by single crystal X-ray crystallography. Common fragments encountered in some of the structures were compared by r.m.s. overlay calculations as well as half-normal probability plots. In these complexes the chelate ligand is coordinated in its neutral form in a tridentate N-3-coordination mode, via pyridine, azomethine and imino nitrogen atoms of the aminoguanidine fragment. In these complexes the Cu(II) ion is situated in moderately or severely distorted square-pyramidal surroundings. The antimicrobial activity of the ligand and the complexes were examined against 6 selected bacterial and 3 fungal strains.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Polyhedron",
title = "Syntheses and characterization of 2-acetylpyridine-aminoguanidine and its copper(II) complexes: Crystallographic and antimicrobial study",
volume = "117",
pages = "526-534",
doi = "10.1016/j.poly.2016.06.032"
}

Vojinović-Ješić, L. S., Radanović, M. M., Rodić, M., Živković-Radovanović, V., Jovanović, L. S.,& Leovac, V. M.. (2016). Syntheses and characterization of 2-acetylpyridine-aminoguanidine and its copper(II) complexes: Crystallographic and antimicrobial study. in Polyhedron
Pergamon-Elsevier Science Ltd, Oxford., 117, 526-534.
https://doi.org/10.1016/j.poly.2016.06.032

Vojinović-Ješić LS, Radanović MM, Rodić M, Živković-Radovanović V, Jovanović LS, Leovac VM. Syntheses and characterization of 2-acetylpyridine-aminoguanidine and its copper(II) complexes: Crystallographic and antimicrobial study. in Polyhedron. 2016;117:526-534.
doi:10.1016/j.poly.2016.06.032 .

Vojinović-Ješić, Ljiljana S., Radanović, Mirjana M., Rodić, Marko, Živković-Radovanović, Vukosava, Jovanović, Ljiljana S., Leovac, Vukadin M., "Syntheses and characterization of 2-acetylpyridine-aminoguanidine and its copper(II) complexes: Crystallographic and antimicrobial study" in Polyhedron, 117 (2016):526-534,
https://doi.org/10.1016/j.poly.2016.06.032 . .

TY  - DATA
AU  - Vojinović-Ješić, Ljiljana S.
AU  - Radanović, Mirjana M.
AU  - Rodić, Marko
AU  - Živković-Radovanović, Vukosava
AU  - Jovanović, Ljiljana S.
AU  - Leovac, Vukadin M.
PY  - 2016
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3583
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - Polyhedron
T1  - Supplementary material for the article: Vojinović-Ješić, L. S.; Radanović, M. M.; Rodić, M. V.; Živković-Radovanović, V.;  Jovanović, L. S.; Leovac, V. M. Syntheses and Characterization of 2-Acetylpyridine Aminoguanidine and Its Copper(II) Complexes: Crystallographic and Antimicrobial Study.  Polyhedron 2016, 117, 526–534. https://doi.org/10.1016/j.poly.2016.06.032
UR  - https://hdl.handle.net/21.15107/rcub_cherry_3583
ER  - 

@misc{
author = "Vojinović-Ješić, Ljiljana S. and Radanović, Mirjana M. and Rodić, Marko and Živković-Radovanović, Vukosava and Jovanović, Ljiljana S. and Leovac, Vukadin M.",
year = "2016",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Polyhedron",
title = "Supplementary material for the article: Vojinović-Ješić, L. S.; Radanović, M. M.; Rodić, M. V.; Živković-Radovanović, V.;  Jovanović, L. S.; Leovac, V. M. Syntheses and Characterization of 2-Acetylpyridine Aminoguanidine and Its Copper(II) Complexes: Crystallographic and Antimicrobial Study.  Polyhedron 2016, 117, 526–534. https://doi.org/10.1016/j.poly.2016.06.032",
url = "https://hdl.handle.net/21.15107/rcub_cherry_3583"
}

Vojinović-Ješić, L. S., Radanović, M. M., Rodić, M., Živković-Radovanović, V., Jovanović, L. S.,& Leovac, V. M.. (2016). Supplementary material for the article: Vojinović-Ješić, L. S.; Radanović, M. M.; Rodić, M. V.; Živković-Radovanović, V.;  Jovanović, L. S.; Leovac, V. M. Syntheses and Characterization of 2-Acetylpyridine Aminoguanidine and Its Copper(II) Complexes: Crystallographic and Antimicrobial Study.  Polyhedron 2016, 117, 526–534. https://doi.org/10.1016/j.poly.2016.06.032. in Polyhedron
Pergamon-Elsevier Science Ltd, Oxford..
https://hdl.handle.net/21.15107/rcub_cherry_3583

Vojinović-Ješić LS, Radanović MM, Rodić M, Živković-Radovanović V, Jovanović LS, Leovac VM. Supplementary material for the article: Vojinović-Ješić, L. S.; Radanović, M. M.; Rodić, M. V.; Živković-Radovanović, V.;  Jovanović, L. S.; Leovac, V. M. Syntheses and Characterization of 2-Acetylpyridine Aminoguanidine and Its Copper(II) Complexes: Crystallographic and Antimicrobial Study.  Polyhedron 2016, 117, 526–534. https://doi.org/10.1016/j.poly.2016.06.032. in Polyhedron. 2016;.
https://hdl.handle.net/21.15107/rcub_cherry_3583 .

Vojinović-Ješić, Ljiljana S., Radanović, Mirjana M., Rodić, Marko, Živković-Radovanović, Vukosava, Jovanović, Ljiljana S., Leovac, Vukadin M., "Supplementary material for the article: Vojinović-Ješić, L. S.; Radanović, M. M.; Rodić, M. V.; Živković-Radovanović, V.;  Jovanović, L. S.; Leovac, V. M. Syntheses and Characterization of 2-Acetylpyridine Aminoguanidine and Its Copper(II) Complexes: Crystallographic and Antimicrobial Study.  Polyhedron 2016, 117, 526–534. https://doi.org/10.1016/j.poly.2016.06.032" in Polyhedron (2016),
https://hdl.handle.net/21.15107/rcub_cherry_3583 .

TY  - JOUR
AU  - Leovac, Vukadin M.
AU  - Rodić, Marko
AU  - Jovanović, Ljiljana S.
AU  - Joksović, Milan D.
AU  - Stanojković, Tatjana
AU  - Vujčić, Miroslava
AU  - Sladić, Dušan
AU  - Marković, Violeta
AU  - Vojinović-Ješić, Ljiljana S.
PY  - 2015
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1657
AB  - Five pentacoordinate copper(II) complexes with 2-acetylpyridine or di(2-pyridyl) ketone 1-adamantoyl hydrazone ligands (Adpy and Addpy, respectively) of the formulae [CuCl2(Adpy)] (1), [Cu-2(-Cl)(2)(Adpy-H)(2)] (2), [Cu(NCS)(2)(Adpy)] (3), [Cu-2(-Cl)(2)(Addpy-H)(2)] (4), and [Cu-2(NCS)(2)(-Addpy-H)(2)] (5) were synthesized and characterized by spectral, electrochemical, and X-ray structural analysis. Flow cytometry and morphological analysis confirmed that the copper(II) complexes 2 and 5 induced accumulation of a sub-G1 phase population, and fluorescence microscopy indicated the presence of large cells in apoptosis. The interaction of the copper(II) complexes with calf thymus DNA (CT-DNA) was monitored by changes in their UV/Vis spectra. The observed intrinsic binding constants for 2 and 5 (K-b = 1.77x10(6) and 3.58x10(6) M-1, respectively) together with ethidium displacement fluorescence experiments indicate intercalative binding. Complexes 2 and 5 showed nuclease activity against pUC19 plasmid DNA.
PB  - Wiley-V C H Verlag Gmbh, Weinheim
T2  - European Journal of Inorganic Chemistry
T1  - Transition Metal Complexes with 1-Adamantoyl Hydrazones - Cytotoxic Copper(II) Complexes of Tri- and Tetradentate Pyridine Chelators Containing an Adamantane Ring System
IS  - 5
SP  - 882
EP  - 895
DO  - 10.1002/ejic.201403050
ER  - 

@article{
author = "Leovac, Vukadin M. and Rodić, Marko and Jovanović, Ljiljana S. and Joksović, Milan D. and Stanojković, Tatjana and Vujčić, Miroslava and Sladić, Dušan and Marković, Violeta and Vojinović-Ješić, Ljiljana S.",
year = "2015",
abstract = "Five pentacoordinate copper(II) complexes with 2-acetylpyridine or di(2-pyridyl) ketone 1-adamantoyl hydrazone ligands (Adpy and Addpy, respectively) of the formulae [CuCl2(Adpy)] (1), [Cu-2(-Cl)(2)(Adpy-H)(2)] (2), [Cu(NCS)(2)(Adpy)] (3), [Cu-2(-Cl)(2)(Addpy-H)(2)] (4), and [Cu-2(NCS)(2)(-Addpy-H)(2)] (5) were synthesized and characterized by spectral, electrochemical, and X-ray structural analysis. Flow cytometry and morphological analysis confirmed that the copper(II) complexes 2 and 5 induced accumulation of a sub-G1 phase population, and fluorescence microscopy indicated the presence of large cells in apoptosis. The interaction of the copper(II) complexes with calf thymus DNA (CT-DNA) was monitored by changes in their UV/Vis spectra. The observed intrinsic binding constants for 2 and 5 (K-b = 1.77x10(6) and 3.58x10(6) M-1, respectively) together with ethidium displacement fluorescence experiments indicate intercalative binding. Complexes 2 and 5 showed nuclease activity against pUC19 plasmid DNA.",
publisher = "Wiley-V C H Verlag Gmbh, Weinheim",
journal = "European Journal of Inorganic Chemistry",
title = "Transition Metal Complexes with 1-Adamantoyl Hydrazones - Cytotoxic Copper(II) Complexes of Tri- and Tetradentate Pyridine Chelators Containing an Adamantane Ring System",
number = "5",
pages = "882-895",
doi = "10.1002/ejic.201403050"
}

Leovac, V. M., Rodić, M., Jovanović, L. S., Joksović, M. D., Stanojković, T., Vujčić, M., Sladić, D., Marković, V.,& Vojinović-Ješić, L. S.. (2015). Transition Metal Complexes with 1-Adamantoyl Hydrazones - Cytotoxic Copper(II) Complexes of Tri- and Tetradentate Pyridine Chelators Containing an Adamantane Ring System. in European Journal of Inorganic Chemistry
Wiley-V C H Verlag Gmbh, Weinheim.(5), 882-895.
https://doi.org/10.1002/ejic.201403050

Leovac VM, Rodić M, Jovanović LS, Joksović MD, Stanojković T, Vujčić M, Sladić D, Marković V, Vojinović-Ješić LS. Transition Metal Complexes with 1-Adamantoyl Hydrazones - Cytotoxic Copper(II) Complexes of Tri- and Tetradentate Pyridine Chelators Containing an Adamantane Ring System. in European Journal of Inorganic Chemistry. 2015;(5):882-895.
doi:10.1002/ejic.201403050 .

Leovac, Vukadin M., Rodić, Marko, Jovanović, Ljiljana S., Joksović, Milan D., Stanojković, Tatjana, Vujčić, Miroslava, Sladić, Dušan, Marković, Violeta, Vojinović-Ješić, Ljiljana S., "Transition Metal Complexes with 1-Adamantoyl Hydrazones - Cytotoxic Copper(II) Complexes of Tri- and Tetradentate Pyridine Chelators Containing an Adamantane Ring System" in European Journal of Inorganic Chemistry, no. 5 (2015):882-895,
https://doi.org/10.1002/ejic.201403050 . .

TY  - JOUR
AU  - Hollo, Berta
AU  - Rodić, Marko
AU  - Vojinović-Ješić, Ljiljana S.
AU  - Živković-Radovanović, Vukosava
AU  - Vuckovic, Gordana
AU  - Leovac, Vukadin M.
AU  - Szecsenyi, Katalin Meszaros
PY  - 2014
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1767
AB  - The synthesis of a potentially bioactive mixed-valence Co-III/Co-II complex with 2-acetylpyridine S-methylisothiosemicarbazone (HL) ligand is described. The crystal and molecular structure of the formed [(CoL2)-L-III][(CoCl3)-Cl-II py]center dot Me2CO (I) compound (py stands for pyridine) is determined by single-crystal X-ray crystallography. It's thermal decomposition along with the decomposition of the ligand and six structurally related complexes with formulas [CoL2]NO3 center dot MeOH (1), [CoL2]Br center dot MeOH (2), [CoL2]HSO4 center dot MeOH (3), [CoL2](2)[Co-II(NCS)(4)] (4), [Co(HL)(L)]I-2 center dot 2MeOH (5), and [Co(HL)(L)][(CoCl4)-Cl-II]center dot MeOH (6) was determined by simultaneous TG/DSC measurements. The decomposition pattern is evaluated using TG/DTA-MS data. The results were related to the solvent/moisture content and the decomposition mechanism of the compounds. The antimicrobial activity of the ligand and of all the complexes was tested in vitro for selected gram-negative and gram-positive bacteria and fungi. The activity of the ligand against all tested bacteria is comparable with those obtained for standard antibiotics, while it is less active against fungi. Surprisingly, the activity of the complexes is very low. The low antimicrobial activity of the complexes may be in connection with their high thermodynamic and kinetic inertness in solution. The results are also supported by the relatively high thermal stability of the complexes.
PB  - Springer, Dordrecht
T2  - Journal of Thermal Analysis and Calorimetry
T1  - Crystal structure, thermal behavior, and microbiological activity of a thiosemicarbazide-type ligand and its cobalt complexes
VL  - 116
IS  - 2
SP  - 655
EP  - 662
DO  - 10.1007/s10973-013-3489-1
ER  - 

@article{
author = "Hollo, Berta and Rodić, Marko and Vojinović-Ješić, Ljiljana S. and Živković-Radovanović, Vukosava and Vuckovic, Gordana and Leovac, Vukadin M. and Szecsenyi, Katalin Meszaros",
year = "2014",
abstract = "The synthesis of a potentially bioactive mixed-valence Co-III/Co-II complex with 2-acetylpyridine S-methylisothiosemicarbazone (HL) ligand is described. The crystal and molecular structure of the formed [(CoL2)-L-III][(CoCl3)-Cl-II py]center dot Me2CO (I) compound (py stands for pyridine) is determined by single-crystal X-ray crystallography. It's thermal decomposition along with the decomposition of the ligand and six structurally related complexes with formulas [CoL2]NO3 center dot MeOH (1), [CoL2]Br center dot MeOH (2), [CoL2]HSO4 center dot MeOH (3), [CoL2](2)[Co-II(NCS)(4)] (4), [Co(HL)(L)]I-2 center dot 2MeOH (5), and [Co(HL)(L)][(CoCl4)-Cl-II]center dot MeOH (6) was determined by simultaneous TG/DSC measurements. The decomposition pattern is evaluated using TG/DTA-MS data. The results were related to the solvent/moisture content and the decomposition mechanism of the compounds. The antimicrobial activity of the ligand and of all the complexes was tested in vitro for selected gram-negative and gram-positive bacteria and fungi. The activity of the ligand against all tested bacteria is comparable with those obtained for standard antibiotics, while it is less active against fungi. Surprisingly, the activity of the complexes is very low. The low antimicrobial activity of the complexes may be in connection with their high thermodynamic and kinetic inertness in solution. The results are also supported by the relatively high thermal stability of the complexes.",
publisher = "Springer, Dordrecht",
journal = "Journal of Thermal Analysis and Calorimetry",
title = "Crystal structure, thermal behavior, and microbiological activity of a thiosemicarbazide-type ligand and its cobalt complexes",
volume = "116",
number = "2",
pages = "655-662",
doi = "10.1007/s10973-013-3489-1"
}

Hollo, B., Rodić, M., Vojinović-Ješić, L. S., Živković-Radovanović, V., Vuckovic, G., Leovac, V. M.,& Szecsenyi, K. M.. (2014). Crystal structure, thermal behavior, and microbiological activity of a thiosemicarbazide-type ligand and its cobalt complexes. in Journal of Thermal Analysis and Calorimetry
Springer, Dordrecht., 116(2), 655-662.
https://doi.org/10.1007/s10973-013-3489-1

Hollo B, Rodić M, Vojinović-Ješić LS, Živković-Radovanović V, Vuckovic G, Leovac VM, Szecsenyi KM. Crystal structure, thermal behavior, and microbiological activity of a thiosemicarbazide-type ligand and its cobalt complexes. in Journal of Thermal Analysis and Calorimetry. 2014;116(2):655-662.
doi:10.1007/s10973-013-3489-1 .

Hollo, Berta, Rodić, Marko, Vojinović-Ješić, Ljiljana S., Živković-Radovanović, Vukosava, Vuckovic, Gordana, Leovac, Vukadin M., Szecsenyi, Katalin Meszaros, "Crystal structure, thermal behavior, and microbiological activity of a thiosemicarbazide-type ligand and its cobalt complexes" in Journal of Thermal Analysis and Calorimetry, 116, no. 2 (2014):655-662,
https://doi.org/10.1007/s10973-013-3489-1 . .