TY  - JOUR
AU  - Stefanović, Ivan S.
AU  - Špírková, Milena
AU  - Poreba, Rafal
AU  - Steinhart, Miloš
AU  - Ostojić, Sanja B.
AU  - Tešević, Vele
AU  - Pergal, Marija V.
PY  - 2016
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1918
AB  - Segmented polyurethanes (PURs) were prepared from alpha,omega-dihydroxypoly(propylene oxide)-b-poly-(dimethylsiloxane)-b-poly(propyleneoxide) (PPO-PDMS) as the soft segment and 4,4'-diphenylmethane diisocyanate and 1,4-butanediol as the hard segment, via two-step polyaddition process in solvent mixture. The content of hard segments is in the range from 10 to 60 wt %. The structure and composition of PURs are determined by H-1 NMR, C-13 NMR, and ATR-FTIR spectroscopy. Incorporation of PPO-PDMS leads to improvements in thermal stability. Small- and wide-angle X-ray scattering experiments indicate that synthesized PURs with higher content of hard segments have more developed and distinct phase separated morphologies. Dynamic mechanical thermal analysis shows that copolymers have multiple transitions, characteristic for phase-separated systems. The water contact angle increases while water absorption decreases with increasing content of PPO-PDMS segments. The PURs prepared in this work show good thermal, mechanical features with phase separated morphology and high water resistance that enable their widespread application.
PB  - Amer Chemical Soc, Washington
T2  - Industrial and Engineering Chemistry Research
T1  - Study of the Properties of Urethane-Siloxane Copolymers Based on Poly(propylene oxide)-b-poly(dimethylsiloxane)-b-poly(propylene oxide) Soft Segments
VL  - 55
IS  - 14
SP  - 3960
EP  - 3973
DO  - 10.1021/acs.iecr.5b04975
ER  - 

@article{
author = "Stefanović, Ivan S. and Špírková, Milena and Poreba, Rafal and Steinhart, Miloš and Ostojić, Sanja B. and Tešević, Vele and Pergal, Marija V.",
year = "2016",
abstract = "Segmented polyurethanes (PURs) were prepared from alpha,omega-dihydroxypoly(propylene oxide)-b-poly-(dimethylsiloxane)-b-poly(propyleneoxide) (PPO-PDMS) as the soft segment and 4,4'-diphenylmethane diisocyanate and 1,4-butanediol as the hard segment, via two-step polyaddition process in solvent mixture. The content of hard segments is in the range from 10 to 60 wt %. The structure and composition of PURs are determined by H-1 NMR, C-13 NMR, and ATR-FTIR spectroscopy. Incorporation of PPO-PDMS leads to improvements in thermal stability. Small- and wide-angle X-ray scattering experiments indicate that synthesized PURs with higher content of hard segments have more developed and distinct phase separated morphologies. Dynamic mechanical thermal analysis shows that copolymers have multiple transitions, characteristic for phase-separated systems. The water contact angle increases while water absorption decreases with increasing content of PPO-PDMS segments. The PURs prepared in this work show good thermal, mechanical features with phase separated morphology and high water resistance that enable their widespread application.",
publisher = "Amer Chemical Soc, Washington",
journal = "Industrial and Engineering Chemistry Research",
title = "Study of the Properties of Urethane-Siloxane Copolymers Based on Poly(propylene oxide)-b-poly(dimethylsiloxane)-b-poly(propylene oxide) Soft Segments",
volume = "55",
number = "14",
pages = "3960-3973",
doi = "10.1021/acs.iecr.5b04975"
}

Stefanović, I. S., Špírková, M., Poreba, R., Steinhart, M., Ostojić, S. B., Tešević, V.,& Pergal, M. V.. (2016). Study of the Properties of Urethane-Siloxane Copolymers Based on Poly(propylene oxide)-b-poly(dimethylsiloxane)-b-poly(propylene oxide) Soft Segments. in Industrial and Engineering Chemistry Research
Amer Chemical Soc, Washington., 55(14), 3960-3973.
https://doi.org/10.1021/acs.iecr.5b04975

Stefanović IS, Špírková M, Poreba R, Steinhart M, Ostojić SB, Tešević V, Pergal MV. Study of the Properties of Urethane-Siloxane Copolymers Based on Poly(propylene oxide)-b-poly(dimethylsiloxane)-b-poly(propylene oxide) Soft Segments. in Industrial and Engineering Chemistry Research. 2016;55(14):3960-3973.
doi:10.1021/acs.iecr.5b04975 .

Stefanović, Ivan S., Špírková, Milena, Poreba, Rafal, Steinhart, Miloš, Ostojić, Sanja B., Tešević, Vele, Pergal, Marija V., "Study of the Properties of Urethane-Siloxane Copolymers Based on Poly(propylene oxide)-b-poly(dimethylsiloxane)-b-poly(propylene oxide) Soft Segments" in Industrial and Engineering Chemistry Research, 55, no. 14 (2016):3960-3973,
https://doi.org/10.1021/acs.iecr.5b04975 . .

TY  - JOUR
AU  - Stefanović, Ivan S.
AU  - Gođevac, Dejan
AU  - Špírková, Milena
AU  - Jovančić, Petar
AU  - Tešević, Vele
AU  - Milačić, Vesna
AU  - Pergal, Marija V.
PY  - 2016
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/2379
AB  - Segmented thermoplastic polyurethane copolymers (PURs) were synthesized using 4,4'-methylenediphenyl diisocyanate and 1,4-butanediol as the hard segment and alpha,omega-dihydroxy-poly(propylene oxide)-b-poly(dimethylsiloxane)-b-poly(propylene oxide) (PPO-PDMS) as the soft segment. The content of incorporated soft segments in PURs varied in the range from 40 to 90 wt.%. The structure, molecular weights and crystallinity of obtained copolymers were monitored by FTIR, H-1- and 2D-NMR spectroscopy, and GPC and DSC analysis, respectively. Surface free energy analysis indicates the presence of hydrophobic (siloxane) groups on the surface, giving highly hydrophobic nature to the obtained PURs films. Water absorption measurements showed that the increase of the hydrophobic PPO-PDMS segment content led to the decrease of percentage of absorbed water in copolymers. SEM and AFM analysis revealed that copolymers with lower content of PPO-PDMS segments have higher microphase separation between segments. The results obtained in this work indicate that synthesized PURs based on PPO-PDMS demonstrated proper surface and morphological properties with a great potential for variety of applications such as hydrophobic coatings in biomedicine.
PB  - Assoc Chemical Engineers Serbia, Belgrade
T2  - Hemijska industrija
T1  - Impact of the poly(propylene oxide)-b-poly(dimethylsiloxane)-b-poly-(propylene oxide) macrodiols on the surface-related properties of polyurethane copolymers
VL  - 70
IS  - 6
SP  - 725
EP  - 738
DO  - 10.2298/HEMIND151127009S
ER  - 

@article{
author = "Stefanović, Ivan S. and Gođevac, Dejan and Špírková, Milena and Jovančić, Petar and Tešević, Vele and Milačić, Vesna and Pergal, Marija V.",
year = "2016",
abstract = "Segmented thermoplastic polyurethane copolymers (PURs) were synthesized using 4,4'-methylenediphenyl diisocyanate and 1,4-butanediol as the hard segment and alpha,omega-dihydroxy-poly(propylene oxide)-b-poly(dimethylsiloxane)-b-poly(propylene oxide) (PPO-PDMS) as the soft segment. The content of incorporated soft segments in PURs varied in the range from 40 to 90 wt.%. The structure, molecular weights and crystallinity of obtained copolymers were monitored by FTIR, H-1- and 2D-NMR spectroscopy, and GPC and DSC analysis, respectively. Surface free energy analysis indicates the presence of hydrophobic (siloxane) groups on the surface, giving highly hydrophobic nature to the obtained PURs films. Water absorption measurements showed that the increase of the hydrophobic PPO-PDMS segment content led to the decrease of percentage of absorbed water in copolymers. SEM and AFM analysis revealed that copolymers with lower content of PPO-PDMS segments have higher microphase separation between segments. The results obtained in this work indicate that synthesized PURs based on PPO-PDMS demonstrated proper surface and morphological properties with a great potential for variety of applications such as hydrophobic coatings in biomedicine.",
publisher = "Assoc Chemical Engineers Serbia, Belgrade",
journal = "Hemijska industrija",
title = "Impact of the poly(propylene oxide)-b-poly(dimethylsiloxane)-b-poly-(propylene oxide) macrodiols on the surface-related properties of polyurethane copolymers",
volume = "70",
number = "6",
pages = "725-738",
doi = "10.2298/HEMIND151127009S"
}

Stefanović, I. S., Gođevac, D., Špírková, M., Jovančić, P., Tešević, V., Milačić, V.,& Pergal, M. V.. (2016). Impact of the poly(propylene oxide)-b-poly(dimethylsiloxane)-b-poly-(propylene oxide) macrodiols on the surface-related properties of polyurethane copolymers. in Hemijska industrija
Assoc Chemical Engineers Serbia, Belgrade., 70(6), 725-738.
https://doi.org/10.2298/HEMIND151127009S

Stefanović IS, Gođevac D, Špírková M, Jovančić P, Tešević V, Milačić V, Pergal MV. Impact of the poly(propylene oxide)-b-poly(dimethylsiloxane)-b-poly-(propylene oxide) macrodiols on the surface-related properties of polyurethane copolymers. in Hemijska industrija. 2016;70(6):725-738.
doi:10.2298/HEMIND151127009S .

Stefanović, Ivan S., Gođevac, Dejan, Špírková, Milena, Jovančić, Petar, Tešević, Vele, Milačić, Vesna, Pergal, Marija V., "Impact of the poly(propylene oxide)-b-poly(dimethylsiloxane)-b-poly-(propylene oxide) macrodiols on the surface-related properties of polyurethane copolymers" in Hemijska industrija, 70, no. 6 (2016):725-738,
https://doi.org/10.2298/HEMIND151127009S . .

TY  - DATA
AU  - Stefanović, Ivan S.
AU  - Špírková, Milena
AU  - Poreba, Rafal
AU  - Steinhart, Miloš
AU  - Ostojić, Sanja B.
AU  - Tešević, Vele
AU  - Pergal, Marija V.
PY  - 2016
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3618
PB  - Amer Chemical Soc, Washington
T2  - Industrial and Engineering Chemistry Research
T1  - Supplementary material for the article: Stefanović, I. S.; Špírková, M.; Poreba, R.; Steinhart, M.; Ostojić, S.; Tešević, V.; Pergal, M. V. Study of the Properties of Urethane-Siloxane Copolymers Based on Poly(Propylene Oxide)-b-Poly(Dimethylsiloxane)-b-Poly(Propylene Oxide) Soft Segments. Industrial and Engineering Chemistry Research 2016, 55 (14), 3960–3973. https://doi.org/10.1021/acs.iecr.5b04975
UR  - https://hdl.handle.net/21.15107/rcub_cherry_3618
ER  - 

@misc{
author = "Stefanović, Ivan S. and Špírková, Milena and Poreba, Rafal and Steinhart, Miloš and Ostojić, Sanja B. and Tešević, Vele and Pergal, Marija V.",
year = "2016",
publisher = "Amer Chemical Soc, Washington",
journal = "Industrial and Engineering Chemistry Research",
title = "Supplementary material for the article: Stefanović, I. S.; Špírková, M.; Poreba, R.; Steinhart, M.; Ostojić, S.; Tešević, V.; Pergal, M. V. Study of the Properties of Urethane-Siloxane Copolymers Based on Poly(Propylene Oxide)-b-Poly(Dimethylsiloxane)-b-Poly(Propylene Oxide) Soft Segments. Industrial and Engineering Chemistry Research 2016, 55 (14), 3960–3973. https://doi.org/10.1021/acs.iecr.5b04975",
url = "https://hdl.handle.net/21.15107/rcub_cherry_3618"
}

Stefanović, I. S., Špírková, M., Poreba, R., Steinhart, M., Ostojić, S. B., Tešević, V.,& Pergal, M. V.. (2016). Supplementary material for the article: Stefanović, I. S.; Špírková, M.; Poreba, R.; Steinhart, M.; Ostojić, S.; Tešević, V.; Pergal, M. V. Study of the Properties of Urethane-Siloxane Copolymers Based on Poly(Propylene Oxide)-b-Poly(Dimethylsiloxane)-b-Poly(Propylene Oxide) Soft Segments. Industrial and Engineering Chemistry Research 2016, 55 (14), 3960–3973. https://doi.org/10.1021/acs.iecr.5b04975. in Industrial and Engineering Chemistry Research
Amer Chemical Soc, Washington..
https://hdl.handle.net/21.15107/rcub_cherry_3618

Stefanović IS, Špírková M, Poreba R, Steinhart M, Ostojić SB, Tešević V, Pergal MV. Supplementary material for the article: Stefanović, I. S.; Špírková, M.; Poreba, R.; Steinhart, M.; Ostojić, S.; Tešević, V.; Pergal, M. V. Study of the Properties of Urethane-Siloxane Copolymers Based on Poly(Propylene Oxide)-b-Poly(Dimethylsiloxane)-b-Poly(Propylene Oxide) Soft Segments. Industrial and Engineering Chemistry Research 2016, 55 (14), 3960–3973. https://doi.org/10.1021/acs.iecr.5b04975. in Industrial and Engineering Chemistry Research. 2016;.
https://hdl.handle.net/21.15107/rcub_cherry_3618 .

Stefanović, Ivan S., Špírková, Milena, Poreba, Rafal, Steinhart, Miloš, Ostojić, Sanja B., Tešević, Vele, Pergal, Marija V., "Supplementary material for the article: Stefanović, I. S.; Špírková, M.; Poreba, R.; Steinhart, M.; Ostojić, S.; Tešević, V.; Pergal, M. V. Study of the Properties of Urethane-Siloxane Copolymers Based on Poly(Propylene Oxide)-b-Poly(Dimethylsiloxane)-b-Poly(Propylene Oxide) Soft Segments. Industrial and Engineering Chemistry Research 2016, 55 (14), 3960–3973. https://doi.org/10.1021/acs.iecr.5b04975" in Industrial and Engineering Chemistry Research (2016),
https://hdl.handle.net/21.15107/rcub_cherry_3618 .