Popović, Aleksandar R.

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Authority KeyName Variants
orcid::0000-0003-0162-9612
  • Popović, Aleksandar R. (134)
Projects
The study of physicochemical and biochemical processes in living environment that have impacts on pollution and the investigation of possibilities for minimizing the consequences Studying climate change and its influence on environment: impacts, adaptation and mitigation
Geohemijska ispitivanja u funkciji pronalaženja novih ležišta fosilnih goriva i zaštite životne sredine Advanced technologies for monitoring and environmental protection from chemical pollutants and radiation burden
Synthesis and characterization of novel functional polymers and polymeric nanocomposites Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200168 (University of Belgrade, Faculty of Chemistry)
Improvement and development of hygienic and technological procedures in production of animal originating foodstuffs with the aim of producing high-quality and safe products competetive on the global market Modeling and Numerical Simulations of Complex Many-Body Systems
Dynamics of nonlinear physicochemical and biochemical systems with modeling and predicting of their behavior under nonequilibrium conditions Rational design and synthesis of biologically active and coordination compounds and functional materials, relevant for (bio)nanotechnology
Simultaneous Bioremediation and Soilification of Degraded Areas to Preserve Natural Resources of Biologically Active Substances, and Development and Production of Biomaterials and Dietetic Products Croatian Science Foundation (Project OPENTOX, No. 8366)
Structure-properties relationships of natural and synthetic molecules and their metal complexes Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200026 (University of Belgrade, Institute of Chemistry, Technology and Metallurgy - IChTM)
Emisija i transmisija polutanata u atmosferi urbane sredine Osmotic dehydration of food - energy and ecological aspects of sustainable production
Joint Institute for Nuclear Research, Dubna, Russia OTKA [K119269]
Bilateral contract between Institute of Physics and Institute for Medical Research and Occupational Health (337-00-205/2019–09/22). City of Belgrade
company NIS (Serbia) Croatian Science Foundation, Croatia (Project OPENTOX, No. 8366).
ERASMUS + programme European Commission
Biosensing Technologies and Global System for Long-Term Research and Integrated Management of Ecosystems Fizička hemija dinamičkih stanja i struktura neravnotežnih sistema - od monotone do oscilatorne evolucije i haosa
Improvement of production capacities of the carp (Cyprinus carpio L) using feeding and selective breeding programs Institute of Physics Belgrade (document number: 0801–116/1).
Ministry of Education and Science of the Republic of Serbia (contract number: 451- 03-1338/2020–14) for postdoctoral investigation for Dr. Tijana Milićević. “Persistent Organic Pollutants - Environmental Impact Assessment and Stability of Human Genetic Material” and the funding was provided by the Institute of Physics, Belgrade, through research supported by the Ministry of Education, Science, and Technological Development.

Author's Bibliography

To Professor Petar Pfendt, In calidum, et plurium retributivus memoriae: FTIR-ATR analysis of post stamps of the Principality of Serbia issued in 1866 and 1868 and their forgeries

Popović, Aleksandar R.; Anđelković, Boban D.; Đorđević, Dragana S.; Sakan, Sanja M.; Vujisić, Ljubodrag V.; Veličković, Sava; Relić, Dubravka

(2022)

TY  - JOUR
AU  - Popović, Aleksandar R.
AU  - Anđelković, Boban D.
AU  - Đorđević, Dragana S.
AU  - Sakan, Sanja M.
AU  - Vujisić, Ljubodrag V.
AU  - Veličković, Sava
AU  - Relić, Dubravka
PY  - 2022
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/4942
AB  - In order to further define the potential use of FTIR-ATR spectroscopy, as a non-destructive and reliable technique, for the analysis of the characteristics of post stamps, certified originals of the Principality of Serbia stamps (“Prince Michael issues”) issued in 1866 and 1868 as well as their forgeries were ana­lyzed. Spectra enabling the comparison of the paper, dye and glue of stamps of so-called “Vienna issues”, having denominations of 10 (orange-yellow), 20 (pink) and 40 para (blue) and “Belgrade issues” (1 para-green and 2 para-reddish brown), as well as 24 expert-certified forgeries, were taken. It was shown that the applied technology was, in most of the cases, a fast and suitable technique for establishing clear differences between the spectral characteristics of the paper and dye used for the original stamps, and forgeries that were most probably made decades after the printing of the genuine stamps. The differences between print­ings of the same issues of the genuine stamps were also elaborated. It is pro­posed, for the first time in philatelic history, the possibility that “Vienna issues” stamps may have been printed on two different papers, and, having in mind the technology of printing in the 19th century, potentially, not even at the same time or in the same printing house.
T2  - Journal of the Serbian Chemical Society
T1  - To Professor Petar Pfendt, In calidum, et plurium retributivus memoriae: FTIR-ATR analysis of post stamps of the Principality of Serbia issued in 1866 and 1868 and their forgeries
VL  - 87
IS  - 1
SP  - 27
EP  - 40
DO  - 10.2298/JSC210901090P
ER  - 
@article{
author = "Popović, Aleksandar R. and Anđelković, Boban D. and Đorđević, Dragana S. and Sakan, Sanja M. and Vujisić, Ljubodrag V. and Veličković, Sava and Relić, Dubravka",
year = "2022",
abstract = "In order to further define the potential use of FTIR-ATR spectroscopy, as a non-destructive and reliable technique, for the analysis of the characteristics of post stamps, certified originals of the Principality of Serbia stamps (“Prince Michael issues”) issued in 1866 and 1868 as well as their forgeries were ana­lyzed. Spectra enabling the comparison of the paper, dye and glue of stamps of so-called “Vienna issues”, having denominations of 10 (orange-yellow), 20 (pink) and 40 para (blue) and “Belgrade issues” (1 para-green and 2 para-reddish brown), as well as 24 expert-certified forgeries, were taken. It was shown that the applied technology was, in most of the cases, a fast and suitable technique for establishing clear differences between the spectral characteristics of the paper and dye used for the original stamps, and forgeries that were most probably made decades after the printing of the genuine stamps. The differences between print­ings of the same issues of the genuine stamps were also elaborated. It is pro­posed, for the first time in philatelic history, the possibility that “Vienna issues” stamps may have been printed on two different papers, and, having in mind the technology of printing in the 19th century, potentially, not even at the same time or in the same printing house.",
journal = "Journal of the Serbian Chemical Society",
title = "To Professor Petar Pfendt, In calidum, et plurium retributivus memoriae: FTIR-ATR analysis of post stamps of the Principality of Serbia issued in 1866 and 1868 and their forgeries",
volume = "87",
number = "1",
pages = "27-40",
doi = "10.2298/JSC210901090P"
}
Popović, A. R., Anđelković, B. D., Đorđević, D. S., Sakan, S. M., Vujisić, L. V., Veličković, S.,& Relić, D.. (2022). To Professor Petar Pfendt, In calidum, et plurium retributivus memoriae: FTIR-ATR analysis of post stamps of the Principality of Serbia issued in 1866 and 1868 and their forgeries. in Journal of the Serbian Chemical Society, 87(1), 27-40.
https://doi.org/10.2298/JSC210901090P
Popović AR, Anđelković BD, Đorđević DS, Sakan SM, Vujisić LV, Veličković S, Relić D. To Professor Petar Pfendt, In calidum, et plurium retributivus memoriae: FTIR-ATR analysis of post stamps of the Principality of Serbia issued in 1866 and 1868 and their forgeries. in Journal of the Serbian Chemical Society. 2022;87(1):27-40.
doi:10.2298/JSC210901090P .
Popović, Aleksandar R., Anđelković, Boban D., Đorđević, Dragana S., Sakan, Sanja M., Vujisić, Ljubodrag V., Veličković, Sava, Relić, Dubravka, "To Professor Petar Pfendt, In calidum, et plurium retributivus memoriae: FTIR-ATR analysis of post stamps of the Principality of Serbia issued in 1866 and 1868 and their forgeries" in Journal of the Serbian Chemical Society, 87, no. 1 (2022):27-40,
https://doi.org/10.2298/JSC210901090P . .

Moss bag sensitivity for the assessment of airborne elements at suburban background site during spring/summer season characterized by Saharan dust intrusions

Aničić Urošević, Mira; Kuzmanoski, Maja; Milićević, Tijana; Kodranov, Igor D.; Vergel, Konstantin; Popović, Aleksandar R.

(SpringerLink, 2022)

TY  - JOUR
AU  - Aničić Urošević, Mira
AU  - Kuzmanoski, Maja
AU  - Milićević, Tijana
AU  - Kodranov, Igor D.
AU  - Vergel, Konstantin
AU  - Popović, Aleksandar R.
PY  - 2022
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5036
AB  - Moss transplants of Hypnum cupressiforme and Sphagnum girgensohnii were tested for efciency in detection of airborne
element pollution at a suburban background site during short time exposure of 15 days (twelve consecutive periods) and
during prolonged exposure from one to six months. Concomitantly, particulate matter (PM10, PM2.5) was sampled during
three identifed Saharan dust episodes, while MERRA-2 data were used for estimation of dust concentration at ground level to
which the moss bags were exposed during 15-day periods. The concentrations of 22 potentially toxic elements were measured
in the moss and PM10 samples. The results showed that 15-day bag exposure at the background location could not provide
a measurable and reliable signature of the elements in the moss transplants, except for Al, V, As, Ga, Y, and Tb, unlike the
extended moss bag exposure of a couple of months. These were also the only elements whose concentrations were increased
multifold in PM10 samples during the most intense dust episode, which was also recorded by S. girgensohnii bags exposed
in the corresponding 15-day period. The ratio of crustal elements (Ca/Al, Mg/Al) in PM10 and moss samples (3-month
exposed) was in line of those reported for dust transported from western Africa. The V/Al, Ga/Al, and Tb/Al concentration
ratio values in PM10 and S. girgensohnii samples were higher for dust days contrary to the As/Al ratio, which could be used
to distinguish between dust and fossil fuel combustion pollution sources. The moss bag technique could be used as a simple
tool for tracking long-range transported elements, but after prolonged moss bag exposure (3 months).
PB  - SpringerLink
T2  - Air Quality, Atmosphere & Health
T1  - Moss bag sensitivity for the assessment of airborne elements at suburban background site during spring/summer season characterized by Saharan dust intrusions
VL  - n/a
DO  - 10.1007/s11869-022-01161-8
ER  - 
@article{
author = "Aničić Urošević, Mira and Kuzmanoski, Maja and Milićević, Tijana and Kodranov, Igor D. and Vergel, Konstantin and Popović, Aleksandar R.",
year = "2022",
abstract = "Moss transplants of Hypnum cupressiforme and Sphagnum girgensohnii were tested for efciency in detection of airborne
element pollution at a suburban background site during short time exposure of 15 days (twelve consecutive periods) and
during prolonged exposure from one to six months. Concomitantly, particulate matter (PM10, PM2.5) was sampled during
three identifed Saharan dust episodes, while MERRA-2 data were used for estimation of dust concentration at ground level to
which the moss bags were exposed during 15-day periods. The concentrations of 22 potentially toxic elements were measured
in the moss and PM10 samples. The results showed that 15-day bag exposure at the background location could not provide
a measurable and reliable signature of the elements in the moss transplants, except for Al, V, As, Ga, Y, and Tb, unlike the
extended moss bag exposure of a couple of months. These were also the only elements whose concentrations were increased
multifold in PM10 samples during the most intense dust episode, which was also recorded by S. girgensohnii bags exposed
in the corresponding 15-day period. The ratio of crustal elements (Ca/Al, Mg/Al) in PM10 and moss samples (3-month
exposed) was in line of those reported for dust transported from western Africa. The V/Al, Ga/Al, and Tb/Al concentration
ratio values in PM10 and S. girgensohnii samples were higher for dust days contrary to the As/Al ratio, which could be used
to distinguish between dust and fossil fuel combustion pollution sources. The moss bag technique could be used as a simple
tool for tracking long-range transported elements, but after prolonged moss bag exposure (3 months).",
publisher = "SpringerLink",
journal = "Air Quality, Atmosphere & Health",
title = "Moss bag sensitivity for the assessment of airborne elements at suburban background site during spring/summer season characterized by Saharan dust intrusions",
volume = "n/a",
doi = "10.1007/s11869-022-01161-8"
}
Aničić Urošević, M., Kuzmanoski, M., Milićević, T., Kodranov, I. D., Vergel, K.,& Popović, A. R.. (2022). Moss bag sensitivity for the assessment of airborne elements at suburban background site during spring/summer season characterized by Saharan dust intrusions. in Air Quality, Atmosphere & Health
SpringerLink., n/a.
https://doi.org/10.1007/s11869-022-01161-8
Aničić Urošević M, Kuzmanoski M, Milićević T, Kodranov ID, Vergel K, Popović AR. Moss bag sensitivity for the assessment of airborne elements at suburban background site during spring/summer season characterized by Saharan dust intrusions. in Air Quality, Atmosphere & Health. 2022;n/a.
doi:10.1007/s11869-022-01161-8 .
Aničić Urošević, Mira, Kuzmanoski, Maja, Milićević, Tijana, Kodranov, Igor D., Vergel, Konstantin, Popović, Aleksandar R., "Moss bag sensitivity for the assessment of airborne elements at suburban background site during spring/summer season characterized by Saharan dust intrusions" in Air Quality, Atmosphere & Health, n/a (2022),
https://doi.org/10.1007/s11869-022-01161-8 . .
1
1

Human health risks and benefits assessment based on OCPs, PCBs, toxic elements and fatty acids in the pelagic fish species from the Adriatic Sea

Milićević, Tijana; Herceg Romanić, Snježana; Popović, Aleksandar R.; Mustać, Bosiljka; Đinović-Stojanović, Jasna; Jovanović, Gordana; Relić, Dubravka

(Elsevier, 2022)

TY  - JOUR
AU  - Milićević, Tijana
AU  - Herceg Romanić, Snježana
AU  - Popović, Aleksandar R.
AU  - Mustać, Bosiljka
AU  - Đinović-Stojanović, Jasna
AU  - Jovanović, Gordana
AU  - Relić, Dubravka
PY  - 2022
UR  - https://www.sciencedirect.com/science/article/pii/S0045653521025406
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/4664
AB  - Benefits and risks of the fish consumption should be assessed to balance the ingestion of healthy omega-3 fatty acids and adverse chemicals. Persistent organic pollutants-POPs (organochlorine pesticides-OCPs and polychlorinated biphenyls-PCB), macro- and micro-elements and fatty acid contents were determined in six fish species from the Adriatic Sea to assess health risks for consumers (worst-case scenario, diseases development risks and benefit-risk). 16 element, 24 POPs and 14 fatty acid contents were determined in six pelagic species which can be used in human diet. Element concentrations were determined by inductively coupled plasma mass spectrometry (ICP-MS), POPs by high-resolution gas chromatography and fatty acid content by gas–liquid chromatography. Diet based on chub mackerel and round sardinella showed lower daily intake (DI) of POPs and highest DI of essential omega-3 fatty acids than other investigated species. Lower ingestion of toxic elements can be observed by consuming anchovy and round sardinella. Based on POP concentrations, there was not observed non-carcinogenic (HI) nor carcinogenic (CR) risks for consumers. Based on element concentrations, there was low HI (0.1 ≥ HI ≥ 1), while the maximum HIs and outlier values (horse mackerel and anchovy samples) implied the presence of HI (HI > 1). The most significant contributor to total non-carcinogenic and carcinogenic risks was inorganic arsenic (inorganic As). Acceptable CR for consumers was assessed, but maximum CR for consumers of horse mackerel and anchovy (CR ≥ 1 × 10–6) showed adverse effects on human health. There were low HIs for developing cardiovascular, nervous, and reproductive diseases, and maximum HIs were higher than 1. Acceptable (1 × 10−4≥CR ≥ 1 × 10−6) risks were observed for developing cancer of nervous system and reproductive organs. Among investigated fish samples, those with higher ƩBR (benefit-risks) and BR for arsenic (As) than median value have a higher risk than benefits in the human diet.
PB  - Elsevier
T2  - Chemosphere
T1  - Human health risks and benefits assessment based on OCPs, PCBs, toxic elements and fatty acids in the pelagic fish species from the Adriatic Sea
VL  - 287
SP  - 132068
DO  - 10.1016/j.chemosphere.2021.132068
ER  - 
@article{
author = "Milićević, Tijana and Herceg Romanić, Snježana and Popović, Aleksandar R. and Mustać, Bosiljka and Đinović-Stojanović, Jasna and Jovanović, Gordana and Relić, Dubravka",
year = "2022",
abstract = "Benefits and risks of the fish consumption should be assessed to balance the ingestion of healthy omega-3 fatty acids and adverse chemicals. Persistent organic pollutants-POPs (organochlorine pesticides-OCPs and polychlorinated biphenyls-PCB), macro- and micro-elements and fatty acid contents were determined in six fish species from the Adriatic Sea to assess health risks for consumers (worst-case scenario, diseases development risks and benefit-risk). 16 element, 24 POPs and 14 fatty acid contents were determined in six pelagic species which can be used in human diet. Element concentrations were determined by inductively coupled plasma mass spectrometry (ICP-MS), POPs by high-resolution gas chromatography and fatty acid content by gas–liquid chromatography. Diet based on chub mackerel and round sardinella showed lower daily intake (DI) of POPs and highest DI of essential omega-3 fatty acids than other investigated species. Lower ingestion of toxic elements can be observed by consuming anchovy and round sardinella. Based on POP concentrations, there was not observed non-carcinogenic (HI) nor carcinogenic (CR) risks for consumers. Based on element concentrations, there was low HI (0.1 ≥ HI ≥ 1), while the maximum HIs and outlier values (horse mackerel and anchovy samples) implied the presence of HI (HI > 1). The most significant contributor to total non-carcinogenic and carcinogenic risks was inorganic arsenic (inorganic As). Acceptable CR for consumers was assessed, but maximum CR for consumers of horse mackerel and anchovy (CR ≥ 1 × 10–6) showed adverse effects on human health. There were low HIs for developing cardiovascular, nervous, and reproductive diseases, and maximum HIs were higher than 1. Acceptable (1 × 10−4≥CR ≥ 1 × 10−6) risks were observed for developing cancer of nervous system and reproductive organs. Among investigated fish samples, those with higher ƩBR (benefit-risks) and BR for arsenic (As) than median value have a higher risk than benefits in the human diet.",
publisher = "Elsevier",
journal = "Chemosphere",
title = "Human health risks and benefits assessment based on OCPs, PCBs, toxic elements and fatty acids in the pelagic fish species from the Adriatic Sea",
volume = "287",
pages = "132068",
doi = "10.1016/j.chemosphere.2021.132068"
}
Milićević, T., Herceg Romanić, S., Popović, A. R., Mustać, B., Đinović-Stojanović, J., Jovanović, G.,& Relić, D.. (2022). Human health risks and benefits assessment based on OCPs, PCBs, toxic elements and fatty acids in the pelagic fish species from the Adriatic Sea. in Chemosphere
Elsevier., 287, 132068.
https://doi.org/10.1016/j.chemosphere.2021.132068
Milićević T, Herceg Romanić S, Popović AR, Mustać B, Đinović-Stojanović J, Jovanović G, Relić D. Human health risks and benefits assessment based on OCPs, PCBs, toxic elements and fatty acids in the pelagic fish species from the Adriatic Sea. in Chemosphere. 2022;287:132068.
doi:10.1016/j.chemosphere.2021.132068 .
Milićević, Tijana, Herceg Romanić, Snježana, Popović, Aleksandar R., Mustać, Bosiljka, Đinović-Stojanović, Jasna, Jovanović, Gordana, Relić, Dubravka, "Human health risks and benefits assessment based on OCPs, PCBs, toxic elements and fatty acids in the pelagic fish species from the Adriatic Sea" in Chemosphere, 287 (2022):132068,
https://doi.org/10.1016/j.chemosphere.2021.132068 . .
6
1
3

Supplementary data for the article: Milićević, T.; Romanić, S. H.; Popović, A.; Mustać, B.; Đinović-Stojanović, J.; Jovanović, G.; Relić, D. Human Health Risks and Benefits Assessment Based on OCPs, PCBs, Toxic Elements and Fatty Acids in the Pelagic Fish Species from the Adriatic Sea. Chemosphere 2022, 287, 132068. https://doi.org/10.1016/j.chemosphere.2021.132068.

Milićević, Tijana; Herceg Romanić, Snježana; Popović, Aleksandar R.; Mustać, Bosiljka; Đinović-Stojanović, Jasna; Jovanović, Gordana; Relić, Dubravka

(Elsevier, 2022)

TY  - DATA
AU  - Milićević, Tijana
AU  - Herceg Romanić, Snježana
AU  - Popović, Aleksandar R.
AU  - Mustać, Bosiljka
AU  - Đinović-Stojanović, Jasna
AU  - Jovanović, Gordana
AU  - Relić, Dubravka
PY  - 2022
UR  - https://www.sciencedirect.com/science/article/pii/S0045653521025406
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/4665
PB  - Elsevier
T2  - Chemosphere
T1  - Supplementary data for the article: Milićević, T.; Romanić, S. H.; Popović, A.; Mustać, B.; Đinović-Stojanović, J.; Jovanović, G.; Relić, D. Human Health Risks and Benefits Assessment Based on OCPs, PCBs, Toxic Elements and Fatty Acids in the Pelagic Fish Species from the Adriatic Sea. Chemosphere 2022, 287, 132068. https://doi.org/10.1016/j.chemosphere.2021.132068.
UR  - https://hdl.handle.net/21.15107/rcub_cherry_4665
ER  - 
@misc{
author = "Milićević, Tijana and Herceg Romanić, Snježana and Popović, Aleksandar R. and Mustać, Bosiljka and Đinović-Stojanović, Jasna and Jovanović, Gordana and Relić, Dubravka",
year = "2022",
publisher = "Elsevier",
journal = "Chemosphere",
title = "Supplementary data for the article: Milićević, T.; Romanić, S. H.; Popović, A.; Mustać, B.; Đinović-Stojanović, J.; Jovanović, G.; Relić, D. Human Health Risks and Benefits Assessment Based on OCPs, PCBs, Toxic Elements and Fatty Acids in the Pelagic Fish Species from the Adriatic Sea. Chemosphere 2022, 287, 132068. https://doi.org/10.1016/j.chemosphere.2021.132068.",
url = "https://hdl.handle.net/21.15107/rcub_cherry_4665"
}
Milićević, T., Herceg Romanić, S., Popović, A. R., Mustać, B., Đinović-Stojanović, J., Jovanović, G.,& Relić, D.. (2022). Supplementary data for the article: Milićević, T.; Romanić, S. H.; Popović, A.; Mustać, B.; Đinović-Stojanović, J.; Jovanović, G.; Relić, D. Human Health Risks and Benefits Assessment Based on OCPs, PCBs, Toxic Elements and Fatty Acids in the Pelagic Fish Species from the Adriatic Sea. Chemosphere 2022, 287, 132068. https://doi.org/10.1016/j.chemosphere.2021.132068.. in Chemosphere
Elsevier..
https://hdl.handle.net/21.15107/rcub_cherry_4665
Milićević T, Herceg Romanić S, Popović AR, Mustać B, Đinović-Stojanović J, Jovanović G, Relić D. Supplementary data for the article: Milićević, T.; Romanić, S. H.; Popović, A.; Mustać, B.; Đinović-Stojanović, J.; Jovanović, G.; Relić, D. Human Health Risks and Benefits Assessment Based on OCPs, PCBs, Toxic Elements and Fatty Acids in the Pelagic Fish Species from the Adriatic Sea. Chemosphere 2022, 287, 132068. https://doi.org/10.1016/j.chemosphere.2021.132068.. in Chemosphere. 2022;.
https://hdl.handle.net/21.15107/rcub_cherry_4665 .
Milićević, Tijana, Herceg Romanić, Snježana, Popović, Aleksandar R., Mustać, Bosiljka, Đinović-Stojanović, Jasna, Jovanović, Gordana, Relić, Dubravka, "Supplementary data for the article: Milićević, T.; Romanić, S. H.; Popović, A.; Mustać, B.; Đinović-Stojanović, J.; Jovanović, G.; Relić, D. Human Health Risks and Benefits Assessment Based on OCPs, PCBs, Toxic Elements and Fatty Acids in the Pelagic Fish Species from the Adriatic Sea. Chemosphere 2022, 287, 132068. https://doi.org/10.1016/j.chemosphere.2021.132068." in Chemosphere (2022),
https://hdl.handle.net/21.15107/rcub_cherry_4665 .

Supplementary data for the article: Mendaš, G.; Herceg Romanić, S.; Jovanović, G.; Aničić Urošević, M.; Ilić, M.; Milićević, T.; Popović, A. Organochlorines Burden in Moss H. Cupressiforme and Topsoil across Serbia. Environ Geochem Health 2021, 43 (1), 273–283. https://doi.org/10.1007/s10653-020-00704-1.

Mendaš, Gordana; Herceg Romanić, Snježana; Jovanović, Gordana; Urošević-Aničić, Mira; Ilić, Miloš; Milićević, Tijana; Popović, Aleksandar R.

(Springer, 2021)

TY  - DATA
AU  - Mendaš, Gordana
AU  - Herceg Romanić, Snježana
AU  - Jovanović, Gordana
AU  - Urošević-Aničić, Mira
AU  - Ilić, Miloš
AU  - Milićević, Tijana
AU  - Popović, Aleksandar R.
PY  - 2021
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/4796
PB  - Springer
T2  - Environmental Geochemistry and Health
T1  - Supplementary data for the article: Mendaš, G.; Herceg Romanić, S.; Jovanović, G.; Aničić Urošević, M.; Ilić, M.; Milićević, T.; Popović, A. Organochlorines Burden in Moss H. Cupressiforme and Topsoil across Serbia. Environ Geochem Health 2021, 43 (1), 273–283. https://doi.org/10.1007/s10653-020-00704-1.
UR  - https://hdl.handle.net/21.15107/rcub_cherry_4796
ER  - 
@misc{
author = "Mendaš, Gordana and Herceg Romanić, Snježana and Jovanović, Gordana and Urošević-Aničić, Mira and Ilić, Miloš and Milićević, Tijana and Popović, Aleksandar R.",
year = "2021",
publisher = "Springer",
journal = "Environmental Geochemistry and Health",
title = "Supplementary data for the article: Mendaš, G.; Herceg Romanić, S.; Jovanović, G.; Aničić Urošević, M.; Ilić, M.; Milićević, T.; Popović, A. Organochlorines Burden in Moss H. Cupressiforme and Topsoil across Serbia. Environ Geochem Health 2021, 43 (1), 273–283. https://doi.org/10.1007/s10653-020-00704-1.",
url = "https://hdl.handle.net/21.15107/rcub_cherry_4796"
}
Mendaš, G., Herceg Romanić, S., Jovanović, G., Urošević-Aničić, M., Ilić, M., Milićević, T.,& Popović, A. R.. (2021). Supplementary data for the article: Mendaš, G.; Herceg Romanić, S.; Jovanović, G.; Aničić Urošević, M.; Ilić, M.; Milićević, T.; Popović, A. Organochlorines Burden in Moss H. Cupressiforme and Topsoil across Serbia. Environ Geochem Health 2021, 43 (1), 273–283. https://doi.org/10.1007/s10653-020-00704-1.. in Environmental Geochemistry and Health
Springer..
https://hdl.handle.net/21.15107/rcub_cherry_4796
Mendaš G, Herceg Romanić S, Jovanović G, Urošević-Aničić M, Ilić M, Milićević T, Popović AR. Supplementary data for the article: Mendaš, G.; Herceg Romanić, S.; Jovanović, G.; Aničić Urošević, M.; Ilić, M.; Milićević, T.; Popović, A. Organochlorines Burden in Moss H. Cupressiforme and Topsoil across Serbia. Environ Geochem Health 2021, 43 (1), 273–283. https://doi.org/10.1007/s10653-020-00704-1.. in Environmental Geochemistry and Health. 2021;.
https://hdl.handle.net/21.15107/rcub_cherry_4796 .
Mendaš, Gordana, Herceg Romanić, Snježana, Jovanović, Gordana, Urošević-Aničić, Mira, Ilić, Miloš, Milićević, Tijana, Popović, Aleksandar R., "Supplementary data for the article: Mendaš, G.; Herceg Romanić, S.; Jovanović, G.; Aničić Urošević, M.; Ilić, M.; Milićević, T.; Popović, A. Organochlorines Burden in Moss H. Cupressiforme and Topsoil across Serbia. Environ Geochem Health 2021, 43 (1), 273–283. https://doi.org/10.1007/s10653-020-00704-1." in Environmental Geochemistry and Health (2021),
https://hdl.handle.net/21.15107/rcub_cherry_4796 .

Supplementary data for the article: Milićević, T.; Aničić Urošević, M.; Relić, D.; Jovanović, G.; Nikolić, D.; Vergel, K.; Popović, A. Environmental Pollution Influence to Soil–Plant–Air System in Organic Vineyard: Bioavailability, Environmental, and Health Risk Assessment. Environ Sci Pollut Res 2021, 28 (3), 3361–3374. https://doi.org/10.1007/s11356-020-10649-8.

Milićević, Tijana; Urošević-Aničić, Mira; Relić, Dubravka; Jovanović, Gordana; Nikolić, Dragica; Vergel, Konstantin; Popović, Aleksandar R.

(Springer, 2021)

TY  - DATA
AU  - Milićević, Tijana
AU  - Urošević-Aničić, Mira
AU  - Relić, Dubravka
AU  - Jovanović, Gordana
AU  - Nikolić, Dragica
AU  - Vergel, Konstantin
AU  - Popović, Aleksandar R.
PY  - 2021
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/4808
PB  - Springer
T2  - Environmental Science and Pollution Research
T1  - Supplementary data for the article: Milićević, T.; Aničić Urošević, M.; Relić, D.; Jovanović, G.; Nikolić, D.; Vergel, K.; Popović, A. Environmental Pollution Influence to Soil–Plant–Air System in Organic Vineyard: Bioavailability, Environmental, and Health Risk Assessment. Environ Sci Pollut Res 2021, 28 (3), 3361–3374. https://doi.org/10.1007/s11356-020-10649-8.
UR  - https://hdl.handle.net/21.15107/rcub_cherry_4808
ER  - 
@misc{
author = "Milićević, Tijana and Urošević-Aničić, Mira and Relić, Dubravka and Jovanović, Gordana and Nikolić, Dragica and Vergel, Konstantin and Popović, Aleksandar R.",
year = "2021",
publisher = "Springer",
journal = "Environmental Science and Pollution Research",
title = "Supplementary data for the article: Milićević, T.; Aničić Urošević, M.; Relić, D.; Jovanović, G.; Nikolić, D.; Vergel, K.; Popović, A. Environmental Pollution Influence to Soil–Plant–Air System in Organic Vineyard: Bioavailability, Environmental, and Health Risk Assessment. Environ Sci Pollut Res 2021, 28 (3), 3361–3374. https://doi.org/10.1007/s11356-020-10649-8.",
url = "https://hdl.handle.net/21.15107/rcub_cherry_4808"
}
Milićević, T., Urošević-Aničić, M., Relić, D., Jovanović, G., Nikolić, D., Vergel, K.,& Popović, A. R.. (2021). Supplementary data for the article: Milićević, T.; Aničić Urošević, M.; Relić, D.; Jovanović, G.; Nikolić, D.; Vergel, K.; Popović, A. Environmental Pollution Influence to Soil–Plant–Air System in Organic Vineyard: Bioavailability, Environmental, and Health Risk Assessment. Environ Sci Pollut Res 2021, 28 (3), 3361–3374. https://doi.org/10.1007/s11356-020-10649-8.. in Environmental Science and Pollution Research
Springer..
https://hdl.handle.net/21.15107/rcub_cherry_4808
Milićević T, Urošević-Aničić M, Relić D, Jovanović G, Nikolić D, Vergel K, Popović AR. Supplementary data for the article: Milićević, T.; Aničić Urošević, M.; Relić, D.; Jovanović, G.; Nikolić, D.; Vergel, K.; Popović, A. Environmental Pollution Influence to Soil–Plant–Air System in Organic Vineyard: Bioavailability, Environmental, and Health Risk Assessment. Environ Sci Pollut Res 2021, 28 (3), 3361–3374. https://doi.org/10.1007/s11356-020-10649-8.. in Environmental Science and Pollution Research. 2021;.
https://hdl.handle.net/21.15107/rcub_cherry_4808 .
Milićević, Tijana, Urošević-Aničić, Mira, Relić, Dubravka, Jovanović, Gordana, Nikolić, Dragica, Vergel, Konstantin, Popović, Aleksandar R., "Supplementary data for the article: Milićević, T.; Aničić Urošević, M.; Relić, D.; Jovanović, G.; Nikolić, D.; Vergel, K.; Popović, A. Environmental Pollution Influence to Soil–Plant–Air System in Organic Vineyard: Bioavailability, Environmental, and Health Risk Assessment. Environ Sci Pollut Res 2021, 28 (3), 3361–3374. https://doi.org/10.1007/s11356-020-10649-8." in Environmental Science and Pollution Research (2021),
https://hdl.handle.net/21.15107/rcub_cherry_4808 .

Environmental pollution influence to soil–plant–air system in organic vineyard: bioavailability, environmental, and health risk assessment

Milićević, Tijana; Urošević-Aničić, Mira; Relić, Dubravka; Jovanović, Gordana; Nikolić, Dragica; Vergel, Konstantin; Popović, Aleksandar R.

(Springer, 2021)

TY  - JOUR
AU  - Milićević, Tijana
AU  - Urošević-Aničić, Mira
AU  - Relić, Dubravka
AU  - Jovanović, Gordana
AU  - Nikolić, Dragica
AU  - Vergel, Konstantin
AU  - Popović, Aleksandar R.
PY  - 2021
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/4807
AB  - This study was performed in organic vineyard to assess integrated pollution in soil–plant–air system by potentially toxic elements (PTE). Concentrations of 26 PTE were determined in soil, grapevine, and air biomonitors (moss bags) using ICP-OES and ICP-MS. Environmental implication assessment of soil did not show pollution by PTE, except for B in samples collected in the middle of grapevine season (July). Despite low total Cd concentrations in soil, it has the highest influence on increase of environmental risk. Based on biological accumulation concentration (BAC), grapevine is not hyperaccumulator of PTE from soil. Advanced classification algorithm, Kohonen self-organizing map (SOM), was applied to compare environmental implications in organic with conventional vineyards. PTE concentrations were significantly lower in organic than conventional grapevine. PTE concentrations were higher in the outer (leaf and petiole) than in the inner grapevine parts (skin, pulp, and seed). Some airborne elements have an influence on outer grapevine parts, especially on leaves (ratio factor—RF > 1). Moss bag technique testified about lower enrichment of airborne elements compared with the conventional vineyard and urban microenvironments. Environmental and health risk assessments confirmed that organic production is harmless for field workers and grape consumers.
PB  - Springer
T2  - Environmental Science and Pollution Research
T1  - Environmental pollution influence to soil–plant–air system in organic vineyard: bioavailability, environmental, and health risk assessment
VL  - 28
IS  - 3
SP  - 3361
EP  - 3374
DO  - 10.1007/s11356-020-10649-8
ER  - 
@article{
author = "Milićević, Tijana and Urošević-Aničić, Mira and Relić, Dubravka and Jovanović, Gordana and Nikolić, Dragica and Vergel, Konstantin and Popović, Aleksandar R.",
year = "2021",
abstract = "This study was performed in organic vineyard to assess integrated pollution in soil–plant–air system by potentially toxic elements (PTE). Concentrations of 26 PTE were determined in soil, grapevine, and air biomonitors (moss bags) using ICP-OES and ICP-MS. Environmental implication assessment of soil did not show pollution by PTE, except for B in samples collected in the middle of grapevine season (July). Despite low total Cd concentrations in soil, it has the highest influence on increase of environmental risk. Based on biological accumulation concentration (BAC), grapevine is not hyperaccumulator of PTE from soil. Advanced classification algorithm, Kohonen self-organizing map (SOM), was applied to compare environmental implications in organic with conventional vineyards. PTE concentrations were significantly lower in organic than conventional grapevine. PTE concentrations were higher in the outer (leaf and petiole) than in the inner grapevine parts (skin, pulp, and seed). Some airborne elements have an influence on outer grapevine parts, especially on leaves (ratio factor—RF > 1). Moss bag technique testified about lower enrichment of airborne elements compared with the conventional vineyard and urban microenvironments. Environmental and health risk assessments confirmed that organic production is harmless for field workers and grape consumers.",
publisher = "Springer",
journal = "Environmental Science and Pollution Research",
title = "Environmental pollution influence to soil–plant–air system in organic vineyard: bioavailability, environmental, and health risk assessment",
volume = "28",
number = "3",
pages = "3361-3374",
doi = "10.1007/s11356-020-10649-8"
}
Milićević, T., Urošević-Aničić, M., Relić, D., Jovanović, G., Nikolić, D., Vergel, K.,& Popović, A. R.. (2021). Environmental pollution influence to soil–plant–air system in organic vineyard: bioavailability, environmental, and health risk assessment. in Environmental Science and Pollution Research
Springer., 28(3), 3361-3374.
https://doi.org/10.1007/s11356-020-10649-8
Milićević T, Urošević-Aničić M, Relić D, Jovanović G, Nikolić D, Vergel K, Popović AR. Environmental pollution influence to soil–plant–air system in organic vineyard: bioavailability, environmental, and health risk assessment. in Environmental Science and Pollution Research. 2021;28(3):3361-3374.
doi:10.1007/s11356-020-10649-8 .
Milićević, Tijana, Urošević-Aničić, Mira, Relić, Dubravka, Jovanović, Gordana, Nikolić, Dragica, Vergel, Konstantin, Popović, Aleksandar R., "Environmental pollution influence to soil–plant–air system in organic vineyard: bioavailability, environmental, and health risk assessment" in Environmental Science and Pollution Research, 28, no. 3 (2021):3361-3374,
https://doi.org/10.1007/s11356-020-10649-8 . .
1
9
4
10

Organochlorines burden in moss H. cupressiforme and topsoil across Serbia

Mendaš, Gordana; Herceg Romanić, Snježana; Jovanović, Gordana; Urošević-Aničić, Mira; Ilić, Miloš; Milićević, Tijana; Popović, Aleksandar R.

(Springer, 2021)

TY  - JOUR
AU  - Mendaš, Gordana
AU  - Herceg Romanić, Snježana
AU  - Jovanović, Gordana
AU  - Urošević-Aničić, Mira
AU  - Ilić, Miloš
AU  - Milićević, Tijana
AU  - Popović, Aleksandar R.
PY  - 2021
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/4795
AB  - Following up-to-date initiatives of the Stockholm Convention, its global monitoring plan, and the International Cooperative Programme on Natural Vegetation and Crops (ICP Vegetation 2015) under the convention on long-range transboundary air pollution, this study examined 17 polychlorinated biphenyls (PCBs) and seven organochlorine pesticides (OCPs) in the moss Hypnum cupressiforme Hedw. and topsoil sampled across Serbia. In the topsoil, OCPs ranged from 0.0158 to 9.6804 ng g−1 while concentrations of individual PCB congeners were in the range between 0.0185 and 0.3107 ng g−1. The levels of OCPs and PCBs in the moss H. cupressiforme ranged from 2.7785 to 23.9501 ng g−1, and from 0.4325 to 15.8013 ng g−1, respectively. POP relationships between topsoil and moss investigated by fugacity model equations indicated that the moss POP enrichment was a result of atmospheric long-range transport rather than secondary reemissions from soil.
PB  - Springer
T2  - Environmental Geochemistry and Health
T1  - Organochlorines burden in moss H. cupressiforme and topsoil across Serbia
VL  - 43
IS  - 1
SP  - 273
EP  - 283
DO  - 10.1007/s10653-020-00704-1
ER  - 
@article{
author = "Mendaš, Gordana and Herceg Romanić, Snježana and Jovanović, Gordana and Urošević-Aničić, Mira and Ilić, Miloš and Milićević, Tijana and Popović, Aleksandar R.",
year = "2021",
abstract = "Following up-to-date initiatives of the Stockholm Convention, its global monitoring plan, and the International Cooperative Programme on Natural Vegetation and Crops (ICP Vegetation 2015) under the convention on long-range transboundary air pollution, this study examined 17 polychlorinated biphenyls (PCBs) and seven organochlorine pesticides (OCPs) in the moss Hypnum cupressiforme Hedw. and topsoil sampled across Serbia. In the topsoil, OCPs ranged from 0.0158 to 9.6804 ng g−1 while concentrations of individual PCB congeners were in the range between 0.0185 and 0.3107 ng g−1. The levels of OCPs and PCBs in the moss H. cupressiforme ranged from 2.7785 to 23.9501 ng g−1, and from 0.4325 to 15.8013 ng g−1, respectively. POP relationships between topsoil and moss investigated by fugacity model equations indicated that the moss POP enrichment was a result of atmospheric long-range transport rather than secondary reemissions from soil.",
publisher = "Springer",
journal = "Environmental Geochemistry and Health",
title = "Organochlorines burden in moss H. cupressiforme and topsoil across Serbia",
volume = "43",
number = "1",
pages = "273-283",
doi = "10.1007/s10653-020-00704-1"
}
Mendaš, G., Herceg Romanić, S., Jovanović, G., Urošević-Aničić, M., Ilić, M., Milićević, T.,& Popović, A. R.. (2021). Organochlorines burden in moss H. cupressiforme and topsoil across Serbia. in Environmental Geochemistry and Health
Springer., 43(1), 273-283.
https://doi.org/10.1007/s10653-020-00704-1
Mendaš G, Herceg Romanić S, Jovanović G, Urošević-Aničić M, Ilić M, Milićević T, Popović AR. Organochlorines burden in moss H. cupressiforme and topsoil across Serbia. in Environmental Geochemistry and Health. 2021;43(1):273-283.
doi:10.1007/s10653-020-00704-1 .
Mendaš, Gordana, Herceg Romanić, Snježana, Jovanović, Gordana, Urošević-Aničić, Mira, Ilić, Miloš, Milićević, Tijana, Popović, Aleksandar R., "Organochlorines burden in moss H. cupressiforme and topsoil across Serbia" in Environmental Geochemistry and Health, 43, no. 1 (2021):273-283,
https://doi.org/10.1007/s10653-020-00704-1 . .
1

Evaluation of Element Mobility in River Sediment Using Different Single Extraction Procedures and Assessment of Probabilistic Ecological Risk

Sakan, Sanja M.; Frančišković-Bilinski, Stanislav; Đorđević, Dragana S.; Popović, Aleksandar R.; Sakan, Nenad; Škrivanj, Sandra B.; Bilinski, Halka

(2021)

TY  - JOUR
AU  - Sakan, Sanja M.
AU  - Frančišković-Bilinski, Stanislav
AU  - Đorđević, Dragana S.
AU  - Popović, Aleksandar R.
AU  - Sakan, Nenad
AU  - Škrivanj, Sandra B.
AU  - Bilinski, Halka
PY  - 2021
UR  - https://www.mdpi.com/2073-4441/13/10/1411
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/4546
AB  - In this manuscript, samples of Kupa River sediments were examined using three different extraction agents. The aim of this study was to evaluate the applicability of single extraction procedures to investigate the bioavailability and mobility of major and trace elements (Al, As, Ba, Cd, Co, Cr, Cu, Fe, K, Li, Mg, Mn, Na, Ni, P, Pb, S, Si, Sr, Ti, V, and Zn) from river sediment. Two forms of studied elements were evaluated: mobile, the most toxic element form (extraction with 1 M CH3COONH4 and 0.01 M CaCl2) and potentially mobilized form (2 M HNO3 extraction). The estimation of the ecological risk, with the application of the probability distribution of RI (potential ecological risk index) values, is yielded with the help of the Monte Carlo simulation (MCS). Ammonium acetate is proved to be a better extraction agent than calcium chloride. A positive correlation between the content of all extracted elements with nitric acid and the total element content indicates that 2 M HNO3 efficiently extracts all studied elements. Results showed anthropogenic sources of cadmium and copper and high barium mobility. The MCS suggests that risk of Cr, Cu, Ni, Pb, and Zn was low; As and Cd posed a lower and median ecological risk in the studied areas.
T2  - Water
T1  - Evaluation of Element Mobility in River Sediment Using Different Single Extraction Procedures and Assessment of Probabilistic Ecological Risk
VL  - 13
IS  - 10
SP  - 1411
DO  - 10.3390/w13101411
ER  - 
@article{
author = "Sakan, Sanja M. and Frančišković-Bilinski, Stanislav and Đorđević, Dragana S. and Popović, Aleksandar R. and Sakan, Nenad and Škrivanj, Sandra B. and Bilinski, Halka",
year = "2021",
abstract = "In this manuscript, samples of Kupa River sediments were examined using three different extraction agents. The aim of this study was to evaluate the applicability of single extraction procedures to investigate the bioavailability and mobility of major and trace elements (Al, As, Ba, Cd, Co, Cr, Cu, Fe, K, Li, Mg, Mn, Na, Ni, P, Pb, S, Si, Sr, Ti, V, and Zn) from river sediment. Two forms of studied elements were evaluated: mobile, the most toxic element form (extraction with 1 M CH3COONH4 and 0.01 M CaCl2) and potentially mobilized form (2 M HNO3 extraction). The estimation of the ecological risk, with the application of the probability distribution of RI (potential ecological risk index) values, is yielded with the help of the Monte Carlo simulation (MCS). Ammonium acetate is proved to be a better extraction agent than calcium chloride. A positive correlation between the content of all extracted elements with nitric acid and the total element content indicates that 2 M HNO3 efficiently extracts all studied elements. Results showed anthropogenic sources of cadmium and copper and high barium mobility. The MCS suggests that risk of Cr, Cu, Ni, Pb, and Zn was low; As and Cd posed a lower and median ecological risk in the studied areas.",
journal = "Water",
title = "Evaluation of Element Mobility in River Sediment Using Different Single Extraction Procedures and Assessment of Probabilistic Ecological Risk",
volume = "13",
number = "10",
pages = "1411",
doi = "10.3390/w13101411"
}
Sakan, S. M., Frančišković-Bilinski, S., Đorđević, D. S., Popović, A. R., Sakan, N., Škrivanj, S. B.,& Bilinski, H.. (2021). Evaluation of Element Mobility in River Sediment Using Different Single Extraction Procedures and Assessment of Probabilistic Ecological Risk. in Water, 13(10), 1411.
https://doi.org/10.3390/w13101411
Sakan SM, Frančišković-Bilinski S, Đorđević DS, Popović AR, Sakan N, Škrivanj SB, Bilinski H. Evaluation of Element Mobility in River Sediment Using Different Single Extraction Procedures and Assessment of Probabilistic Ecological Risk. in Water. 2021;13(10):1411.
doi:10.3390/w13101411 .
Sakan, Sanja M., Frančišković-Bilinski, Stanislav, Đorđević, Dragana S., Popović, Aleksandar R., Sakan, Nenad, Škrivanj, Sandra B., Bilinski, Halka, "Evaluation of Element Mobility in River Sediment Using Different Single Extraction Procedures and Assessment of Probabilistic Ecological Risk" in Water, 13, no. 10 (2021):1411,
https://doi.org/10.3390/w13101411 . .

Supplementary data for the article: Sakan, S.; Frančišković-Bilinski, S.; Đorđević, D.; Popović, A.; Sakan, N.; Škrivanj, S.; Bilinski, H. Evaluation of Element Mobility in River Sediment Using Different Single Extraction Procedures and Assessment of Probabilistic Ecological Risk. Water 2021, 13 (10), 1411. https://doi.org/10.3390/w13101411.

Sakan, Sanja M.; Frančišković-Bilinski, Stanislav; Đorđević, Dragana S.; Popović, Aleksandar R.; Sakan, Nenad; Škrivanj, Sandra B.; Bilinski, Halka

(2021)

TY  - DATA
AU  - Sakan, Sanja M.
AU  - Frančišković-Bilinski, Stanislav
AU  - Đorđević, Dragana S.
AU  - Popović, Aleksandar R.
AU  - Sakan, Nenad
AU  - Škrivanj, Sandra B.
AU  - Bilinski, Halka
PY  - 2021
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/4547
T2  - Water
T1  - Supplementary data for the article: Sakan, S.; Frančišković-Bilinski, S.; Đorđević, D.; Popović, A.; Sakan, N.; Škrivanj, S.; Bilinski, H. Evaluation of Element Mobility in River Sediment Using Different Single Extraction Procedures and Assessment of Probabilistic Ecological Risk. Water 2021, 13 (10), 1411. https://doi.org/10.3390/w13101411.
UR  - https://hdl.handle.net/21.15107/rcub_cherry_4547
ER  - 
@misc{
author = "Sakan, Sanja M. and Frančišković-Bilinski, Stanislav and Đorđević, Dragana S. and Popović, Aleksandar R. and Sakan, Nenad and Škrivanj, Sandra B. and Bilinski, Halka",
year = "2021",
journal = "Water",
title = "Supplementary data for the article: Sakan, S.; Frančišković-Bilinski, S.; Đorđević, D.; Popović, A.; Sakan, N.; Škrivanj, S.; Bilinski, H. Evaluation of Element Mobility in River Sediment Using Different Single Extraction Procedures and Assessment of Probabilistic Ecological Risk. Water 2021, 13 (10), 1411. https://doi.org/10.3390/w13101411.",
url = "https://hdl.handle.net/21.15107/rcub_cherry_4547"
}
Sakan, S. M., Frančišković-Bilinski, S., Đorđević, D. S., Popović, A. R., Sakan, N., Škrivanj, S. B.,& Bilinski, H.. (2021). Supplementary data for the article: Sakan, S.; Frančišković-Bilinski, S.; Đorđević, D.; Popović, A.; Sakan, N.; Škrivanj, S.; Bilinski, H. Evaluation of Element Mobility in River Sediment Using Different Single Extraction Procedures and Assessment of Probabilistic Ecological Risk. Water 2021, 13 (10), 1411. https://doi.org/10.3390/w13101411.. in Water.
https://hdl.handle.net/21.15107/rcub_cherry_4547
Sakan SM, Frančišković-Bilinski S, Đorđević DS, Popović AR, Sakan N, Škrivanj SB, Bilinski H. Supplementary data for the article: Sakan, S.; Frančišković-Bilinski, S.; Đorđević, D.; Popović, A.; Sakan, N.; Škrivanj, S.; Bilinski, H. Evaluation of Element Mobility in River Sediment Using Different Single Extraction Procedures and Assessment of Probabilistic Ecological Risk. Water 2021, 13 (10), 1411. https://doi.org/10.3390/w13101411.. in Water. 2021;.
https://hdl.handle.net/21.15107/rcub_cherry_4547 .
Sakan, Sanja M., Frančišković-Bilinski, Stanislav, Đorđević, Dragana S., Popović, Aleksandar R., Sakan, Nenad, Škrivanj, Sandra B., Bilinski, Halka, "Supplementary data for the article: Sakan, S.; Frančišković-Bilinski, S.; Đorđević, D.; Popović, A.; Sakan, N.; Škrivanj, S.; Bilinski, H. Evaluation of Element Mobility in River Sediment Using Different Single Extraction Procedures and Assessment of Probabilistic Ecological Risk. Water 2021, 13 (10), 1411. https://doi.org/10.3390/w13101411." in Water (2021),
https://hdl.handle.net/21.15107/rcub_cherry_4547 .

Fatty acids, persistent organic pollutants, and trace elements in small pelagic fish from the eastern Mediterranean Sea

Herceg Romanić, Snježana; Jovanović, Gordana; Mustać, Bosiljka; Stojanović-Đinović, Jasna; Stojić, Andreja; Čadež, Tena; Popović, Aleksandar R.

(Elsevier, 2021)

TY  - JOUR
AU  - Herceg Romanić, Snježana
AU  - Jovanović, Gordana
AU  - Mustać, Bosiljka
AU  - Stojanović-Đinović, Jasna
AU  - Stojić, Andreja
AU  - Čadež, Tena
AU  - Popović, Aleksandar R.
PY  - 2021
UR  - https://www.sciencedirect.com/science/article/pii/S0025326X21006883
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/4593
AB  - Fatty acids (FAs) composition, 24 persistent organic pollutants (POPs), and 16 trace elements were examined in small pelagic fish (sardine, anchovy, round sardinella, chub and horse mackerels) caught by a fishing fleet for more than three years in the eastern Mediterranean Sea. Five Unmix source profiles associated with both sources, such as overlapping diet, including low-niche marine organisms and inputs from the surrounding environmental compartments were resolved. Inorganic compounds were notably more abundant in fish tissue than organochlorine xenobiotics. Comparison with the values of toxicological parameters revealed that the examined fish species are safe for human consumption, while the content of FAs emphasized the studied species as a valuable source of nutrients. A significant linear correlation was not observed between the 18 FAs and lipophilic organochlorines. Based on the obtained database, future assessments of the quality of edible fish species and the aquatic environment of the eastern Mediterranean Sea, which is known as an important fishing ground, could be significantly improved.
PB  - Elsevier
T2  - Marine Pollution Bulletin
T2  - Marine Pollution BulletinMarine Pollution Bulletin
T1  - Fatty acids, persistent organic pollutants, and trace elements in small pelagic fish from the eastern Mediterranean Sea
VL  - 170
SP  - 112654
DO  - 10.1016/j.marpolbul.2021.112654
ER  - 
@article{
author = "Herceg Romanić, Snježana and Jovanović, Gordana and Mustać, Bosiljka and Stojanović-Đinović, Jasna and Stojić, Andreja and Čadež, Tena and Popović, Aleksandar R.",
year = "2021",
abstract = "Fatty acids (FAs) composition, 24 persistent organic pollutants (POPs), and 16 trace elements were examined in small pelagic fish (sardine, anchovy, round sardinella, chub and horse mackerels) caught by a fishing fleet for more than three years in the eastern Mediterranean Sea. Five Unmix source profiles associated with both sources, such as overlapping diet, including low-niche marine organisms and inputs from the surrounding environmental compartments were resolved. Inorganic compounds were notably more abundant in fish tissue than organochlorine xenobiotics. Comparison with the values of toxicological parameters revealed that the examined fish species are safe for human consumption, while the content of FAs emphasized the studied species as a valuable source of nutrients. A significant linear correlation was not observed between the 18 FAs and lipophilic organochlorines. Based on the obtained database, future assessments of the quality of edible fish species and the aquatic environment of the eastern Mediterranean Sea, which is known as an important fishing ground, could be significantly improved.",
publisher = "Elsevier",
journal = "Marine Pollution Bulletin, Marine Pollution BulletinMarine Pollution Bulletin",
title = "Fatty acids, persistent organic pollutants, and trace elements in small pelagic fish from the eastern Mediterranean Sea",
volume = "170",
pages = "112654",
doi = "10.1016/j.marpolbul.2021.112654"
}
Herceg Romanić, S., Jovanović, G., Mustać, B., Stojanović-Đinović, J., Stojić, A., Čadež, T.,& Popović, A. R.. (2021). Fatty acids, persistent organic pollutants, and trace elements in small pelagic fish from the eastern Mediterranean Sea. in Marine Pollution Bulletin
Elsevier., 170, 112654.
https://doi.org/10.1016/j.marpolbul.2021.112654
Herceg Romanić S, Jovanović G, Mustać B, Stojanović-Đinović J, Stojić A, Čadež T, Popović AR. Fatty acids, persistent organic pollutants, and trace elements in small pelagic fish from the eastern Mediterranean Sea. in Marine Pollution Bulletin. 2021;170:112654.
doi:10.1016/j.marpolbul.2021.112654 .
Herceg Romanić, Snježana, Jovanović, Gordana, Mustać, Bosiljka, Stojanović-Đinović, Jasna, Stojić, Andreja, Čadež, Tena, Popović, Aleksandar R., "Fatty acids, persistent organic pollutants, and trace elements in small pelagic fish from the eastern Mediterranean Sea" in Marine Pollution Bulletin, 170 (2021):112654,
https://doi.org/10.1016/j.marpolbul.2021.112654 . .
1
4
1
4

Supplementary data for the article: Herceg Romanić, S.; Jovanović, G.; Mustać, B.; Stojanović-Đinović, J.; Stojić, A.; Čadež, T.; Popović, A. Fatty Acids, Persistent Organic Pollutants, and Trace Elements in Small Pelagic Fish from the Eastern Mediterranean Sea. Marine Pollution Bulletin 2021, 170, 112654. https://doi.org/10.1016/j.marpolbul.2021.112654.

Herceg Romanić, Snježana; Jovanović, Gordana; Mustać, Bosiljka; Stojanović-Đinović, Jasna; Stojić, Andreja; Čadež, Tena; Popović, Aleksandar R.

(Elsevier, 2021)

TY  - DATA
AU  - Herceg Romanić, Snježana
AU  - Jovanović, Gordana
AU  - Mustać, Bosiljka
AU  - Stojanović-Đinović, Jasna
AU  - Stojić, Andreja
AU  - Čadež, Tena
AU  - Popović, Aleksandar R.
PY  - 2021
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/4594
PB  - Elsevier
T2  - Marine Pollution Bulletin
T1  - Supplementary data for the article: Herceg Romanić, S.; Jovanović, G.; Mustać, B.; Stojanović-Đinović, J.; Stojić, A.; Čadež, T.; Popović, A. Fatty Acids, Persistent Organic Pollutants, and Trace Elements in Small Pelagic Fish from the Eastern Mediterranean Sea. Marine Pollution Bulletin 2021, 170, 112654. https://doi.org/10.1016/j.marpolbul.2021.112654.
UR  - https://hdl.handle.net/21.15107/rcub_cherry_4594
ER  - 
@misc{
author = "Herceg Romanić, Snježana and Jovanović, Gordana and Mustać, Bosiljka and Stojanović-Đinović, Jasna and Stojić, Andreja and Čadež, Tena and Popović, Aleksandar R.",
year = "2021",
publisher = "Elsevier",
journal = "Marine Pollution Bulletin",
title = "Supplementary data for the article: Herceg Romanić, S.; Jovanović, G.; Mustać, B.; Stojanović-Đinović, J.; Stojić, A.; Čadež, T.; Popović, A. Fatty Acids, Persistent Organic Pollutants, and Trace Elements in Small Pelagic Fish from the Eastern Mediterranean Sea. Marine Pollution Bulletin 2021, 170, 112654. https://doi.org/10.1016/j.marpolbul.2021.112654.",
url = "https://hdl.handle.net/21.15107/rcub_cherry_4594"
}
Herceg Romanić, S., Jovanović, G., Mustać, B., Stojanović-Đinović, J., Stojić, A., Čadež, T.,& Popović, A. R.. (2021). Supplementary data for the article: Herceg Romanić, S.; Jovanović, G.; Mustać, B.; Stojanović-Đinović, J.; Stojić, A.; Čadež, T.; Popović, A. Fatty Acids, Persistent Organic Pollutants, and Trace Elements in Small Pelagic Fish from the Eastern Mediterranean Sea. Marine Pollution Bulletin 2021, 170, 112654. https://doi.org/10.1016/j.marpolbul.2021.112654.. in Marine Pollution Bulletin
Elsevier..
https://hdl.handle.net/21.15107/rcub_cherry_4594
Herceg Romanić S, Jovanović G, Mustać B, Stojanović-Đinović J, Stojić A, Čadež T, Popović AR. Supplementary data for the article: Herceg Romanić, S.; Jovanović, G.; Mustać, B.; Stojanović-Đinović, J.; Stojić, A.; Čadež, T.; Popović, A. Fatty Acids, Persistent Organic Pollutants, and Trace Elements in Small Pelagic Fish from the Eastern Mediterranean Sea. Marine Pollution Bulletin 2021, 170, 112654. https://doi.org/10.1016/j.marpolbul.2021.112654.. in Marine Pollution Bulletin. 2021;.
https://hdl.handle.net/21.15107/rcub_cherry_4594 .
Herceg Romanić, Snježana, Jovanović, Gordana, Mustać, Bosiljka, Stojanović-Đinović, Jasna, Stojić, Andreja, Čadež, Tena, Popović, Aleksandar R., "Supplementary data for the article: Herceg Romanić, S.; Jovanović, G.; Mustać, B.; Stojanović-Đinović, J.; Stojić, A.; Čadež, T.; Popović, A. Fatty Acids, Persistent Organic Pollutants, and Trace Elements in Small Pelagic Fish from the Eastern Mediterranean Sea. Marine Pollution Bulletin 2021, 170, 112654. https://doi.org/10.1016/j.marpolbul.2021.112654." in Marine Pollution Bulletin (2021),
https://hdl.handle.net/21.15107/rcub_cherry_4594 .

Patterns of PCB-138 Occurrence in the Breast Milk of Primiparae and Multiparae Using SHapley Additive exPlanations Analysis

Jovanović, Gordana; Matek Sarić, Marijana; Herceg Romanić, Snježana; Stanišić, Svetlana M.; Mitrović Dankulov, Marija; Popović, Aleksandar R.; Perišić, Mirjana; Pap, Endre

(Springer International Publishing, 2021)

TY  - CHAP
AU  - Jovanović, Gordana
AU  - Matek Sarić, Marijana
AU  - Herceg Romanić, Snježana
AU  - Stanišić, Svetlana M.
AU  - Mitrović Dankulov, Marija
AU  - Popović, Aleksandar R.
AU  - Perišić, Mirjana
AU  - Pap, Endre
PY  - 2021
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/4743
AB  - Breastfeeding provides numerous health benefits for newborns by meeting infants’ nutritional needs and supporting associated immunological protection. Maternal milk is high in fat, and therefore, represents a very suitable medium for the bioaccumulation of lipophilic pollutants, such as organochlorine pesticides (OCPs) and polychlorinated biphenyls (PCBs). This makes breast milk the infant’s primary source of postnatal exposure to persistent toxic xenobiotics. In this study, we applied a novel SHapley Additive exPlanations (SHAP) method to examine the key parameters that govern the distribution of PCB-138, an indicator of non-dioxin congeners, in the mother’s milk. According to the accuracy metrics, the eXtreme Gradient Boosting regression was employed successfully, with a predicted/observed relative error below 20% and a high correlation coefficient (r === 0.97), for modeling the relationships between PCB-138 and other non-dioxin congeners, the mother’s age, and the number of births. According to the results, PCB-156, PCB-180, HCB, HCH and PCB-118 have a major impact, while PCB-28, PCB-52 and PCB-189 have a minor impact on PCB-138 distribution in breast milk. Similar contaminant behaviors, which belong to both the indicator congener group (−28, −52, −180) and the toxicologically relevant PCBs (−118, −189), were also noted. The SHAP conclusions were only partially consistent with the results of the correlation analysis suggesting that POPs exhibit non-linear dynamics and interrelations. Therefore, current knowledge on the contamination of complex biomatrices would benefit from further detailed analyses of pollutant intermittent relationships.
PB  - Springer International Publishing
T2  - Artificial Intelligence: Theory and Applications
T1  - Patterns of PCB-138 Occurrence in the Breast Milk of Primiparae and Multiparae Using SHapley Additive exPlanations Analysis
SP  - 191
EP  - 206
DO  - 10.1007/978-3-030-72711-6_11
ER  - 
@inbook{
author = "Jovanović, Gordana and Matek Sarić, Marijana and Herceg Romanić, Snježana and Stanišić, Svetlana M. and Mitrović Dankulov, Marija and Popović, Aleksandar R. and Perišić, Mirjana and Pap, Endre",
year = "2021",
abstract = "Breastfeeding provides numerous health benefits for newborns by meeting infants’ nutritional needs and supporting associated immunological protection. Maternal milk is high in fat, and therefore, represents a very suitable medium for the bioaccumulation of lipophilic pollutants, such as organochlorine pesticides (OCPs) and polychlorinated biphenyls (PCBs). This makes breast milk the infant’s primary source of postnatal exposure to persistent toxic xenobiotics. In this study, we applied a novel SHapley Additive exPlanations (SHAP) method to examine the key parameters that govern the distribution of PCB-138, an indicator of non-dioxin congeners, in the mother’s milk. According to the accuracy metrics, the eXtreme Gradient Boosting regression was employed successfully, with a predicted/observed relative error below 20% and a high correlation coefficient (r === 0.97), for modeling the relationships between PCB-138 and other non-dioxin congeners, the mother’s age, and the number of births. According to the results, PCB-156, PCB-180, HCB, HCH and PCB-118 have a major impact, while PCB-28, PCB-52 and PCB-189 have a minor impact on PCB-138 distribution in breast milk. Similar contaminant behaviors, which belong to both the indicator congener group (−28, −52, −180) and the toxicologically relevant PCBs (−118, −189), were also noted. The SHAP conclusions were only partially consistent with the results of the correlation analysis suggesting that POPs exhibit non-linear dynamics and interrelations. Therefore, current knowledge on the contamination of complex biomatrices would benefit from further detailed analyses of pollutant intermittent relationships.",
publisher = "Springer International Publishing",
journal = "Artificial Intelligence: Theory and Applications",
booktitle = "Patterns of PCB-138 Occurrence in the Breast Milk of Primiparae and Multiparae Using SHapley Additive exPlanations Analysis",
pages = "191-206",
doi = "10.1007/978-3-030-72711-6_11"
}
Jovanović, G., Matek Sarić, M., Herceg Romanić, S., Stanišić, S. M., Mitrović Dankulov, M., Popović, A. R., Perišić, M.,& Pap, E.. (2021). Patterns of PCB-138 Occurrence in the Breast Milk of Primiparae and Multiparae Using SHapley Additive exPlanations Analysis. in Artificial Intelligence: Theory and Applications
Springer International Publishing., 191-206.
https://doi.org/10.1007/978-3-030-72711-6_11
Jovanović G, Matek Sarić M, Herceg Romanić S, Stanišić SM, Mitrović Dankulov M, Popović AR, Perišić M, Pap E. Patterns of PCB-138 Occurrence in the Breast Milk of Primiparae and Multiparae Using SHapley Additive exPlanations Analysis. in Artificial Intelligence: Theory and Applications. 2021;:191-206.
doi:10.1007/978-3-030-72711-6_11 .
Jovanović, Gordana, Matek Sarić, Marijana, Herceg Romanić, Snježana, Stanišić, Svetlana M., Mitrović Dankulov, Marija, Popović, Aleksandar R., Perišić, Mirjana, Pap, Endre, "Patterns of PCB-138 Occurrence in the Breast Milk of Primiparae and Multiparae Using SHapley Additive exPlanations Analysis" in Artificial Intelligence: Theory and Applications (2021):191-206,
https://doi.org/10.1007/978-3-030-72711-6_11 . .

Comparative Study of Removal Efficiency for Ni and Cd from Industrial Wastewater and Aqueous Solution by Sunflower Husk Using ICP-OES and LIBS

Radenković, M.; Petrović, J.; Momčilović, M.; Živković, S.; Relić, Dubravka; Popović, Aleksandar R.

(Belgrade : Serbian Chemical Society, 2021)

TY  - CONF
AU  - Radenković, M.
AU  - Petrović, J.
AU  - Momčilović, M.
AU  - Živković, S.
AU  - Relić, Dubravka
AU  - Popović, Aleksandar R.
PY  - 2021
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/4914
AB  - With the growth of the industrial world and the rise of anthropogenic activities, environmental challenges have also increased. Wastewater, especially from industrial sources can contain a wide variety of heavy metals [1]. The presence of heavy metals in water resources is a cause for concern due to their toxicity and tendency to bioaccumulation, which leads to significant problems for the environment as well as for animals and humans [2]. There are various conventional treatment technologies that are used for the removal of heavy metals from wastewater such as reverse osmosis, electrodialysis, ultrafiltration, industrial ion exchange process, and chemical precipitation. These techniques have some drawbacks such a being expensive due to high reagent and energy requirements, incomplete metal removal at low concentrations of heavy metals and generation of sludge [1]. Therefore, biosorption has been the subject of research by scientists for almost 70 years in order to find efficient, effective, and low-cost biomaterials for wastewater treatment [3]. In this study, a sunflower husk treated with 1% hydrochloric acid was used to evaluate removal efficiency for Ni from real wastewater samples, as well as to estimate the adsorption capacity as a function of contact time between the heavy metal ions such as Cd in the aqueous solution and the sunflower husk as a biosorbent. Two techniques were used for quantitative analysis, Inductively Coupled Plasma Optical Emission Spectrometry (ICP-OES) as a standard reference method and laser-induced plasma spectroscopy (LIBS) as an innovative non-standard analytical method. What makes the LIBS superior from the other standard optical techniques is that it allows fast multi-elemental analysis without prior sample preparation, leads to minimal sample damage, and is considered almost non-destructive, this method is also by the principles of green analytical chemistry, which means that it does not use toxic reagents and therefore no chemical waste [4]. The results of these two methods were compared, to examine the possibility of using laser-induced plasma spectroscopy as an alternative green analytical technology for quantitative analysis of sunflower husk as a biosorbent and evaluation of biosorption efficiency as a function of contact time.
PB  - Belgrade : Serbian Chemical Society
C3  - Book of Abstracts 21st; European Meeting on Environmental Chemistry
T1  - Comparative Study of Removal Efficiency for Ni and Cd from Industrial Wastewater and Aqueous Solution by Sunflower Husk Using ICP-OES and LIBS
SP  - 100
EP  - 100
UR  - https://hdl.handle.net/21.15107/rcub_cherry_4914
ER  - 
@conference{
author = "Radenković, M. and Petrović, J. and Momčilović, M. and Živković, S. and Relić, Dubravka and Popović, Aleksandar R.",
year = "2021",
abstract = "With the growth of the industrial world and the rise of anthropogenic activities, environmental challenges have also increased. Wastewater, especially from industrial sources can contain a wide variety of heavy metals [1]. The presence of heavy metals in water resources is a cause for concern due to their toxicity and tendency to bioaccumulation, which leads to significant problems for the environment as well as for animals and humans [2]. There are various conventional treatment technologies that are used for the removal of heavy metals from wastewater such as reverse osmosis, electrodialysis, ultrafiltration, industrial ion exchange process, and chemical precipitation. These techniques have some drawbacks such a being expensive due to high reagent and energy requirements, incomplete metal removal at low concentrations of heavy metals and generation of sludge [1]. Therefore, biosorption has been the subject of research by scientists for almost 70 years in order to find efficient, effective, and low-cost biomaterials for wastewater treatment [3]. In this study, a sunflower husk treated with 1% hydrochloric acid was used to evaluate removal efficiency for Ni from real wastewater samples, as well as to estimate the adsorption capacity as a function of contact time between the heavy metal ions such as Cd in the aqueous solution and the sunflower husk as a biosorbent. Two techniques were used for quantitative analysis, Inductively Coupled Plasma Optical Emission Spectrometry (ICP-OES) as a standard reference method and laser-induced plasma spectroscopy (LIBS) as an innovative non-standard analytical method. What makes the LIBS superior from the other standard optical techniques is that it allows fast multi-elemental analysis without prior sample preparation, leads to minimal sample damage, and is considered almost non-destructive, this method is also by the principles of green analytical chemistry, which means that it does not use toxic reagents and therefore no chemical waste [4]. The results of these two methods were compared, to examine the possibility of using laser-induced plasma spectroscopy as an alternative green analytical technology for quantitative analysis of sunflower husk as a biosorbent and evaluation of biosorption efficiency as a function of contact time.",
publisher = "Belgrade : Serbian Chemical Society",
journal = "Book of Abstracts 21st; European Meeting on Environmental Chemistry",
title = "Comparative Study of Removal Efficiency for Ni and Cd from Industrial Wastewater and Aqueous Solution by Sunflower Husk Using ICP-OES and LIBS",
pages = "100-100",
url = "https://hdl.handle.net/21.15107/rcub_cherry_4914"
}
Radenković, M., Petrović, J., Momčilović, M., Živković, S., Relić, D.,& Popović, A. R.. (2021). Comparative Study of Removal Efficiency for Ni and Cd from Industrial Wastewater and Aqueous Solution by Sunflower Husk Using ICP-OES and LIBS. in Book of Abstracts 21st; European Meeting on Environmental Chemistry
Belgrade : Serbian Chemical Society., 100-100.
https://hdl.handle.net/21.15107/rcub_cherry_4914
Radenković M, Petrović J, Momčilović M, Živković S, Relić D, Popović AR. Comparative Study of Removal Efficiency for Ni and Cd from Industrial Wastewater and Aqueous Solution by Sunflower Husk Using ICP-OES and LIBS. in Book of Abstracts 21st; European Meeting on Environmental Chemistry. 2021;:100-100.
https://hdl.handle.net/21.15107/rcub_cherry_4914 .
Radenković, M., Petrović, J., Momčilović, M., Živković, S., Relić, Dubravka, Popović, Aleksandar R., "Comparative Study of Removal Efficiency for Ni and Cd from Industrial Wastewater and Aqueous Solution by Sunflower Husk Using ICP-OES and LIBS" in Book of Abstracts 21st; European Meeting on Environmental Chemistry (2021):100-100,
https://hdl.handle.net/21.15107/rcub_cherry_4914 .

Health Risk Assessment for Residents and Workers Based on Toxic and Carcinogenic Element Content from PM2.5 in Belgrade Suburban Area

Mutavdžić, D.; Aničić Urošević, M.; Kuzmanoski, M.; Kodranov, I.; Popović, Aleksandar R.; Relić, Dubravka

(Belgrade : Serbian Chemical Society, 2021)

TY  - CONF
AU  - Mutavdžić, D.
AU  - Aničić Urošević, M.
AU  - Kuzmanoski, M.
AU  - Kodranov, I.
AU  - Popović, Aleksandar R.
AU  - Relić, Dubravka
PY  - 2021
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/4921
AB  - Particulate matter of diametar <2.5 µm (PM2.5) pollution is recognized as one of primary pollution contaminant which directly affect human health. Toxic and carcinogenic elements originating from different pollution sources can be constituents of PM2.5. Because of their small size, particles can penetrate deeper into the lungs and enter the bloodstream causing different disorders and threats to human health [1]. We performed elemental characterization of PM2.5 samples collected during the spring/summer season 2019 in a suburban part of Belgrade (in the inner courtyard of Institute of Physics Belgrade). The spring/ summer period was characterized by the industrial or different outdoor activities with several Saharan dust episodes. In addition, April and October were partly characterized by heating sources. The quartz filters with PM2.5 were digested by the microwave digestion system using 7 mL 65% HNO3 and 1 mL 30% H2 O2 . The concentrations of Al, B, Ba, Bi, Ca, K, Fe, Mn, Ni, P, S and Sr were measured using inductively coupled plasma-optical emission spectrometry (ICP-OES), while concentrations of Ag, As, Be, Cd, Co, Cu, Cr, Hg, Pb, Se, Sb and Tl were measured using inductively coupled plasma mass spectrometry (ICP-MS). The non-carcinogenic and carcinogenic risks for residents and for five different types of workers (outdoor, indoor, composite, construction and excavation workers) in this ambient were assessed by equations provided by The Risk Assessment Information System – RAIS [2]. Comparing the investigated scenarios, the highest non-carcinogenic and carcinogenic risks were observed for the residents. There were observed non-carcinogenic (HI>1) and carcinogenic (R≥1×10-5) risks for the residents from this area. The residents spent the most of their time in this ambient and they are most at the risk caused by the measured PM2.5 pollution (HImedian: 2.28; Rmedian: 1.25 × 10-4). Observing the scenarios for workers, the risk mostly depends on the time that workers spent outside during working hours. Similar non-carcinogenic risks were observed for outdoor, indoor and composite workers, slightly higher risk was observed for construction workers, while the lowest risk was obtained for an excavation worker who is less exposed to the PM2.5 atmospheric deposition than soil dust resuspension. The same was observed for the carcinogenic risk, while the similar risks were observed for all workers. Only for an excavation worker, the carcinogenic risk was significantly lower than for other workers. The most significant contributor to the non-carcinogenic risk in all scenarios was the concentration of Mn, and then the concentration of Be, while the most significant contributor to the carcinogenic risk was Cr6+. Observing the risks among the investigated period the highest non-carcinogenic and carcinogenic risks were observed in April and October based on the toxic and carcinogenic elements in PM2.5. In these months beside the influence of the industrial activities, dust episodes or activity of heating sorces possibly caused the increase of the toxic and carcinogenic elements in PM2.5.
PB  - Belgrade : Serbian Chemical Society
C3  - Book of Abstracts 21st; European Meeting on Environmental Chemistry
T1  - Health Risk Assessment for Residents and Workers Based on Toxic and Carcinogenic Element Content from PM2.5 in Belgrade Suburban Area
SP  - 134
EP  - 134
UR  - https://hdl.handle.net/21.15107/rcub_cherry_4921
ER  - 
@conference{
author = "Mutavdžić, D. and Aničić Urošević, M. and Kuzmanoski, M. and Kodranov, I. and Popović, Aleksandar R. and Relić, Dubravka",
year = "2021",
abstract = "Particulate matter of diametar <2.5 µm (PM2.5) pollution is recognized as one of primary pollution contaminant which directly affect human health. Toxic and carcinogenic elements originating from different pollution sources can be constituents of PM2.5. Because of their small size, particles can penetrate deeper into the lungs and enter the bloodstream causing different disorders and threats to human health [1]. We performed elemental characterization of PM2.5 samples collected during the spring/summer season 2019 in a suburban part of Belgrade (in the inner courtyard of Institute of Physics Belgrade). The spring/ summer period was characterized by the industrial or different outdoor activities with several Saharan dust episodes. In addition, April and October were partly characterized by heating sources. The quartz filters with PM2.5 were digested by the microwave digestion system using 7 mL 65% HNO3 and 1 mL 30% H2 O2 . The concentrations of Al, B, Ba, Bi, Ca, K, Fe, Mn, Ni, P, S and Sr were measured using inductively coupled plasma-optical emission spectrometry (ICP-OES), while concentrations of Ag, As, Be, Cd, Co, Cu, Cr, Hg, Pb, Se, Sb and Tl were measured using inductively coupled plasma mass spectrometry (ICP-MS). The non-carcinogenic and carcinogenic risks for residents and for five different types of workers (outdoor, indoor, composite, construction and excavation workers) in this ambient were assessed by equations provided by The Risk Assessment Information System – RAIS [2]. Comparing the investigated scenarios, the highest non-carcinogenic and carcinogenic risks were observed for the residents. There were observed non-carcinogenic (HI>1) and carcinogenic (R≥1×10-5) risks for the residents from this area. The residents spent the most of their time in this ambient and they are most at the risk caused by the measured PM2.5 pollution (HImedian: 2.28; Rmedian: 1.25 × 10-4). Observing the scenarios for workers, the risk mostly depends on the time that workers spent outside during working hours. Similar non-carcinogenic risks were observed for outdoor, indoor and composite workers, slightly higher risk was observed for construction workers, while the lowest risk was obtained for an excavation worker who is less exposed to the PM2.5 atmospheric deposition than soil dust resuspension. The same was observed for the carcinogenic risk, while the similar risks were observed for all workers. Only for an excavation worker, the carcinogenic risk was significantly lower than for other workers. The most significant contributor to the non-carcinogenic risk in all scenarios was the concentration of Mn, and then the concentration of Be, while the most significant contributor to the carcinogenic risk was Cr6+. Observing the risks among the investigated period the highest non-carcinogenic and carcinogenic risks were observed in April and October based on the toxic and carcinogenic elements in PM2.5. In these months beside the influence of the industrial activities, dust episodes or activity of heating sorces possibly caused the increase of the toxic and carcinogenic elements in PM2.5.",
publisher = "Belgrade : Serbian Chemical Society",
journal = "Book of Abstracts 21st; European Meeting on Environmental Chemistry",
title = "Health Risk Assessment for Residents and Workers Based on Toxic and Carcinogenic Element Content from PM2.5 in Belgrade Suburban Area",
pages = "134-134",
url = "https://hdl.handle.net/21.15107/rcub_cherry_4921"
}
Mutavdžić, D., Aničić Urošević, M., Kuzmanoski, M., Kodranov, I., Popović, A. R.,& Relić, D.. (2021). Health Risk Assessment for Residents and Workers Based on Toxic and Carcinogenic Element Content from PM2.5 in Belgrade Suburban Area. in Book of Abstracts 21st; European Meeting on Environmental Chemistry
Belgrade : Serbian Chemical Society., 134-134.
https://hdl.handle.net/21.15107/rcub_cherry_4921
Mutavdžić D, Aničić Urošević M, Kuzmanoski M, Kodranov I, Popović AR, Relić D. Health Risk Assessment for Residents and Workers Based on Toxic and Carcinogenic Element Content from PM2.5 in Belgrade Suburban Area. in Book of Abstracts 21st; European Meeting on Environmental Chemistry. 2021;:134-134.
https://hdl.handle.net/21.15107/rcub_cherry_4921 .
Mutavdžić, D., Aničić Urošević, M., Kuzmanoski, M., Kodranov, I., Popović, Aleksandar R., Relić, Dubravka, "Health Risk Assessment for Residents and Workers Based on Toxic and Carcinogenic Element Content from PM2.5 in Belgrade Suburban Area" in Book of Abstracts 21st; European Meeting on Environmental Chemistry (2021):134-134,
https://hdl.handle.net/21.15107/rcub_cherry_4921 .

Optimization of Gas Chromatography-Electron Ionization-Tandem Mass Spectrometry for Determining Toxic Non-ortho Polychlorinated Biphenyls in Breast Milk

Šimić, Iva; Jovanović, Gordana; Herceg Romanić, Snježana; Klinčić, Darija; Matek Sarić, Marijana; Popović, Aleksandar R.

(Chinese Center for Disease Control and Prevention, 2020)

TY  - JOUR
AU  - Šimić, Iva
AU  - Jovanović, Gordana
AU  - Herceg Romanić, Snježana
AU  - Klinčić, Darija
AU  - Matek Sarić, Marijana
AU  - Popović, Aleksandar R.
PY  - 2020
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5063
PB  - Chinese Center for Disease Control and Prevention
T2  - Biomedical and Environmental Sciences
T1  - Optimization of Gas Chromatography-Electron Ionization-Tandem Mass Spectrometry for Determining Toxic Non-ortho Polychlorinated Biphenyls in Breast Milk
VL  - 33
IS  - 1
SP  - 58
EP  - 61
DO  - 10.3967/bes2020.008
ER  - 
@article{
author = "Šimić, Iva and Jovanović, Gordana and Herceg Romanić, Snježana and Klinčić, Darija and Matek Sarić, Marijana and Popović, Aleksandar R.",
year = "2020",
publisher = "Chinese Center for Disease Control and Prevention",
journal = "Biomedical and Environmental Sciences",
title = "Optimization of Gas Chromatography-Electron Ionization-Tandem Mass Spectrometry for Determining Toxic Non-ortho Polychlorinated Biphenyls in Breast Milk",
volume = "33",
number = "1",
pages = "58-61",
doi = "10.3967/bes2020.008"
}
Šimić, I., Jovanović, G., Herceg Romanić, S., Klinčić, D., Matek Sarić, M.,& Popović, A. R.. (2020). Optimization of Gas Chromatography-Electron Ionization-Tandem Mass Spectrometry for Determining Toxic Non-ortho Polychlorinated Biphenyls in Breast Milk. in Biomedical and Environmental Sciences
Chinese Center for Disease Control and Prevention., 33(1), 58-61.
https://doi.org/10.3967/bes2020.008
Šimić I, Jovanović G, Herceg Romanić S, Klinčić D, Matek Sarić M, Popović AR. Optimization of Gas Chromatography-Electron Ionization-Tandem Mass Spectrometry for Determining Toxic Non-ortho Polychlorinated Biphenyls in Breast Milk. in Biomedical and Environmental Sciences. 2020;33(1):58-61.
doi:10.3967/bes2020.008 .
Šimić, Iva, Jovanović, Gordana, Herceg Romanić, Snježana, Klinčić, Darija, Matek Sarić, Marijana, Popović, Aleksandar R., "Optimization of Gas Chromatography-Electron Ionization-Tandem Mass Spectrometry for Determining Toxic Non-ortho Polychlorinated Biphenyls in Breast Milk" in Biomedical and Environmental Sciences, 33, no. 1 (2020):58-61,
https://doi.org/10.3967/bes2020.008 . .
1
1

The use of moss as an indicator of rare earth element deposition over large area

Urošević-Aničić, Mira; Krmar, Miodrag D.; Radnović, Dragan V.; Jovanović, Gordana; Jakšić, Tatjana R.; Vasić, Predrag S.; Popović, Aleksandar R.

(Elsevier, 2020)

TY  - JOUR
AU  - Urošević-Aničić, Mira
AU  - Krmar, Miodrag D.
AU  - Radnović, Dragan V.
AU  - Jovanović, Gordana
AU  - Jakšić, Tatjana R.
AU  - Vasić, Predrag S.
AU  - Popović, Aleksandar R.
PY  - 2020
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3766
AB  - Nowadays, rare earth elements (REEs) represent a group of emerging pollutants due to their growing application in industry and agriculture, hence, the environmental and human exposures undergone a steady spread. Since REEs can be a part of airborne particulate matter (PM), moss biomonitoring could be a tool for the assessment of their atmospheric deposition. In 2015, moss samples of Hypnum cupressiforme Hedw. were collected at 212 sites across Serbia, and 16 REEs, including Lanthanides (La to Lu), Sc and Y, were determined in the samples by inductively coupled plasma mass spectrometry (ICP-MS). The measured element concentrations were normalised according to different natural reference systems searching for the REE enrichment in the studied environmental samples, and their possible anomalies. The ratios of REEs, specified in the literature, were used to reveal the element origin. In this study, the order of REE abundance in the moss samples was similar to that found in other environmental compartments, which together with the obtained strong correlations among the elements imply their similar origin, probably geogenic. Nevertheless, the ratio La/Sm (5.1) entered the range that characterised coal combustion. In addition, the median enrichment factors (EFs) of the elements calculated according to typical crustal elements, Al and Sc, were not exceeded the value 5 which suggests slightly anthropogenic stake. However, high values of EF REEs (≈40) were obtained in the moss samples from certain regions of Serbia (south and northeast) characterised by the extensive exploitation of coal and mineral deposits, and their further manufacturing or combustion. The results of this study found that the moss is a sensitive tool reflecting the presence of REEs in atmospheric deposition even those in traces (Ho, Er, Tm, Yb, Lu).
PB  - Elsevier
T2  - Ecological Indicators
T1  - The use of moss as an indicator of rare earth element deposition over large area
VL  - 109
DO  - 10.1016/j.ecolind.2019.105828
ER  - 
@article{
author = "Urošević-Aničić, Mira and Krmar, Miodrag D. and Radnović, Dragan V. and Jovanović, Gordana and Jakšić, Tatjana R. and Vasić, Predrag S. and Popović, Aleksandar R.",
year = "2020",
abstract = "Nowadays, rare earth elements (REEs) represent a group of emerging pollutants due to their growing application in industry and agriculture, hence, the environmental and human exposures undergone a steady spread. Since REEs can be a part of airborne particulate matter (PM), moss biomonitoring could be a tool for the assessment of their atmospheric deposition. In 2015, moss samples of Hypnum cupressiforme Hedw. were collected at 212 sites across Serbia, and 16 REEs, including Lanthanides (La to Lu), Sc and Y, were determined in the samples by inductively coupled plasma mass spectrometry (ICP-MS). The measured element concentrations were normalised according to different natural reference systems searching for the REE enrichment in the studied environmental samples, and their possible anomalies. The ratios of REEs, specified in the literature, were used to reveal the element origin. In this study, the order of REE abundance in the moss samples was similar to that found in other environmental compartments, which together with the obtained strong correlations among the elements imply their similar origin, probably geogenic. Nevertheless, the ratio La/Sm (5.1) entered the range that characterised coal combustion. In addition, the median enrichment factors (EFs) of the elements calculated according to typical crustal elements, Al and Sc, were not exceeded the value 5 which suggests slightly anthropogenic stake. However, high values of EF REEs (≈40) were obtained in the moss samples from certain regions of Serbia (south and northeast) characterised by the extensive exploitation of coal and mineral deposits, and their further manufacturing or combustion. The results of this study found that the moss is a sensitive tool reflecting the presence of REEs in atmospheric deposition even those in traces (Ho, Er, Tm, Yb, Lu).",
publisher = "Elsevier",
journal = "Ecological Indicators",
title = "The use of moss as an indicator of rare earth element deposition over large area",
volume = "109",
doi = "10.1016/j.ecolind.2019.105828"
}
Urošević-Aničić, M., Krmar, M. D., Radnović, D. V., Jovanović, G., Jakšić, T. R., Vasić, P. S.,& Popović, A. R.. (2020). The use of moss as an indicator of rare earth element deposition over large area. in Ecological Indicators
Elsevier., 109.
https://doi.org/10.1016/j.ecolind.2019.105828
Urošević-Aničić M, Krmar MD, Radnović DV, Jovanović G, Jakšić TR, Vasić PS, Popović AR. The use of moss as an indicator of rare earth element deposition over large area. in Ecological Indicators. 2020;109.
doi:10.1016/j.ecolind.2019.105828 .
Urošević-Aničić, Mira, Krmar, Miodrag D., Radnović, Dragan V., Jovanović, Gordana, Jakšić, Tatjana R., Vasić, Predrag S., Popović, Aleksandar R., "The use of moss as an indicator of rare earth element deposition over large area" in Ecological Indicators, 109 (2020),
https://doi.org/10.1016/j.ecolind.2019.105828 . .
7
1
5

Geochemical Fractionation and Risk Assessment of Potentially Toxic Elements in Sediments from Kupa River, Croatia

Sakan, Sanja M.; Frančišković-Bilinski, Stanislav; Đorđević, Dragana S.; Popović, Aleksandar R.; Škrivanj, Sandra B.; Bilinski, Halka

(Multidisciplinary Digital Publishing Institute (MDPI), 2020)

TY  - JOUR
AU  - Sakan, Sanja M.
AU  - Frančišković-Bilinski, Stanislav
AU  - Đorđević, Dragana S.
AU  - Popović, Aleksandar R.
AU  - Škrivanj, Sandra B.
AU  - Bilinski, Halka
PY  - 2020
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/4038
AB  - This study investigated the quality of Kupa River sediment using sequential extraction, ecological risk, and contamination indexes (Risk assessment code, Index of geoaccumulation, Enrichment factor, Ecological risk factor, Ecological risk index), determination of magnetic susceptibility of sediments, and statistical methods. The BCR sequential extraction technique was used for evaluating various element-binding forms. Most of the elements were considered to be immobile due to the high availability in the residual fraction. Lead was present mainly in the reducible fraction, while more easily mobile and bioavailable forms were predominant for cadmium and barium. Sediment samples from the river catchment exhibited low ecological risk. The most toxic element, Cd, is the main contributor to the total potentially ecological risk. Increased values of contamination factors have been observed for Zn, Cr, and Ba in some localities. Results of the comparison of element contents in sediments in a 15-year period (2018 vs. 2003) indicated that the situation with toxic element content in sediments along Kupa River improved formost of its course. Unfortunately, on the lower course of the river, the situation has worsened. Using the example of Kupa River sediments, it was shown that the magnetic susceptibility method is excellent indetecting increased values of Cr.
PB  - Multidisciplinary Digital Publishing Institute (MDPI)
T2  - Water
T1  - Geochemical Fractionation and Risk Assessment of Potentially Toxic Elements in Sediments from Kupa River, Croatia
VL  - 12
IS  - 7
SP  - 2024
DO  - 10.3390/w12072024
ER  - 
@article{
author = "Sakan, Sanja M. and Frančišković-Bilinski, Stanislav and Đorđević, Dragana S. and Popović, Aleksandar R. and Škrivanj, Sandra B. and Bilinski, Halka",
year = "2020",
abstract = "This study investigated the quality of Kupa River sediment using sequential extraction, ecological risk, and contamination indexes (Risk assessment code, Index of geoaccumulation, Enrichment factor, Ecological risk factor, Ecological risk index), determination of magnetic susceptibility of sediments, and statistical methods. The BCR sequential extraction technique was used for evaluating various element-binding forms. Most of the elements were considered to be immobile due to the high availability in the residual fraction. Lead was present mainly in the reducible fraction, while more easily mobile and bioavailable forms were predominant for cadmium and barium. Sediment samples from the river catchment exhibited low ecological risk. The most toxic element, Cd, is the main contributor to the total potentially ecological risk. Increased values of contamination factors have been observed for Zn, Cr, and Ba in some localities. Results of the comparison of element contents in sediments in a 15-year period (2018 vs. 2003) indicated that the situation with toxic element content in sediments along Kupa River improved formost of its course. Unfortunately, on the lower course of the river, the situation has worsened. Using the example of Kupa River sediments, it was shown that the magnetic susceptibility method is excellent indetecting increased values of Cr.",
publisher = "Multidisciplinary Digital Publishing Institute (MDPI)",
journal = "Water",
title = "Geochemical Fractionation and Risk Assessment of Potentially Toxic Elements in Sediments from Kupa River, Croatia",
volume = "12",
number = "7",
pages = "2024",
doi = "10.3390/w12072024"
}
Sakan, S. M., Frančišković-Bilinski, S., Đorđević, D. S., Popović, A. R., Škrivanj, S. B.,& Bilinski, H.. (2020). Geochemical Fractionation and Risk Assessment of Potentially Toxic Elements in Sediments from Kupa River, Croatia. in Water
Multidisciplinary Digital Publishing Institute (MDPI)., 12(7), 2024.
https://doi.org/10.3390/w12072024
Sakan SM, Frančišković-Bilinski S, Đorđević DS, Popović AR, Škrivanj SB, Bilinski H. Geochemical Fractionation and Risk Assessment of Potentially Toxic Elements in Sediments from Kupa River, Croatia. in Water. 2020;12(7):2024.
doi:10.3390/w12072024 .
Sakan, Sanja M., Frančišković-Bilinski, Stanislav, Đorđević, Dragana S., Popović, Aleksandar R., Škrivanj, Sandra B., Bilinski, Halka, "Geochemical Fractionation and Risk Assessment of Potentially Toxic Elements in Sediments from Kupa River, Croatia" in Water, 12, no. 7 (2020):2024,
https://doi.org/10.3390/w12072024 . .
10
7
9

Theoretical Modeling of Sorption of Metal Ions on Amino-Functionalized Macroporous Copolymer in Aqueous Solution

Suručić, Ljiljana; Janjić, Goran V.; Rakić, Aleksandra A.; Nastasović, Aleksandra B.; Popović, Aleksandar R.; Milčić, Miloš K.; Onjia, Antonije

(Springer-Verlag GmbH, 2019)

TY  - JOUR
AU  - Suručić, Ljiljana
AU  - Janjić, Goran V.
AU  - Rakić, Aleksandra A.
AU  - Nastasović, Aleksandra B.
AU  - Popović, Aleksandar R.
AU  - Milčić, Miloš K.
AU  - Onjia, Antonije
PY  - 2019
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5059
AB  - With regard to the harmful effects of heavy metals on human health and the environment, the demand for synthesis and
investigation of macromolecules with large capacity of harmful substances sorption is ever greater. Quantum-chemical methods
may be applied in structural modeling, prediction, and characterization of such molecules and reactions. Sorption of metal ions
(Cu2+, Cd2+, Co2+, and Ni2+) to triethylenetetramine-functionalized copolymer poly(GMA-co-EGDMA)-teta was successfully
modeled by quantumchemical calculations, at the B3LYP//6–311++G**/lanl2dz level. Optimized structures of metal complexes
were used for calculation of real binding energy of metal ion within the complex (ΔEr). Solvent and hydrolyzation effects were
essential for obtaining the objective values. Solvent effect was included inΔEr by using the total solvation energy for reaction of
formation of tetaOH complex (ΔEs1, the first approach) or by using dehydration energy of free metal ion (ΔEs2, the second
approach). Experimental results were confirmed in our theoretical analyses (using the second approach).
PB  - Springer-Verlag GmbH
T2  - Journal of Molecular Modeling
T1  - Theoretical Modeling of Sorption of Metal Ions on Amino-Functionalized Macroporous Copolymer in Aqueous Solution
VL  - 25
SP  - 177
DO  - 10.1007/s00894-019-4053-0
ER  - 
@article{
author = "Suručić, Ljiljana and Janjić, Goran V. and Rakić, Aleksandra A. and Nastasović, Aleksandra B. and Popović, Aleksandar R. and Milčić, Miloš K. and Onjia, Antonije",
year = "2019",
abstract = "With regard to the harmful effects of heavy metals on human health and the environment, the demand for synthesis and
investigation of macromolecules with large capacity of harmful substances sorption is ever greater. Quantum-chemical methods
may be applied in structural modeling, prediction, and characterization of such molecules and reactions. Sorption of metal ions
(Cu2+, Cd2+, Co2+, and Ni2+) to triethylenetetramine-functionalized copolymer poly(GMA-co-EGDMA)-teta was successfully
modeled by quantumchemical calculations, at the B3LYP//6–311++G**/lanl2dz level. Optimized structures of metal complexes
were used for calculation of real binding energy of metal ion within the complex (ΔEr). Solvent and hydrolyzation effects were
essential for obtaining the objective values. Solvent effect was included inΔEr by using the total solvation energy for reaction of
formation of tetaOH complex (ΔEs1, the first approach) or by using dehydration energy of free metal ion (ΔEs2, the second
approach). Experimental results were confirmed in our theoretical analyses (using the second approach).",
publisher = "Springer-Verlag GmbH",
journal = "Journal of Molecular Modeling",
title = "Theoretical Modeling of Sorption of Metal Ions on Amino-Functionalized Macroporous Copolymer in Aqueous Solution",
volume = "25",
pages = "177",
doi = "10.1007/s00894-019-4053-0"
}
Suručić, L., Janjić, G. V., Rakić, A. A., Nastasović, A. B., Popović, A. R., Milčić, M. K.,& Onjia, A.. (2019). Theoretical Modeling of Sorption of Metal Ions on Amino-Functionalized Macroporous Copolymer in Aqueous Solution. in Journal of Molecular Modeling
Springer-Verlag GmbH., 25, 177.
https://doi.org/10.1007/s00894-019-4053-0
Suručić L, Janjić GV, Rakić AA, Nastasović AB, Popović AR, Milčić MK, Onjia A. Theoretical Modeling of Sorption of Metal Ions on Amino-Functionalized Macroporous Copolymer in Aqueous Solution. in Journal of Molecular Modeling. 2019;25:177.
doi:10.1007/s00894-019-4053-0 .
Suručić, Ljiljana, Janjić, Goran V., Rakić, Aleksandra A., Nastasović, Aleksandra B., Popović, Aleksandar R., Milčić, Miloš K., Onjia, Antonije, "Theoretical Modeling of Sorption of Metal Ions on Amino-Functionalized Macroporous Copolymer in Aqueous Solution" in Journal of Molecular Modeling, 25 (2019):177,
https://doi.org/10.1007/s00894-019-4053-0 . .
2
1
2

Comparative study of W(VI) and Cr(VI) oxyanions binding ability with magnetic polymer nanocomposite

Suručić, Ljiljana; Nastasović, Aleksandra; Rakić, Aleksandra A.; Onjia, Antonije E.; Popović, Aleksandar R.; Janjić, Goran V.

(Avestia Publishing, 2019)

TY  - CONF
AU  - Suručić, Ljiljana
AU  - Nastasović, Aleksandra
AU  - Rakić, Aleksandra A.
AU  - Onjia, Antonije E.
AU  - Popović, Aleksandar R.
AU  - Janjić, Goran V.
PY  - 2019
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3943
AB  - Magnetite particles are widely used as sorbents for removal of heavy metal ions, organic dyes, drug delivery, cell labelling, magnetic resonance imaging, sensing, etc. [1,2]. Also, the functionalization of polymer by specific ligands enables customizing these composites for specific applications. Magnetic crosslinked macroporous copolymer of glycidyl methacrylate, GMA, and ethylene glycol dimethacrylate, EGDMA, mPGME was synthesized by suspension copolymerisation of GMA and EGDMA, in the presence of inert component (mixture of cyclohexanol and aliphatic alcohol) [3] and magnetite nanoparticles coated with (3-aminopropyl)trimethoxysilane (APTMS) as silanization agent. The sample was additionally functionalized with diethylene triamine mPGME-deta. Magnetic amino-functionalized copolymer was fully characterized in terms of its structural and magnetic properties using: FTIR analysis, SEM/EDX, XRD and SQUID magnetometry. Synthesized magnetic macroporous copolymer mPGME-deta was tested as sorbent of W(VI) and Cr(VI) oxyanions from diluted aqueous solutions (Ci=25 ppm) in a batch system, under uncompetitive conditions, at room temperature (T=25 °C). The oxyanions concentrations in solution after 60 min of sorption, were determined by inductively coupled plasma atomic emission spectroscopy (ICP-AES). The maximal experimental values of oxyanions sorption capacities (Qmax μmol/g) were compared with theoretically values determined by theoretical modeling, using quantum-chemical methods: Density Functional Theory (DFT), statistic analysis of the crystal structure extracted from the Cambridge Structural Database (CSD) and by implicit solvation model (SMD). It was found that the process is spontaneous and exothermic, and that the active sites of magnetic copolymer sorbent are amino groups (of diethylenetriamine and APTMS) which forms electrostatic interactions with oxianions W(VI) and Cr(VI).
PB  - Avestia Publishing
C3  - 5th World Congress on Mechanical, Chemical, and Material Engineering, MCM 2019; Lisbon; Portugal; 15 August 2019 through 17 August 2019; Code 141318
T1  - Comparative study of W(VI) and Cr(VI) oxyanions binding ability with magnetic polymer nanocomposite
SP  - 125
DO  - 10.11159/iccpe19.125
ER  - 
@conference{
author = "Suručić, Ljiljana and Nastasović, Aleksandra and Rakić, Aleksandra A. and Onjia, Antonije E. and Popović, Aleksandar R. and Janjić, Goran V.",
year = "2019",
abstract = "Magnetite particles are widely used as sorbents for removal of heavy metal ions, organic dyes, drug delivery, cell labelling, magnetic resonance imaging, sensing, etc. [1,2]. Also, the functionalization of polymer by specific ligands enables customizing these composites for specific applications. Magnetic crosslinked macroporous copolymer of glycidyl methacrylate, GMA, and ethylene glycol dimethacrylate, EGDMA, mPGME was synthesized by suspension copolymerisation of GMA and EGDMA, in the presence of inert component (mixture of cyclohexanol and aliphatic alcohol) [3] and magnetite nanoparticles coated with (3-aminopropyl)trimethoxysilane (APTMS) as silanization agent. The sample was additionally functionalized with diethylene triamine mPGME-deta. Magnetic amino-functionalized copolymer was fully characterized in terms of its structural and magnetic properties using: FTIR analysis, SEM/EDX, XRD and SQUID magnetometry. Synthesized magnetic macroporous copolymer mPGME-deta was tested as sorbent of W(VI) and Cr(VI) oxyanions from diluted aqueous solutions (Ci=25 ppm) in a batch system, under uncompetitive conditions, at room temperature (T=25 °C). The oxyanions concentrations in solution after 60 min of sorption, were determined by inductively coupled plasma atomic emission spectroscopy (ICP-AES). The maximal experimental values of oxyanions sorption capacities (Qmax μmol/g) were compared with theoretically values determined by theoretical modeling, using quantum-chemical methods: Density Functional Theory (DFT), statistic analysis of the crystal structure extracted from the Cambridge Structural Database (CSD) and by implicit solvation model (SMD). It was found that the process is spontaneous and exothermic, and that the active sites of magnetic copolymer sorbent are amino groups (of diethylenetriamine and APTMS) which forms electrostatic interactions with oxianions W(VI) and Cr(VI).",
publisher = "Avestia Publishing",
journal = "5th World Congress on Mechanical, Chemical, and Material Engineering, MCM 2019; Lisbon; Portugal; 15 August 2019 through 17 August 2019; Code 141318",
title = "Comparative study of W(VI) and Cr(VI) oxyanions binding ability with magnetic polymer nanocomposite",
pages = "125",
doi = "10.11159/iccpe19.125"
}
Suručić, L., Nastasović, A., Rakić, A. A., Onjia, A. E., Popović, A. R.,& Janjić, G. V.. (2019). Comparative study of W(VI) and Cr(VI) oxyanions binding ability with magnetic polymer nanocomposite. in 5th World Congress on Mechanical, Chemical, and Material Engineering, MCM 2019; Lisbon; Portugal; 15 August 2019 through 17 August 2019; Code 141318
Avestia Publishing., 125.
https://doi.org/10.11159/iccpe19.125
Suručić L, Nastasović A, Rakić AA, Onjia AE, Popović AR, Janjić GV. Comparative study of W(VI) and Cr(VI) oxyanions binding ability with magnetic polymer nanocomposite. in 5th World Congress on Mechanical, Chemical, and Material Engineering, MCM 2019; Lisbon; Portugal; 15 August 2019 through 17 August 2019; Code 141318. 2019;:125.
doi:10.11159/iccpe19.125 .
Suručić, Ljiljana, Nastasović, Aleksandra, Rakić, Aleksandra A., Onjia, Antonije E., Popović, Aleksandar R., Janjić, Goran V., "Comparative study of W(VI) and Cr(VI) oxyanions binding ability with magnetic polymer nanocomposite" in 5th World Congress on Mechanical, Chemical, and Material Engineering, MCM 2019; Lisbon; Portugal; 15 August 2019 through 17 August 2019; Code 141318 (2019):125,
https://doi.org/10.11159/iccpe19.125 . .

Pollution and health risk assessments of potentially toxic elements in soil and sediment samples in a petrochemical industry and surrounding area

Relić, Dubravka; Sakan, Sanja M.; Anđelković, Ivan; Popović, Aleksandar R.; Đorđević, Dragana S.

(MDPI, 2019)

TY  - JOUR
AU  - Relić, Dubravka
AU  - Sakan, Sanja M.
AU  - Anđelković, Ivan
AU  - Popović, Aleksandar R.
AU  - Đorđević, Dragana S.
PY  - 2019
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3146
AB  - The pollution state and health risk assessment of potentially toxic elements (PTE) in soil and sediment samples of the petrochemical industry and its surrounding area are evaluated in this study. The pseudo-total contents of Ba, Cd, Co, Cu, Cr, Mn, Ni, Pb, V, Zn, As, Hg, and Se were measured by inductively coupled plasma–optical emission spectrometry (ICP/OES) in analyzed samples. Instead of determining total content, we performed aqua regia of the samples. The silicate matrix remained, and the quantities of elements that are within the silicate matrix do not represent an environmental danger. The soils from the chlor–alkali plant are highly polluted by Hg (the enrichment factor values were above 6000), and by Cu, Cd, Pb, and Zn, while the sediment samples from the wastewater channel are polluted with Cr, Cd, and Hg. The measured element contents are used for calculating health risk criteria for a composite worker (a worker who is exposed, long-term, during the work day) and for residential people. Hg is the element that mainly contributes to non-carcinogenic risks within the petrochemical area. The highest value of total carcinogenic risk obtained in the sediment sample from the wastewater channel, and the metal that mostly contributes is Cr. The areas closest to the petrochemical industry have higher values of health risk criteria parameters and pollution indices. The areas that are located further to the north and south from the petrochemical industry are less burdened with the analyzed elements, which is significant because the closest city and village are situated in those directions.
PB  - MDPI
T2  - Molecules
T1  - Pollution and health risk assessments of potentially toxic elements in soil and sediment samples in a petrochemical industry and surrounding area
VL  - 24
IS  - 11
SP  - 1
EP  - 19
DO  - 10.3390/molecules24112139
ER  - 
@article{
author = "Relić, Dubravka and Sakan, Sanja M. and Anđelković, Ivan and Popović, Aleksandar R. and Đorđević, Dragana S.",
year = "2019",
abstract = "The pollution state and health risk assessment of potentially toxic elements (PTE) in soil and sediment samples of the petrochemical industry and its surrounding area are evaluated in this study. The pseudo-total contents of Ba, Cd, Co, Cu, Cr, Mn, Ni, Pb, V, Zn, As, Hg, and Se were measured by inductively coupled plasma–optical emission spectrometry (ICP/OES) in analyzed samples. Instead of determining total content, we performed aqua regia of the samples. The silicate matrix remained, and the quantities of elements that are within the silicate matrix do not represent an environmental danger. The soils from the chlor–alkali plant are highly polluted by Hg (the enrichment factor values were above 6000), and by Cu, Cd, Pb, and Zn, while the sediment samples from the wastewater channel are polluted with Cr, Cd, and Hg. The measured element contents are used for calculating health risk criteria for a composite worker (a worker who is exposed, long-term, during the work day) and for residential people. Hg is the element that mainly contributes to non-carcinogenic risks within the petrochemical area. The highest value of total carcinogenic risk obtained in the sediment sample from the wastewater channel, and the metal that mostly contributes is Cr. The areas closest to the petrochemical industry have higher values of health risk criteria parameters and pollution indices. The areas that are located further to the north and south from the petrochemical industry are less burdened with the analyzed elements, which is significant because the closest city and village are situated in those directions.",
publisher = "MDPI",
journal = "Molecules",
title = "Pollution and health risk assessments of potentially toxic elements in soil and sediment samples in a petrochemical industry and surrounding area",
volume = "24",
number = "11",
pages = "1-19",
doi = "10.3390/molecules24112139"
}
Relić, D., Sakan, S. M., Anđelković, I., Popović, A. R.,& Đorđević, D. S.. (2019). Pollution and health risk assessments of potentially toxic elements in soil and sediment samples in a petrochemical industry and surrounding area. in Molecules
MDPI., 24(11), 1-19.
https://doi.org/10.3390/molecules24112139
Relić D, Sakan SM, Anđelković I, Popović AR, Đorđević DS. Pollution and health risk assessments of potentially toxic elements in soil and sediment samples in a petrochemical industry and surrounding area. in Molecules. 2019;24(11):1-19.
doi:10.3390/molecules24112139 .
Relić, Dubravka, Sakan, Sanja M., Anđelković, Ivan, Popović, Aleksandar R., Đorđević, Dragana S., "Pollution and health risk assessments of potentially toxic elements in soil and sediment samples in a petrochemical industry and surrounding area" in Molecules, 24, no. 11 (2019):1-19,
https://doi.org/10.3390/molecules24112139 . .
1
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Supplementary data for article: Relić, D.; Sakan, S.; Anđelković, I.; Popović, A.; Đorđević, D. Pollution and Health Risk Assessments of Potentially Toxic Elements in Soil and Sediment Samples in a Petrochemical Industry and Surrounding Area. Molecules 2019, 24 (11). https://doi.org/10.3390/molecules24112139

Relić, Dubravka; Sakan, Sanja M.; Anđelković, Ivan; Popović, Aleksandar R.; Đorđević, Dragana S.

(MDPI, 2019)

TY  - DATA
AU  - Relić, Dubravka
AU  - Sakan, Sanja M.
AU  - Anđelković, Ivan
AU  - Popović, Aleksandar R.
AU  - Đorđević, Dragana S.
PY  - 2019
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3147
PB  - MDPI
T2  - Molecules
T1  - Supplementary data for article: Relić, D.; Sakan, S.; Anđelković, I.; Popović, A.; Đorđević, D. Pollution and Health Risk Assessments of Potentially Toxic Elements in Soil and Sediment Samples in a Petrochemical Industry and Surrounding Area. Molecules 2019, 24 (11). https://doi.org/10.3390/molecules24112139
UR  - https://hdl.handle.net/21.15107/rcub_cherry_3147
ER  - 
@misc{
author = "Relić, Dubravka and Sakan, Sanja M. and Anđelković, Ivan and Popović, Aleksandar R. and Đorđević, Dragana S.",
year = "2019",
publisher = "MDPI",
journal = "Molecules",
title = "Supplementary data for article: Relić, D.; Sakan, S.; Anđelković, I.; Popović, A.; Đorđević, D. Pollution and Health Risk Assessments of Potentially Toxic Elements in Soil and Sediment Samples in a Petrochemical Industry and Surrounding Area. Molecules 2019, 24 (11). https://doi.org/10.3390/molecules24112139",
url = "https://hdl.handle.net/21.15107/rcub_cherry_3147"
}
Relić, D., Sakan, S. M., Anđelković, I., Popović, A. R.,& Đorđević, D. S.. (2019). Supplementary data for article: Relić, D.; Sakan, S.; Anđelković, I.; Popović, A.; Đorđević, D. Pollution and Health Risk Assessments of Potentially Toxic Elements in Soil and Sediment Samples in a Petrochemical Industry and Surrounding Area. Molecules 2019, 24 (11). https://doi.org/10.3390/molecules24112139. in Molecules
MDPI..
https://hdl.handle.net/21.15107/rcub_cherry_3147
Relić D, Sakan SM, Anđelković I, Popović AR, Đorđević DS. Supplementary data for article: Relić, D.; Sakan, S.; Anđelković, I.; Popović, A.; Đorđević, D. Pollution and Health Risk Assessments of Potentially Toxic Elements in Soil and Sediment Samples in a Petrochemical Industry and Surrounding Area. Molecules 2019, 24 (11). https://doi.org/10.3390/molecules24112139. in Molecules. 2019;.
https://hdl.handle.net/21.15107/rcub_cherry_3147 .
Relić, Dubravka, Sakan, Sanja M., Anđelković, Ivan, Popović, Aleksandar R., Đorđević, Dragana S., "Supplementary data for article: Relić, D.; Sakan, S.; Anđelković, I.; Popović, A.; Đorđević, D. Pollution and Health Risk Assessments of Potentially Toxic Elements in Soil and Sediment Samples in a Petrochemical Industry and Surrounding Area. Molecules 2019, 24 (11). https://doi.org/10.3390/molecules24112139" in Molecules (2019),
https://hdl.handle.net/21.15107/rcub_cherry_3147 .

Geochemical fractionation and assessment of probabilistic ecological risk of potential toxic elements in sediments using Monte Carlo simulations

Sakan, Sanja M.; Sakan, Nenad; Popović, Aleksandar R.; Škrivanj, Sandra B.; Đorđević, Dragana S.

(MDPI, 2019)

TY  - JOUR
AU  - Sakan, Sanja M.
AU  - Sakan, Nenad
AU  - Popović, Aleksandar R.
AU  - Škrivanj, Sandra B.
AU  - Đorđević, Dragana S.
PY  - 2019
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3707
AB  - The need for further research into potentially toxic elements in Serbian rivers led to an investigation of distributions, sources, and ecological risks in a sample base of sediments from 15 rivers. The analyses were carried out through both experimental and theoretical methods. Geochemical fractionation of Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb, As, V, and Zn in sediments was studied using a sequential extraction procedure. Both a Håkanson risk index (RI) and a Monte Carlo simulation (MCS) were used in order to estimate ecological risk, applying the probability distribution of RI values instead of single-point calculations. In order to both further the development of the used method and include additional processes, software for the simulations was developed instead of using proprietary solutions. Metal fractionation showed high percentage recoveries of Cd, Cr, Co, Cu, Fe, Ni, and V in residual fractions. The high content of Pb, Mn, and Zn in mobile fractions might cause serious environmental concerns. In some localities, Cu and Cd could be problematic elements, since their mobility was high. An environmental assessment based on the described criteria provided risk levels varying from low to median (mainly contributed by Cd and Cu).
PB  - MDPI
T2  - Molecules
T1  - Geochemical fractionation and assessment of probabilistic ecological risk of potential toxic elements in sediments using Monte Carlo simulations
VL  - 24
IS  - 11
DO  - 10.3390/molecules24112145
ER  - 
@article{
author = "Sakan, Sanja M. and Sakan, Nenad and Popović, Aleksandar R. and Škrivanj, Sandra B. and Đorđević, Dragana S.",
year = "2019",
abstract = "The need for further research into potentially toxic elements in Serbian rivers led to an investigation of distributions, sources, and ecological risks in a sample base of sediments from 15 rivers. The analyses were carried out through both experimental and theoretical methods. Geochemical fractionation of Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb, As, V, and Zn in sediments was studied using a sequential extraction procedure. Both a Håkanson risk index (RI) and a Monte Carlo simulation (MCS) were used in order to estimate ecological risk, applying the probability distribution of RI values instead of single-point calculations. In order to both further the development of the used method and include additional processes, software for the simulations was developed instead of using proprietary solutions. Metal fractionation showed high percentage recoveries of Cd, Cr, Co, Cu, Fe, Ni, and V in residual fractions. The high content of Pb, Mn, and Zn in mobile fractions might cause serious environmental concerns. In some localities, Cu and Cd could be problematic elements, since their mobility was high. An environmental assessment based on the described criteria provided risk levels varying from low to median (mainly contributed by Cd and Cu).",
publisher = "MDPI",
journal = "Molecules",
title = "Geochemical fractionation and assessment of probabilistic ecological risk of potential toxic elements in sediments using Monte Carlo simulations",
volume = "24",
number = "11",
doi = "10.3390/molecules24112145"
}
Sakan, S. M., Sakan, N., Popović, A. R., Škrivanj, S. B.,& Đorđević, D. S.. (2019). Geochemical fractionation and assessment of probabilistic ecological risk of potential toxic elements in sediments using Monte Carlo simulations. in Molecules
MDPI., 24(11).
https://doi.org/10.3390/molecules24112145
Sakan SM, Sakan N, Popović AR, Škrivanj SB, Đorđević DS. Geochemical fractionation and assessment of probabilistic ecological risk of potential toxic elements in sediments using Monte Carlo simulations. in Molecules. 2019;24(11).
doi:10.3390/molecules24112145 .
Sakan, Sanja M., Sakan, Nenad, Popović, Aleksandar R., Škrivanj, Sandra B., Đorđević, Dragana S., "Geochemical fractionation and assessment of probabilistic ecological risk of potential toxic elements in sediments using Monte Carlo simulations" in Molecules, 24, no. 11 (2019),
https://doi.org/10.3390/molecules24112145 . .
3
2
3

Changes of ba contents in sediments of Kupa river (Croatia) 15 years after discovery of ba anomaly complemented by sequential extraction

Frančišković-Bilinski, Stanislav; Bilinski, Halka; Sakan, Sanja M.; Đorđević, Dragana S.; Popović, Aleksandar R.

(International Multidisciplinary Scientific Geoconference, 2019)

TY  - CONF
AU  - Frančišković-Bilinski, Stanislav
AU  - Bilinski, Halka
AU  - Sakan, Sanja M.
AU  - Đorđević, Dragana S.
AU  - Popović, Aleksandar R.
PY  - 2019
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3723
AB  - The Kupa River, located in the west-central part of Croatia, is a 294 km long tributary of the Sava River, belonging to the Danube watershed. An extreme barium anomaly in sediments of Kupica and Kupa rivers was discovered during 2003 by Frančišković-Bilinski. It originates from an abundant barite mine in Homer-Lokve area, from where it penetrated to Kupica River source. From there the Ba-anomaly in sediments was followed more than 120 km downstream along both rivers. This discovery has a big potential to be used in future sediment transport studies in rivers. Therefore, we repeated sampling on most important locations in 2018, exactly 15 years since the anomaly discovery. The sequential extraction procedure of the EC Bureau of Reference was applied to investigate the transport and fractionation of Ba. During mentioned period of 15 years following processes related with Ba-distribution were observed in fraction <63 µm: Ba-concentrations decreased more than 10 times in Kupica River, from 5790 to 385 mg/kg at Brod na Kupi and 473 mg/kg at Iševnica near the Kupica source. Also, at the first location in Kupa River after confluence with Kupica Ba-concentration decreased from 1070 to 429 mg/kg. This significant decrease is a consequence of abandoning of barite mine in 1994, after which self-purification process of Kupica and Kupa river sediments gradually started. Large quantities of Ba gradually shifted more downstream and in the middle course of the river Ba-deposition in sediments is still going on. At location Jurovo in the middle course of the river concentrations remained about the same in both years, while in Ozalj several km downstream concentration moderately decreased from 341 to 241 mg/kg. Very important finding is that Ba-anomaly in the time frame of 15 years arrived at least 50 km more downstream. Namely, in 2003 at location Pokupsko in the lower course of Kupa River, Ba-concentration was only 78.4 mg/kg, what is about the background level for this region. In 2018 Ba-concentrations significantly increased to 209 mg/kg. At the far end of the river course in Sisak, Ba-anomaly has not yet been observed - concentrations of Ba remained almost the same (65 mg/kg in 2003 and 63.8 mg/kg in 2018). From analysis of coarser sediment fraction 63-2000 µm can be concluded that barium is bound with fine particles. Results of sequential analysis showed that Ba was extracted in the following order for < 63 µm sediment fraction: reducible > residual > soluble in acid > oxidizable, while for 63-2000 µm sediment fraction: reducible > soluble in acid > residual > oxidizable. The highest Ba-content was found in reducible fraction, what indicated that Fe and Mn minerals acted as natural accumulators for Ba in investigated sediments. This association indicated that Ba was potentially extractable. It could have been mobilized from the sediment into the aquatic environment due to decomposition of Fe and Mn oxides under slightly reducing conditions.
PB  - International Multidisciplinary Scientific Geoconference
C3  - 19th International Multidisciplinary Scientific Geoconference, SGEM 2019; Albena; Bulgaria; 30 June 2019 through 6 July 2019
T1  - Changes of ba contents in sediments of Kupa river (Croatia) 15 years after discovery of ba anomaly complemented by sequential extraction
VL  - 19
SP  - 73
EP  - 80
DO  - 10.5593/sgem2019/3.1/S12.010
ER  - 
@conference{
author = "Frančišković-Bilinski, Stanislav and Bilinski, Halka and Sakan, Sanja M. and Đorđević, Dragana S. and Popović, Aleksandar R.",
year = "2019",
abstract = "The Kupa River, located in the west-central part of Croatia, is a 294 km long tributary of the Sava River, belonging to the Danube watershed. An extreme barium anomaly in sediments of Kupica and Kupa rivers was discovered during 2003 by Frančišković-Bilinski. It originates from an abundant barite mine in Homer-Lokve area, from where it penetrated to Kupica River source. From there the Ba-anomaly in sediments was followed more than 120 km downstream along both rivers. This discovery has a big potential to be used in future sediment transport studies in rivers. Therefore, we repeated sampling on most important locations in 2018, exactly 15 years since the anomaly discovery. The sequential extraction procedure of the EC Bureau of Reference was applied to investigate the transport and fractionation of Ba. During mentioned period of 15 years following processes related with Ba-distribution were observed in fraction <63 µm: Ba-concentrations decreased more than 10 times in Kupica River, from 5790 to 385 mg/kg at Brod na Kupi and 473 mg/kg at Iševnica near the Kupica source. Also, at the first location in Kupa River after confluence with Kupica Ba-concentration decreased from 1070 to 429 mg/kg. This significant decrease is a consequence of abandoning of barite mine in 1994, after which self-purification process of Kupica and Kupa river sediments gradually started. Large quantities of Ba gradually shifted more downstream and in the middle course of the river Ba-deposition in sediments is still going on. At location Jurovo in the middle course of the river concentrations remained about the same in both years, while in Ozalj several km downstream concentration moderately decreased from 341 to 241 mg/kg. Very important finding is that Ba-anomaly in the time frame of 15 years arrived at least 50 km more downstream. Namely, in 2003 at location Pokupsko in the lower course of Kupa River, Ba-concentration was only 78.4 mg/kg, what is about the background level for this region. In 2018 Ba-concentrations significantly increased to 209 mg/kg. At the far end of the river course in Sisak, Ba-anomaly has not yet been observed - concentrations of Ba remained almost the same (65 mg/kg in 2003 and 63.8 mg/kg in 2018). From analysis of coarser sediment fraction 63-2000 µm can be concluded that barium is bound with fine particles. Results of sequential analysis showed that Ba was extracted in the following order for < 63 µm sediment fraction: reducible > residual > soluble in acid > oxidizable, while for 63-2000 µm sediment fraction: reducible > soluble in acid > residual > oxidizable. The highest Ba-content was found in reducible fraction, what indicated that Fe and Mn minerals acted as natural accumulators for Ba in investigated sediments. This association indicated that Ba was potentially extractable. It could have been mobilized from the sediment into the aquatic environment due to decomposition of Fe and Mn oxides under slightly reducing conditions.",
publisher = "International Multidisciplinary Scientific Geoconference",
journal = "19th International Multidisciplinary Scientific Geoconference, SGEM 2019; Albena; Bulgaria; 30 June 2019 through 6 July 2019",
title = "Changes of ba contents in sediments of Kupa river (Croatia) 15 years after discovery of ba anomaly complemented by sequential extraction",
volume = "19",
pages = "73-80",
doi = "10.5593/sgem2019/3.1/S12.010"
}
Frančišković-Bilinski, S., Bilinski, H., Sakan, S. M., Đorđević, D. S.,& Popović, A. R.. (2019). Changes of ba contents in sediments of Kupa river (Croatia) 15 years after discovery of ba anomaly complemented by sequential extraction. in 19th International Multidisciplinary Scientific Geoconference, SGEM 2019; Albena; Bulgaria; 30 June 2019 through 6 July 2019
International Multidisciplinary Scientific Geoconference., 19, 73-80.
https://doi.org/10.5593/sgem2019/3.1/S12.010
Frančišković-Bilinski S, Bilinski H, Sakan SM, Đorđević DS, Popović AR. Changes of ba contents in sediments of Kupa river (Croatia) 15 years after discovery of ba anomaly complemented by sequential extraction. in 19th International Multidisciplinary Scientific Geoconference, SGEM 2019; Albena; Bulgaria; 30 June 2019 through 6 July 2019. 2019;19:73-80.
doi:10.5593/sgem2019/3.1/S12.010 .
Frančišković-Bilinski, Stanislav, Bilinski, Halka, Sakan, Sanja M., Đorđević, Dragana S., Popović, Aleksandar R., "Changes of ba contents in sediments of Kupa river (Croatia) 15 years after discovery of ba anomaly complemented by sequential extraction" in 19th International Multidisciplinary Scientific Geoconference, SGEM 2019; Albena; Bulgaria; 30 June 2019 through 6 July 2019, 19 (2019):73-80,
https://doi.org/10.5593/sgem2019/3.1/S12.010 . .

Introducing of modeling techniques in the research of POPs in breast milk – A pilot study

Jovanović, Gordana; Herceg Romanić, Snježana; Stojić, Andreja; Klinčić, Darija; Matek Sarić, Marijana; Grzunov Letinić, Judita; Popović, Aleksandar R.

(Elsevier, 2019)

TY  - JOUR
AU  - Jovanović, Gordana
AU  - Herceg Romanić, Snježana
AU  - Stojić, Andreja
AU  - Klinčić, Darija
AU  - Matek Sarić, Marijana
AU  - Grzunov Letinić, Judita
AU  - Popović, Aleksandar R.
PY  - 2019
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/2836
AB  - This study used advanced statistical and machine learning methods to investigate organochlorine pesticides (OCPs) and polychlorinated biphenyls (PCBs) in breast milk, assuming that in a complex biological mixture, the pollutants emitted from the same source or with similar properties are statistically interrelated and possibly exhibit non-linear dynamics. The elaborated analyses such as Unmix source apportionment characterized individual source groups, while guided regularized random forest indicated the pollutant dependence on the ortho-chlorine atom attached to the congener's phenyl ring and mother's age. Mutual associations among PCBs were further discussed, but the results implied they were mostly not related to child delivery. PCB congeners −153, −180, −170, −118, −156, −105, and −138 appeared to be compounds of the outmost importance for mutual prediction with reference to their interrelations regarding chemical structure and metabolic processes in the mother's body. Finally, machine learning methods, which provided prediction relative errors lower than 30% and correlation coefficients higher than 0.90, suggested a possible strong non-linear relationship among the pollutants and consequently, the complexity of their pathways in the breast milk.
PB  - Elsevier
T2  - Ecotoxicology and Environmental Safety
T1  - Introducing of modeling techniques in the research of POPs in breast milk – A pilot study
VL  - 172
SP  - 341
EP  - 347
DO  - 10.1016/j.ecoenv.2019.01.087
ER  - 
@article{
author = "Jovanović, Gordana and Herceg Romanić, Snježana and Stojić, Andreja and Klinčić, Darija and Matek Sarić, Marijana and Grzunov Letinić, Judita and Popović, Aleksandar R.",
year = "2019",
abstract = "This study used advanced statistical and machine learning methods to investigate organochlorine pesticides (OCPs) and polychlorinated biphenyls (PCBs) in breast milk, assuming that in a complex biological mixture, the pollutants emitted from the same source or with similar properties are statistically interrelated and possibly exhibit non-linear dynamics. The elaborated analyses such as Unmix source apportionment characterized individual source groups, while guided regularized random forest indicated the pollutant dependence on the ortho-chlorine atom attached to the congener's phenyl ring and mother's age. Mutual associations among PCBs were further discussed, but the results implied they were mostly not related to child delivery. PCB congeners −153, −180, −170, −118, −156, −105, and −138 appeared to be compounds of the outmost importance for mutual prediction with reference to their interrelations regarding chemical structure and metabolic processes in the mother's body. Finally, machine learning methods, which provided prediction relative errors lower than 30% and correlation coefficients higher than 0.90, suggested a possible strong non-linear relationship among the pollutants and consequently, the complexity of their pathways in the breast milk.",
publisher = "Elsevier",
journal = "Ecotoxicology and Environmental Safety",
title = "Introducing of modeling techniques in the research of POPs in breast milk – A pilot study",
volume = "172",
pages = "341-347",
doi = "10.1016/j.ecoenv.2019.01.087"
}
Jovanović, G., Herceg Romanić, S., Stojić, A., Klinčić, D., Matek Sarić, M., Grzunov Letinić, J.,& Popović, A. R.. (2019). Introducing of modeling techniques in the research of POPs in breast milk – A pilot study. in Ecotoxicology and Environmental Safety
Elsevier., 172, 341-347.
https://doi.org/10.1016/j.ecoenv.2019.01.087
Jovanović G, Herceg Romanić S, Stojić A, Klinčić D, Matek Sarić M, Grzunov Letinić J, Popović AR. Introducing of modeling techniques in the research of POPs in breast milk – A pilot study. in Ecotoxicology and Environmental Safety. 2019;172:341-347.
doi:10.1016/j.ecoenv.2019.01.087 .
Jovanović, Gordana, Herceg Romanić, Snježana, Stojić, Andreja, Klinčić, Darija, Matek Sarić, Marijana, Grzunov Letinić, Judita, Popović, Aleksandar R., "Introducing of modeling techniques in the research of POPs in breast milk – A pilot study" in Ecotoxicology and Environmental Safety, 172 (2019):341-347,
https://doi.org/10.1016/j.ecoenv.2019.01.087 . .
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