Lukov, Vladimir V.

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  • Lukov, Vladimir V. (1)
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Author's Bibliography

Theoretical and experimental study of triphenylphosphonium Schiff base of 5-hydroxy-3-methyl-1-phenyl-4-formylpyrazole

Borodkin, Sergey A.; Popov, Leonid D.; Tsaturyan, Arshak A.; Milenković, Milica R.; Shcherbakov, Igor N.; Lukov, Vladimir V.

(Taylor & Francis Ltd, Abingdon, 2018)

TY  - JOUR
AU  - Borodkin, Sergey A.
AU  - Popov, Leonid D.
AU  - Tsaturyan, Arshak A.
AU  - Milenković, Milica R.
AU  - Shcherbakov, Igor N.
AU  - Lukov, Vladimir V.
PY  - 2018
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/2149
AB  - The Schiff base (HLBr), containing a chelating unit and triphenylphosphonium moiety has been synthesized in the reaction of 4-aminobenzyl(triphenyl)phosphonium bromide with 5-hydroxy-3-methyl-1-phenyl-4-formylpyrazole. The composition and structure of HLBr have been determined by elemental analysis, IR, 1D and 2D NMR, electronic spectroscopy and mass spectrometry. Density functional theory (DFT) calculations (6-311G(d,p) level of theory) have been carried out to investigate tautomeric forms of HL+ and the reaction mechanism of its formation and spectral properties. The most stable form in the solid state and in DMSO solution is pyrazolone (keto-amine) tautomeric form. [GRAPHICS] .
PB  - Taylor & Francis Ltd, Abingdon
T2  - Phosphorus Sulfur and Silicon and the Related Elements
T1  - Theoretical and experimental study of triphenylphosphonium Schiff base of 5-hydroxy-3-methyl-1-phenyl-4-formylpyrazole
VL  - 193
IS  - 6
SP  - 375
EP  - 381
DO  - 10.1080/10426507.2018.1424159
UR  - Kon_3480
ER  - 
@article{
author = "Borodkin, Sergey A. and Popov, Leonid D. and Tsaturyan, Arshak A. and Milenković, Milica R. and Shcherbakov, Igor N. and Lukov, Vladimir V.",
year = "2018",
abstract = "The Schiff base (HLBr), containing a chelating unit and triphenylphosphonium moiety has been synthesized in the reaction of 4-aminobenzyl(triphenyl)phosphonium bromide with 5-hydroxy-3-methyl-1-phenyl-4-formylpyrazole. The composition and structure of HLBr have been determined by elemental analysis, IR, 1D and 2D NMR, electronic spectroscopy and mass spectrometry. Density functional theory (DFT) calculations (6-311G(d,p) level of theory) have been carried out to investigate tautomeric forms of HL+ and the reaction mechanism of its formation and spectral properties. The most stable form in the solid state and in DMSO solution is pyrazolone (keto-amine) tautomeric form. [GRAPHICS] .",
publisher = "Taylor & Francis Ltd, Abingdon",
journal = "Phosphorus Sulfur and Silicon and the Related Elements",
title = "Theoretical and experimental study of triphenylphosphonium Schiff base of 5-hydroxy-3-methyl-1-phenyl-4-formylpyrazole",
volume = "193",
number = "6",
pages = "375-381",
doi = "10.1080/10426507.2018.1424159",
url = "Kon_3480"
}
Borodkin, S. A., Popov, L. D., Tsaturyan, A. A., Milenković, M. R., Shcherbakov, I. N.,& Lukov, V. V.. (2018). Theoretical and experimental study of triphenylphosphonium Schiff base of 5-hydroxy-3-methyl-1-phenyl-4-formylpyrazole. in Phosphorus Sulfur and Silicon and the Related Elements
Taylor & Francis Ltd, Abingdon., 193(6), 375-381.
https://doi.org/10.1080/10426507.2018.1424159
Kon_3480
Borodkin SA, Popov LD, Tsaturyan AA, Milenković MR, Shcherbakov IN, Lukov VV. Theoretical and experimental study of triphenylphosphonium Schiff base of 5-hydroxy-3-methyl-1-phenyl-4-formylpyrazole. in Phosphorus Sulfur and Silicon and the Related Elements. 2018;193(6):375-381.
doi:10.1080/10426507.2018.1424159
Kon_3480 .
Borodkin, Sergey A., Popov, Leonid D., Tsaturyan, Arshak A., Milenković, Milica R., Shcherbakov, Igor N., Lukov, Vladimir V., "Theoretical and experimental study of triphenylphosphonium Schiff base of 5-hydroxy-3-methyl-1-phenyl-4-formylpyrazole" in Phosphorus Sulfur and Silicon and the Related Elements, 193, no. 6 (2018):375-381,
https://doi.org/10.1080/10426507.2018.1424159 .,
Kon_3480 .
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